When Design Defines a City

Both Spain and China’s practices in urban design show how urban governance,local social development,and people’s needs shape a city’s landscape.IN the 20th century,China and Spain faced the common challenge of urban transition.In China,it began with the urbanization and revitalization process with the inception of the reform and opening-up in 1978,and in Spain.

Collaborative Effect of Fines on Changes in Grain Distribution in the Process of Improving the Geotechnical Properties of an Alluvial Gravel 0/14

The technical and economic optimization of road projects has led to research into the use of materials obtained by mechanical stabilization for pavement construction. This research has enabled us to outline a solution capable of giving the sub-base layer the necessary and sufficient capacity to support the induced loads forecast for the traffic. This work evaluates the effect of adding fine silty clay (Cl) and clayey silt (Csp), two corrective materials to alluvial gravel (0/14), the main material, in the process of improving its cohesion and geotechnical properties. The results obtained show that the optimum mix is obtained with 10% by weight of Cl and 15% Csp. The granulometry of the mixes is spread out, but poorly calibrated. The Ag-Cl mixtures made at 10%, 15%, 20%, 25% 30% and Ag-Csp at 15%, 20%, 25%, 30%, and 35%, do not obey the law of mixtures. Mixing with 10% Cl reduces the sand equivalent of alluvial gravel by 60.23%, while mixing with 15% Cl reduces the sand equivalent by 6.82%. The addition of correctors increases the optimum water content and fine sand content of the mixes. Increasing the fine sand content reduces the optimum dry density, CBR index and static modulus. Mixes containing 10% Cl and 15% Csp have CBR values of CBRCl (96%) and CBRCsp (84%) and are not suitable for pavement base layers. In fact, the hardness of the grains has a Los Anges value of 41%, higher than the maximum permitted by the standard of 35%. The mixes obtained can be used as pavement base layers for traffic levels in a cumulative number of heavy goods vehicles 5 × 105 6 for an approximate life of 15 years.

The Effect of Mineral Composition and Quantity of Fines on the Atterberg Limits and Compaction Characteristics of Soils

Because of the various elements that come into play in natural soil formation, the impact of varied proportions of mineral composition and fines amount on Atterberg limits and compaction characteristics of soils is not well known. Three distinct soil samples were used in this investigation. The findings indicated the effect of varied mineral composition proportions and fines amount on the liquid limit, plastic limit, and plasticity index as assessed by the Casagrande test and hand-rolling method. The fluctuation of maximum dry density and optimal moisture content with these three soils has also been studied. Furthermore, correlations were established to indicate the compaction parameters and the amount of minerals and particles in the soil. The data show that the mineral content of the soil has a direct impact on the Atterberg limits and compaction characteristics. Soils containing larger percentages of expansive minerals, such as montmorillonite, have more flexibility and volume change capability. Mineral composition influences compaction parameters such as maximum dry density, ideal water content, axial strain, and axial stress. Soils with a larger proportion of fines, such as Soil 2 and Soil 3, have stronger flexibility and lower compaction qualities, with higher ideal water content and lower maximum dry density. Soil 1 has moderate flexibility and intermediate compaction qualities due to its low fines percentage. The effect of different mineral compositions and fines on the Atterberg limits and compaction characteristics of soils can be used to predict the behavior of compacted soils encountered in engineering practices, reducing the time and effort required to assess soil suitability for engineering use.

Evaluation of VSK separation in the classification of two mineralogically different iron ore fines

With gradually diminishing Fe grade in tandem with the ever-increasing demand for high-grade iron ores,iron ore industries are now focusing on the beneficiation of low-grade iron ore fines,mainly considered waste.Besides,the scarcity of water at many of the mines’sites and the new water conservation policies of the governments have necessitated research on suitable dry beneficiation routes.In this context,an effort has been made to evaluate the efficacy of a dry classification unit,such as the VSK separator,in upgrading the iron values of two low-grade Indian iron ore fines,named Sample 1 and Sample 2.The mineralogical studies,involving scanning electron microscopy and X-ray diffraction,suggest that Sample 1 is a low-grade blue dust sample(51.2wt%Fe)containing hematite and quartz as the major minerals,while Sample 2(53.3wt%Fe)shows the presence of goethite in addition to hematite and quartz.The experiments,carried out using Box-Benkhen statistical design,indicate that blower speed,followed by feed rate,is the most influencing operating parameter in obtaining a good product in the VSK separator.At optimum levels of the operating factors,a fines product with~55wt%Fe at a yield of~40%can be obtained from Sample 1,while Sample 2 can be upgraded to~56wt%Fe at a yield of~85%.The results suggest that the VSK separator can be employed as an efficient intermediate unit operation in a processing circuit to upgrade the iron contents of iron ore fines.

Floc flotation of marmatite fines in aqueous suspensions induced by butyl xanthate and ammonium dibutyl dithiophosphate

The hydrophobic flocculation of marmatite fines in aqueous suspensions induced by butyl xanthate （KBX） and ammonium dibutyl dithiophosphate （ADD） was investigated using laser particle size analysis, microscopy analysis, electrophoretic light scattering, contact angle measurement and infrared spectroscopy. The studies were performed on single minerals with size 〈20 μm by varying several parameters, including pH, collector concentration and kerosene addition. The results show that the floc fotation closely correlated with the size of flocs and the particle hydrophobicity, but was not lowered with increasing the particle surface charges due to collector adsorption. Under good operating conditions, the floc flotation of marmatite fines as a function of KBX and ADD can all reach floatability over 90%, in comparison with conventional flotation obtaining floatability of about 60%. It also has been found that a small addition of kerosene greatly improved the floc flotation because of the formation of oil films on marmatite particles. The results of FTIR spectra indicate that adsorption of the two collectors onto marmatite were chemical adsorption.

Hydrophobic flocculation flotation of rutile fines in presence of styryl phosphonic acid

The hydrophobic flocculation flotation of rutile fines in the presence of styryl phosphonic acid（SPA） was investigated by flotation tests, zeta-potential measurement, optical microscope observation, laser-based particle size analysis, adsorption measurements and DLVO theory. The flotation tests indicated that rutile fines could be flocculated by SPA, and pH, shear force（stirring speed） and stirring time played significant roles in flocculation. The isoelectric point（IEP） and zeta-potential in whole range all moved to negative values as SPA was added according to the results from zeta-potential measurement. It was demonstrated that the primary reason for above was chemical adsorption. The laser-based particle size results showed the particle size at a stirring speed of 1800 r/min and 1000 mg/L SPA was the largest in all experiments. Furthermore, using the optical microscope observation and flotation tests, it was important for flotation of rutile fines to produce the flocculant. In the light of above-mentioned facts, floc flotation of rutile fines could be induced in the form of chemical adsorption by SPA to increase particle size. The data calculated from DLVO theory also indicated that chemical adsorption was the main reason for the formation of flocculant.

New Progress on the Coal Fines Affecting the Development of Coalbed Methane

Objective The production of coal fines is very common in the development of coalbed methane（CBM）in the eastern margin of the Ordos Basin,China.A large amount of produced coal fines seriously affect the productivity of CBM wells（Wei Yingchun et al.,2013）.Therefore,the production problems of CBM wells caused by coal fines have attracted extensive attention.

Carburization of ferrochromium metals in chromium ore fines containing coal during voluminal reduction by microwave heating

Chromium ore fines containing coal (COFCC) can be rapidly heated by microwave to conduct the voluminal reduction, which lays a foundation of getting sponge ferrochromium powders with a lower content of C. Under the conditions of COFCC with n(O)-n(C) (molar ratio) as 1.00-0.84 and n(SiO2)-n(CaO) as 1.00-0.39, the samples were heated by 10 kW microwave power to reach the given temperatures and held for different times respectively. The results show that the low-C-Cr ferrochromium metal phase in the reduced materials forms before the high-C-Cr ferrochromium metal phase does. With increasing temperature the C content of ferrochromium metals is in a positive correlation with the content of Cr. The C content of ferrochromium metal in reduced materials is 0-10.07% with an average value of 4.68%. With the increase of holding time the Cr content in ferrochromium metals is in a negative correlation with the content of C, while the content of Fe changes in the contrary way. In the microwave field the kinetic conditions of carburization are closely related with the temperature of microwave heating, holding time and carbon fitting ratio.

Comparison of selective flocculation of low grade goethitic iron ore fines using natural and synthetic polymers and a graft copolymer

This study aims to beneficiate low grade goethitic iron ore fines using a selective flocculation process. Selective flocculation studies were conducted using different polymers such as starch amylopectin(AP), poly acrylic acid(PAA), and a graft copolymer(AP-g-PAA). The obtained results were analyzed; they indicate the enhancement of the iron ore grade from 58.49% to 67.52% using AP-g-PAA with a recovery of 95.08%. In addition, 64.45% Fe with a recovery of 88.79% was obtained using AP. Similarly, using PAA, the grade increased to 63.46% Fe with a recovery of 82.10%. The findings are also supported by characterizing concentrates using X-ray diffraction(XRD) and electron probe microanalysis(EPMA) techniques.

Strengthening pelletization of manganese ore fines containing high combined water by high pressure roll grinding and optimized temperature elevation system

Pelletization is one of useful processes for the agglomeration of iron ore or concentrates. However, manganese ore fines are mainly agglomerated by sintering due to its high combined water which adversely affects the roasting performance of pellets. In this work, high pressure roll grinding(HPRG) process and optimization of temperature elevation system were investigated to improve the strength of fired manganese ore pellets. It is shown that the manganese ore possesses good ballability after being pretreated by HPRG twice, and good green balls were produced under the conditions of blending 2.0% bentonite in the feed, balling for 7 min at 16.00% moisture. High quality roasted pellets with the compressive strength of 2711 N per pellet were manufactured through preheating at 1050 °C for 10 min and firing at 1335 °C for 15 min by controlling the cracks formation. The fired manganese pellets keep the strength by the solid interconnection of recrystallized pyrolusite grains and the binding of manganite liquid phase which filled the pores and clearance among minerals. The product pellets contain high Mn grade and low impurities, and can be used to smelt ferromanganese, which provides a possible way to use imported manganese ore fines containing high combined water to produce high value ferromanganese.

Particle size distribution and property of bacteria attached to carbon fines in drinking water treatment

The quantitative change and size distribution of particles in the effluents from a sand filter and a granular activated carbon （GAC） filter in a drinking water treatment plant were investigated. The average total concentration of particles in the sand filter effluent during a filter cycle was 148 particles/mL, 27 of which were larger than 2 μm in size. The concentration in the GAC effluent （561 particles/mL） was significantly greater than that in the sand filter effluent. The concentration of particles larger than 2 μm in the GAC filter effluent reached 201 particles/mL, with the amount of particles with sizes between 2 μm and 15 μm increasing. The most probable number （MPN） of carbon fines reached 43 unit/L after six hours and fines between 0.45 μm and 8.0 μm accounted for more than 50%. The total concentration of outflowing bacteria in the GAC filter effluent, 350 CFU （colony-forming units） /mL, was greater than that in the sand filter effluent, 210 CFU/mL. The desorbed bacteria concentration reached an average of 310 CFU/mg fines. The disinfection efficiency of desorbed bacteria was lower than 40% with 1.5 mg/L of chlorine. The disinfection effect showed that the inactivation rate with 2.0 mg/L of chloramine （90%） was higher than that with chlorine （70%）. Experimental results indicated that the high particle concentration in raw water and sedimentation effluent led to high levels of outflowing particles in the sand filter effluent. The activated carbon fines in the effluent accounted for a small proportion of the total particle amount, but the existing bacteria attached to carbon fines may influence the drinking water safety. The disinfection efficiency of desorbed bacteria was lower than that of free bacteria with chlorine, and the disinfection effect on bacteria attached to carbon fines with chloramine was better than that with only chlorine.

Flotation mechanisms of molybdenite fines by neutral oils

The flotation mechanisms of molybdenite fines by neutral oils were investigated through microflotation test, turbidity measure- ments, infrared spectroscopy, and interracial interaction calculations. The results of the flotation test show that at pH 2-11, the floatability of molybdenite fines in the presence of transformer oil is markedly better than that in the presence of kerosene and diesel oil. The addition of transformer oil, which enhances the floatability of molybdenite fines, promotes the aggregation of molybdenite particles. Fourier transform infrared measurements illustrate that physical interaction dominates the adsorption mechanism of neutral oil on molybdenite. Interracial inte- raction calculations indicate that hydrophobic attraction is the crucial force that acts among the oil collector, water, and molybdenite. Strong hydrophobic attraction between the oily collector and water provides the strong dispersion capability of the collector in water. Furthermore, the dispersion capability of the collector, not the interaction strength role in the flotation system of molybdenite fines. Our findings provide between the oily collectors and molybdenite, has a highly significant insights into the mechanism ofmolybdenite flotation.

An effective approach for improving flotation recovery of molybdenite fines from a finely-disseminated molybdenum ore

An effective flotation approach is proposed for improving the recovery of molybdenite fines from a finely-disseminated molybdenum ore. To maximize the flotation recovery of molybdenum, process mineralogy of raw ore, contrast tests, optimization of operation conditions and particle size analysis were systematically investigated. Process mineralogy suggests that in the raw ore, 61.63% of molybdenite particles distribute in the 〈20 pm size fraction, and intergrow with muscovite and pyrite as the contained and disseminated type. Contrast tests indicate that conventional flotation responds to poor collection efficiency for particles less than 25 pm. Oil agglomerate flotation （OAF） process demonstrates an obvious superiority in improving the flotation recovery of molybdenite fines. Furthermore, the flotation results of OAF process reveal that the dosage of transformer oil plays a critical role on the average size of collected mineral particles （d（0）, agglomerates （d^0） and the molybdenum recovery. In addition, industrial tests illustrate that compared with the Mo-S bulk flotation approach, OAF process not only increases Mo recovery and grade of molybdenum concentrate by 22.75% and 17.47% respectively, but also achieves a sulfur concentrate with a superior grade of 38.92%.

Stochastic and upscaled analytical modeling of fines migration in porous media induced by low-salinity water injection

Fines migration induced by injection of low-salinity water(LSW) into porous media can lead to severe pore plugging and consequent permeability reduction. The deepbed filtration(DBF) theory is used to model the aforementioned phenomenon, which allows us to predict the effluent concentration history and the distribution profile of entrapped particles. However, the previous models fail to consider the movement of the waterflood front. In this study, we derive a stochastic model for fines migration during LSW flooding, in which the Rankine-Hugoniot condition is used to calculate the concentration of detached particles behind and ahead of the moving water front. A downscaling procedure is developed to determine the evolution of pore-size distribution from the exact solution of a large-scale equation system. To validate the proposed model,the obtained exact solutions are used to treat the laboratory data of LSW flooding in artificial soil-packed columns. The tuning results show that the proposed model yields a considerably higher value of the coefficient of determination, compared with the previous models, indicating that the new model can successfully capture the effect of the moving water front on fines migration and precisely match the effluent history of the detached particles.

Hydro-mechanical analysis of rainfall-induced fines migration process within unsaturated soils

Seepage-induced fines migration under rainfall infiltration is a main cause leading to shallow failures in loose colluvial slopes. To describe the full process of fines migration within unsaturated soils during rainfall infiltration and the associated hydromechanical behaviors, a seepage-erosion-deformation coupled formulation is proposed in this paper. The governing equations proposed are implemented into a finite element code and used to investigate the influences of skeleton deformation on the rainfall infiltration process through unsaturated soil columns.The numerical results were presented in detail for a better understanding of the rainfall-induced fines migration process within unsaturated soils. Further,the obtained results are integrated into an infinite slope model for slope stability analysis. The results show that, the skeleton deformation will affect the rainfall infiltration rate and hence the timing of slope failures; meanwhile their influences are more evident if the fines deposition process is taken into account.Moreover, the slope stability could be reduced gradually due to the soil strength loss along with loss of fine particles. Therefore, particular attentions should be paid to analyzing the stability of soil slopes susceptible to internal erosion.

Self-compacting Concrete-filled Steel Tubes Prepared from Manufactured Sand with a High Content of Limestone Fines

To meet the requirements of construction of concretes filled in the steel tube arches,a C60 grade micro-expansive self-compacting concrete （SCC） was prepared from manufactured sand （MS）.The utilization of MS with a high content of quarry limestone fines was dealed for SCC applications.The workability,compressive and splitting strength,modulus of elasticity,restrained expansion and chloride ion permeability as well as freeze-thaw resistance of three MS-SCC mixes with fines content of 3%,7% and 10% were tested and compared with those of the natural sand （NS）-SCC mix.The experimental results indicate that the performances of the C60 MS-SCC with fines content of 7% are excellent and compared favorably with those of C60 NS-SCC.

The space time CE/SE method for solving one-dimensional batch crystallization model with fines dissolution

This article is concerned with the numerical investigation of one-dimensional population balance models for batch crystallization process with fines dissolution.In batch crystallization,dissolution of smaller unwanted nuclei below some critical size is of vital importance as it improves the quality of product.The crystal growth rates for both size-independent and size-dependent cases are considered.A delay in recycle pipe is also included in the model.The space–time conservation element and solution element method,originally derived for non-reacting flows,is used to solve the model.This scheme has already been applied to a range of PDEs,mainly in the area of fluid mechanics.The numerical results are compared with those obtained from the Koren scheme,showing that the proposed scheme is more efficient.

Influence of fines content on the anti-frost properties of coarse-grained soil

This paper aims to determine the optimal fines content of coarse-grained soil required to simultaneously achieve weaker frost susceptibility and better bearing capacity. We studied the frost susceptibility and strength properties of coarse-grained soil by means of frost heaving tests and static triaxial tests, and the results are as follows： （1） the freezing temperature of coarse-grained soil decreased gradually and then leveled off with incremental increases in the percent content of fines; （2） the fines content proved to be an important factor influencing the frost heave susceptibility and strength properties of coarse-grained soil. With incremental increases in the percent content of fines, the frost heave ratio increased gradually and the cohesion function of fines effectively enhanced the shear strength of coarse-grained soil before freeze-thaw, but the frost susceptibility of fines weakened the shear strength of coarse-grained soil after freeze-thaw; （3） with increasing numbers of freeze-thaw cycles, the shear strength of coarse-grained soil decreased and then stabilized after the ninth freeze-thaw cycle, and therefore the mechanical indexes of the ninth freeze-thaw cycle are recommended for the engi- neering design values; and （4） considering frost susceptibility and strength properties as a whole, the optimal fines content of 5% is recommended for railway sub,fade coarse-~rained soil fillings in frozen re^ions.

Floc flotation of jamesonite fines in aqueous suspensions induced by ammonium dibutyl dithiophosphate

The hydrophobic flocculation of jamesonite fines in aqueous suspensions induced by ammonium dibutyl dithiophosphate was investigated using laser particle size analysis, microscope analysis, electrophoretic light scattering and infrared spectroscopy.Single minerals of 4.607 μm for the 50% volumetric diameters were researched by varying several parameters, including p H,ammonium dibutyl dithiophosphate concentration, stirring strength and kerosene addition. It is found that the maximal floatability of jamesonite fines is induced by ammonium dibutyl dithiophosphate at p H 6, and the floc flotation increases with increasing ammonium dibutyl dithiophosphate concentration despite a simultaneous increase in the negative ζ potential of jamesonite, meaning that hydrophobic interaction between the particles increases much more strongly than electric double layer repulsion from the adsorption of ammonium dibutyl dithiophosphate. It is also found that the floc flotation is closely correlated with the size of flocs,which is strongly influenced by the stirring strength and enhanced by the addition of a small amount of kerosene. The results of FTIR spectra indicate that adsorption of ammonium dibutyl dithiophosphate onto jamesonite is chemical adsorption and the adsorption product is lead dibutyl dithiophosphate.

Packing Density Improvement through Addition of Limestone Fines, Superfine Cement and Condensed Silica Fume

Adoption of a low water/powder (W/P) ratio is the key to improve the strength and durability of concrete, which relies on a high packing density because fresh concrete requires excess water to offer flowability. To obtain a high packing density, powders with different particle sizes, including limestone fines (LSF), superfine cement (SFC), condensed silica fume (CSF), were added to the cement paste and the resulting packing densities were measured directly by a newly-developed wet packing test. Results demonstrated that addition of powders with a finer size would more significantly improve the packing density but the powders should be at least as fine as 1/4 of the OPC to effectively improve the packing density. Packing density and voids ratio relationship showed that a small increase in packing density can significantly decrease the voids ratio, which could allow the W/P ratio to be reduced to improve the strength and durability of the concrete without compromising the flowability.