WMTC,which means a worldwide motorcycle testing cycle,is now regarded as the most possible choice for the global motorcycle emission testing cycle,but whether or not it can be used in China is still unknown.In this st...WMTC,which means a worldwide motorcycle testing cycle,is now regarded as the most possible choice for the global motorcycle emission testing cycle,but whether or not it can be used in China is still unknown.In this study,a large number of data on the speed-time trace of motorcycles were sampled from various kinds of roads in 5 cities in China.Based on a series of criterion numbers defined,the driving character of motorcycles in the real-road conditions of China was obtained.With the aid of a specially designed program,an emission testing cycle that can indicate the driving characteristics of motorcycle in the real-road conditions was synthesized,and the exhaust emission tests of 20 motorcycles under the synchronized cycle and WMTC were carried out based on a CVS system and a motorcycle chassis dynamometer.The results show that although there do exist differences in some criterion numbers between the real-road condition and WMTC,such as proportion of idling mode,mean speed,mean running speed and the average acceleration and deceleration rates,the driving behaviors are similar.The results of exhaust emission tests indicate that the emission values of motorcycles under the synchronized cycle and WMTC have a relatively strong correlation.This means that WMTC can be introduced as a standard motorcycle emission test regulation into China.展开更多
管理者过度自信的非理性特征对公司治理有效性的抑制作用已经得到学者的广泛关注,但鲜有文献关注私营企业家的个人自信特征与其薪酬-业绩敏感性之间的关系。基于Aggarwal and Samwick(2006)的理论框架,选择2012年全国私营企业调查问卷...管理者过度自信的非理性特征对公司治理有效性的抑制作用已经得到学者的广泛关注,但鲜有文献关注私营企业家的个人自信特征与其薪酬-业绩敏感性之间的关系。基于Aggarwal and Samwick(2006)的理论框架,选择2012年全国私营企业调查问卷中企业家对自己所处经济地位、社会地位、政治地位的自我评价得分刻画企业家自信,进而构建连续型交互项计量模型进行实证检验。结果表明:企业家自信对其薪酬-业绩敏感性存在显著的促进效应,并且这种效应在适度自信与高薪酬两个子样本中更突出,而过度自信与自信不足这两种非理性自信特征对薪酬-业绩敏感性的影响并不明显。展开更多
Potassium-ion batteries(PIBs)are considered promising alternatives to lithium-ion batteries owing to cost-effective potassium resources and a suitable redox potential of-2.93 V(vs.-3.04 V for Li+/Li).However,the explo...Potassium-ion batteries(PIBs)are considered promising alternatives to lithium-ion batteries owing to cost-effective potassium resources and a suitable redox potential of-2.93 V(vs.-3.04 V for Li+/Li).However,the exploration of appro-priate electrode materials with the correct size for reversibly accommodating large K+ions presents a significant challenge.In addition,the reaction mecha-nisms and origins of enhanced performance remain elusive.Here,tetragonal FeSe nanoflakes of different sizes are designed to serve as an anode for PIBs,and their live and atomic-scale potassiation/depotassiation mechanisms are revealed for the first time through in situ high-resolution transmission electron micros-copy.We found that FeSe undergoes two distinct structural evolutions,sequen-tially characterized by intercalation and conversion reactions,and the initial intercalation behavior is size-dependent.Apparent expansion induced by the intercalation of K+ions is observed in small-sized FeSe nanoflakes,whereas unexpected cracks are formed along the direction of ionic diffusion in large-sized nanoflakes.The significant stress generation and crack extension originating from the combined effect of mechanical and electrochemical interactions are elucidated by geometric phase analysis and finite-element analysis.Despite the different intercalation behaviors,the formed products of Fe and K_(2)Se after full potassiation can be converted back into the original FeSe phase upon depotassiation.In particular,small-sized nanoflakes exhibit better cycling perfor-mance with well-maintained structural integrity.This article presents the first successful demonstration of atomic-scale visualization that can reveal size-dependent potassiation dynamics.Moreover,it provides valuable guidelines for optimizing the dimensions of electrode materials for advanced PIBs.展开更多
基金Supported by Tianjin Municipal Science and Technology Commission(No.05YFJMJC11100and No.07JCYBJC03900)Ministry of Education of China(No.20020056046).
文摘WMTC,which means a worldwide motorcycle testing cycle,is now regarded as the most possible choice for the global motorcycle emission testing cycle,but whether or not it can be used in China is still unknown.In this study,a large number of data on the speed-time trace of motorcycles were sampled from various kinds of roads in 5 cities in China.Based on a series of criterion numbers defined,the driving character of motorcycles in the real-road conditions of China was obtained.With the aid of a specially designed program,an emission testing cycle that can indicate the driving characteristics of motorcycle in the real-road conditions was synthesized,and the exhaust emission tests of 20 motorcycles under the synchronized cycle and WMTC were carried out based on a CVS system and a motorcycle chassis dynamometer.The results show that although there do exist differences in some criterion numbers between the real-road condition and WMTC,such as proportion of idling mode,mean speed,mean running speed and the average acceleration and deceleration rates,the driving behaviors are similar.The results of exhaust emission tests indicate that the emission values of motorcycles under the synchronized cycle and WMTC have a relatively strong correlation.This means that WMTC can be introduced as a standard motorcycle emission test regulation into China.
文摘管理者过度自信的非理性特征对公司治理有效性的抑制作用已经得到学者的广泛关注,但鲜有文献关注私营企业家的个人自信特征与其薪酬-业绩敏感性之间的关系。基于Aggarwal and Samwick(2006)的理论框架,选择2012年全国私营企业调查问卷中企业家对自己所处经济地位、社会地位、政治地位的自我评价得分刻画企业家自信,进而构建连续型交互项计量模型进行实证检验。结果表明:企业家自信对其薪酬-业绩敏感性存在显著的促进效应,并且这种效应在适度自信与高薪酬两个子样本中更突出,而过度自信与自信不足这两种非理性自信特征对薪酬-业绩敏感性的影响并不明显。
基金This work was supported by the National Key R&D Program of China(Grant No.2018YFB1304902)the National Natural Science Foundation of China(Grant Nos.12004034,U1813211,22005247,11904372,51502007,52072323,52122211,12174019,and 51972058)+1 种基金the Gen-eral Research Fund of Hong Kong(Project No.11217221)China Postdoctoral Science Foundation Funded Project(Grant No.2021M690386).
文摘Potassium-ion batteries(PIBs)are considered promising alternatives to lithium-ion batteries owing to cost-effective potassium resources and a suitable redox potential of-2.93 V(vs.-3.04 V for Li+/Li).However,the exploration of appro-priate electrode materials with the correct size for reversibly accommodating large K+ions presents a significant challenge.In addition,the reaction mecha-nisms and origins of enhanced performance remain elusive.Here,tetragonal FeSe nanoflakes of different sizes are designed to serve as an anode for PIBs,and their live and atomic-scale potassiation/depotassiation mechanisms are revealed for the first time through in situ high-resolution transmission electron micros-copy.We found that FeSe undergoes two distinct structural evolutions,sequen-tially characterized by intercalation and conversion reactions,and the initial intercalation behavior is size-dependent.Apparent expansion induced by the intercalation of K+ions is observed in small-sized FeSe nanoflakes,whereas unexpected cracks are formed along the direction of ionic diffusion in large-sized nanoflakes.The significant stress generation and crack extension originating from the combined effect of mechanical and electrochemical interactions are elucidated by geometric phase analysis and finite-element analysis.Despite the different intercalation behaviors,the formed products of Fe and K_(2)Se after full potassiation can be converted back into the original FeSe phase upon depotassiation.In particular,small-sized nanoflakes exhibit better cycling perfor-mance with well-maintained structural integrity.This article presents the first successful demonstration of atomic-scale visualization that can reveal size-dependent potassiation dynamics.Moreover,it provides valuable guidelines for optimizing the dimensions of electrode materials for advanced PIBs.
