A process to recover rare earth（RE） metals from spent fluid catalytic cracking（FCC） catalysts by solvent extraction was studied, using saponified 2-ethylhexyl phosphoric acid-2-ethylhexyl ester（EHEHPA or P507）. ...A process to recover rare earth（RE） metals from spent fluid catalytic cracking（FCC） catalysts by solvent extraction was studied, using saponified 2-ethylhexyl phosphoric acid-2-ethylhexyl ester（EHEHPA or P507）. The recovery process involved three steps：（1） leaching REs（mainly lanthanum and cerium）;（2） solvent extraction by applying saponified P507-kerosene system;（3） stripping. Experiments to assure optimal operating conditions were conducted. Results indicated that RE metals could be recovered effectively from spent catalyst with saponified P507-kerosene-HCl system. At room temperature of 25 oC, 10 g spent catalyst with 110 m L of HCl（1 mol/L） could achieve a leaching efficiency of 85%. For extraction, initial pH value of 3.17, organic/aqueous ratio（O/A ratio） of 2：1 with an extractants＇ saponification rate of 20% could obtain 100% efficiency. In the stripping process, 1 mol/L HCl with O/A ratio of 1：1 led to a stripping efficiency of 96%. In the present study, RE metals from spent FCC catalysts were effectively recovered, which avoided wasting a large amount of RE resources. It provides a theoretical support for commercial recycling of RE resources.展开更多
To investigate the gas-solid flow pattern of a combustor-style fluid catalytic cracking regenerator, a laboratory-scale regenerator was designed. In scaling down from an actual regenerator, large-diameter hydrodynamic...To investigate the gas-solid flow pattern of a combustor-style fluid catalytic cracking regenerator, a laboratory-scale regenerator was designed. In scaling down from an actual regenerator, large-diameter hydrodynamic effects were taken into consideration. These considerations are the novelties of the present study. Applying the Eulerian-Eulerian approach, a three-dimensional computational fluid dynamics （CFD） model of the regenerator was developed. Using this model, various aspects of the hydrodynamic behavior that are potentially effective in catalyst regeneration were investigated. The CFD simulation results show that at various sections the gas-solid flow patterns exhibit different behavior because of the asymmetric location of the catalyst inlets and the lift outlets. The ratio of the recirculated catalyst to spent catalyst determines the quality of the spent and recirculated catalyst mixing and distribution because the location and quality of vortices change in the lower part of the combustor. The simulation results show that recirculated catalyst considerably reduces the air bypass that disperses the catalyst particles widely over the cross section. Decreasing the velocity of superficial air produces a complex flow pattern whereas the variation in catalyst mass flux does not alter the flow pattern significantly as the flow is dilute.展开更多
基金Project supported by the National Key Basic Research Program of China(2012CBA01203)the Specialized Research Fund for Doctoral Programme of Higher Education of MOE of China(20130002110018)in the State Key Laboratory of Chemical Engineering of Tsinghua University
文摘A process to recover rare earth（RE） metals from spent fluid catalytic cracking（FCC） catalysts by solvent extraction was studied, using saponified 2-ethylhexyl phosphoric acid-2-ethylhexyl ester（EHEHPA or P507）. The recovery process involved three steps：（1） leaching REs（mainly lanthanum and cerium）;（2） solvent extraction by applying saponified P507-kerosene system;（3） stripping. Experiments to assure optimal operating conditions were conducted. Results indicated that RE metals could be recovered effectively from spent catalyst with saponified P507-kerosene-HCl system. At room temperature of 25 oC, 10 g spent catalyst with 110 m L of HCl（1 mol/L） could achieve a leaching efficiency of 85%. For extraction, initial pH value of 3.17, organic/aqueous ratio（O/A ratio） of 2：1 with an extractants＇ saponification rate of 20% could obtain 100% efficiency. In the stripping process, 1 mol/L HCl with O/A ratio of 1：1 led to a stripping efficiency of 96%. In the present study, RE metals from spent FCC catalysts were effectively recovered, which avoided wasting a large amount of RE resources. It provides a theoretical support for commercial recycling of RE resources.
文摘To investigate the gas-solid flow pattern of a combustor-style fluid catalytic cracking regenerator, a laboratory-scale regenerator was designed. In scaling down from an actual regenerator, large-diameter hydrodynamic effects were taken into consideration. These considerations are the novelties of the present study. Applying the Eulerian-Eulerian approach, a three-dimensional computational fluid dynamics （CFD） model of the regenerator was developed. Using this model, various aspects of the hydrodynamic behavior that are potentially effective in catalyst regeneration were investigated. The CFD simulation results show that at various sections the gas-solid flow patterns exhibit different behavior because of the asymmetric location of the catalyst inlets and the lift outlets. The ratio of the recirculated catalyst to spent catalyst determines the quality of the spent and recirculated catalyst mixing and distribution because the location and quality of vortices change in the lower part of the combustor. The simulation results show that recirculated catalyst considerably reduces the air bypass that disperses the catalyst particles widely over the cross section. Decreasing the velocity of superficial air produces a complex flow pattern whereas the variation in catalyst mass flux does not alter the flow pattern significantly as the flow is dilute.
