Polyimide matrix composites interpenetrated with foamed copper were prepared via pressure impregnation and vacuum immersion to focus on their thermostability, mechanical and tribological behaviors as sliding electrica...Polyimide matrix composites interpenetrated with foamed copper were prepared via pressure impregnation and vacuum immersion to focus on their thermostability, mechanical and tribological behaviors as sliding electrical contact materials. The results show that the interpenetrating phase composites（IPC） are very heat-resistant and exhibit higher hardness as well as bending strength, when compared with homologous polyimide matrix composites without foamed copper. Sliding electrical contact property of the materials is also remarkably improved, from the point of contact voltage drops. Moreover, it is believed that fatigue wear is the main mechanism involved, along with slight abrasive wear and oxidation wear. The better abrasive resistance of the IPC under different testing conditions was detected, which was mainly attributed to the successful hybrid of foamed copper and polyimide.展开更多
The effects of copper content on the microstructural and mechanical properties of steel foams are investigated. Spherical urea granules, used as a water-leachable space holder, were coated with a mixture of iron, ultr...The effects of copper content on the microstructural and mechanical properties of steel foams are investigated. Spherical urea granules, used as a water-leachable space holder, were coated with a mixture of iron, ultrafine carbon, and different amounts of copper powders. After the mixture was compacted and the space holder was removed by leaching, a sintering process was performed under an atmosphere of thermally dissociated ammonia. Microstructural evaluations of the cell walls were carried out using optical microscopy and scanning electron microscopy in conjunction with energy-dispersive X-ray spectroscopy. In addition, compression tests were conducted to investigate the mechanical properties of the manufactured steel foams. The results showed that the total porosity decreases from 77.2% to 71.9% with increasing copper content in the steel foams. In the foams' microstructure, copper islands are mostly distributed in pearlite and intergranular carbide phases are formed in the grain boundaries. When the copper content was increased from 0 to 4 wt%, the elastic modulus, plateau stress, fracture stress, and fracture strain of manufactured steel foams improved 4.5, 6, 6.4, and 2.5 times, respectively.展开更多
Using forming-knitting technology and organic materials, copper foam with high porosity (>80%) and open-pore structure was successfully prepared. According to the method of immersion, the technical characteristics ...Using forming-knitting technology and organic materials, copper foam with high porosity (>80%) and open-pore structure was successfully prepared. According to the method of immersion, the technical characteristics of metal paste performance and influence factors of sinter process were discussed. The pore morphology and compressibility of copper foam were detected simultaneously, and the structural property of copper foam prepared by the process of once-infiltrating was compared with the one of copper foam prepared by the process of twice-infiltrating. The results show that pH value of metal paste has a large influence on rheological properties of slurry. By twice-infiltrating process, the microstructure of copper foam was altered. In case of the porosity dropping indistinctly, the compression stress of copper foam platform was raised from 0.5 MPa to 1 Mpa which was of great significance to improve the energy absorption capacity of the material.展开更多
In order to obtain substrates with good conductive foam for high porosity foam metal materials used in the metal electrodes,the technique of electroless copper plating on the microcellular polyurethane foam with pore ...In order to obtain substrates with good conductive foam for high porosity foam metal materials used in the metal electrodes,the technique of electroless copper plating on the microcellular polyurethane foam with pore size of 0.3 mm was investigated.The main factors affecting the deposition rate such as the solution composition,temperature,pH value and adding ultrasonic were explored.The results show that the optimum process conditions are CuSO4 16 g/L,HCHO 5 mL/L,NaKC4H4O6 30 g/L,Na2EDTA 20 g/L,K4Fe(CN)6 25 mg/L,pH value of 12.5-13.0 and temperature of 40-50℃.Under these technical conditions, the process has excellent bath stability.Adding ultrasonic on the process can elevate the deposition rate of copper by 20%-30%.The foam metal material with a porosity of 92.2%and a three-dimensional network structure,was fabricated by electro-deposition after the electroless copper plating.展开更多
Enhanced pool boiling heat transfer of the porous structure is critical to the thermal management technology.In this paper,pool boiling heat transfer experiments are performed on copper foam welded surfaces in de-ioni...Enhanced pool boiling heat transfer of the porous structure is critical to the thermal management technology.In this paper,pool boiling heat transfer experiments are performed on copper foam welded surfaces in de-ionized water to investigate the effects of basic parameters of copper foam on heat transfer enhancement.Boiling phenomenon is observed to facilitate the understanding of enhancement mechanism.The results show that copper foam welded surfaces can significantly enhance the pool boiling heat transfer performance,reduce the boiling incipience temperature by 7-9℃,and reach two times heat transfer coefficient compared with smooth plain surfaces due to numerous nucleation sites,extended surface areas,and enhanced turbulent effect.Pore density and thickness of foam have two side effects on heat transfer.展开更多
In the present work,a compressible and lubricating space-holder material commonly known as "acrawax" was used to process Cu foams with various pore sizes and various porosities.The foams were processed witho...In the present work,a compressible and lubricating space-holder material commonly known as "acrawax" was used to process Cu foams with various pore sizes and various porosities.The foams were processed without using binders to avoid contamination of their metal matrices.The lubricant space-holder material was found to facilitate more uniform flow and distribution of metal powder around the surface of the space holder.In addition,the use of acrawax as a space-holder material yielded considerably dense cell walls,which are an essential prerequisite for better material properties.The foams processed with a smaller-sized space holder were found to exhibit better electrical and mechanical properties than those processed with a coarser-sized space holder.The isotropic pore shape,uniform pore distribution throughout the metal matrix,and uniform cell wall thickness were found to enhance the properties pertaining to fine-pore foam samples.The processed foams exhibit properties similar to those of the foams processed through the lost-carbonate sintering process.展开更多
Flow boiling in microchannels with porous walls has received extensive attention in recent years. Compared with the emphasis on heat transfer, there is a lack of research on the effect of the porous wall structures on...Flow boiling in microchannels with porous walls has received extensive attention in recent years. Compared with the emphasis on heat transfer, there is a lack of research on the effect of the porous wall structures on the pressure drop characteristics. In this study, systematic experiments are performed to measure the pressure drop of water-vapor two-phase flow in five microchannels with copper foam fins, which consist of nine or six channels and fins of copper foam. The porosities of the foam fins range from0.78 to 0.82 and ratios of fin width to channel width range from 0.5 to 2. The channels are approximately 0.5 or 1 mm in width and 1 mm in height. Both adiabatic and flow boiling experiments are conducted with water at mass fluxes ranging from 66 to 407 kg/(m^(2)s). In the adiabatic experiments, the average quality in channels is between 0.017 and 0.846. In the flow boiling experiments, the outlet quality of channels is between 0.040 and 0.863. Slug flow, churn flow, annular flow, and wispy-annular flow are observed in adiabatic experiments. A two-phase frictional pressure drop correlation based on the Lockhart-Martinelli model is developed for copper foam fin microchannels by introducing the effects of the mass flux, porosity, ratio of fin width to channel width, and heating condition step by step. The mean absolute percentage errors of the new correlation are 7.53% for 325data points under adiabatic conditions and 5.51% for 268 data points under flow boiling conditions, respectively. This work provides insight into the correlations of frictional pressure drop in microchannels with porous walls.展开更多
文摘Polyimide matrix composites interpenetrated with foamed copper were prepared via pressure impregnation and vacuum immersion to focus on their thermostability, mechanical and tribological behaviors as sliding electrical contact materials. The results show that the interpenetrating phase composites（IPC） are very heat-resistant and exhibit higher hardness as well as bending strength, when compared with homologous polyimide matrix composites without foamed copper. Sliding electrical contact property of the materials is also remarkably improved, from the point of contact voltage drops. Moreover, it is believed that fatigue wear is the main mechanism involved, along with slight abrasive wear and oxidation wear. The better abrasive resistance of the IPC under different testing conditions was detected, which was mainly attributed to the successful hybrid of foamed copper and polyimide.
文摘The effects of copper content on the microstructural and mechanical properties of steel foams are investigated. Spherical urea granules, used as a water-leachable space holder, were coated with a mixture of iron, ultrafine carbon, and different amounts of copper powders. After the mixture was compacted and the space holder was removed by leaching, a sintering process was performed under an atmosphere of thermally dissociated ammonia. Microstructural evaluations of the cell walls were carried out using optical microscopy and scanning electron microscopy in conjunction with energy-dispersive X-ray spectroscopy. In addition, compression tests were conducted to investigate the mechanical properties of the manufactured steel foams. The results showed that the total porosity decreases from 77.2% to 71.9% with increasing copper content in the steel foams. In the foams' microstructure, copper islands are mostly distributed in pearlite and intergranular carbide phases are formed in the grain boundaries. When the copper content was increased from 0 to 4 wt%, the elastic modulus, plateau stress, fracture stress, and fracture strain of manufactured steel foams improved 4.5, 6, 6.4, and 2.5 times, respectively.
基金National Natural Science Foundation of China(No.50572084)Natural Science Basic Research Plan in Shaanxi Province of China(No.2012JQ6011)+1 种基金Shaanxi Provincial Key Laboratory Scientific Research Project,China(No.12JS044)Shaanxi Leading Academic Discipline Project,China(No.[2008]169)
文摘Using forming-knitting technology and organic materials, copper foam with high porosity (>80%) and open-pore structure was successfully prepared. According to the method of immersion, the technical characteristics of metal paste performance and influence factors of sinter process were discussed. The pore morphology and compressibility of copper foam were detected simultaneously, and the structural property of copper foam prepared by the process of once-infiltrating was compared with the one of copper foam prepared by the process of twice-infiltrating. The results show that pH value of metal paste has a large influence on rheological properties of slurry. By twice-infiltrating process, the microstructure of copper foam was altered. In case of the porosity dropping indistinctly, the compression stress of copper foam platform was raised from 0.5 MPa to 1 Mpa which was of great significance to improve the energy absorption capacity of the material.
文摘In order to obtain substrates with good conductive foam for high porosity foam metal materials used in the metal electrodes,the technique of electroless copper plating on the microcellular polyurethane foam with pore size of 0.3 mm was investigated.The main factors affecting the deposition rate such as the solution composition,temperature,pH value and adding ultrasonic were explored.The results show that the optimum process conditions are CuSO4 16 g/L,HCHO 5 mL/L,NaKC4H4O6 30 g/L,Na2EDTA 20 g/L,K4Fe(CN)6 25 mg/L,pH value of 12.5-13.0 and temperature of 40-50℃.Under these technical conditions, the process has excellent bath stability.Adding ultrasonic on the process can elevate the deposition rate of copper by 20%-30%.The foam metal material with a porosity of 92.2%and a three-dimensional network structure,was fabricated by electro-deposition after the electroless copper plating.
基金supported by the National Natural Science Foundation of China(No.52075249)the Foundation of Jiangsu Key Laboratory of Bionic Functional Materials(No.NJ2020026)
文摘Enhanced pool boiling heat transfer of the porous structure is critical to the thermal management technology.In this paper,pool boiling heat transfer experiments are performed on copper foam welded surfaces in de-ionized water to investigate the effects of basic parameters of copper foam on heat transfer enhancement.Boiling phenomenon is observed to facilitate the understanding of enhancement mechanism.The results show that copper foam welded surfaces can significantly enhance the pool boiling heat transfer performance,reduce the boiling incipience temperature by 7-9℃,and reach two times heat transfer coefficient compared with smooth plain surfaces due to numerous nucleation sites,extended surface areas,and enhanced turbulent effect.Pore density and thickness of foam have two side effects on heat transfer.
文摘In the present work,a compressible and lubricating space-holder material commonly known as "acrawax" was used to process Cu foams with various pore sizes and various porosities.The foams were processed without using binders to avoid contamination of their metal matrices.The lubricant space-holder material was found to facilitate more uniform flow and distribution of metal powder around the surface of the space holder.In addition,the use of acrawax as a space-holder material yielded considerably dense cell walls,which are an essential prerequisite for better material properties.The foams processed with a smaller-sized space holder were found to exhibit better electrical and mechanical properties than those processed with a coarser-sized space holder.The isotropic pore shape,uniform pore distribution throughout the metal matrix,and uniform cell wall thickness were found to enhance the properties pertaining to fine-pore foam samples.The processed foams exhibit properties similar to those of the foams processed through the lost-carbonate sintering process.
基金supported by the National Natural Science Foundation of China(Grant No.51876102)the Tsinghua University Initiative Scientific Research Program。
文摘Flow boiling in microchannels with porous walls has received extensive attention in recent years. Compared with the emphasis on heat transfer, there is a lack of research on the effect of the porous wall structures on the pressure drop characteristics. In this study, systematic experiments are performed to measure the pressure drop of water-vapor two-phase flow in five microchannels with copper foam fins, which consist of nine or six channels and fins of copper foam. The porosities of the foam fins range from0.78 to 0.82 and ratios of fin width to channel width range from 0.5 to 2. The channels are approximately 0.5 or 1 mm in width and 1 mm in height. Both adiabatic and flow boiling experiments are conducted with water at mass fluxes ranging from 66 to 407 kg/(m^(2)s). In the adiabatic experiments, the average quality in channels is between 0.017 and 0.846. In the flow boiling experiments, the outlet quality of channels is between 0.040 and 0.863. Slug flow, churn flow, annular flow, and wispy-annular flow are observed in adiabatic experiments. A two-phase frictional pressure drop correlation based on the Lockhart-Martinelli model is developed for copper foam fin microchannels by introducing the effects of the mass flux, porosity, ratio of fin width to channel width, and heating condition step by step. The mean absolute percentage errors of the new correlation are 7.53% for 325data points under adiabatic conditions and 5.51% for 268 data points under flow boiling conditions, respectively. This work provides insight into the correlations of frictional pressure drop in microchannels with porous walls.
