Physical and mathematical models as well as calculation methods of nitrogen bed on porous media have been introduced to evaluate the structural parameters of mesoporous materials. Kelvin＇s equation is a link between ...Physical and mathematical models as well as calculation methods of nitrogen bed on porous media have been introduced to evaluate the structural parameters of mesoporous materials. Kelvin＇s equation is a link between the relative adsorbate pressure, the mean pore radius, and pore capillarity on the basis of macroscopic capillary condensation. However, Kelvin＇s equation has been identified that it underestimates the calculated pore size of a material especially in the boundary of pore size which is between 2 and 4 nm.Various modifications on Kelvin＇s equation were mentioned in order to develop a new model to improve the accuracy of pore size calculation. The problems on conventional mathematical models were analyzed and discussed. A number of calculation methods on physisorption and pore size, especially fundamental theories of physisorption, basis of models and their deficiencies are reviewed. It can provide guidance on developing a modified Kelvin＇s equation for pore size calculation.展开更多
Discrete element modeling was used to investigate the effect of particle size distribution on the small strain shear stiffness of granular soils and explore the fundamental mechanism controlling this small strain shea...Discrete element modeling was used to investigate the effect of particle size distribution on the small strain shear stiffness of granular soils and explore the fundamental mechanism controlling this small strain shear stiffness at the particle level. The results indicate that the mean particle size has a negligible effect on the small strain shear modulus. The observed increase of the shear modulus with increasing particle size is caused by a scale effect. It is suggested that the ratio of sample size to the mean particle size should be larger than 11.5 to avoid this possible scale effect. At the same confining pressure and void ratio, the small strain shear modulus decreases as the coefficient of uniformity of the soil increases. The Poisson＇s ratio decreases with decreasing void ratio and increasing confining pressure instead of being constant as is commonly assumed. Microscopic analyses indicate that the small strain shear stiffness and Poisson＇s ratio depend uniquely on the soil＇s coordination number.展开更多
According to the statistical shape-slope （μ-A） relationship observed for the first time by several 2D-Video-Distro-meters （2DVD） in southern China, a constrained gamma （C-G） model was proposed for the retrieval...According to the statistical shape-slope （μ-A） relationship observed for the first time by several 2D-Video-Distro-meters （2DVD） in southern China, a constrained gamma （C-G） model was proposed for the retrieval of rain drop size distributions （DSDs） from Guangzhou S-band polarimetric radar observations. Two typical precipitation processes were selected to verify the accuracy of the retrieval scheme. The p-A relationship： A = 0.0241μ^2 ＋ 0.867μ ＋ 2.453 was obtained based on the 2DVD observation results from at Huizhou Longmen station, which is a very representat-ive location in the area. Relying on the Guangzhou polarimetric radar measurements of radar reflectivity （ZHH） and differential reflectivity （ZDR）, the gamma （F） size distribution parameters （No, μ, and A） can be retrieved by the C-G model retrieval scheme. The results show that the Guangzhou polarimetric radar retrievals of DSDs were close to the 2DVD observations at Guangzhou Maofengshan station. The rain rate, mass mean diameter, and normalized inter-cept parameter of radar retrievals were in good agreement with the 2DVD observations, and the relative errors were less than 10%. The overall accuracy of the retrieval scheme was high. The retrieval scheme has established the rela-tionship between the polarimetric radar measurements and gamma size distribution parameters. It will be helpful to in-depth research and application of the dual-polarization radar data in microphysical precipitation processes analysis, as well as convection-resolved numerical model data assimilation and prediction effect evaluation.展开更多
Dispersive soils which occur in many parts of the world are easily erodible and segregate in water pose serious problems of stability of earth and earth retaining structures. The mechanism of dispersivity of soils is ...Dispersive soils which occur in many parts of the world are easily erodible and segregate in water pose serious problems of stability of earth and earth retaining structures. The mechanism of dispersivity of soils is reasonably well understood. However there is simple method to identify the dispersivity of the soils and even more difficult to quantify the dispersivity. Visual classification, Atterberg’s limits and particle size analysis do not provide sufficient basis to differentiate between dispersive clays and ordinary erosion resistant clays. Pinhole test and double hydrometer test are the only two tests that are in vogue to identify the dispersive soils. This paper explores the possibility of using other standard tests such as shrinkage limit and unconfined compressive strength tests to quantify the dispersivity of the soils. The rationale of using the methods and correlation between the dispersivity determined by various methods has been explained. It has been concluded that dispersivity ascertained from strength tests is more reliable.展开更多
基金The paper has been presented in the 1st Sino-German workshop on the evolutionary economics, March, 2004, Beijing, China. The work is supported by the NSFC under grant No. 70371072 and grant No. 79990580.
文摘Physical and mathematical models as well as calculation methods of nitrogen bed on porous media have been introduced to evaluate the structural parameters of mesoporous materials. Kelvin＇s equation is a link between the relative adsorbate pressure, the mean pore radius, and pore capillarity on the basis of macroscopic capillary condensation. However, Kelvin＇s equation has been identified that it underestimates the calculated pore size of a material especially in the boundary of pore size which is between 2 and 4 nm.Various modifications on Kelvin＇s equation were mentioned in order to develop a new model to improve the accuracy of pore size calculation. The problems on conventional mathematical models were analyzed and discussed. A number of calculation methods on physisorption and pore size, especially fundamental theories of physisorption, basis of models and their deficiencies are reviewed. It can provide guidance on developing a modified Kelvin＇s equation for pore size calculation.
基金The work presented in this paper was supported by the National Natural Science Foundation of China （Grant Nos. 51308408, 41272291,51238009） and the Fundamental Research Funds for the Central Universities, and the Open Foundation of State Key Labo- ratory of Hydrology-Water Resources and Hydraulic Engineering （Grant No. 2014492311 ）.
文摘Discrete element modeling was used to investigate the effect of particle size distribution on the small strain shear stiffness of granular soils and explore the fundamental mechanism controlling this small strain shear stiffness at the particle level. The results indicate that the mean particle size has a negligible effect on the small strain shear modulus. The observed increase of the shear modulus with increasing particle size is caused by a scale effect. It is suggested that the ratio of sample size to the mean particle size should be larger than 11.5 to avoid this possible scale effect. At the same confining pressure and void ratio, the small strain shear modulus decreases as the coefficient of uniformity of the soil increases. The Poisson＇s ratio decreases with decreasing void ratio and increasing confining pressure instead of being constant as is commonly assumed. Microscopic analyses indicate that the small strain shear stiffness and Poisson＇s ratio depend uniquely on the soil＇s coordination number.
基金Supported by the National(Key)Basic Research and Development(973)Program of China(2015CB452802)Natrional Key Research and Development Program of China(2017YFC1501701)+3 种基金National Natural Science Foundation of China(41475102,41705020,and 41705120)China Meteorological Administration Special Public Welfare Research Fund(GYHY201406013)Guangdong Province Science and Technology Project(2015B020217001)Natural Science Foundation of Guangdong Province(2016A030313141)
文摘According to the statistical shape-slope （μ-A） relationship observed for the first time by several 2D-Video-Distro-meters （2DVD） in southern China, a constrained gamma （C-G） model was proposed for the retrieval of rain drop size distributions （DSDs） from Guangzhou S-band polarimetric radar observations. Two typical precipitation processes were selected to verify the accuracy of the retrieval scheme. The p-A relationship： A = 0.0241μ^2 ＋ 0.867μ ＋ 2.453 was obtained based on the 2DVD observation results from at Huizhou Longmen station, which is a very representat-ive location in the area. Relying on the Guangzhou polarimetric radar measurements of radar reflectivity （ZHH） and differential reflectivity （ZDR）, the gamma （F） size distribution parameters （No, μ, and A） can be retrieved by the C-G model retrieval scheme. The results show that the Guangzhou polarimetric radar retrievals of DSDs were close to the 2DVD observations at Guangzhou Maofengshan station. The rain rate, mass mean diameter, and normalized inter-cept parameter of radar retrievals were in good agreement with the 2DVD observations, and the relative errors were less than 10%. The overall accuracy of the retrieval scheme was high. The retrieval scheme has established the rela-tionship between the polarimetric radar measurements and gamma size distribution parameters. It will be helpful to in-depth research and application of the dual-polarization radar data in microphysical precipitation processes analysis, as well as convection-resolved numerical model data assimilation and prediction effect evaluation.
文摘Dispersive soils which occur in many parts of the world are easily erodible and segregate in water pose serious problems of stability of earth and earth retaining structures. The mechanism of dispersivity of soils is reasonably well understood. However there is simple method to identify the dispersivity of the soils and even more difficult to quantify the dispersivity. Visual classification, Atterberg’s limits and particle size analysis do not provide sufficient basis to differentiate between dispersive clays and ordinary erosion resistant clays. Pinhole test and double hydrometer test are the only two tests that are in vogue to identify the dispersive soils. This paper explores the possibility of using other standard tests such as shrinkage limit and unconfined compressive strength tests to quantify the dispersivity of the soils. The rationale of using the methods and correlation between the dispersivity determined by various methods has been explained. It has been concluded that dispersivity ascertained from strength tests is more reliable.
