Cationic fluorinated acrylate latex was prepared via semi-continuous emulsion copolymerization of cationic monomer and other monomers. The resultant latex and its film were characterized with dynamic light scattering ...Cationic fluorinated acrylate latex was prepared via semi-continuous emulsion copolymerization of cationic monomer and other monomers. The resultant latex and its film were characterized with dynamic light scattering detector and contact angle meter. Influences of amount of DMDAAC on the properties of resultant latex and its film were investigated in detail. Results show that the particle size of the latex has the minimum value knd the zeta potential of the latex is increased when the amount of DMDAAC is increased. In addition, the particle size of the latex is unimodal distribution when the amount of DMDAAC is not more than 2.5%. However, the particle size of the latex is bimodal distribution when the amount of DMDAAC is more than 2.5%. The contact angle is varied slightly with the increase of amount of DMDAAC when it is not more than 2.5%. Nevertheless, the contact angle is decreased with the increase of the amount of DMDAAC when it is more than 2.5%.展开更多
Novel self cross-linking fluorinated acrylic latex（SCLFAL） has been successfully prepared via starved seeded semi-batch emulsion polymerization.The resultant SCLFAL is characterized by Fourier transform infrared（F...Novel self cross-linking fluorinated acrylic latex（SCLFAL） has been successfully prepared via starved seeded semi-batch emulsion polymerization.The resultant SCLFAL is characterized by Fourier transform infrared（FTIR） spectrometry.Contact angle （CA） and glass transition temperature（T_g） of the film are investigated.Results show that CA and T_g of the film can be improved when the moderate amount of HPMA is introduced into the mixed monomers.展开更多
基金supported by the Science and Technology Department of Zhejiang Province under Grant No. 2010C31040the financial support of Zhejiang Provincial Natural Science Foundation of China(No. Y4100152)Zhejiang University of Technology Natural Science Foundation(No.20100202)
文摘Cationic fluorinated acrylate latex was prepared via semi-continuous emulsion copolymerization of cationic monomer and other monomers. The resultant latex and its film were characterized with dynamic light scattering detector and contact angle meter. Influences of amount of DMDAAC on the properties of resultant latex and its film were investigated in detail. Results show that the particle size of the latex has the minimum value knd the zeta potential of the latex is increased when the amount of DMDAAC is increased. In addition, the particle size of the latex is unimodal distribution when the amount of DMDAAC is not more than 2.5%. However, the particle size of the latex is bimodal distribution when the amount of DMDAAC is more than 2.5%. The contact angle is varied slightly with the increase of amount of DMDAAC when it is not more than 2.5%. Nevertheless, the contact angle is decreased with the increase of the amount of DMDAAC when it is more than 2.5%.
基金supported by the Science and Technology Department of Zhejiang Province under Grant No. 2010C31040.In additionthe financial support of Zhejiang Provincial Natural Science Foundation of China(No. Y4100152)
文摘Novel self cross-linking fluorinated acrylic latex（SCLFAL） has been successfully prepared via starved seeded semi-batch emulsion polymerization.The resultant SCLFAL is characterized by Fourier transform infrared（FTIR） spectrometry.Contact angle （CA） and glass transition temperature（T_g） of the film are investigated.Results show that CA and T_g of the film can be improved when the moderate amount of HPMA is introduced into the mixed monomers.
