BACKGROUND The incidence of Barrett’s esophagus(BE)in China is lower compared to the Western populations.Hence,studies conducted in the Chinese population has been limited.The current treatment options available for ...BACKGROUND The incidence of Barrett’s esophagus(BE)in China is lower compared to the Western populations.Hence,studies conducted in the Chinese population has been limited.The current treatment options available for BE treatment includes argon plasma coagulation(APC),radiofrequency ablation and cryoablation,all with varying degrees of success.AIM To determine the efficacy and safety of HybridAPC in the treatment of BE.METHODS The study cohort consisted of patients with BE who underwent HybridAPC ablation treatment.These procedures were performed by seven endoscopists from different tertiary hospitals.The duration of the procedure,curative rate,complications and recurrent rate by 1-year follow-up were recorded.RESULTS Eighty individuals were enrolled for treatment from July 2017 to June 2020,comprising of 39 males and 41 females with a median age of 54 years(range,30 to 83 years).The technical success rate of HybridAPC was 100%and the overall curative rate was 98.15%.No severe complications occurred during the operation.BE cases were classified as short-segment BE and long-segment BE.Patients with short-segment BE were all considered cured without complications.Thirty-six patients completed the one-year follow-up without recurrence.Twenty-four percent had mild dysplasia which were all resolved with one post-procedural treatment.The mean duration of the procedure was 10.94±6.52 min.CONCLUSION Treatment of BE with HybridAPC was found to be a simple and quick procedure that is safe and effective during the short-term follow-up,especially in cases of short-segment BE.This technique could be considered as a feasible alternative ablation therapy for BE.展开更多
Cadmium sulfide(CdS)is an n-type semiconductor with excellent electrical conductivity that is widely used as an electron transport material(ETM)in solar cells.At present,numerous methods for preparing CdS thin films h...Cadmium sulfide(CdS)is an n-type semiconductor with excellent electrical conductivity that is widely used as an electron transport material(ETM)in solar cells.At present,numerous methods for preparing CdS thin films have emerged,among which magnetron sputtering(MS)is one of the most commonly used vacuum techniques.For this type of technique,the substrate temperature is one of the key deposition parameters that affects the interfacial properties between the target film and substrate,determining the specific growth habits of the films.Herein,the effect of substrate temperature on the microstructure and electrical properties of magnetron-sputtered CdS(MS-CdS)films was studied and applied for the first time in hydrothermally deposited antimony selenosulfide(Sb_(2)(S,Se)_(3))solar cells.Adjusting the substrate temperature not only results in the design of the flat and dense film with enhanced crystallinity but also leads to the formation of an energy level arrangement with a Sb_(2)(S,Se)_(3)layer that is more favorable for electron transfer.In addition,we developed an oxygen plasma treatment for CdS,reducing the parasitic absorption of the device and resulting in an increase in the short-circuit current density of the solar cell.This study demonstrates the feasibility of MS-CdS in the fabrication of hydrothermal Sb_(2)(S,Se)_(3)solar cells and provides interface optimization strategies to improve device performance.展开更多
This study investigated the effect of cold helium plasma treatment on seed germina- tion, growth and yield of wheat. The effects of different power of cold plasma on the germination of treated wheat seeds were studied...This study investigated the effect of cold helium plasma treatment on seed germina- tion, growth and yield of wheat. The effects of different power of cold plasma on the germination of treated wheat seeds were studied. We found that the treatment of 80 W could significantly improve seed germination potential (6.0%) and germination rate (6.7%) compared to the control group. Field experiments were carried out for wheat seeds treated with 80 W cold plasma. Com- pared with the control, plant height (20.3%), root length (9.0%) and fresh weight (21.8%) were improved significantly at seedling stage. At booting stage, plant height, root length, fresh weight, stem diameter, leaf area and leaf thickness of the treated plant were respectively increased by 21.8%, 11.0%, 7.0%, 9.0%, 13.0% and 25.5%. At the same time, the chlorophyll content (9.8%), nitrogen (10.0%) and moisture content (10.0%) were higher than those of the control, indicating that cold plasma treatment could promote the growth of wheat. The yield of treated wheat was 7.55 t-ha-1, 5.89% more than that of the control. Therefore, our results show that cold plasma has important application prospects for increasing wheat yield.展开更多
In the electrical discharge plasma process, various chemical and physical processes can participate in the removal of contaminants. In this paper, the chemical and physical processes that occur as a result of the elec...In the electrical discharge plasma process, various chemical and physical processes can participate in the removal of contaminants. In this paper, the chemical and physical processes that occur as a result of the electrical discharge plasma are reviewed, and their possible roles in the degradation of contaminants are discussed. Measurement methods for the quantification of important reactive species and their advantages and shortcomings are presented. Approaches on how to enhance the diffusion of the reactive species in solution are examined. In addition, the formation of typical reactive species in different electrical discharge plasma is compared.展开更多
Cold plasma technology was used to treat the surface of carbon fibers braided by PET in this paper and SEM was used to analyze the fracture microstructure of composite interlaminar shear stress (ILSS). The result show...Cold plasma technology was used to treat the surface of carbon fibers braided by PET in this paper and SEM was used to analyze the fracture microstructure of composite interlaminar shear stress (ILSS). The result shows that the surface polarity of carbon fibers was modified by cold plasma treatment, which increases the impregnation of PET braided carbon fibers during the process of resin flowing, improves the interfacial properties of RTM composites, and therefore enhances the mechanical properties of the KTM composites.展开更多
Catalysis and regeneration efficiency of granular activated carbon (GAC) and activated carbon fiber (ACF) were investigated in a non-equilibrium plasma water treatment reactor with a combination of pulsed streamer...Catalysis and regeneration efficiency of granular activated carbon (GAC) and activated carbon fiber (ACF) were investigated in a non-equilibrium plasma water treatment reactor with a combination of pulsed streamer discharge and GAC or ACF. The experimental results show that the degradation efficiency of methyl orange (MO) by the combined treatment can increase 22% (for GAC) and 24% (for ACF) respectively compared to pulsed discharge treatment alone, indicating that the combined treatment has a synergetic effect. The MO degradation efficiency by the combined treatment with pulsed discharge and saturated GAC or ACF can increase 12% and 17% respectively compared to pulsed discharge treatment alone. Both GAC and ACF show catalysis and the catalysis of ACF is prominent. Meanwhile, the regeneration of GAC and ACF are realized in this process. When H202 is introduced into the system, the utilization efficiency of ozone and ultraviolet light is improved and the regeneration efficiency of GAC and ACF is also increased.展开更多
An experiment and analysis on removal of gaseous benzene by pulse corona induced-plasma is presented in this article. Important parameters effecting removal efficiency have been investigated, such as pulse peak voltag...An experiment and analysis on removal of gaseous benzene by pulse corona induced-plasma is presented in this article. Important parameters effecting removal efficiency have been investigated, such as pulse peak voltage, pulse frequency, gas inlet concentration, gas flow rate and reactor temperature. The result shows that the removal efficiency increases with the increase in pulse peak voltage, pulse frequency and reactor temperature, but decreases in the rise of gas inlet concentration and gas flow rate. On the condition of Vp= 36 kV, f= 80 Hz, C=1440 mg/m3 and Q=640 ml/min, the largest removal efficiency is 98%. Finally, the reacted products are qualitatively analysed and the reaction processes are deduced in combination with plasma-chemistry theory.展开更多
Objective To determine the safety and efficacy of fresh frozen plasma (FFP) iniusion for the treat- ment of hereditary angioedema (FIAE). Methods The medical records of patients with HAE admitted to Peking Union ...Objective To determine the safety and efficacy of fresh frozen plasma (FFP) iniusion for the treat- ment of hereditary angioedema (FIAE). Methods The medical records of patients with HAE admitted to Peking Union Medical College Fiospital who had received FFP infusion during 2004 and 2010 were reviewed and PubMed database iFom 1966 to the present were searched using the following key words: hereditary angioedema and fresh frozen plasma. The patient's age, sex, body location of HAE attacks, the dose of FFP infusion, time of beginning to improvenaent, time to complete remission, complication, C 1 inhibitor activity, and outcome were analyzed. Results A total of 13 enrolled patients (7 male and 6 female) received 16 times of FFP infusion, in- cluding 2 patients undergoing FFP infusion in Peking Union Medical College Hospital and 11 patients re- ported in the literature. The mean dosage of FFP infusion was 586±337 mL. Two cases suffered from wors- ening abdominal pain and one case experienced skin rash. Only I patient had no improvement in symptom owing to transfusion related reaction. There was a definite improvement in symptom 49± 19 minutes after beginning FFP infusion. The remission time decreased from 61.7±27.0 hours to 3.3 (2.0, 12.0) hours after FFP infusion. FFP infusion was effective for both type I and type Ⅱ HAE. Conclusion FFP seems to be safe and effective for acute attacks of HAE.展开更多
In this study, commercial biaxially oriented polypropylene (BOPP), polyvinyl chlo- ride (PVC) and poly (methyl methacrylate) (PMMA) films were treated with nitrogen plasma over different exposure times in a Py...In this study, commercial biaxially oriented polypropylene (BOPP), polyvinyl chlo- ride (PVC) and poly (methyl methacrylate) (PMMA) films were treated with nitrogen plasma over different exposure times in a Pyrex tube surrounded by a DC variable magnetic field. The chemi- cal changes that appeared on the surface of the samples were investigated using Fourier transform infrared (FT4R) spectroscopy and attenuated total reflectance Fourier transform infrared (ATR- FTIR) spectroscopy after treatment for 2 min, 4 min and 6 rain in a nitrogen plasma chamber. Effects of the plasma treatment on the surface topographies and contact angles of the untreated and plasma treated films were also analyzed by atomic force microscopy (AFM) and a contact angle measuring system. The results show that the plasma treated films become more hydrophilic with an enhanced wettability due to the formation of some new polar groups on the surface of the treated films. Moreover, at higher exposure times, the total surface energy in all treated films increased while a reduction in contact angle occurred. The behavior of surface roughness in each sample was completely different at higher exposure times.展开更多
To reduce time and energy during thermal binder removal in the ceramic process, plasma surface treatment was applied before the lamination process.The adhesion strength in the lamination films was enhanced by oxidativ...To reduce time and energy during thermal binder removal in the ceramic process, plasma surface treatment was applied before the lamination process.The adhesion strength in the lamination films was enhanced by oxidative plasma treatment of the porous green ceramic film with polymeric binding materials.The oxygen plasma characteristics were investigated through experimental parameters and weight loss analysis.The experimental results revealed the need for parameter analysis,including gas material,process time,flow rate,and discharge power,and supported a mechanism consisting of competing ablation and deposition processes.The weight loss analysis was conducted for cyclic plasma treatment rather than continuous plasma treatment for the purpose of improving the film’s permeability by suppressing deposition of the ablated species.The cyclic plasma treatment improved the permeability compared to the continuous plasma treatment.展开更多
The soybean (Glycine max) Heihe No. 23 is sensitive to imbibitional chilling injury. Polyethylene glycol (PEG) treatment can improve chilling tolerance of soybean seeds to a certain extent. The changes of hydrolyt...The soybean (Glycine max) Heihe No. 23 is sensitive to imbibitional chilling injury. Polyethylene glycol (PEG) treatment can improve chilling tolerance of soybean seeds to a certain extent. The changes of hydrolytic ATPase in plasma membranes and H^+-pumping responses in soybean seeds were investigated during PEG treatments. Effects of exogenous calcium and exogenous ABA on the hydrolytic ATPase were also examined in order to understand the mechanism of chilling resistance. Highly purified plasma membranes were isolated by 6.0% aqueous two-phase partitioning from soybean seeds, as judged by the sensitivity of hydrolytic ATPase to sodium vanadate. PEG treatment resulted in a slight increase of the hydrolytic ATPase activity in 12 h. Then the activity decreased gradually, but still higher than the control. The H^+-pumping activity increased steadily during PEG treatment. Exogenous calcium had both activating and inhibiting effects on the hydrolytic ATPase, but the activity was inhibited in soybean seeds treated with exogenous ABA. Results suggested that PEG treatment, not the exogenous calcium and ABA, up-regulated H^+-ATPase activities in soybean seeds.展开更多
The 10%Ni/Al_2O_3 catalyst for partial oxidation of methane was treated byDBD (dielectric barrier discharge) plasma in a continuous system under atmospheric pressure and roomtemperature by flowing He. It was found tha...The 10%Ni/Al_2O_3 catalyst for partial oxidation of methane was treated byDBD (dielectric barrier discharge) plasma in a continuous system under atmospheric pressure and roomtemperature by flowing He. It was found that 10%Ni/Al_2O_3 catalyst treated by plasma presents ahigher catalytic activity and an enhanced stability than the catalysts prepared without plasmatreatment. The methane conversion over the catalyst treated by plasma is 3%-5% higher than thecatalysts untreated by plasma. Moreover, the enhanced dispersion of the catalyst can be achieved byplasma treatment, which can improve the interaction between active species and supports, catalyticactivity and the resistance to carbon deposition.展开更多
This paper presents the results of aluminum surface treatment by diffuse coplanar surface barrier discharge. The goals are to study the effectiveness of the plasma treatment and the dependence of its efficiency on ope...This paper presents the results of aluminum surface treatment by diffuse coplanar surface barrier discharge. The goals are to study the effectiveness of the plasma treatment and the dependence of its efficiency on operation parameters, such as sample-to-electrode distance, treatment time or gas atmosphere. Three types of aluminum materials (bricks, sheets and thin films) were tested to ensure the reliability of the treatment. The changes in the surface properties were characterized by the surface free energy, atomic force microscopy, attenuated total reflectance Fourier transform infrared spectroscopy (ATR FTIR) and X-ray photoelectron spec- troscopy (XPS). The influence of aging effect on the treatment was also measured and discussed.展开更多
Plasma treatment can be used to modify the structure of natural fibre like jute for a variety of applications. Environmentally friendly jute fibre was treated with argon and oxygen plasma. The treated samples were cha...Plasma treatment can be used to modify the structure of natural fibre like jute for a variety of applications. Environmentally friendly jute fibre was treated with argon and oxygen plasma. The treated samples were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and optical microscope. The macromolecular and microstructural changes in cellulose confirmed the change by plasma treatment. The XRD results confirmed that the crystal size and the crystallinity of the plasma treated fibre increased. Argon plasma treated fibre had a smooth and compact surface, compared to oxygen plasma treated fibre. The maximum stain (i.e. stress) concentrated in the oxygen plasma treated fibre. Optical micrographs showed the oxygen plasma treated fibre tended to rupture due to higher strain (i.e., stress) compared to fibre with argon plasma treatment. FTIR results also provided the evidence of change in the chemical constituents with plasma treatment.展开更多
A radio frequency argon plasma reactor with a stirrer was employed for the surface treatment of polypropylene (PP) powders. The changes in the superficial contact angle and the superficial composition of the un-trea...A radio frequency argon plasma reactor with a stirrer was employed for the surface treatment of polypropylene (PP) powders. The changes in the superficial contact angle and the superficial composition of the un-treated and treated PP powders were analyzed by means of water contact angle (WCA) measurement, X-ray photoelectron spectroscopy (XPS) and attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR). The water contact angle changed from the original value of 130.2° before plasma treatment to the value of 73.6° after treatment for 5 minutes. With the increase in plasma treating time, there were a decrease in the water contact angle and an increase in the content of oxygen containing polar functional groups (i.e., C-O, C=O and O-C=O). Both XPS and ATR-FTIR results indicated that the plasma treatment led to the formation of oxygen containing polar functional groups due to oxidation on the surface of the PP powders, and the trend of variation of the water contact angle with plasma treating time was related to the concentration of oxygen atom on the treated PP powders surface. Furthermore, the aging of the plasma-treated PP powders was investigated.展开更多
Natural cellulose was treated by an atmospheidc DBD plasma. The solubility of cellulose in a diluted alkaline solution after the plasma treatment was investigated. The properties were characterized by X-ray photoelect...Natural cellulose was treated by an atmospheidc DBD plasma. The solubility of cellulose in a diluted alkaline solution after the plasma treatment was investigated. The properties were characterized by X-ray photoelectron spectroscopy (XPS), Fourier-transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). The results indicated that the surface of cellulose treated by the argon DBD plasma was significantly etched, and the relevant force of hydrogen bonding was decreased. This might be the essential reason for the solubility improvement of natural cellulose in the diluted alkaline solution. Through a comparison of two discharge modes, the atmospheric DBD plasma gun and the parallel plate capacitively coupled DBD plasma, it was found that the atmospheric DBD plasma gun was more effective in fragmentizing the cellulose due to its production of a high energy plasma based on its special structure.展开更多
Air plasma spraying process was employed to fabricate various hydroxyapatite(HA)coatings on titanium substrates.The influence of processing parameters on the phase composition and the microstructure of the obtained co...Air plasma spraying process was employed to fabricate various hydroxyapatite(HA)coatings on titanium substrates.The influence of processing parameters on the phase composition and the microstructure of the obtained coatings was investigated.The effect of heat treatment on as-sprayed coating in terms of the crystallinity and microstructure was also studied.The phase composition of coatings was analyzed by X-ray diffraction(XRD)and FTIR.The surface and cross-section morphologies and microstructure of coatings as well as the morphology of feedstock were evaluated using scanning electron microscope(SEM).The crystallization temperature of amorphous HA phase in as-sprayed coating was examined by using differential thermal analysis(DTA). The results suggest that phase composition and microstructure of as-sprayed HA coatings strongly depend on the spraying parameters,and heat treatment at 760 ℃for 2 h is one of effective means for increasing the crystallinity and improvement in microstructure of as-sprayed HA coatings.展开更多
Microbial contamination induces surface deformations and strength degradation of cotton fabrics by invading deeply into the fibers. In this study, the sterilization effects of low pressure plasmas on bacteria-inoculat...Microbial contamination induces surface deformations and strength degradation of cotton fabrics by invading deeply into the fibers. In this study, the sterilization effects of low pressure plasmas on bacteria-inoculated cotton fabrics were investigated. Oxygen plasma treatment completely sterilized the cotton fabrics inoculated with various concentrations of staphylococcus aureus. Also, the influence of plasma treatment on physical properties of fabrics was examined. It was found that the plasma treatment did not affect ultimate tensile strength and surface morphology of the fabrics because it took advantage of relatively low plasma temperature.展开更多
HEREDITARY angioedema (HAE) is an autosomal dominant inherited condition which was initially described by Osier in 1888.1 Patients with HAE can develop rapid subcutaneous or submucosal edema involving the hands, fee...HEREDITARY angioedema (HAE) is an autosomal dominant inherited condition which was initially described by Osier in 1888.1 Patients with HAE can develop rapid subcutaneous or submucosal edema involving the hands, feet, limbs, face, intestinal tract, even larynx and trachea. The mortality of an acute attack of HAE without treatment was reported as high as 30%.2 HAE is caused by the deficiency of Cl esterase inhibitor (CIINH) which results in episodes of edema in parts of the human body,展开更多
Commercial carbon cloth(CC)is an ideal electrocatalysis material to produce oxygen evolution reaction(OER)due to its high conductive and 3D flexible structure,but the lacked active sites limit its application.For impr...Commercial carbon cloth(CC)is an ideal electrocatalysis material to produce oxygen evolution reaction(OER)due to its high conductive and 3D flexible structure,but the lacked active sites limit its application.For improving its OER performance,the present study proposed an effective method combining plasma and acid treatment to introduce oxygen-containing functional groups and produce more active sites on its surface.Compared to the pristine CC,the plasma and acid treated carbon cloth(PN-CC)delivers a reduced overpotential by 34.6%to achieve current density of 10 mA cm^(−2).The Tafel slope declines from 97.5 mV dec^(–1)(pristine CC)to 55.9 mV dec–1(PN-CC),showing an increased OER kinetic.Additionally,PN-CC electrocatalyst shows outstanding stability after 5000 cycles or 25000 s.The combination of plasma and acid treatment shows a significant potential in surface modification for electrocatalysts.展开更多
文摘BACKGROUND The incidence of Barrett’s esophagus(BE)in China is lower compared to the Western populations.Hence,studies conducted in the Chinese population has been limited.The current treatment options available for BE treatment includes argon plasma coagulation(APC),radiofrequency ablation and cryoablation,all with varying degrees of success.AIM To determine the efficacy and safety of HybridAPC in the treatment of BE.METHODS The study cohort consisted of patients with BE who underwent HybridAPC ablation treatment.These procedures were performed by seven endoscopists from different tertiary hospitals.The duration of the procedure,curative rate,complications and recurrent rate by 1-year follow-up were recorded.RESULTS Eighty individuals were enrolled for treatment from July 2017 to June 2020,comprising of 39 males and 41 females with a median age of 54 years(range,30 to 83 years).The technical success rate of HybridAPC was 100%and the overall curative rate was 98.15%.No severe complications occurred during the operation.BE cases were classified as short-segment BE and long-segment BE.Patients with short-segment BE were all considered cured without complications.Thirty-six patients completed the one-year follow-up without recurrence.Twenty-four percent had mild dysplasia which were all resolved with one post-procedural treatment.The mean duration of the procedure was 10.94±6.52 min.CONCLUSION Treatment of BE with HybridAPC was found to be a simple and quick procedure that is safe and effective during the short-term follow-up,especially in cases of short-segment BE.This technique could be considered as a feasible alternative ablation therapy for BE.
基金supported by the National Natural Science Foundation of China(22275180)the National Key Research and Development Program of China(2019YFA0405600)the Collaborative Innovation Program of Hefei Science Center,CAS,and the University Synergy Innovation Program of Anhui Province(GXXT-2023-031).
文摘Cadmium sulfide(CdS)is an n-type semiconductor with excellent electrical conductivity that is widely used as an electron transport material(ETM)in solar cells.At present,numerous methods for preparing CdS thin films have emerged,among which magnetron sputtering(MS)is one of the most commonly used vacuum techniques.For this type of technique,the substrate temperature is one of the key deposition parameters that affects the interfacial properties between the target film and substrate,determining the specific growth habits of the films.Herein,the effect of substrate temperature on the microstructure and electrical properties of magnetron-sputtered CdS(MS-CdS)films was studied and applied for the first time in hydrothermally deposited antimony selenosulfide(Sb_(2)(S,Se)_(3))solar cells.Adjusting the substrate temperature not only results in the design of the flat and dense film with enhanced crystallinity but also leads to the formation of an energy level arrangement with a Sb_(2)(S,Se)_(3)layer that is more favorable for electron transfer.In addition,we developed an oxygen plasma treatment for CdS,reducing the parasitic absorption of the device and resulting in an increase in the short-circuit current density of the solar cell.This study demonstrates the feasibility of MS-CdS in the fabrication of hydrothermal Sb_(2)(S,Se)_(3)solar cells and provides interface optimization strategies to improve device performance.
基金supported by Jiangsu Province Science and Technology Support Program of China(No.BE2013452)Main Direction Program of Knowledge Innovation of Chinese Academy of Sciences(No.KSCX-EW-B-6)
文摘This study investigated the effect of cold helium plasma treatment on seed germina- tion, growth and yield of wheat. The effects of different power of cold plasma on the germination of treated wheat seeds were studied. We found that the treatment of 80 W could significantly improve seed germination potential (6.0%) and germination rate (6.7%) compared to the control group. Field experiments were carried out for wheat seeds treated with 80 W cold plasma. Com- pared with the control, plant height (20.3%), root length (9.0%) and fresh weight (21.8%) were improved significantly at seedling stage. At booting stage, plant height, root length, fresh weight, stem diameter, leaf area and leaf thickness of the treated plant were respectively increased by 21.8%, 11.0%, 7.0%, 9.0%, 13.0% and 25.5%. At the same time, the chlorophyll content (9.8%), nitrogen (10.0%) and moisture content (10.0%) were higher than those of the control, indicating that cold plasma treatment could promote the growth of wheat. The yield of treated wheat was 7.55 t-ha-1, 5.89% more than that of the control. Therefore, our results show that cold plasma has important application prospects for increasing wheat yield.
基金funded by National Natural Science Foundation of China (Nos. 51608448 and 21737003)Young Talent Cultivation Scheme Funding of Northwest A&F University (No. Z109021802)the Fundamental Research Funds for the Central Universities (No. Z109021617) for their financial support in this research
文摘In the electrical discharge plasma process, various chemical and physical processes can participate in the removal of contaminants. In this paper, the chemical and physical processes that occur as a result of the electrical discharge plasma are reviewed, and their possible roles in the degradation of contaminants are discussed. Measurement methods for the quantification of important reactive species and their advantages and shortcomings are presented. Approaches on how to enhance the diffusion of the reactive species in solution are examined. In addition, the formation of typical reactive species in different electrical discharge plasma is compared.
文摘Cold plasma technology was used to treat the surface of carbon fibers braided by PET in this paper and SEM was used to analyze the fracture microstructure of composite interlaminar shear stress (ILSS). The result shows that the surface polarity of carbon fibers was modified by cold plasma treatment, which increases the impregnation of PET braided carbon fibers during the process of resin flowing, improves the interfacial properties of RTM composites, and therefore enhances the mechanical properties of the KTM composites.
基金National Natural Science Foundation of China(Nos.20576079,20776159)
文摘Catalysis and regeneration efficiency of granular activated carbon (GAC) and activated carbon fiber (ACF) were investigated in a non-equilibrium plasma water treatment reactor with a combination of pulsed streamer discharge and GAC or ACF. The experimental results show that the degradation efficiency of methyl orange (MO) by the combined treatment can increase 22% (for GAC) and 24% (for ACF) respectively compared to pulsed discharge treatment alone, indicating that the combined treatment has a synergetic effect. The MO degradation efficiency by the combined treatment with pulsed discharge and saturated GAC or ACF can increase 12% and 17% respectively compared to pulsed discharge treatment alone. Both GAC and ACF show catalysis and the catalysis of ACF is prominent. Meanwhile, the regeneration of GAC and ACF are realized in this process. When H202 is introduced into the system, the utilization efficiency of ozone and ultraviolet light is improved and the regeneration efficiency of GAC and ACF is also increased.
基金The project supported by the Dean Foundation of Research Institute of Chemical Defence
文摘An experiment and analysis on removal of gaseous benzene by pulse corona induced-plasma is presented in this article. Important parameters effecting removal efficiency have been investigated, such as pulse peak voltage, pulse frequency, gas inlet concentration, gas flow rate and reactor temperature. The result shows that the removal efficiency increases with the increase in pulse peak voltage, pulse frequency and reactor temperature, but decreases in the rise of gas inlet concentration and gas flow rate. On the condition of Vp= 36 kV, f= 80 Hz, C=1440 mg/m3 and Q=640 ml/min, the largest removal efficiency is 98%. Finally, the reacted products are qualitatively analysed and the reaction processes are deduced in combination with plasma-chemistry theory.
文摘Objective To determine the safety and efficacy of fresh frozen plasma (FFP) iniusion for the treat- ment of hereditary angioedema (FIAE). Methods The medical records of patients with HAE admitted to Peking Union Medical College Fiospital who had received FFP infusion during 2004 and 2010 were reviewed and PubMed database iFom 1966 to the present were searched using the following key words: hereditary angioedema and fresh frozen plasma. The patient's age, sex, body location of HAE attacks, the dose of FFP infusion, time of beginning to improvenaent, time to complete remission, complication, C 1 inhibitor activity, and outcome were analyzed. Results A total of 13 enrolled patients (7 male and 6 female) received 16 times of FFP infusion, in- cluding 2 patients undergoing FFP infusion in Peking Union Medical College Hospital and 11 patients re- ported in the literature. The mean dosage of FFP infusion was 586±337 mL. Two cases suffered from wors- ening abdominal pain and one case experienced skin rash. Only I patient had no improvement in symptom owing to transfusion related reaction. There was a definite improvement in symptom 49± 19 minutes after beginning FFP infusion. The remission time decreased from 61.7±27.0 hours to 3.3 (2.0, 12.0) hours after FFP infusion. FFP infusion was effective for both type I and type Ⅱ HAE. Conclusion FFP seems to be safe and effective for acute attacks of HAE.
文摘In this study, commercial biaxially oriented polypropylene (BOPP), polyvinyl chlo- ride (PVC) and poly (methyl methacrylate) (PMMA) films were treated with nitrogen plasma over different exposure times in a Pyrex tube surrounded by a DC variable magnetic field. The chemi- cal changes that appeared on the surface of the samples were investigated using Fourier transform infrared (FT4R) spectroscopy and attenuated total reflectance Fourier transform infrared (ATR- FTIR) spectroscopy after treatment for 2 min, 4 min and 6 rain in a nitrogen plasma chamber. Effects of the plasma treatment on the surface topographies and contact angles of the untreated and plasma treated films were also analyzed by atomic force microscopy (AFM) and a contact angle measuring system. The results show that the plasma treated films become more hydrophilic with an enhanced wettability due to the formation of some new polar groups on the surface of the treated films. Moreover, at higher exposure times, the total surface energy in all treated films increased while a reduction in contact angle occurred. The behavior of surface roughness in each sample was completely different at higher exposure times.
基金supported by Basic Science Research Program through the National Research Foundation of Korea(NRF) funded by the Ministry of Education, Science and Technology(2011-0013211).
文摘To reduce time and energy during thermal binder removal in the ceramic process, plasma surface treatment was applied before the lamination process.The adhesion strength in the lamination films was enhanced by oxidative plasma treatment of the porous green ceramic film with polymeric binding materials.The oxygen plasma characteristics were investigated through experimental parameters and weight loss analysis.The experimental results revealed the need for parameter analysis,including gas material,process time,flow rate,and discharge power,and supported a mechanism consisting of competing ablation and deposition processes.The weight loss analysis was conducted for cyclic plasma treatment rather than continuous plasma treatment for the purpose of improving the film’s permeability by suppressing deposition of the ablated species.The cyclic plasma treatment improved the permeability compared to the continuous plasma treatment.
基金Supported by the National Natural Science Foundation of China (Grant No. 30170100)
文摘The soybean (Glycine max) Heihe No. 23 is sensitive to imbibitional chilling injury. Polyethylene glycol (PEG) treatment can improve chilling tolerance of soybean seeds to a certain extent. The changes of hydrolytic ATPase in plasma membranes and H^+-pumping responses in soybean seeds were investigated during PEG treatments. Effects of exogenous calcium and exogenous ABA on the hydrolytic ATPase were also examined in order to understand the mechanism of chilling resistance. Highly purified plasma membranes were isolated by 6.0% aqueous two-phase partitioning from soybean seeds, as judged by the sensitivity of hydrolytic ATPase to sodium vanadate. PEG treatment resulted in a slight increase of the hydrolytic ATPase activity in 12 h. Then the activity decreased gradually, but still higher than the control. The H^+-pumping activity increased steadily during PEG treatment. Exogenous calcium had both activating and inhibiting effects on the hydrolytic ATPase, but the activity was inhibited in soybean seeds treated with exogenous ABA. Results suggested that PEG treatment, not the exogenous calcium and ABA, up-regulated H^+-ATPase activities in soybean seeds.
基金This work was supported by National Science Foundation Committee of China (Grant number 20106013).
文摘The 10%Ni/Al_2O_3 catalyst for partial oxidation of methane was treated byDBD (dielectric barrier discharge) plasma in a continuous system under atmospheric pressure and roomtemperature by flowing He. It was found that 10%Ni/Al_2O_3 catalyst treated by plasma presents ahigher catalytic activity and an enhanced stability than the catalysts prepared without plasmatreatment. The methane conversion over the catalyst treated by plasma is 3%-5% higher than thecatalysts untreated by plasma. Moreover, the enhanced dispersion of the catalyst can be achieved byplasma treatment, which can improve the interaction between active species and supports, catalyticactivity and the resistance to carbon deposition.
基金supported by the Czech Science Foundation(Project No.104/08/02290)
文摘This paper presents the results of aluminum surface treatment by diffuse coplanar surface barrier discharge. The goals are to study the effectiveness of the plasma treatment and the dependence of its efficiency on operation parameters, such as sample-to-electrode distance, treatment time or gas atmosphere. Three types of aluminum materials (bricks, sheets and thin films) were tested to ensure the reliability of the treatment. The changes in the surface properties were characterized by the surface free energy, atomic force microscopy, attenuated total reflectance Fourier transform infrared spectroscopy (ATR FTIR) and X-ray photoelectron spec- troscopy (XPS). The influence of aging effect on the treatment was also measured and discussed.
文摘Plasma treatment can be used to modify the structure of natural fibre like jute for a variety of applications. Environmentally friendly jute fibre was treated with argon and oxygen plasma. The treated samples were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and optical microscope. The macromolecular and microstructural changes in cellulose confirmed the change by plasma treatment. The XRD results confirmed that the crystal size and the crystallinity of the plasma treated fibre increased. Argon plasma treated fibre had a smooth and compact surface, compared to oxygen plasma treated fibre. The maximum stain (i.e. stress) concentrated in the oxygen plasma treated fibre. Optical micrographs showed the oxygen plasma treated fibre tended to rupture due to higher strain (i.e., stress) compared to fibre with argon plasma treatment. FTIR results also provided the evidence of change in the chemical constituents with plasma treatment.
文摘A radio frequency argon plasma reactor with a stirrer was employed for the surface treatment of polypropylene (PP) powders. The changes in the superficial contact angle and the superficial composition of the un-treated and treated PP powders were analyzed by means of water contact angle (WCA) measurement, X-ray photoelectron spectroscopy (XPS) and attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR). The water contact angle changed from the original value of 130.2° before plasma treatment to the value of 73.6° after treatment for 5 minutes. With the increase in plasma treating time, there were a decrease in the water contact angle and an increase in the content of oxygen containing polar functional groups (i.e., C-O, C=O and O-C=O). Both XPS and ATR-FTIR results indicated that the plasma treatment led to the formation of oxygen containing polar functional groups due to oxidation on the surface of the PP powders, and the trend of variation of the water contact angle with plasma treating time was related to the concentration of oxygen atom on the treated PP powders surface. Furthermore, the aging of the plasma-treated PP powders was investigated.
基金Beijing Natural Science Foundation of China(No.2063026)
文摘Natural cellulose was treated by an atmospheidc DBD plasma. The solubility of cellulose in a diluted alkaline solution after the plasma treatment was investigated. The properties were characterized by X-ray photoelectron spectroscopy (XPS), Fourier-transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). The results indicated that the surface of cellulose treated by the argon DBD plasma was significantly etched, and the relevant force of hydrogen bonding was decreased. This might be the essential reason for the solubility improvement of natural cellulose in the diluted alkaline solution. Through a comparison of two discharge modes, the atmospheric DBD plasma gun and the parallel plate capacitively coupled DBD plasma, it was found that the atmospheric DBD plasma gun was more effective in fragmentizing the cellulose due to its production of a high energy plasma based on its special structure.
文摘Air plasma spraying process was employed to fabricate various hydroxyapatite(HA)coatings on titanium substrates.The influence of processing parameters on the phase composition and the microstructure of the obtained coatings was investigated.The effect of heat treatment on as-sprayed coating in terms of the crystallinity and microstructure was also studied.The phase composition of coatings was analyzed by X-ray diffraction(XRD)and FTIR.The surface and cross-section morphologies and microstructure of coatings as well as the morphology of feedstock were evaluated using scanning electron microscope(SEM).The crystallization temperature of amorphous HA phase in as-sprayed coating was examined by using differential thermal analysis(DTA). The results suggest that phase composition and microstructure of as-sprayed HA coatings strongly depend on the spraying parameters,and heat treatment at 760 ℃for 2 h is one of effective means for increasing the crystallinity and improvement in microstructure of as-sprayed HA coatings.
基金Iran National Science Foundation(INSF) for providing grant of members
文摘Microbial contamination induces surface deformations and strength degradation of cotton fabrics by invading deeply into the fibers. In this study, the sterilization effects of low pressure plasmas on bacteria-inoculated cotton fabrics were investigated. Oxygen plasma treatment completely sterilized the cotton fabrics inoculated with various concentrations of staphylococcus aureus. Also, the influence of plasma treatment on physical properties of fabrics was examined. It was found that the plasma treatment did not affect ultimate tensile strength and surface morphology of the fabrics because it took advantage of relatively low plasma temperature.
文摘HEREDITARY angioedema (HAE) is an autosomal dominant inherited condition which was initially described by Osier in 1888.1 Patients with HAE can develop rapid subcutaneous or submucosal edema involving the hands, feet, limbs, face, intestinal tract, even larynx and trachea. The mortality of an acute attack of HAE without treatment was reported as high as 30%.2 HAE is caused by the deficiency of Cl esterase inhibitor (CIINH) which results in episodes of edema in parts of the human body,
基金by Shenzhen Science and Technology Innovation Committee(No.JCYJ20180507182200750)。
文摘Commercial carbon cloth(CC)is an ideal electrocatalysis material to produce oxygen evolution reaction(OER)due to its high conductive and 3D flexible structure,but the lacked active sites limit its application.For improving its OER performance,the present study proposed an effective method combining plasma and acid treatment to introduce oxygen-containing functional groups and produce more active sites on its surface.Compared to the pristine CC,the plasma and acid treated carbon cloth(PN-CC)delivers a reduced overpotential by 34.6%to achieve current density of 10 mA cm^(−2).The Tafel slope declines from 97.5 mV dec^(–1)(pristine CC)to 55.9 mV dec–1(PN-CC),showing an increased OER kinetic.Additionally,PN-CC electrocatalyst shows outstanding stability after 5000 cycles or 25000 s.The combination of plasma and acid treatment shows a significant potential in surface modification for electrocatalysts.