In China, according to the relative up-to-date regulations and standards, the maincontrol measure for NOX emission of coal-fired power plants is, in principle, low NOXcombustion. However, in recent years, more and mor...In China, according to the relative up-to-date regulations and standards, the maincontrol measure for NOX emission of coal-fired power plants is, in principle, low NOXcombustion. However, in recent years, more and more newlyapproved coal-fired plantswere required to install flue gas denitrification equipment. This article expounds if fluegas denitrification is necessary from several aspects, including constitution of NOX, itsimpact to environment, operation ofdeNOXequipment in USA, as wellas the differencein ambient air quality standard between China and World Health Organization. It setsforth themes in urgent need of study and areas where deNOX equipment is necessaryfor new projects, besides a recommendation that the emission standards for thermalpowerplants should be revised as soon as possible in China.展开更多
A waste heat recovery and denitrification system was developed for improving energy conservation and emissions control especially for control of PM2.5 particles and haze. The system uses enhanced heat and mass transfe...A waste heat recovery and denitrification system was developed for improving energy conservation and emissions control especially for control of PM2.5 particles and haze. The system uses enhanced heat and mass transfer techniques in a packed heat exchange tower with self-rotation and zero-pressure spraying, low temperature NO oxidation by ozone, and neutralization with an alkali solution. Operating data in a test project gave NOx in the exhaust flue gas of less than 30 mg/Nm3 with an ozone addition rate of 8 kg/h and spray water p H of 7.5–8, an average heat recovery of 3 MW, and an average heat supply of 7.2 MW.展开更多
An ＂Oxygen-enriched＂ highly reactive absor- bent was prepared by mixing fly ash, lime and a small quantity of KMnO4 for simultaneous desulfiarization and denitrification. Removal of SO2 and NO simultaneously was car...An ＂Oxygen-enriched＂ highly reactive absor- bent was prepared by mixing fly ash, lime and a small quantity of KMnO4 for simultaneous desulfiarization and denitrification. Removal of SO2 and NO simultaneously was carried out using this absorbent in a flue gas circulating fluidized bed （CFB）. The highest simultaneous removal efficiency, 94.5% of SO2 and 64.2% of NO, was achieved under the optimal experiment conditions. Scanning Electron Microscope （SEM） and Accessory X-ray Energy Spectrometer （EDX） were used to observe the surface characteristics of fly ash, lime, ＂Oxygen-enriched＂ highly reactive absorbent and the spent absorbent. An ion chromatograph （IC） and chemical analysis methods were used to determine the contents of sulfate, sulfite, nitrate and nitrite in the spent absorbents, the results showed that sulfate and nitrite were the main products for desulfurization and denitrification respectively. The mechanism of removing SO2 and NO simultaneously was proposed based on the analysis results of SEM, EDX, IC and the chemical analysis methods.展开更多
Nitrogen oxides(NOx) from flue gas can be removed efficiently by activated carbon continuously irradiated by microwave,which,however,needs high temperature and consumes excessive carbon. If catalyst is added into acti...Nitrogen oxides(NOx) from flue gas can be removed efficiently by activated carbon continuously irradiated by microwave,which,however,needs high temperature and consumes excessive carbon. If catalyst is added into activated carbon,then reaction temperature can be reduced and selectivity of reaction enhanced. The effects on flue gas denitrification by adding different catalysts to microwave reactor were studied in this paper. It was found that the addition of catalyst could reduce the microwave power required by the same removal efficiency obviously;the difference of removal efficiency was different due to different catalysts,and the Cu-based catalyst has more catalytic action efficiency. Reaction temperature decreased by about 200℃ and removal efficiency increased by 25% after adding Cu-based catalyst. In addition,characteristic analysis for activated carbon conducted by X-ray diffraction confirmed that active component of catalyst existed on the surface of activated carbon.展开更多
文摘In China, according to the relative up-to-date regulations and standards, the maincontrol measure for NOX emission of coal-fired power plants is, in principle, low NOXcombustion. However, in recent years, more and more newlyapproved coal-fired plantswere required to install flue gas denitrification equipment. This article expounds if fluegas denitrification is necessary from several aspects, including constitution of NOX, itsimpact to environment, operation ofdeNOXequipment in USA, as wellas the differencein ambient air quality standard between China and World Health Organization. It setsforth themes in urgent need of study and areas where deNOX equipment is necessaryfor new projects, besides a recommendation that the emission standards for thermalpowerplants should be revised as soon as possible in China.
基金supported by the National Basic Research Program of China(Grant No.2013CB228301)
文摘A waste heat recovery and denitrification system was developed for improving energy conservation and emissions control especially for control of PM2.5 particles and haze. The system uses enhanced heat and mass transfer techniques in a packed heat exchange tower with self-rotation and zero-pressure spraying, low temperature NO oxidation by ozone, and neutralization with an alkali solution. Operating data in a test project gave NOx in the exhaust flue gas of less than 30 mg/Nm3 with an ozone addition rate of 8 kg/h and spray water p H of 7.5–8, an average heat recovery of 3 MW, and an average heat supply of 7.2 MW.
文摘An ＂Oxygen-enriched＂ highly reactive absor- bent was prepared by mixing fly ash, lime and a small quantity of KMnO4 for simultaneous desulfiarization and denitrification. Removal of SO2 and NO simultaneously was carried out using this absorbent in a flue gas circulating fluidized bed （CFB）. The highest simultaneous removal efficiency, 94.5% of SO2 and 64.2% of NO, was achieved under the optimal experiment conditions. Scanning Electron Microscope （SEM） and Accessory X-ray Energy Spectrometer （EDX） were used to observe the surface characteristics of fly ash, lime, ＂Oxygen-enriched＂ highly reactive absorbent and the spent absorbent. An ion chromatograph （IC） and chemical analysis methods were used to determine the contents of sulfate, sulfite, nitrate and nitrite in the spent absorbents, the results showed that sulfate and nitrite were the main products for desulfurization and denitrification respectively. The mechanism of removing SO2 and NO simultaneously was proposed based on the analysis results of SEM, EDX, IC and the chemical analysis methods.
基金supported by the National Natural Science Foundation of China (Grant No.50976035)
文摘Nitrogen oxides(NOx) from flue gas can be removed efficiently by activated carbon continuously irradiated by microwave,which,however,needs high temperature and consumes excessive carbon. If catalyst is added into activated carbon,then reaction temperature can be reduced and selectivity of reaction enhanced. The effects on flue gas denitrification by adding different catalysts to microwave reactor were studied in this paper. It was found that the addition of catalyst could reduce the microwave power required by the same removal efficiency obviously;the difference of removal efficiency was different due to different catalysts,and the Cu-based catalyst has more catalytic action efficiency. Reaction temperature decreased by about 200℃ and removal efficiency increased by 25% after adding Cu-based catalyst. In addition,characteristic analysis for activated carbon conducted by X-ray diffraction confirmed that active component of catalyst existed on the surface of activated carbon.
