Transforming liquid flow fuel cells to controllable reactors for highlyefficient oxidation of 5-hydroxymethylfurfural to 2, 5-furandicarboxylic acid at low temperature

Highly-efficient oxidation of 5-hydroxymethylfurtural(HMF) to 2,5-furandicarboxylic acid(FDCA) at low temperature with air as the oxidant is still challenging.Herein,inspired by the respirato ry electron transport chain(ETC) of living cells mediated by electron carriers,we constructed artificial ETCs and transformed liquid flow fuel cells(LFFCs) to flexible reactors for efficient oxidation of HMF to produce FDCA under mild conditions.This LFFC reactor employed an electrodeposition modified nickel foam as an anode to promote HMF oxidation and(VO_(2))_(2)SO_(4) as a cathode electron carrier to facilitate the electron transfer to air.The reaction rate could be easily controlled by selecting the anode catalyst,adjusting the external loading and changing the cathodic electron carrier or oxidants.A maximal power density of 44.9 mW cm^(-2) at room temperature was achieved,while for FDCA production,short-circuit condition was preferred to achieve quick transfer of electrons.For a single batch operation with 0.1 M initial HMF,FDCA yield reached 97.1%.By fed-batch operation,FDCA concentration reached 144.5 g L^(-1) with a total yield of 96%.Ni^(2+)/Ni^(3+) redox couple was the active species mediating the electron transfer,while both experimental and DFT calculation results indicated that HMFCA pathway was the preferred reaction mechanism.

ENERGY CONSERVATION FOR THE WEAK SOLUTIONS TO THE 3D COMPRESSIBLE NEMATIC LIQUID CRYSTAL FLOW

In this paper,we establish some regularity conditions on the density and velocity fields to guarantee the energy conservation of the weak solutions for the three-dimensional compressible nematic liquid crystal flow in the periodic domain.

Simultaneous measurement of velocity profile and liquid film thickness in horizontal gas–liquid slug flow by using ultrasonic Doppler method

Horizontal gas-liquid two-phase flows widely exist in chemical engineering,oil/gas production and other important industrial processes.Slug flow pattern is the main form of horizontal gas-liquid flows and characterized by intermittent motion of film region and slug region.This work aims to develop the ultrasonic Doppler method to realize the simultaneous measurement of the velocity profile and liquid film thickness of slug flow.A single-frequency single-channel transducer is adopted in the design of the field-programmable gate array based ultrasonic Doppler system.A multiple echo repetition technology is used to improve the temporal-spatial resolution for the velocity profile.An experiment of horizontal gas-liquid two-phase flow is implemented in an acrylic pipe with an inner diameter of 20 mm.Considering the aerated characteristics of the liquid slug,slug flow is divided into low-aerated slug flow,high-aerated slug flow and pseudo slug flow.The temporal-spatial velocity distributions of the three kinds of slug flows are reconstructed by using the ultrasonic velocity profile measurement.The evolution characteristics of the average velocity profile in slug flows are investigated.A novel method is proposed to derive the liquid film thickness based on the instantaneous velocity profile.The liquid film thickness can be effectively measured by detecting the position and the size of the bubbles nearly below the elongated gas bubble.Compared with the time of flight method,the film thickness measured by the Doppler system shows a higher accuracy as a bubble layer occurs in the film region.The effect of the gas distribution on the film thickness is uncovered in three kinds of slug flows.

Numerical simulation of gas–liquid flow in the bubble column using Wray–Agarwal turbulence model coupled with population balance model

In this paper,an improved computational fluid dynamic(CFD)model for gas-liquid flow in bubble column was developed using the one-equation Wary-Agarwal(WA)turbulence model coupled with the population balance model(PBM).Through 18 orthogonal test cases,the optimal combination of interfacial force models,including drag force,lift force,turbulent dispersion force.The modified wall lubrication force model was proposed to improve the predictive ability for hydrodynamic behavior near the wall of the bubble column.The values simulated by optimized CFD model were in agreement with experimental data,and the errors were within±20%.In addition,the axial velocity,turbulent kinetic energy,bubble size distribution,and the dynamic characteristic of bubble plume were analyzed at different superficial gas velocities.This research work could provide a theoretical basis for the extension of the CFD-PBM coupled model to other multiphase reactors..

Multistate transition and coupled solid-liquid modeling of motion process of long-runout landslide

The recognition,repetition and prediction of the post-failure motion process of long-runout landslides are key scientific problems in the prevention and mitigation of geological disasters.In this study,a new numerical method involving LPF3D based on a multialgorithm and multiconstitutive model was proposed to simulate long-runout landslides with high precision and efficiency.The following results were obtained:(a)The motion process of landslides showed a steric effect with mobility,including gradual disintegration and spreading.The sliding mass can be divided into three states(dense,dilute and ultradilute)in the motion process,which can be solved by three dynamic regimes(friction,collision,and inertial);(b)Coupling simulation between the solid grain and liquid phases was achieved,focusing on drag force influences;(c)Different algorithms and constitutive models were employed in phase-state simulations.The volume fraction is an important indicator to distinguish different state types and solid‒liquid ratios.The flume experimental results were favorably validated against long-runout landslide case data;and(d)In this method,matched dynamic numerical modeling was developed to better capture the realistic motion process of long-runout landslides,and the advantages of continuum media and discrete media were combined to improve the computational accuracy and efficiency.This new method can reflect the realistic physical and mechanical processes in long-runout landslide motion and provide a suitable method for risk assessment and pre-failure prediction.

基于Flow-Simulation的气液分离器设计仿真分析研究

为解决燃气发电机组瓦斯气源含水量高的问题,对燃气发电机组气液分离器进行了设计与仿真分析。首先根据功能要求进行气液分离器设计参数计算,用Solidworks三维建模,然后利用Flow-Simulation进行CFD流体动力学仿真,得到气液分离器内的压力云图、速度云图和运动轨迹图;从压力云图中看出压力损失为784 Pa,能够满足压力损失≤1 kPa的要求。后经现场试验气液分离器分离效率达到93.6%,有效地提高了燃气发电机组的发电效率。该款设计优化后的旋风式气液分离器能够满足设计使用要求。

A Model on the Void Fraction in Liquid Slugs for Vertical Slug Flow

Aim To develop a hydrodynamic model on the void fraction in liquid slugs for gas liquid slug flow in vertical tubes. Methods Developing the model by considering the gas exchange between the Taylor bubble and the following liquid slug. Results Some experimental data are obtained to check the model. In comparison with previous published results, the predictions from this model are better and in good agreement with the experimental data. The error is within ±20%. Conclusion The proposed model can correctly predict the void fraction in liquid slugs for gas liquid two phase slug flow in vertical tubes.

Investigation of erosion behavior of 304 stainless steel under solid–liquid jet flow impinging at 30°

This work carried out liquid-solid two-phase jet experiments and simulations to study the erosion behavior of 304 stainless steel at 30° impingement.The single-phase impinging jet was simulated using dense grid by one-way coupling of solid phase due to its dilute distribution.The simulation results agreed well with experiments.It was found that after impinging particle attrition occurred and particles became round with decreasing length-ratio and particle breakage occurred along the "long" direction.Both experiment and simulations found that the erosion generated on the sample could be divided into three regions that were nominated as stagnant region,cutting transition region and wall jet region.Most particle-wall impacts were found to occur in the cutting transition region and the wall jet region.In the cutting transition region,holes and lip-shaped hogbacks were generated in the same direction as the flow imping.In the wall jet region,furrows and grooves were generated.The averaged grooves depth tended to become constant with the progress of impinging and reach the steady state of erosion in the end.In addition,it was found that impinging effect increased erosion and anti-wear rate.

Gas–liquid flow mass transfer in a T-shape microreactor stimulated with 1.7 MHz ultrasound waves

This paper describes the application of ultrasound waves on hydrodynamics and mass transfer characteristics in the gas–liquid flow in a T-shape microreactor with a diameter of 800 μm. A 1.7 MHz piezoelectric transducer(PZT) was employed to induce the vibration in this microreactor. Liquid side volumetric mass transfer coefficients were measured by physical and chemical methods of CO_2 absorption into water and Na OH solution. The approach of absorption of CO_2 into a 1 mol·L^(-1) Na OH solution was used for analysis of interfacial areas. With the help of a photography system, the fluid flow patterns inside the microreactor were analyzed. The effects of superficial liquid velocity, initial concentration of Na OH, superficial CO_2 gas velocity and length of microreactor on the mass transfer rate were investigated. The comparison between sonicated and plain microreactors(microreactor with and without ultrasound) shows that the ultrasound wave irradiation has a significant effect on kLa and interfacial area at various operational conditions. For the microreactor length of 12 cm, ultrasound waves improved kLa and interfacial area about 21% and 22%, respectively. From this study, it can be concluded that ultrasound wave irradiation in microreactor has a great effect on the mass transfer rate. This study suggests a new enhancement technique to establish high interfacial area and kLa in microreactors.

Experimental Investigation of Vibration Response of A Free-Hanging Flexible Riser Induced by Internal Gas-Liquid Slug Flow

The vibration response of a free-hanging flexible riser induced by internal gas-liquid slug flow was studied experimentally in a small-diameter tube model based on Froude number criterion. The flow regime in a curved riser model and the response displacements of the riser were simultaneously recorded by high speed cameras. The gas superficial velocity ranges from 0.1 m/s to 0.6 m/s while the liquid superficial velocity from 0.06 m/s to 0.3 m/s.Severe slugging type 3, unstable oscillation flow and relatively stable slug flow were observed in the considered flow rates. Severe slugging type 3 characterized by premature gas penetration occurs at relatively low flow rates. Both the cycle time and slug length become shorter as the gas flow rate increases. The pressure at the riser base undergoes a longer period and larger amplitude of fluctuation as compared with the other two flow regimes. Additionally, severe slugging leads to the most vigorous in-plane vibration. However, the responses in the vertical and horizontal directions are not synchronized. The vertical vibration is dominated by the second mode while the horizontal vibration is dominated by the first mode. Similar to the vortex-induced vibration, three branches are identified as initial branch, build-up branch and descending branch for the response versus the mixture velocity of gas-liquid flow.

LPS'S CRITERION FOR INCOMPRESSIBLE NEMATIC LIQUID CRYSTAL FLOWS

In this paper we derive LPS＇s criterion for the breakdown of classical solutions to the incompressible nematic liquid crystal flow, a simplified version of Ericksen-Leslie system modeling the hydrodynamic evolution of nematic liquid crystals in R^3. We show that if 0 〈 T 〈 ＋∞ is the maximal time interval for the unique smooth solution u ∈ C^∞（[0, T）,R^3）,then ｜u｜＋｜△d｜∈L^q（[0,T],L^p（R^3））,where p and q satisfy the Ladyzhenskaya-Prodi-Serrin＇s condition：3/p＋2/q=1 and p∈（3,＋∞].

SIMULATION OF TWO DIMENSIONAL LIQUID PHASE FLOW ON A DISTILLATION TRAY

A mathematical model describing the two dimensional liquid phase flow on a tray is presented, in which the k-ε model of turbulent flow was adopted with consideration of the rising vapor as a resisting force. The calculated results show that the theoretical prediction is in agreement with the experimental measurement.

EFFECT OF LIQUID FLOW ON PRIMARY ARM SPACING OF CONSTRAINED COLUMNAR CRYSTALS

An experimental apparatus,which has a convection generator and an aid-heater,is developed for the study of the effect of stable laminar liquid flow on the directional solidification process by the use of transparent alloy SCN-2wt-% Ace.The flow is perpendicular to primary arms. By in-situ observation and photographing at different specific moments,it has been found that such a flow can cause a great change in primary spacings of constrained columnar crystals:for cells,the spacings become smaller;but for dendrites,they become larger.The former is mainly due to the tilted growth of upstreamside branches,while the latter is mainly due to the coup- ling effect of liquid flow with solutal field around dendrite tips.The faster the liquid flows,the further smaller the cell spacing and the further larger the dendrite spacing.

Parametric study of gas−liquid two-phase flow field in horizontal stirred tank

Based on Fluent software,the gas−liquid two-phase flow in the horizontal stirred tank was simulated with SST k−ωturbulence model,Eulerian−Eulerian two-fluid model,and multi-reference flame method.The mixing process in the tank was calculated by tracer method.The results show that increasing the rotating speed or gas flow is conducive to a more uniform distribution of the gas phase and accelerates the mixing of the liquid phase.When the rotating speed exceeds 93 r/min,the relative power demand remains basically constant.The change in the inclination angle of the upper impeller has minimal effect on the gas phase distribution.When the inclination angle is 50°,the relative power demand reaches the maximum.An appropriate increase in the impeller distance from the bottom improves the gas holdup and gas phase distribution but increases the liquid phase mixing time.

Application of time–frequency entropy from wake oscillation to gas–liquid flow pattern identification

Gas–liquid two-phase flow abounds in industrial processes and facilities. Identification of its flow pattern plays an essential role in the field of multiphase flow measurement. A bluff body was introduced in this study to recognize gas–liquid flow patterns by inducing fluid oscillation that enlarged differences between each flow pattern. Experiments with air–water mixtures were carried out in horizontal pipelines at ambient temperature and atmospheric pressure. Differential pressure signals from the bluff-body wake were obtained in bubble, bubble/plug transitional, plug, slug, and annular flows. Utilizing the adaptive ensemble empirical mode decomposition method and the Hilbert transform, the time–frequency entropy S of the differential pressure signals was obtained. By combining S and other flow parameters, such as the volumetric void fraction β, the dryness x, the ratio of density φ and the modified fluid coefficient ψ, a new flow pattern map was constructed which adopted S（1–x）φ and （1–β）ψ as the vertical and horizontal coordinates, respectively. The overall rate of classification of the map was verified to be 92.9% by the experimental data. It provides an effective and simple solution to the gas–liquid flow pattern identification problems.

A mechanistic model of heat transfer for gas–liquid flow in vertical wellbore annuli

The most prominent aspect of multiphase flow is the variation in the physical distribution of the phases in the flow conduit known as the flow pattern. Several different flow patterns can exist under different flow conditions which have significant effects on liquid holdup, pressure gradient and heat transfer. Gas-liquid two-phase flow in an annulus can be found in a variety of practical situations. In high rate oil and gas production, it may be beneficial to flow fluids vertically through the annulus configuration between well tubing and casing. The flow patterns in annuli are different from pipe flow. There are both casing and tubing liquid films in slug flow and annular flow in the annulus. Multiphase heat transfer depends on the hydrodynamic behavior of the flow. There are very limited research results that can be found in the open literature for multiphase heat transfer in wellbore annuli. A mechanistic model of multiphase heat transfer is developed for different flow patterns of upward gas-liquid flow in vertical annuli. The required local flow parameters are predicted by use of the hydraulic model of steady-state multiphase flow in wellbore annuli recently developed by Yin et al. The modified heat-transfer model for single gas or liquid flow is verified by comparison with Manabe＇s experimental results. For different flow patterns, it is compared with modified unified Zhang et al. model based on representative diameters.

Measurement of Liquid Concentration Fields Near Interface with Cocurrent Gas-Liquid Flow Absorption Using Holographic Interferometry

Real-time laser holographic interferometry was applied to measure liquid concentrations of CO2 in the vicinity of gas-liquid free interface under the conditions of cocurrent gas-liquid flow for absorption of CO2 by ethanol. The influences of the Reynolds number on the measurable interface concentration and on the film thickness were discussed. The results show that CO2 concentration decreases exponentially along the mass transfer direction,and the concentration gradient increases as Reynolds number of either liquid or gas increases. CO2 concentrations fluctuate slightly along the direction of flow; on the whole, there is an increase in CO2 concentration. The investigation also demonstrated that film thickness decreases with the increase of Reynolds number of either of the two phases. Sherwood number representing the mass transfer coefficient was finally correlated as a function of the hydrodynamic parameters and the physical properties.

CFD simulation of effect of anode configuration on gas–liquid flow and alumina transport process in an aluminum reduction cell

Numerical simulations of gas–liquid two-phase flow and alumina transport process in an aluminum reduction cell were conducted to investigate the effects of anode configurations on the bath flow, gas volume fraction and alumina content distributions. An Euler–Euler two-fluid model was employed coupled with a species transport equation for alumina content. Three different anode configurations such as anode without a slot, anode with a longitudinal slot and anode with a transversal slot were studied in the simulation. The simulation results clearly show that the slots can reduce the bath velocity and promote the releasing of the anode gas, but can not contribute to the uniformity of the alumina content. Comparisons of the effects between the longitudinal and transversal slots indicate that the longitudinal slot is better in terms of gas–liquid flow but is disadvantageous for alumina mixing and transport process due to a decrease of anode gas under the anode bottom surface. It is demonstrated from the simulations that the mixing and transfer characteristics of alumina are controlled to great extent by the anode gas forces while the electromagnetic forces(EMFs) play the second role.

Two-flow model for piping erosion based on liquid-solid coupling

Previous studies have indicated that piping erosion greatly threatens the safe operation of various hydraulic structures. However, few mathematical models are available to perfectly describe the erosion process due to the complexity of piping. The focus of the present work is to propose a new fluid solid coupling model to eliminate the shortcomings of existing work. A 'pseudo-liquid' assumption is suggested to simulate the particle movement in the erosion process. Then, based on the mass and momentum conservations of the moving particles and flowing water, a new two-flow model is established by using the continuity equations and motion equations. In the model, the erosion rate of soil is determined with a particle erosion law derived from tests results of STERPI. And ERGUN's empirical equation is used to determine the interaction forces between the liquid and the solid. A numerical approach is proposed to solve the model with the finite volume method and SIMPLE algorithm. The new model is validated with the tests results of STERPI. And the soil erosion principles in piping are also explored.

Analysis of one-dimensional consolidation of soft soils with non-Darcian flow caused by non-Newtonian liquid

Based on non-Darcian flow caused by non-Newtonian liquid, the theory of one-dimensional (1D) consolidation was modified to consider variation in the total vertical stress with depth and time. The finite difference method (FDM) was adopted to obtain numerical solutions for excess pore water pressure and average degree of consolidation. When non-Darcian flow is degenerated into Darcian flow, a comparison between numerical solutions and analytical solutions was made to verify reliability of finite difference solutions. Finally, taking into account the ramp time-dependent loading, consolidation behaviors with non-Darcian flow under various parameters were analyzed. Thus, a comprehensive analysis of 1D consolidation combined with non-Darcian flow caused by non-Newtonian liquid was conducted in this paper.