A simple and rapid dispersive liquid-liquid microextraction(DLLME)technique coupled with gas chromatography-ion trap mass spectrometry(GC-MS)was developed for the extraction and analysis of five endosulfan pesticides ...A simple and rapid dispersive liquid-liquid microextraction(DLLME)technique coupled with gas chromatography-ion trap mass spectrometry(GC-MS)was developed for the extraction and analysis of five endosulfan pesticides from the fish pond water.In this work,different parameters affecting the extraction process such as the type and volume of extraction solvent,type and volume of disperser solvent,and extraction time were studied and optimized.Under optimized conditions,the enrichment factor ranged from 189 to 269 and the relative recovery ranged from 88.5%to 94.9%.The linear range was 2.0-80.0 mg/L;the limits of detection and quantitation were in the range 0.04-1.06 mg/L and 0.12-3.53 mg/L,respectively.The relative standard deviations were in the range 0.94%-2.08%(n D 5).The obtained results show that DLLME combined with GC-MS is a fast and simple method for the determination of endosulfan pesticides in fish pond water.展开更多
Poultry production clusters (PPC) in Nong Khai raise layer chickens in the poultry houses constructed over fish ponds. Layer farmers use chicken manure to feed their fish. However, unbalance between chicken raising an...Poultry production clusters (PPC) in Nong Khai raise layer chickens in the poultry houses constructed over fish ponds. Layer farmers use chicken manure to feed their fish. However, unbalance between chicken raising and the size of fish pond or number of fish results in low water quality, which affects fish production and the community’s public water resource. In this field study, data was collected from layer farms in three poultry production clusters in Nong Khai province in the northeast of Thailand (a total of 90 farms) between April and August 2013. Data collected consisted of observations of dissolved oxygen (DO) values of water in the fish ponds, the number of egg-laying chickens raised above the fish ponds, the number of fish and size of the fish ponds. When all of these four observations were analyzed, mathematical equations for calculating the number of chickens raised, the number of fish per one rai (1600 m2), and the size of pond suitable for the number of chickens and fish were obtained as follows: 1) number of fish/rai = 5796 + 1097(size of pond) (R2 = 0.71), 2) number of chicken/rai = 513 + 223(size of pond) (R2 = 0.48) and 3) size of pond =-0.328474 + 0.000262(Fish) + 0.00117(Chicken) (R2 = 0.40). When pond = desired pond size, fish = number of fish to be raised and chicken = number of chickens to be raised.展开更多
文摘A simple and rapid dispersive liquid-liquid microextraction(DLLME)technique coupled with gas chromatography-ion trap mass spectrometry(GC-MS)was developed for the extraction and analysis of five endosulfan pesticides from the fish pond water.In this work,different parameters affecting the extraction process such as the type and volume of extraction solvent,type and volume of disperser solvent,and extraction time were studied and optimized.Under optimized conditions,the enrichment factor ranged from 189 to 269 and the relative recovery ranged from 88.5%to 94.9%.The linear range was 2.0-80.0 mg/L;the limits of detection and quantitation were in the range 0.04-1.06 mg/L and 0.12-3.53 mg/L,respectively.The relative standard deviations were in the range 0.94%-2.08%(n D 5).The obtained results show that DLLME combined with GC-MS is a fast and simple method for the determination of endosulfan pesticides in fish pond water.
文摘Poultry production clusters (PPC) in Nong Khai raise layer chickens in the poultry houses constructed over fish ponds. Layer farmers use chicken manure to feed their fish. However, unbalance between chicken raising and the size of fish pond or number of fish results in low water quality, which affects fish production and the community’s public water resource. In this field study, data was collected from layer farms in three poultry production clusters in Nong Khai province in the northeast of Thailand (a total of 90 farms) between April and August 2013. Data collected consisted of observations of dissolved oxygen (DO) values of water in the fish ponds, the number of egg-laying chickens raised above the fish ponds, the number of fish and size of the fish ponds. When all of these four observations were analyzed, mathematical equations for calculating the number of chickens raised, the number of fish per one rai (1600 m2), and the size of pond suitable for the number of chickens and fish were obtained as follows: 1) number of fish/rai = 5796 + 1097(size of pond) (R2 = 0.71), 2) number of chicken/rai = 513 + 223(size of pond) (R2 = 0.48) and 3) size of pond =-0.328474 + 0.000262(Fish) + 0.00117(Chicken) (R2 = 0.40). When pond = desired pond size, fish = number of fish to be raised and chicken = number of chickens to be raised.
