Photocatalytic splitting of water over p-type semiconductors is a promising strategy for production of hydrogen.However,the determination of rate law is rarely reported.To this purpose,copper oxide(CuO)is selected as ...Photocatalytic splitting of water over p-type semiconductors is a promising strategy for production of hydrogen.However,the determination of rate law is rarely reported.To this purpose,copper oxide(CuO)is selected as a model photocathode in this study,and the photogenerated surface charge density,interfacial charge transfer rate constant and their relation to the water reduction rate(in terms of photocurrent)were investigated by a combination of(photo)electrochemical techniques.The results showed that the charge transfer rate constant is exponential-dependent on the surface charge density,and that the photocurrent equals to the product of the charge transfer rate constant and surface charge density.The reaction is first-order in terms of surface charge density.Such an unconventional rate law contrasts with the reports in literature.The charge density-dependent rate constant results from the Fermi level pinning(i.e.,Galvani potential is the main driving force for the reaction)due to accumulation of charge in the surface states and/or Frumkin behavior(i.e.,chemical potential is the main driving force).This study,therefore,may be helpful for further investigation on the mechanism of hydrogen evolution over a CuO photocathode and for designing more efficient CuO-based photocatalysts.展开更多
To satisfy the terminal position and impact angel constraints,an optimal guidance problem was discussed for homing missiles. For a stationary or a slowly moving target on the ground,an extended trajectory shaping guid...To satisfy the terminal position and impact angel constraints,an optimal guidance problem was discussed for homing missiles. For a stationary or a slowly moving target on the ground,an extended trajectory shaping guidance lawconsidering a first-order autopilot lag（ ETSG L-C FAL） was proposed. To derive the ETSG L-C FAL,a time-to-go- nth power weighted objection function was adopted and three different derivation methods were demonstrated while the Schwartz inequality method was mainly demonstrated.The performance of the ETSG L-C FAL and the ETSG L guidance laws was compared through simulation.Simulation results showthat although a first-order autopilot is introduced into the ETSG L-C FAL guidance system,the position miss distance and terminal impact angle error induced by the impact angle is zero for different guidance time.展开更多
This article is concerned with the pointwise error estimates for vanishing vis- cosity approximations to scalar convex conservation laws with boundary.By the weighted error function and a bootstrap extrapolation techn...This article is concerned with the pointwise error estimates for vanishing vis- cosity approximations to scalar convex conservation laws with boundary.By the weighted error function and a bootstrap extrapolation technique introduced by Tadmor-Tang,an optimal pointwise convergence rate is derived for the vanishing viscosity approximations to the initial-boundary value problem for scalar convex conservation laws,whose weak entropy solution is piecewise C 2 -smooth with interaction of elementary waves and the ...展开更多
The use of peat for the removal of nickel from aqueous solutions has been investigated at various pH values by means of static conditions. The present research shows that the ability of Ni to bind to peat increases as...The use of peat for the removal of nickel from aqueous solutions has been investigated at various pH values by means of static conditions. The present research shows that the ability of Ni to bind to peat increases as the pH value increases. The solutions reach adsorption equilibrium rapidly. A reasonable kinetic model, first-order in nickel concentration, has been developed and fitted to the adsorption of nickel （Ⅱ） onto peat. The first-order model provides a good correlation to the experimental data. The characteristic parameters of the Langmuir isotherm were determined at various temperatures. The relationship between kinetics and equilibrium isotherms was established through the forward- and backward-rate-constants, k~ and k2, and the equilibrium constant, K.展开更多
The classical power law relaxation, i.e. relaxation of current with inverse of power of time for a step-voltage excitation to dielectric—as popularly known as Curie-von Schweidler law is empirically derived and is ob...The classical power law relaxation, i.e. relaxation of current with inverse of power of time for a step-voltage excitation to dielectric—as popularly known as Curie-von Schweidler law is empirically derived and is observed in several relaxation experiments on various dielectrics studies since late 19th Century. This relaxation law is also regarded as “universal-law” for dielectric relaxations;and is also termed as power law. This empirical Curie-von Schewidler relaxation law is then used to derive fractional differential equations describing constituent expression for capacitor. In this paper, we give simple mathematical treatment to derive the distribution of relaxation rates of this Curie-von Schweidler law, and show that the relaxation rate follows Zipf’s power law distribution. We also show the method developed here give Zipfian power law distribution for relaxing time constants. Then we will show however mathematically correct this may be, but physical interpretation from the obtained time constants distribution are contradictory to the Zipfian rate relaxation distribution. In this paper, we develop possible explanation that as to why Zipfian distribution of relaxation rates appears for Curie-von Schweidler Law, and relate this law to time variant rate of relaxation. In this paper, we derive appearance of fractional derivative while using Zipfian power law distribution that gives notion of scale dependent relaxation rate function for Curie-von Schweidler relaxation phenomena. This paper gives analytical approach to get insight of a non-Debye relaxation and gives a new treatment to especially much used empirical Curie-von Schweidler (universal) relaxation law.展开更多
At high temperature rise rate, the mechanical properties of 10 # steel were determined experimentally in a very wide range of temperature and strain rates. A new constitutive relationship was put forward, which can fi...At high temperature rise rate, the mechanical properties of 10 # steel were determined experimentally in a very wide range of temperature and strain rates. A new constitutive relationship was put forward, which can fit with the experimental results and describe various phenomena observed in our experiments. Meanwhile, some interesting characteristics about the temperature rise rate, strain and strain rate hardening and thermal softening are also shown in this paper. Finally, the reliability of the constitutive law and the correctness of the constitutive parameters were verified by comparing the calculation results with the experimental data.展开更多
The two one-state-variable, rate- and state-dependent friction laws, i.e., the slip and slowness laws, are com- pared on the basis of dynamical behavior of a one-degree-of-freedom spring-slider model through numerical...The two one-state-variable, rate- and state-dependent friction laws, i.e., the slip and slowness laws, are com- pared on the basis of dynamical behavior of a one-degree-of-freedom spring-slider model through numerical simulations. Results show that two （normalized） model parameters, i.e., A （the normalized characteristic slip distance） and β-α （the difference in two normalized parameters of friction laws）, control the solutions. From given values of △, β, and α, for the slowness laws, the solution exists and the unique non-zero fixed point is stable when △〉（β-α）, yet not when △ 〈（β-α）. For the slip law, the solution exists for large ranges of model parameters and the number and stability of the non-zero fixed points change from one case to another. Results suggest that the slip law is more appropriate for controlling earthquake dynamics than the slowness law.展开更多
Sliding mode control(SMC) becomes a common tool in designing robust nonlinear control systems, due to its inherent characteristics such as insensitivity to system uncertainties and fast dynamic response.Two modes are ...Sliding mode control(SMC) becomes a common tool in designing robust nonlinear control systems, due to its inherent characteristics such as insensitivity to system uncertainties and fast dynamic response.Two modes are involved in the SMC operation, namely reaching mode and sliding mode.In the reaching mode, the system state is forced to reach the sliding surface in a finite time.The major drawback of the SMC approach is the occurrence of chattering in the sliding mode, which is undesirable in most applications.Generally, the trade-off between chattering reduction and fast reaching time must be considered in the conventional SMC design.This paper proposes SMC design with a novel reaching law called the exponential rate reaching law(ERRL) to reduce chattering, and the control structure of the converter is designed based on the multiinput SMC that is applied to a three-phase AC/DC power converter.The simulation and experimental results show the effectiveness of the proposed technique.展开更多
This paper calculates the potential GDP growth rates and the natural rates of unemployment in China using the dual decomposition of the simple Okun＇s law. The results show that every 1% increase in China＇s urban reg...This paper calculates the potential GDP growth rates and the natural rates of unemployment in China using the dual decomposition of the simple Okun＇s law. The results show that every 1% increase in China＇s urban registered unemployment rate leads to a 1.98% drop of GDP, the potential growth rate of GDP of China is about 10%, and the average natural rate of unemployment is about 3.2% in China in the past three decades. The paper finds that Olcun＇s law is still valid in China in the long run, but the Okun coefficient is about -3.79, overestimating the impact of the registered unemployment rate on GDP growth, and needs to be corrected based on China＇s dual economic structure.展开更多
In the paper,we get the precise results of Hájek-Rényi type inequalities for the partial sums of negatively orthant dependent sequences,which improve the results of Theorem 3.1and Corollary 3.2 in Kim(2006)a...In the paper,we get the precise results of Hájek-Rényi type inequalities for the partial sums of negatively orthant dependent sequences,which improve the results of Theorem 3.1and Corollary 3.2 in Kim(2006)and the strong law of large numbers and strong growth rate for negatively orthant dependent sequences.展开更多
A numerical model of hydraulic fracture propagation is introduced for a representative reservoir(Yuanba continental tight sandstone gas reservoir in Northeast Sichuan).Different parameters are considered,i.e.,the inte...A numerical model of hydraulic fracture propagation is introduced for a representative reservoir(Yuanba continental tight sandstone gas reservoir in Northeast Sichuan).Different parameters are considered,i.e.,the interlayer stress difference,the fracturing discharge rate and the fracturing fluid viscosity.The results show that these factors affect the gas and water production by influencing the fracture size.The interlayer stress difference can effectively control the fracture height.The greater the stress difference,the smaller the dimensionless reconstruction volume of the reservoir,while the flowback rate and gas production are lower.A large displacement fracturing construction increases the fracture-forming efficiency and expands the fracture size.The larger the displacement of fracturing construction,the larger the dimensionless reconstruction volume of the reservoir,and the higher the fracture-forming efficiency of fracturing fluid,the flowback rate,and the gas production.Low viscosity fracturing fluid is suitable for long fractures,while high viscosity fracturing fluid is suitable for wide fractures.With an increase in the fracturing fluid viscosity,the dimensionless reconstruction volume and flowback rate of the reservoir display a non-monotonic behavior,however,their changes are relatively small.展开更多
基金the National Basic Research Development of China(2011CB936003)the National Natural Science Foundation of China(50971116)。
文摘Photocatalytic splitting of water over p-type semiconductors is a promising strategy for production of hydrogen.However,the determination of rate law is rarely reported.To this purpose,copper oxide(CuO)is selected as a model photocathode in this study,and the photogenerated surface charge density,interfacial charge transfer rate constant and their relation to the water reduction rate(in terms of photocurrent)were investigated by a combination of(photo)electrochemical techniques.The results showed that the charge transfer rate constant is exponential-dependent on the surface charge density,and that the photocurrent equals to the product of the charge transfer rate constant and surface charge density.The reaction is first-order in terms of surface charge density.Such an unconventional rate law contrasts with the reports in literature.The charge density-dependent rate constant results from the Fermi level pinning(i.e.,Galvani potential is the main driving force for the reaction)due to accumulation of charge in the surface states and/or Frumkin behavior(i.e.,chemical potential is the main driving force).This study,therefore,may be helpful for further investigation on the mechanism of hydrogen evolution over a CuO photocathode and for designing more efficient CuO-based photocatalysts.
基金Supported by the National Natural Science Foundation of China(61172182)
文摘To satisfy the terminal position and impact angel constraints,an optimal guidance problem was discussed for homing missiles. For a stationary or a slowly moving target on the ground,an extended trajectory shaping guidance lawconsidering a first-order autopilot lag（ ETSG L-C FAL） was proposed. To derive the ETSG L-C FAL,a time-to-go- nth power weighted objection function was adopted and three different derivation methods were demonstrated while the Schwartz inequality method was mainly demonstrated.The performance of the ETSG L-C FAL and the ETSG L guidance laws was compared through simulation.Simulation results showthat although a first-order autopilot is introduced into the ETSG L-C FAL guidance system,the position miss distance and terminal impact angle error induced by the impact angle is zero for different guidance time.
基金supported by the NSF China#10571075NSF-Guangdong China#04010473+1 种基金The research of the second author was supported by Jinan University Foundation#51204033the Scientific Research Foundation for the Returned Overseas Chinese Scholars,State education Ministry#2005-383
文摘This article is concerned with the pointwise error estimates for vanishing vis- cosity approximations to scalar convex conservation laws with boundary.By the weighted error function and a bootstrap extrapolation technique introduced by Tadmor-Tang,an optimal pointwise convergence rate is derived for the vanishing viscosity approximations to the initial-boundary value problem for scalar convex conservation laws,whose weak entropy solution is piecewise C 2 -smooth with interaction of elementary waves and the ...
基金Projects [2006]331 supported by the Scientific Research Foundation for the Returned Overseas Chinese Scholars070712 by the Key Laboratory ofNuclear Resources and Environment,Ministry of Education of China
文摘The use of peat for the removal of nickel from aqueous solutions has been investigated at various pH values by means of static conditions. The present research shows that the ability of Ni to bind to peat increases as the pH value increases. The solutions reach adsorption equilibrium rapidly. A reasonable kinetic model, first-order in nickel concentration, has been developed and fitted to the adsorption of nickel （Ⅱ） onto peat. The first-order model provides a good correlation to the experimental data. The characteristic parameters of the Langmuir isotherm were determined at various temperatures. The relationship between kinetics and equilibrium isotherms was established through the forward- and backward-rate-constants, k~ and k2, and the equilibrium constant, K.
文摘The classical power law relaxation, i.e. relaxation of current with inverse of power of time for a step-voltage excitation to dielectric—as popularly known as Curie-von Schweidler law is empirically derived and is observed in several relaxation experiments on various dielectrics studies since late 19th Century. This relaxation law is also regarded as “universal-law” for dielectric relaxations;and is also termed as power law. This empirical Curie-von Schewidler relaxation law is then used to derive fractional differential equations describing constituent expression for capacitor. In this paper, we give simple mathematical treatment to derive the distribution of relaxation rates of this Curie-von Schweidler law, and show that the relaxation rate follows Zipf’s power law distribution. We also show the method developed here give Zipfian power law distribution for relaxing time constants. Then we will show however mathematically correct this may be, but physical interpretation from the obtained time constants distribution are contradictory to the Zipfian rate relaxation distribution. In this paper, we develop possible explanation that as to why Zipfian distribution of relaxation rates appears for Curie-von Schweidler Law, and relate this law to time variant rate of relaxation. In this paper, we derive appearance of fractional derivative while using Zipfian power law distribution that gives notion of scale dependent relaxation rate function for Curie-von Schweidler relaxation phenomena. This paper gives analytical approach to get insight of a non-Debye relaxation and gives a new treatment to especially much used empirical Curie-von Schweidler (universal) relaxation law.
基金The Laser Technology Field of National High Technology PlanKey-Grant of NNSF of China (No.19591180-4)
文摘At high temperature rise rate, the mechanical properties of 10 # steel were determined experimentally in a very wide range of temperature and strain rates. A new constitutive relationship was put forward, which can fit with the experimental results and describe various phenomena observed in our experiments. Meanwhile, some interesting characteristics about the temperature rise rate, strain and strain rate hardening and thermal softening are also shown in this paper. Finally, the reliability of the constitutive law and the correctness of the constitutive parameters were verified by comparing the calculation results with the experimental data.
基金supported by Academia Sinica (Taipei) and Science Council (Grant NSC96-2116-M-001-012-MY3).
文摘The two one-state-variable, rate- and state-dependent friction laws, i.e., the slip and slowness laws, are com- pared on the basis of dynamical behavior of a one-degree-of-freedom spring-slider model through numerical simulations. Results show that two （normalized） model parameters, i.e., A （the normalized characteristic slip distance） and β-α （the difference in two normalized parameters of friction laws）, control the solutions. From given values of △, β, and α, for the slowness laws, the solution exists and the unique non-zero fixed point is stable when △〉（β-α）, yet not when △ 〈（β-α）. For the slip law, the solution exists for large ranges of model parameters and the number and stability of the non-zero fixed points change from one case to another. Results suggest that the slip law is more appropriate for controlling earthquake dynamics than the slowness law.
文摘Sliding mode control(SMC) becomes a common tool in designing robust nonlinear control systems, due to its inherent characteristics such as insensitivity to system uncertainties and fast dynamic response.Two modes are involved in the SMC operation, namely reaching mode and sliding mode.In the reaching mode, the system state is forced to reach the sliding surface in a finite time.The major drawback of the SMC approach is the occurrence of chattering in the sliding mode, which is undesirable in most applications.Generally, the trade-off between chattering reduction and fast reaching time must be considered in the conventional SMC design.This paper proposes SMC design with a novel reaching law called the exponential rate reaching law(ERRL) to reduce chattering, and the control structure of the converter is designed based on the multiinput SMC that is applied to a three-phase AC/DC power converter.The simulation and experimental results show the effectiveness of the proposed technique.
文摘This paper calculates the potential GDP growth rates and the natural rates of unemployment in China using the dual decomposition of the simple Okun＇s law. The results show that every 1% increase in China＇s urban registered unemployment rate leads to a 1.98% drop of GDP, the potential growth rate of GDP of China is about 10%, and the average natural rate of unemployment is about 3.2% in China in the past three decades. The paper finds that Olcun＇s law is still valid in China in the long run, but the Okun coefficient is about -3.79, overestimating the impact of the registered unemployment rate on GDP growth, and needs to be corrected based on China＇s dual economic structure.
基金Foundation of Anhui Educational Committee(No.KJ2013Z225)
文摘In the paper,we get the precise results of Hájek-Rényi type inequalities for the partial sums of negatively orthant dependent sequences,which improve the results of Theorem 3.1and Corollary 3.2 in Kim(2006)and the strong law of large numbers and strong growth rate for negatively orthant dependent sequences.
文摘A numerical model of hydraulic fracture propagation is introduced for a representative reservoir(Yuanba continental tight sandstone gas reservoir in Northeast Sichuan).Different parameters are considered,i.e.,the interlayer stress difference,the fracturing discharge rate and the fracturing fluid viscosity.The results show that these factors affect the gas and water production by influencing the fracture size.The interlayer stress difference can effectively control the fracture height.The greater the stress difference,the smaller the dimensionless reconstruction volume of the reservoir,while the flowback rate and gas production are lower.A large displacement fracturing construction increases the fracture-forming efficiency and expands the fracture size.The larger the displacement of fracturing construction,the larger the dimensionless reconstruction volume of the reservoir,and the higher the fracture-forming efficiency of fracturing fluid,the flowback rate,and the gas production.Low viscosity fracturing fluid is suitable for long fractures,while high viscosity fracturing fluid is suitable for wide fractures.With an increase in the fracturing fluid viscosity,the dimensionless reconstruction volume and flowback rate of the reservoir display a non-monotonic behavior,however,their changes are relatively small.
