期刊文献+
共找到1,990篇文章
< 1 2 100 >
每页显示 20 50 100
Novel wood-plastic composite fabricated via modified steel slag:Preparation,mechanical and flammability properties
1
作者 Ling Zhao Kai Zhao +4 位作者 Zhenwei Shen Yifan Wang Xiaojie Xia Hao Zhang Hongming Long 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第9期2110-2120,共11页
A novel method was developed to enhance the utilization rate of steel slag(SS).Through treatment of SS with phosphoric acid and aminopropyl triethoxysilane(KH550),we obtained modified SS(MSS),which was used to prepare... A novel method was developed to enhance the utilization rate of steel slag(SS).Through treatment of SS with phosphoric acid and aminopropyl triethoxysilane(KH550),we obtained modified SS(MSS),which was used to prepare MSS/wood-plastic composites(MSS/WPCs)by replacing talcum powder(TP).The composites were fabricated through melting blending and hot pressing.Their mechanical and combustion properties,which comprise heat release,smoke release,and thermal stability,were systematically investigated.MSS can improve the mechanical strength of the composites through grafting reactions between wood powder and thermoplastics.Notably,MSS/WPC#50(16wt%MSS)with an MSS-to-TP mass ratio of 1:1 exhibited optimal comprehensive performance.Compared with those of WPC#0 without MSS,the tensile,flexural,and impact strengths of MSS/WPC#50 were increased by 18.5%,12.8%,and 18.0%,respectively.Moreover,the MSS/WPC#50 sample achieved the highest limited oxygen index of 22.5%,the highest vertical burning rating at the V-1 level,and the lowest horizontal burning rate at 44.2 mm/min.The formation of a dense and stable char layer led to improved thermal stability and a considerable reduction in heat and smoke releases of MSS/WPC#50.However,the partial replacement of TP with MSS slightly compromised the mechanical and flame-retardant properties,possibly due to the weak grafting caused by SS powder agglomeration.These findings suggest the suitability of MSS/WPCs for high-value-added applications as decorative panels indoors or outdoors. 展开更多
关键词 modified steel slag wood–plastic composites preparation method mechanical property flame retardant
下载PDF
A multi-mineral model for predicting petrophysical properties of complex metamorphic reservoirs:Case study of the Bozhong Depression,Bohai Sea
2
作者 Guoqiang Zhang Zhongjian Tan +5 位作者 Guibin Zhang Dong Li Chenchen Liu Zhang Zhang Jun Cao Xin Lei 《Energy Geoscience》 EI 2024年第3期66-76,共11页
Interpreting reservoir properties through log data and logging responses in complex strata is critical for efficient petroleum exploitation,particularly for metamorphic rocks.However,the unsatisfactory accuracy of suc... Interpreting reservoir properties through log data and logging responses in complex strata is critical for efficient petroleum exploitation,particularly for metamorphic rocks.However,the unsatisfactory accuracy of such interpretations in complex reservoirs has hindered their widespread application,resulting in severe inconvenience.In this study,we proposed a multi-mineral model based on the least-square method and an optimal principle to interpret the logging responses and petrophysical properties of complex hydrocarbon reservoirs.We began by selecting the main minerals based on a comprehensive analysis of log data,X-ray diffraction,petrographic thin sections and scanning electron microscopy(SEM)for three wells in the Bozhong 19-6 structural zone.In combination of the physical properties of these minerals with logging responses,we constructed the multi-mineral model,which can predict the log curves,petrophysical properties and mineral profile.The predicted and measured log data are evaluated using a weighted average error,which shows that the multi-mineral model has satisfactory prediction performance with errors below 11%in most intervals.Finally,we apply the model to a new well“x”in the Bozhong 19-6 structural zone,and the predicted logging responses match well with measured data with the weighted average error below 11.8%for most intervals.Moreover,the lithology is dominated by plagioclase,K-feldspar,and quartz as shown by the mineral profile,which correlates with the lithology of the Archean metamorphic rocks in this region.It is concluded that the multi-mineral model presented in this study provides reasonable methods for interpreting log data in complex metamorphic hydrocarbon reservoirs and could assist in efficient development in the future. 展开更多
关键词 Logging interpretation Metamorphic rock Buried hill reservoir Petrophysical property prediction Bozhong 19-6 structural zone
下载PDF
PRELIMINARY STUDIES ON STRUCTURES AND PROPERTIES OF WATER-RETENTIVE, FLAME-RETARDANT ACRYLIC FIBERS
3
作者 刘兆峰 林伟平 +1 位作者 杨明远 吴宗铨 《Journal of China Textile University(English Edition)》 EI CAS 1990年第1期45-52,共8页
The blend fibers of acrylonitrile-vinylidene chloride-sodium methallysulfonate copolymer(AN-VDC-SMAS) and cellulose acetate (CA) with various blend ratios were investigated bymeans of SEM, DDV, WAXD, etc. The results ... The blend fibers of acrylonitrile-vinylidene chloride-sodium methallysulfonate copolymer(AN-VDC-SMAS) and cellulose acetate (CA) with various blend ratios were investigated bymeans of SEM, DDV, WAXD, etc. The results show that AN-VDC-SMAS and CA areincompatibale; the numerous microvoids in the blend fiber resulted from the phase seperationcan remarkably improve the water absorbability and the dyeing behavior but hardly influencethe mechanical properties. On the other hand, the crystal structure of the continuous phaseAN-VDC-SMAS is not influnced by the dispersed phase CA. 展开更多
关键词 compatibility CRYSTAL PERFECTION CRYSTAL structure morphology mechanical properties WATER absorbability flame retardancy DYEING saturation UPTAKE
下载PDF
Mechanical Properties and Fire Retardancy of Wood Flour/High-Density Polyethylene Composites Reinforced with Continuous Honeycomb-Like Nano-SiO_(2)Network and Fire Retardant
4
作者 Haiyang Zhou Xiaoyu Wang +2 位作者 Xiaolong Hao Qingwen Wang Rongxian Ou 《Journal of Renewable Materials》 SCIE EI 2020年第5期485-498,共14页
The mechanical properties of wood flour/high-density polyethylene composites(WPC)were improved by adding a small amount of nano-SiO_(2)to obtain a network-structured WPC with a continuous honeycomb-like nano-SiO_(2)ne... The mechanical properties of wood flour/high-density polyethylene composites(WPC)were improved by adding a small amount of nano-SiO_(2)to obtain a network-structured WPC with a continuous honeycomb-like nano-SiO_(2)network.The wood flour was modified with a fire retardant(a mixture of sodium octabonate and amidine urea phosphate)to improve its fire retardancy.The flexural properties,creep resistance,thermal expansion,and fire retardancy of the WPC were compared to a control(WPCCTRL)without nano-SiO_(2)or fire retardant.The flexural strength and modulus of the WPC containing only 0.55 wt.%nano-SiO_(2)were 6.6%and 9.1%higher than the control,respectively,while the creep strain and thermal expansion rate at 90°C were 33.8%and 13.6%lower,respectively.The cone calorimetry tests revealed that the nano-SiO_(2)network physically shielded the WPC,giving it lower heat release and smoke production rates.The thermal expansion was further decreased by incorporating fire retardants into the WPC,which showed the lowest total heat release and total smoke production and the highest mass retention.This study demonstrates a facile procedure for producing WPC with desired performances by forming a continuous honeycomb-like network by adding a small amount of nanoparticles. 展开更多
关键词 Wood plastic composites nano-SiO_(2) mechanical properties CREEP fire retardancy
下载PDF
硅烷-二氧化硅气凝胶颗粒不同复配比例浸渍处理对增强杨木阻燃性能的影响
5
作者 韦宇 邱哲 +3 位作者 张天鹏 王永贵 谢延军 肖泽芳 《东北林业大学学报》 CAS CSCD 北大核心 2024年第8期134-144,共11页
以γ-缩水甘油基氧基丙基三甲氧基硅烷水解液(GPS)、二氧化硅气凝胶(SA)为改性剂原料,在质量分数为30%的GPS水解液中,加入占GPS质量2%、4%、6%、8%、10%的SA颗粒,制备复合改性的浸渍液;以杨木(Populus adenopoda)木材为试材,采用对木材... 以γ-缩水甘油基氧基丙基三甲氧基硅烷水解液(GPS)、二氧化硅气凝胶(SA)为改性剂原料,在质量分数为30%的GPS水解液中,加入占GPS质量2%、4%、6%、8%、10%的SA颗粒,制备复合改性的浸渍液;以杨木(Populus adenopoda)木材为试材,采用对木材试件进行真空加压浸渍处理方法,使用不同配比的复合改性的浸渍液浸渍处理木材试件制备5种复合改性浸渍液的改性木材、使用GPS水解液浸渍处理木材试件制备GPS改性木材、使用占GPS质量6%的SA水溶液浸渍处理木材试件制备SA改性木材;按照相关标准和试验方案,测定改性材的质量增加率、浸渍液流失率、微观形貌、隔热性能、表面接触角、硅元素化学组分构成、热稳定性、燃烧性能,分析硅烷-二氧化硅气凝胶颗粒不同复配比例浸渍处理杨木对增强杨木阻燃性能的影响。结果表明,GPS-SA复合改性有效改善了木材的疏水性,与单纯使用SA颗粒处理木材相比较,GPS-SA复合改性组水洗10 d后浸渍液流失率最高可降低了42%。扫描电镜分析结果表明,GPS主要在木材细胞腔中自聚形成大分子聚合物,而SA颗粒则主要附着于木材的导管上,且随着SA颗粒质量比例提高,SA颗粒团聚现象增加。GPS-SA复合改性后,木材的密度比未处理木材提高38%,而密度变大会导致热导率升高,但“GPS+占GPS质量6%的SA”组的热导率仍比未处理木材降低6%,且面积热容比未处理木材提高59%。热质量分析结果表明,GPS-SA处理,提高了木材的热解温度和剩余物质量。锥形量热仪分析结果表明,“GPS+占GPS质量6%的SA”处理木材比未处理木材的点燃时间滞后28s、热释放速率峰值下降44.5%、热释放总量下降47.8%、烟释放速率峰值降低29.4%、烟释放总量减少39.1%,处理材的CO、CO_(2)产量也明显比未处理材少。综合研究结果,GPS-SA复合处理能有效改善木材阻燃性能,并且制备方法简洁环保。 展开更多
关键词 杨木 阻燃性能 硅烷偶联剂 二氧化硅气凝胶 水基型阻燃剂
下载PDF
DOPO-APTES的制备及其对涤纶织物阻燃抗熔滴性能的研究
6
作者 王以红 潘虹 +4 位作者 沈勇 徐丽慧 胡磊 王黎明 丁颖 《功能材料》 CAS CSCD 北大核心 2024年第2期2201-2206,2223,共7页
为了提高涤纶织物的阻燃性和抗熔滴性能,采用Atherton-Todd反应,以DOPO和APTES为原料合成了一种含有N,P,Si 3种元素的阻燃剂DOPO-APTES。通过溶胶-凝胶法,将DOPO-APTES整理到涤纶织物上。与涤纶原样相比,整理后涤纶织物的残炭率明显增加... 为了提高涤纶织物的阻燃性和抗熔滴性能,采用Atherton-Todd反应,以DOPO和APTES为原料合成了一种含有N,P,Si 3种元素的阻燃剂DOPO-APTES。通过溶胶-凝胶法,将DOPO-APTES整理到涤纶织物上。与涤纶原样相比,整理后涤纶织物的残炭率明显增加,具有较好的阻燃效果,同时抗熔滴性能大大提高。 展开更多
关键词 DOPO衍生物 涤纶织物 溶胶-凝胶法 阻燃性能 抗熔滴
下载PDF
双基阻燃剂DOPS-TEAIC的合成及阻燃环氧树脂的性能
7
作者 胥秋 侯泽明 +7 位作者 宦宣英 祁钰昭 许松江 宝冬梅 高成涛 邹光龙 张玉鹏 文竹 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2024年第9期74-85,共12页
以9,10-二氢-9-氧杂-10-磷杂菲-10-硫化物(DOPS)与三(2-丙烯酰氧乙基)异氰脲酸酯(TEAIC)为原料,合成了一种新型双基阻燃剂三(2-(9,10-二氢-9-氧杂-10-磷杂菲-10-硫化物)-丙酸乙酯基)三嗪三酮(DOPS-TEAIC)。采用傅里叶变换红外光谱、核... 以9,10-二氢-9-氧杂-10-磷杂菲-10-硫化物(DOPS)与三(2-丙烯酰氧乙基)异氰脲酸酯(TEAIC)为原料,合成了一种新型双基阻燃剂三(2-(9,10-二氢-9-氧杂-10-磷杂菲-10-硫化物)-丙酸乙酯基)三嗪三酮(DOPS-TEAIC)。采用傅里叶变换红外光谱、核磁共振和质谱确定其结构,并将其应用于环氧树脂(EP)制备了EP/DOPS-TEAIC。采用热重分析、垂直燃烧、极限氧指数、锥形量热、热重-红外光谱联用和热裂解-气相色谱/质谱联用等手段研究了阻燃剂DOPS-TEAIC对EP的热稳定性、阻燃性能及热降解行为的影响,并深入分析了其阻燃机理。结果表明,阻燃剂DOPS-TEAIC能够提高EP的热稳定性、残炭量和阻燃性能,降低其热释放速率峰值(PHRR)和平均热释放速率(av-HRR)。当DOPS-TEAIC的质量分数为10.0%时,EP/DOPS-TEAIC的LOI值提高至33.4%,达到UL-94 V-0级,其PHRR和av-HRR值比纯EP分别降低了34.2%和22.8%。阻燃剂DOPS-TEAIC主要通过稀释作用和自由基猝灭作用在气相发挥阻燃作用。 展开更多
关键词 9 10-二氢-9-氧杂-10-磷杂菲-10-硫化物 三嗪三酮 环氧树脂 阻燃性能 阻燃机理
下载PDF
γ-脲基丙基三乙氧基硅烷/苯基膦酸阻燃抗菌棉织物的制备及其性能
8
作者 刘慧 李平 +1 位作者 朱平 刘云 《纺织学报》 EI CAS CSCD 北大核心 2024年第8期205-214,共10页
针对棉织物易燃烧、易为有害细菌的滋生提供适宜生长环境,给人们正常生活带来重大安全隐患和健康危害等问题,采用γ-脲基丙基三乙氧基硅烷(TESPR)和苯基膦酸(PPOA),通过溶胶-凝胶法制备了阻燃抗菌棉织物。借助扫描电子显微镜、热重分析... 针对棉织物易燃烧、易为有害细菌的滋生提供适宜生长环境,给人们正常生活带来重大安全隐患和健康危害等问题,采用γ-脲基丙基三乙氧基硅烷(TESPR)和苯基膦酸(PPOA),通过溶胶-凝胶法制备了阻燃抗菌棉织物。借助扫描电子显微镜、热重分析仪、锥型量热测试仪、万能材料试验机、织物透气仪等对制得的阻燃棉织物进行表征,研究了其阻燃性能、热稳定性能、力学性能、抗菌性能以及透气性能等。结果表明:TESPR/PPOA成功附着于棉织物表面,极限氧指数达到27.2%;TESPR/PPOA涂层阻燃整理棉织物初始热降解温度低于未处理棉织物,但高温区的残炭量增加,表明在低温区生成的残炭能够作为隔热屏障保护内部棉织物;此外,TESPR/PPOA在棉织物表面的沉积,在大幅度提升抗菌性能的同时,保留了较好的透气性。 展开更多
关键词 阻燃性能 抗菌性能 棉织物 γ-脲基丙基三乙氧基硅烷 苯基膦酸 功能性纺织品
下载PDF
A Vanillin-Derived,DOPO-Contained Bisphenol as a Reactive Flame Retardant for High-Performance Epoxy Thermosets 被引量:2
9
作者 Li Wang Rongbai Tong +4 位作者 Juanli Wang Jintao Wan Yuhu Li Pujun Jin Daodao Hu 《Journal of Renewable Materials》 SCIE EI 2022年第5期1349-1364,共16页
Quest for bio-based halogen-free green flame retardant has attracted many concerns in recent years.Herein a reactive functional flame retardant containing phosphorus VDP is synthesized from vanillin,9,10-dihydro-9-oxa... Quest for bio-based halogen-free green flame retardant has attracted many concerns in recent years.Herein a reactive functional flame retardant containing phosphorus VDP is synthesized from vanillin,9,10-dihydro-9-oxa-10-phosphophene-10-oxide(DOPO)and phenol via a facile way.VDP is characterized with^(1)H NMR,^(31)P NMR,FTIR and Time of Flight Mass Spectrometry,and used as a new reactive flame retardant for bisphenol epoxy thermosets.Thermogravimetry analysis shows that when the VDP loading is only 0.5P%(based on phosphorus content),the residue increases from 14.2%to 21.1%at 750℃ in N_(2)compare with neat DGEBA.Correspondingly,the limit oxygen index increased to 29.6%,and flame retardancy reaches UL-94 V0 grade.Micro combustion calorimetry(MCC)and cone calorimetry analyses demonstrate that VDP can significantly lower flammability of the epoxy thermoset.With only 0.5P%of VDP,the heat release rate,total heat release rate and smoke production are reduced markedly.At the same time,the mechanical properties of the modified epoxy thermosets are also improved.The impact strength increases by 34%and the flexural strength increased by 23%,with 1.5P%of VDP.In short,VDP not only improves the flame retardancy,but also improves the mechanical properties of the epoxy thermosets. 展开更多
关键词 Epoxy resin bio-based flame retardant VANILLIN properties of thermosets
下载PDF
聚吡咯微胶囊γ-Fe_(2)O_(3)的合成及在膨胀阻燃环氧树脂中的应用
10
作者 张泽瑞 龙邈天 +1 位作者 颜龙 徐志胜 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2024年第5期47-55,共9页
以聚吡咯(PPy)微胶囊γ-Fe_(2)O_(3)得到的PPy-Fe_(2)O_(3)为协效剂、二氨基二苯甲烷改性聚磷酸铵(DDP)为阻燃剂制备了膨胀阻燃环氧树脂(EP)复合材料。结合极限氧指数(LOI)、UL94、热重分析、锥形量热仪及扫描电镜探究PPy-Fe_(2)O_(3)对... 以聚吡咯(PPy)微胶囊γ-Fe_(2)O_(3)得到的PPy-Fe_(2)O_(3)为协效剂、二氨基二苯甲烷改性聚磷酸铵(DDP)为阻燃剂制备了膨胀阻燃环氧树脂(EP)复合材料。结合极限氧指数(LOI)、UL94、热重分析、锥形量热仪及扫描电镜探究PPy-Fe_(2)O_(3)对EP/DDP体系的阻燃性、热稳定性及成炭性能的影响。结果表明,PPy-Fe_(2)O_(3)的加入可增强EP/DDP体系的阻燃性能、抑烟性能及热稳定性。利用PPy-Fe_(2)O_(3)与DDP复配有助于形成更加致密和稳定的炭层结构以减少热释放和生烟量,其中添加0.2%PPy-Fe_(2)O_(3)与9.8%DDP可使EP复合材料的峰值热释放速率(PHRR)与峰值生烟速率(PSPR)分别下降12.3%与11.0%,并成功通过UL94 V-0级且具有35.5%的LOI值。热重分析表明,PPy-Fe_(2)O_(3)的加入显著提高了EP/DDP体系的热稳定性与成炭性能,其中含0.2%PPy-Fe_(2)O_(3)的EP复合材料在700℃时的残炭量达到32.0%。 展开更多
关键词 γ-Fe_(2)O_(3) 聚吡咯 环氧树脂 阻燃性能 微胶囊
下载PDF
A Novel Bio-Based Zirconium Phosphonate as a Flame Retardant and Smoke Suppressant for Epoxy Resin 被引量:1
11
作者 Xianling Fu Hongliang Ding +2 位作者 Xin Wang Lei Song Yuan Hu 《Journal of Renewable Materials》 SCIE EI 2022年第9期2303-2317,共15页
Although epoxy resin has been widely used in various fields,it still suffers from some problems including brittleness and flammability.In this study,a new phosphonic acid,N,N-bis(phosphomethyl)glycine(GDMP),was prepar... Although epoxy resin has been widely used in various fields,it still suffers from some problems including brittleness and flammability.In this study,a new phosphonic acid,N,N-bis(phosphomethyl)glycine(GDMP),was prepared by Mannich reaction with bio-based glycine and then a novel layered zirconium phosphonate(ZrGDMP)was synthesized using GDMP and zirconyl chloride hydrate as reactants.The chemical structure of ZrGDMP was well characterized by 1 H and 31P NMR,SEM,XRD and XPS.The effect of ZrGDMP on the flame retardancy,smoke suppression,strengthening and toughening performances of the epoxy matrix was investigated and evaluated.TGA results indicated that compared with pure EP,ZrGDMP-EP composites showed higher char yield due to the catalytic charring effect of ZrGDMP.The pure EP exhibited high flammability,while ZrGDMP-EP composites possessed excellent thermal stability and remarkable fire resistance.The PHRR,THR,and TSP values of 3wt%ZrGDMP-EP were obviously declined by 39.6%,40.2%,and 24.9%compared to these of pure EP.Moreover,the tensile and impact tests implied that the addition of ZrGDMP can significantly reinforce the toughness as well as the strength of EP in terms of higher impact strength(24.8 kJ/m^(2))and tensile strength(57.7 MPa),which was mainly contributed to the uniform dispersion of ZrGDMP within the EP matrix. 展开更多
关键词 Zirconium phosphonate epoxy resin flame retardant mechanical property
下载PDF
Improved continuous precipitation kinetics and tensile properties of extruded AZ80 alloy through {10-12} twin formation
12
作者 Hyun Ji Kim Sumi Jo Sung Hyuk Park 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2023年第9期3323-3337,共15页
This study investigates the effect of{10-12}deformation twins on the continuous precipitation behavior of an extruded Mg-8.0Al-0.5Zn-0.2Mn(AZ80)alloy during aging.The extruded AZ80 alloy is compressed along the transv... This study investigates the effect of{10-12}deformation twins on the continuous precipitation behavior of an extruded Mg-8.0Al-0.5Zn-0.2Mn(AZ80)alloy during aging.The extruded AZ80 alloy is compressed along the transverse direction to introduce{10-12}twins,followed by an aging treatment at 300℃.The extruded material exhibits a twin-free microstructure with low internal strain energy,whereas the pre-twinned material possesses abundant{10-12}twins and has high internal strain energy.The aging results reveal that the peak-aging time of the pre-twinned material(1 h)is one-eighth of that of the extruded material(8 h).Although Mg_(17)Al_(12)continuous precipitates(CPs)are observed in both the peak-aged materials,these CPs are much smaller and more densely distributed in the pre-twinned material despite the significantly shorter aging time.The CPs size in the peak-aged materials increases in the following order:twinned region in the pre-twinned material(0.47μm)<residual matrix region in the pre-twinned material(1.71μm)<matrix region in the extruded material(2.55μm).Moreover,the CPs number density in the twinned region of the pre-twinned material is approximately 11 times higher than that in the matrix region of the extruded material.The peak-aged pre-twinned material exhibits significantly higher tensile strength and ductility than the peak-aged extruded material.These results demonstrate that the formation of{10-12}twins in the extruded AZ80 alloy substantially accelerates the static precipitation of CPs during aging at 300℃and improves the tensile properties of the peak-aged material. 展开更多
关键词 AZ80 alloy {10-12}twin AGING Continuous precipitation Tensile properties
下载PDF
Flame-retardant Mechanism of Magnesium Oxychloride in Epoxy Resin 被引量:6
13
作者 秦麟卿 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2009年第1期127-131,共5页
Flame-retardant mechanism of magnesium oxychloride (M OC) in EP was in-vestigated by limiting oxygen index (LOI), XRD, SEM, TG-DTG and DSC. The results show that MOC performed well as an inorganic flame-retardant ... Flame-retardant mechanism of magnesium oxychloride (M OC) in EP was in-vestigated by limiting oxygen index (LOI), XRD, SEM, TG-DTG and DSC. The results show that MOC performed well as an inorganic flame-retardant in EP. When the content of MOC is 50%, the LOI of EP reaches 29.6% and mass of residual char reaches 9.6%. The flame retarde mechanism of MOC is due to the synergies of diluting, cooling, catalyzing char forming and obstructing effects. 展开更多
关键词 magnesium oxychloride epoxy resin flame-retardant properties flame retardedmechanism
下载PDF
Al_(2)O_(3)-SiO_(2)/纤维素复合气凝胶的制备及其阻燃性能
14
作者 何亮 邱宇洪 +3 位作者 周立春 刘文龙 王思哲 廖家轩 《电子元件与材料》 CAS 北大核心 2024年第2期169-175,共7页
针对纤维素气凝胶隔热性能差、易燃烧等问题,基于液氮定向冷冻及真空冷冻干燥技术,以低成本、环境友好的微晶纤维素为原材料,Al_(2)O_(3)-SiO_(2)溶胶为阻燃剂,去离子水为溶剂,加入硼酸作为催化剂控制共水解进程,制备出隔热阻燃性能良好... 针对纤维素气凝胶隔热性能差、易燃烧等问题,基于液氮定向冷冻及真空冷冻干燥技术,以低成本、环境友好的微晶纤维素为原材料,Al_(2)O_(3)-SiO_(2)溶胶为阻燃剂,去离子水为溶剂,加入硼酸作为催化剂控制共水解进程,制备出隔热阻燃性能良好的Al_(2)O_(3)-SiO_(2)/纤维素复合气凝胶。采用扫描电子显微镜、傅里叶变换红外光谱仪、热重分析仪、锥形量热仪等研究了Al_(2)O_(3)-SiO_(2)溶胶含量对材料结构与性能的影响,并分析了复合气凝胶的阻燃机制。结果表明,随着Al_(2)O_(3)-SiO_(2)溶胶含量的增加,Al_(2)O_(3)-SiO_(2)/纤维素复合气凝胶从蜂窝状结构向多孔三维网络结构转变,孔径减小。Al_(2)O_(3)-SiO_(2)溶胶与微晶纤维素溶液体积比为2∶10时,具有最高分解温度205.21℃和最大质量保持率35.191%。点燃时间为11 s,热释放速率峰值为127.13 kW/m^(2),表现出更好的阻燃性与抑制火焰生成能力。 展开更多
关键词 复合气凝胶 微晶纤维素 Al_(2)O_(3)-SiO_(2) 隔热保温 阻燃性能
下载PDF
Effect of Blending Ratio on Properties of Core Yarn and Fabric of Polysulfonamide(PSA)/Flame Retardant Viscose(FRV)/Conductive Filament
15
作者 WU Gaihong WU Jie +1 位作者 JIANG Yan LIU Shuqiang 《Journal of Donghua University(English Edition)》 CAS 2021年第1期57-62,共6页
In order to develop a fabric with excellent flame resistance function,antistatic function,moisture absorption and breathability,the polysulfonamide(PSA)fiber and the flame retardant viscose(FRV)fiber were blended.Mean... In order to develop a fabric with excellent flame resistance function,antistatic function,moisture absorption and breathability,the polysulfonamide(PSA)fiber and the flame retardant viscose(FRV)fiber were blended.Meanwhile,the conductive filaments were used as the core yarn,and then they were made into the core-spun yarn and the fabric at different blending ratios of PSA/FRV.The effects of the blending ratio of PSA/FRV on the mechanical properties and the evenness of the yarn were studied.The effects of the blending ratio of PSA/FRV on mechanical properties,flame retardant properties,antistatic properties,moisture permeability and drape of the fabric were analyzed.With the increase of the blending ratios of PSA/FRV,the strength and the elongation of the core-spun yarn increased firstly and then decreased.Moreover,the evenness of the core-spun yarn was improved,the fabric strength increased firstly and then decreased,the flame resistance decreased,and the antistatic performance improved.These results provide an important basis for the preparation and wide application of fabrics made of PSA/FRV/conductive filament. 展开更多
关键词 flame retardant viscose(FRV) conductive filament flame resistance antistatic property
下载PDF
石墨烯-聚苯乙烯复合材料的制备及阻燃性能研究
16
作者 朱晓菲 《功能材料》 CAS CSCD 北大核心 2024年第7期7091-7097,共7页
采用溶液共混法制备了石墨烯-聚苯乙烯复合材料,通过XRD、SEM、FT-IR、力学性能测试、热失重分析、导热系数及THR分析等手段,研究了复合材料中氧化石墨烯(GO)的质量分数对复合材料物相结构、微观形貌、力学性能、热性能和阻燃性能的影... 采用溶液共混法制备了石墨烯-聚苯乙烯复合材料,通过XRD、SEM、FT-IR、力学性能测试、热失重分析、导热系数及THR分析等手段,研究了复合材料中氧化石墨烯(GO)的质量分数对复合材料物相结构、微观形貌、力学性能、热性能和阻燃性能的影响。结果表明,聚苯乙烯吸附在GO表面,GO与聚苯乙烯复合后增大了表面粗糙度,复合后没有改变聚合物的链结构。适量GO的掺杂改善了石墨烯-聚苯乙烯复合材料的力学性能,PG-6%的复合材料的拉伸强度、断裂延伸率、弹性模量均达到最大值,分别为38.8 MPa、10.37%和1505 MPa,相比纯PS分别提高了26.38%、8.06%和31.90%。复合材料的导热系数和热扩散系数均随GO占比的增大而先增大后降低,PG-6%复合材料的导热系数和热扩散系数达到最大值,分别为0.170 W/(m·K)和0.171 mm^(2)/s。适量GO的添加改善了复合材料的阻燃性能,使点燃难度增加,放热率降低,PG-6%的复合材料的阻燃性能最优,FPI最高为0.386。 展开更多
关键词 氧化石墨烯 聚苯乙烯 复合材料 力学性能 阻燃性能
下载PDF
ADP/A-SEP复配体系对EVA/MPE线缆复合材料的改性研究
17
作者 常子衡 李薇 +4 位作者 刘志成 陈彪 孟强 杜敬亮 杜永刚 《塑料工业》 CAS CSCD 北大核心 2024年第1期147-153,共7页
采用乙烯基三乙氧基硅烷(A151)对海泡石(SEP)进行表面处理制得A-SEP,并同二乙基次磷酸铝(ADP)复配用作乙烯-醋酸乙烯共聚物(EVA)/茂金属聚乙烯(MPE)线缆复合材料的阻燃改性剂。考察了ADP/A-SEP复配体系组成对EVA/MPE线缆复合材料拉伸性... 采用乙烯基三乙氧基硅烷(A151)对海泡石(SEP)进行表面处理制得A-SEP,并同二乙基次磷酸铝(ADP)复配用作乙烯-醋酸乙烯共聚物(EVA)/茂金属聚乙烯(MPE)线缆复合材料的阻燃改性剂。考察了ADP/A-SEP复配体系组成对EVA/MPE线缆复合材料拉伸性能、阻燃性能和加工流动性的影响。结果表明,ADP虽能明显改善EVA/MPE线缆复合材料的阻燃性能,但对拉伸性能负面影响较大。A-SEP同ADP具有较好的协效阻燃效果,且能够同时改善EVA/MPE线缆复合材料的拉伸性能。当ADP添加量为25%、A-SEP添加量为3%时,EVA/MPE线缆复合材料的拉伸强度与断裂伸长率分别为11.43 MPa和689%;极限氧指数(LOI)达到32%,初始热降解温度和残炭率分别为352.89℃和5.75%,体积电阻率为2.63×10^(13)Ω·cm。此外A-SEP添加量不超过3%时,其对EVA/MPE/线缆复合材料的加工流动性影响不大。 展开更多
关键词 乙烯-醋酸乙烯共聚物 二乙基次磷酸铝 海泡石 阻燃性能 拉伸性能 加工性能
下载PDF
一种氮-硫协同高效三聚氰胺苯磺酸盐阻燃剂制备及应用研究
18
作者 马祥伟 郎俊 +3 位作者 钟尧 李鉴 王乙婷 代莉 《聚酯工业》 CAS 2024年第5期24-26,30,共4页
本研究合成了一种氮-硫协同高效三聚氰胺苯磺酸盐(MBSA),并运用傅里叶变换红外光谱和热重分析仪对其进行了结构和性能表征。将MBSA添加到聚酰胺6(PA6)中,通过UL-94评级和熔融指数评估了MBSA/PA6复合材料的阻燃性能和加工性能。结果显示,... 本研究合成了一种氮-硫协同高效三聚氰胺苯磺酸盐(MBSA),并运用傅里叶变换红外光谱和热重分析仪对其进行了结构和性能表征。将MBSA添加到聚酰胺6(PA6)中,通过UL-94评级和熔融指数评估了MBSA/PA6复合材料的阻燃性能和加工性能。结果显示,MBSA表现出优异的热稳定性,其分解温度显著高于PA6的加工温度,适合于高温条件下的加工应用。当MBSA添加量为8%时,MBSA/PA6复合材料达到了UL-94 V0等级。此外,MBSA的加入显著提高了复合材料的熔融指数,改善了其加工性能,有利于工业生产和成型。本研究揭示了MBSA作为PA6阻燃添加剂的巨大潜力,为提升聚酰胺类复合材料的性能和应用提供了新的途径和策略。 展开更多
关键词 三聚氰胺 苯磺酸 聚酰胺 阻燃性能
下载PDF
高取向氢氧化镁的改性及其在乙烯-醋酸乙烯酯共聚物中的应用
19
作者 张金帅 马亚丽 +4 位作者 王海棠 司傲龙 郑强 贾松岩 李雪 《塑料工业》 CAS CSCD 北大核心 2024年第6期121-129,120,共10页
以菱镁矿煅烧得到的轻烧粉(主要成分为MgO)为原料,硝酸铵溶液为蒸氨母液,改变蒸氨条件提高蒸氨转化率,采用氨循环法合成层状高取向Mg(OH)_(2)。研究了蒸氨过程中硝酸铵的起始物质的量浓度(C_(NH_(4)NO_(3)))、蒸氨温度、氨/镁物质的量... 以菱镁矿煅烧得到的轻烧粉(主要成分为MgO)为原料,硝酸铵溶液为蒸氨母液,改变蒸氨条件提高蒸氨转化率,采用氨循环法合成层状高取向Mg(OH)_(2)。研究了蒸氨过程中硝酸铵的起始物质的量浓度(C_(NH_(4)NO_(3)))、蒸氨温度、氨/镁物质的量比对蒸氨转化率的影响;并以制得的Mg(OH)_(2)为研究对象,采用硅烷偶联剂乙烯基三甲氧基硅烷(HD-171)和乙烯基三(β-甲氧基乙氧基)硅烷(HD-172)作为表面改性剂,对Mg(OH)_(2)进行改性,将改性剂HD-171和HD-172改性后Mg(OH)_(2)添加到乙烯-醋酸乙烯酯共聚物(EVA)中,并对复合材料的拉伸性能和阻燃性进行表征。结果表明,温度、氨/镁物质的量比是影响蒸氨反应镁离子浸出率的关键因素,成功制备出纯度为99.98%、粒径为1.3μm、六方片状的高取向[I(001)/I(101)=1.3,I为晶面衍射峰强度]Mg(OH)_(2)产物。通过对比改性前后Mg(OH)_(2)的吸油值可知:在反应温度75℃,改性剂HD-171的质量分数为4%,反应60 min的条件下,改性剂HD-171对Mg(OH)_(2)的改性效果最好;在反应温度85℃,改性剂HD-172的质量分数为4%,反应60 min的条件下,改性剂HD-172对Mg(OH)_(2)的改性效果最好。在添加剂的质量分数均为70%的情况下,与未改性Mg(OH)_(2)/EVA复合材料相比,HD-171和HD-172改性Mg(OH)_(2)/EVA复合材料的拉伸强度分别提高了4.05和2.53 MPa,氧指数分别提升了2.6%和1.1%,说明HD-171和HD-172改性后的Mg(OH)_(2)可以有效地提高EVA的阻燃性和拉伸性能。 展开更多
关键词 氢氧化镁 高取向 乙烯-醋酸乙烯酯共聚物 硅烷偶联剂 阻燃性 拉伸性能
下载PDF
Anti-Bacterial and Flame Retardant for Cotton Fabric by One-Bath Finishing
20
作者 朱平 隋淑英 +1 位作者 王炳 孙铠 《Journal of China Textile University(English Edition)》 EI CAS 1998年第2期82-84,共3页
A research on the process of cotton fabric flame-re-tarding,anti-bacterial finishing and one-bath finish-ing of anti-bacterial and flame-retarding is discussed.The flame retardant agent was phosphorous-contained,and t... A research on the process of cotton fabric flame-re-tarding,anti-bacterial finishing and one-bath finish-ing of anti-bacterial and flame-retarding is discussed.The flame retardant agent was phosphorous-contained,and the bacteriostatic finishing agent named SFR-1 wassynthesized.The flame retardancy of the fabric finishedcan meet the DOC FF3-71 Children Sleepwear Stan-dard.Its bacterial inhibiting capacity can meet and ex-ceed the requirements of similar products 展开更多
关键词 cotton fabric flame - retardING FINISHING anti - BACTERIAL FINISHING one - BATH
全文增补中
上一页 1 2 100 下一页 到第
使用帮助 返回顶部