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A local f-x Cadzow method for noise reduction of seismic data obtained in complex formations 被引量:7
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作者 Yuan Sanyi Wang Shangxu 《Petroleum Science》 SCIE CAS CSCD 2011年第3期269-277,共9页
A noise-reduction method with sliding called the local f-x Cadzow noise-reduction method, windows in the frequency-space (f-x) domain, is presented in this paper. This method is based on the assumption that the sign... A noise-reduction method with sliding called the local f-x Cadzow noise-reduction method, windows in the frequency-space (f-x) domain, is presented in this paper. This method is based on the assumption that the signal in each window is linearly predictable in the spatial direction while the random noise is not. For each Toeplitz matrix constructed by constant frequency slice, a singular value decomposition (SVD) is applied to separate signal from noise. To avoid edge artifacts caused by zero percent overlap between windows and to remove more noise, an appropriate overlap is adopted. Besides flat and dipping events, this method can enhance curved and conflicting events. However, it is not suitable for seismic data that contains big spikes or null traces. It is also compared with the SVD, f-x deconvolution, and Cadzow method without windows. The comparison results show that the local Cadzow method performs well in removing random noise and preserving signal. In addition, a real data example proves that it is a potential noise-reduction technique for seismic data obtained in areas of complex formations. 展开更多
关键词 Cadzow sliding window noise reduction FIDELITY complex formations Toeplitz matrix singular value decomposition
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Numerical simulation and dimension reduction analysis of electromagnetic logging while drilling of horizontal wells in complex structures 被引量:7
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作者 Zhen-Guan Wu Shao-Gui Deng +5 位作者 Xu-Quan He Runren Zhang Yi-Ren Fan Xi-Yong Yuan Yi-Zhi Wu Qing Huo Liu 《Petroleum Science》 SCIE CAS CSCD 2020年第3期645-657,共13页
Electromagnetic logging while drilling(LWD)is one of the key technologies of the geosteering and formation evaluation for high-angle and horizontal wells.In this paper,we solve the dipole source-generated magnetic/ele... Electromagnetic logging while drilling(LWD)is one of the key technologies of the geosteering and formation evaluation for high-angle and horizontal wells.In this paper,we solve the dipole source-generated magnetic/electric fields in 2D formations efficiently by the 2.5D finite diff erence method.Particularly,by leveraging the field’s rapid attenuation in spectral domain,we propose truncated Gauss–Hermite quadrature,which is several tens of times faster than traditional inverse fast Fourier transform.By applying the algorithm to the LWD modeling under complex formations,e.g.,folds,fault and sandstone pinch-outs,we analyze the feasibility of the dimension reduction from 2D to 1D.For the formations with smooth lateral changes,like folds,the simplified 1D model’s results agree well with the true responses,which indicate that the 1D simplification with sliding window is feasible.However,for the formation structures with drastic rock properties changes and sharp boundaries,for instance,faults and sandstone pinch-outs,the simplified 1D model will lead to large errors and,therefore,2.5D algorithms should be applied to ensure the accuracy. 展开更多
关键词 complex formation structures Horizontal wells Electromagnetic logging while drilling 2.5D algorithm-Model simplification
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Log identification method in complex sand reservoirs 被引量:3
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作者 ZHAO Xiao-liang LIAO Xin-wei +2 位作者 CHEN Xi XU Sheng-feng XU An-zhu 《Mining Science and Technology》 EI CAS 2009年第4期531-536,共6页
In order to obtain effective parameters for complex sand reservoirs,a log evaluation method for relevant reservoir parameters is established based on an analysis in the gas-bearing sandstone with high porosity and low... In order to obtain effective parameters for complex sand reservoirs,a log evaluation method for relevant reservoir parameters is established based on an analysis in the gas-bearing sandstone with high porosity and low permeability,low porosity and permeability and on various characteristics of log responses to reservoir lithologies and physical properties in the Neopleozoic sand reservoir of the Ordos basin.This log evaluation method covers the Cook method that is used to evaluate the porosity and oiliness in high porosity and low permeability reservoirs and another method in which the mineral content,derived from geochemical logs,is used to identify formation lithologies.Some areas have high calcium and low silt content,not uniformly distributed,the results of which show up in the complex formation lithologies and conventional log responses with great deviation.The reliability of the method is verified by comparison with conventional log data and core analyses.The calculation results coincide with the core analytical data and gas tests,which indicate that this log evaluation method is available,provides novel ideas for study of similar complex reservoir lithologies and has some reference value. 展开更多
关键词 complex formation lithology reservoir parameter evaluation Cook method geochemical element element content mineral constituent lithological identification
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Determination of Formation Constants of Co ̄(2+), Ni ̄(2+),Cu ̄(2+) and Zn ̄(2+) Complexes with Humic and Fulvic Acidsby Potentiometric Titration Method 被引量:1
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作者 DUJIN-ZHOU LUCHANG-QING 《Pedosphere》 SCIE CAS CSCD 1994年第4期289-296,共8页
The formation constants of Co ̄(2+), Ni ̄(2+), Cu ̄(2+) and Zn ̄(2+) complexes with humic acid (HA) and fulvicacid (FA) in red soil were determined by the potentiometric titration method. The constants as a functionof... The formation constants of Co ̄(2+), Ni ̄(2+), Cu ̄(2+) and Zn ̄(2+) complexes with humic acid (HA) and fulvicacid (FA) in red soil were determined by the potentiometric titration method. The constants as a functionof composition of the complexation solutions were obtained by two graphical approaches respectively Theformation constants decreased with increasing concentration of metal in the solution. The results provideunambiguous evidence for the heterogeneity of the function groups of humic substances. The formationconstants of FA were much smaller than those of HA, and the formation constants of Cu ̄(2+) were muchgreater than those of Co ̄(2+) , Ni ̄(2+) and Zn ̄(2+) . The potentiometric titration method for determining formationconstants are also discussed in the article. 展开更多
关键词 formation constants of complexes humic and fulvic acids potentiometric titration red soil
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New U-Pb Geochronological Constraints on Formation and Evolution of the Susong Complex Zone in the Dabie Orogen 被引量:6
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作者 LI Yuan LIU Yican +1 位作者 YANG Yang DENG Liangpeng 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2017年第5期1915-1918,共4页
Objective The Susong complex zone(SCZ)is a relatively lowgrade metamorphic unit mostly with an epidoteamphibolite facies,located in the southernmost part of the Dabie orogen.However,its rock compositions,ages,
关键词 Pb New U-Pb Geochronological Constraints on Formation and Evolution of the Susong complex Zone in the Dabie Orogen
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Complex Formation between Heptakis(2,3,6-tri-O-butyl)-β-cyclodextrin with p-Nitrophenol in Heptane
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作者 Le Xin SONG Bao Long LI +1 位作者 Rong JIANG Jian Gang DING and Qing Jin MENG(Department of Chemistry, Suzhou University. Suzhou 215006)(Coordination Chemistry State Key Laboratory, Coordination Chemistry Institute, Nanjing University, Nanjing 210093) 《Chinese Chemical Letters》 SCIE CAS CSCD 1997年第7期613-614,共2页
Heptakis(2, 3, 6-tri-o-n-butyl)- β-cyclodextrin(TB- β-CD) has been found to form an inclusion compound with p-nitrophenol in heptane. The stability constent of the inclusion compound of p-nitrophenol with TB-β-CD i... Heptakis(2, 3, 6-tri-o-n-butyl)- β-cyclodextrin(TB- β-CD) has been found to form an inclusion compound with p-nitrophenol in heptane. The stability constent of the inclusion compound of p-nitrophenol with TB-β-CD in heptane is an order of magnitude greater than that in water. 展开更多
关键词 tri-O-butyl CD PNP cyclodextrin with p-Nitrophenol in Heptane complex Formation between Heptakis
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SCIENTIFIC PRINCIPLES FOR MODIFICATION OF WATER-SOLUBLE POLYMERS. FORMATION OF MACROMOLECULAR COMPLEXES
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作者 PAUTOV V.D. ANUFRIEVA E.V. KRAKOVYAK M.G. 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 1998年第3期268-278,共11页
The study of nanosecond dynamics of macromolecules with the lumines-cent methods make it possible to investigate the formation and functioning of polymericcomplexes, polymeric conjugates and macromolecular metal compl... The study of nanosecond dynamics of macromolecules with the lumines-cent methods make it possible to investigate the formation and functioning of polymericcomplexes, polymeric conjugates and macromolecular metal complexes, which are widelyused for solving many practical tasks. The nanosecond dynamics of macromolecules are ahighly sensitive indicator of interpolymer complexes (IPC) formation. It enables us to solvethe problems of studying IPC formation and stability and to investigate the interpolymerreactions of exchange and substitution. The investigation of changes in the rotational mo-bility of globular protein molecules as a whole makes it possible to determine the complexcomposition and its stability, and to control the course of polymer-protein conjugate forma-tion reaction. The nanosecond dynamics of polymers interacting with surfacants' ions (S)are the sensitive indicator of the S-polymer complex formation. A method for determin-ing the equilibrium constants of the S-polymer complex formation was developed on thebasis of the study of polymer chains mobility. It is established that nanosecond dynamicsinfluences the course of chemical reactions in polymer chains. Moreover, the marked effectof the nanosecond dynamics is also revealed in the study of photophysical processes (theformation of excimers and energy migration of electron excitation) in polymers with pho-toactive groups. It was found that the efficiency of both processes increases with increasingthe mobility of side chains, the carriers of photoactive groups. 展开更多
关键词 Modification of water-soluble polymers Formation of complexes
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Acid-base behavior of cryptand 1, 4, 7, 10, 13, 16, 21, 24-octaaza-bicyclo [8, 8, 8] hexacosan-3, 8, 12, 17, 20, 25-hexone and complex formation
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作者 MO Zunli, CHEN Hong and GAO Jinzhang Institute of Chemistry, Northwest Normal University, Lanzhou 730070, China 《Rare Metals》 SCIE EI CAS CSCD 2002年第1期12-19,共8页
The bicyclic cryptand 1,4,7, 10,13,16,21, 24-octaaza-bigcyclo [8, 8,8] hexacosan-3, 8, 12, 17, 20, 25-hex-one (COBH) bearing diaminoethane groups along the eight-atom bridges was synthesized. The structure consists of... The bicyclic cryptand 1,4,7, 10,13,16,21, 24-octaaza-bigcyclo [8, 8,8] hexacosan-3, 8, 12, 17, 20, 25-hex-one (COBH) bearing diaminoethane groups along the eight-atom bridges was synthesized. The structure consists of discrete neutral macrobicyclic units; the two cycles share the two tertiary amine nitrogen atoms, which exhibit an endo-cndo conformation. Three identical branches formed by 1, 2-diaminoethane link the two tertiary amine groups. The protonation reactions of cryptand (COBH) and its complex formation with copper (II) were investigated by potentiometry in water and in a DMSO/water (80:20 in mass ratio) mixture as solvents. The cryptand acts as a his-base through its two N-bridgehead and exhibits a strong cooperativity that favors the first protonation and makes the second one difficult (△pK= 5.0). An inward rotation of the amide groups to form hydrogen bonds accounts for this cooperativity. The interaction of COBH with copper (II) leads to several binuclear complex proton contents. 展开更多
关键词 COBH(cryptand 1 4 7 10 13 16 21 24-octaaza-bigcyclo [8 8 8] hexacosan -3 8 12 17 20 25 - hex-one) macrobicyclic acid-base behavior complex formation proton contents
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Samarium(II) Diiodide Induced Polarity Inversion of π-Allyl Palladium Complexes: The Formation of Allylic Selenides
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作者 XinJianZHAO HuaRongZHAO 《Chinese Chemical Letters》 SCIE CAS CSCD 2002年第5期396-397,共2页
Allylic acetates were reduced with Pd(0)-SmI2 in the presence of ArSeBr to form corresponding allylic selenides in good yields.
关键词 Allyl acetates allylic selenides arylselenenyl bromides palladium complexes polarity inversion. Samarium(II) Diiodide Induced Polarity Inversion of p-Allyl Palladium complexes: The Formation of Allylic Selenides Xin Jian ZHAO1 Hua Rong ZH
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Expression and Purification of Goose HSP70 and Compound Formation with Virus Polypeptide
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作者 WANG Bao-wei WU Xiao-ping ZHANG Xu-hui JIA Xiao-hui ZHANG Ming-ai LONG Fang-yu YANG Zhi-gang WANG Lei 《Agricultural Sciences in China》 CAS CSCD 2008年第2期239-247,共9页
The experiment was conducted to study the specific expression of HSP70 caused by heat shock, HSP70 purification and the characteristics of coalescence with antigenic peptide in the formation of the complex. Sixty heal... The experiment was conducted to study the specific expression of HSP70 caused by heat shock, HSP70 purification and the characteristics of coalescence with antigenic peptide in the formation of the complex. Sixty healthy 6-week-old male Wulong geese were selected and randomly divided into three groups. The control group was slaughtered without heat treatment. Treatment group 1 was shocked with an acute heat treatment at (42 ± 1)℃ for 5 h before they were immediately slaughtered. Treatment group 2 was kept for 12 h after the heat treatment under normal conditions in order to recover and was then slaughtered. Cardiac tissue was taken in order to make paraffin sections for the immunohistochemistry experiment and the liver tissue was used to purify HSP70. The geese heart HSP70 expression differences in the three groups were determined and at the same time the experiments of HSP70 purification and appraisal in the liver tissue were carried on. HSP70 purification and synthesis of HBV PreS1 multi-peptides unified the complex, which was determined by bi-specific antibody enzyme-linked immune sandwich assay. The results indicated that widespread HSP70 positive pellets in the cardiac muscle were found under hot shock conditions. HSP70 expression in the treatment group 1 was centered in the karyotheca and its periphery, but in treatment group 2, it was centered in the surrounding cell membrane. The HSP70 purification could be obtained through two sets of purification plans; both the synthesis peptide and the HSP70 purification form the complex under certain conditions. The double antibody sandwich ELISA technique was applied to detect if the complex had been formed. Positive results showed that the complex was formed. The specific expression of HSP70 under heat shock shifted with time, suggesting that HSP70 possibly had some function in cell protection. High-purity HSP70 protein can be obtained under low-pressure chromatography conditions, and in comparison with each other, it was better in the flow of the molecular sieve preliminary separation, ConA-agarose chromatography and the ADP-agarose chromatography. Under certain condition in vitro, the synthetic peptide could combine with HSP70 to form the compound, thereby providing a further experimental foundation for the immunity function of the complex. 展开更多
关键词 heat shock GOOSE HSP70 expression purification APPRAISAL viral multi-peptides complex formation
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Synthesis and Crystal Structure of Potassium Crown Ether Tetrathiosquarate
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作者 Johannes Beck Younis O. Ben Amer 《Journal of Chemistry and Chemical Engineering》 2012年第5期470-474,共5页
Slow diffusion of diethylether into a concentrated solution of K2C454.H20 and two equivalents of 18-crown-6 in pyridine affords dark orange crystals of bis(potassium{18-crown-6})(3-cyclobutene-1,2-dithione-3,4-dith... Slow diffusion of diethylether into a concentrated solution of K2C454.H20 and two equivalents of 18-crown-6 in pyridine affords dark orange crystals of bis(potassium{18-crown-6})(3-cyclobutene-1,2-dithione-3,4-dithiolate) [K(C12H2406)]2(CnS4). The crystal structure determination (monoclinic, P 2t/n, a = 12.2095(8) A, b = 11.3263(8) A, c = 14.0552(7) A, fl = 101.032(3)~, Z = 2) shows the presence of C4S42 - ions with almost undistorted D4h symmetry having C-C bond lengths of 1.442(10) A and 1.478(8) A and C-S bond lengths of 1.651(8) A and 1.664(7) A. Since the K+ ions are shielded in a half-spherical way by the crown ether ligands, the crystal structures is built of centrosymmetric molecular entities [(18-crown-6)K(C4S4)K(18-crown-6)]. The K+ ions have eight of coordination number, C4S42- acts as a chelating and bridging ligand towards two K+ with K-S distances of 3.434(2) A and 3.380(2) A. 展开更多
关键词 Tetrathiosquarate crown ether potassium ion complex formation crystal structure.
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Determination of Lisinopril in Bulk and Pharmaceutical Formulations by Cloud Point Extraction—A Green Method
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作者 V. Mallikarjuna Sarma N. V. S. Venugopal L. Giribabu 《American Journal of Analytical Chemistry》 2020年第8期289-300,共12页
<span style="font-family:Verdana;">A sensitive and eco-friendly method was developed for the spectrophotometric determination of Lisinopril (LSP) in bulk and pharmaceutical formulations by cloud point ... <span style="font-family:Verdana;">A sensitive and eco-friendly method was developed for the spectrophotometric determination of Lisinopril (LSP) in bulk and pharmaceutical formulations by cloud point extraction technique. The method was based on the formation of a blue</span><span style="font-family:Verdana;">-</span><span style="font-family:Verdana;">colored coordination complex between Lisinopril (LSP) and Cobalt Thiocyanate (CTC) at a suitable pH.</span><span style="font-family:""> </span><span style="font-family:""><span style="font-family:Verdana;">The Complex in aqueous medium</span><span style="font-family:Verdana;"> was extracted into surfactant layer by cloud point extraction using</span><span style="font-family:Verdana;"> a non-ionic surfactant Triton X-114 and then the surfactant layer was dissolved in a suitable volume of ethanol and the amount of Lisinopril was determined spectrophotometrically at a wavelength of 625</span></span><span style="font-family:""> </span><span style="font-family:Verdana;">nm.</span><span style="font-family:""> </span><span style="font-family:""><span style="font-family:Verdana;">The conditions like concentration of the drug, concentration of CTC and of Triton X-114, P</span><sup><span style="font-family:Verdana;">H</span></sup></span><span style="font-family:Verdana;">,</span><span style="font-family:Verdana;"> etc. were optimized by OFAT (One Factor At a Time) method. The linear range of calibration curve was 1</span><span style="font-family:""> </span><span style="font-family:Verdana;">-</span><span style="font-family:""> </span><span style="font-family:Verdana;">6 μg/ml and the linear regression equation with a correlation coefficient of 0.99996 was y = 0.0021</span><span style="font-family:""> </span><span style="font-family:Verdana;">+</span><span style="font-family:""> </span><span style="font-family:Verdana;">0.084x.</span><span style="font-family:""> </span><span style="font-family:Verdana;">Preconcentration and enrichment factors were found to be 100 and 3.12 respectively, achieving the detection limit of 0.0588</span><span style="font-family:""> </span><span style="font-family:Verdana;">μg/ml. The proposed method was successfully applied for the determination of LSP in the drug formulations. The obtained values were in agreement with the values as quoted by the manufacturers. 展开更多
关键词 Lisinopril (LSP) Cobalt Thiocyanate (CTC) Coordination complex Formation Cloud Pint Extraction (CPE) SPECTROPHOTOMETRY
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Thermochemical Heat Storage Performance in the Gas/Liquid-Solid Reactions of SrCl2 with NH3
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作者 Kazuki Kuwata Soichirou Masuda +2 位作者 Noriyuki Kobayashi Takuya Fuse Toru Okamura 《Natural Resources》 2016年第11期655-665,共11页
Thermochemical heat storage is a promising technology for improving energy efficiency through the utilization of low-grade waste heat. The formation of a SrCl<sub>2</sub> ammine complex was selected as the... Thermochemical heat storage is a promising technology for improving energy efficiency through the utilization of low-grade waste heat. The formation of a SrCl<sub>2</sub> ammine complex was selected as the reaction system for the purpose of this study. Discharge characteristics were evaluated in a packed bed reactor for both the gas-solid reaction and the liquid-solid reaction. The average power of the gas-solid reaction was influenced by the pressure of the supplied ammonia gas, with greater powers being recorded at higher ammonia pressure. For the liquid-solid reaction, the obtained average power was comparable to that obtained for the gas-solid reaction at 0.2 MPa. Moreover, the lower heat transfer resistance in the reactor was observed, which was likely caused by the presence of liquid ammonia in the system. Finally, the short-term durability of the liquid-solid reaction system was demonstrated over 10 stable charge/discharge cycles. 展开更多
关键词 Thermochemical Heat Storage SrCl2 Ammine complex Formation Gas/Liquid-Solid Reaction
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Comparative DFT Study of [Mg(CHZ)_3](ClO_4)_2 and [Mg(CHZ)_3](NO_3)_2(CHZ=Carbohydrazide)
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作者 聂西度 黄辉胜 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2012年第4期679-683,共5页
The molecular geometry,electronic structure,thermochemistry and infrared spectra of [Mg(CHZ)3](ClO4)2 and [Mg(CHZ)3](NO3)2 were comparatively studied using the Heyd-Scuseria-Ernzerhof(HSE) screened hybrid de... The molecular geometry,electronic structure,thermochemistry and infrared spectra of [Mg(CHZ)3](ClO4)2 and [Mg(CHZ)3](NO3)2 were comparatively studied using the Heyd-Scuseria-Ernzerhof(HSE) screened hybrid density functional with 6-31G** basis set.The experimental results show that the complexes have six-coordinated octahedron feature,and the metal-ligand interactions are predominantly ionic in nature.The calculated heats of formation predict that [Mg(CHZ)3](NO3)2 is more stable than [Mg(CHZ)3](ClO4)2.Detailed NBO analyses indicate that the ligand-anion interaction plays an important role in the stability for these two energetic complexes.Moreover,the stretching vibration frequencies of N-H bonds shift to lower wave number compared to the free CHZ ligand,which are caused by the delocalizations from N-H bond orbital to lone-pair electron antibond orbital of magnesium. 展开更多
关键词 energetic complex carbohydrazide density functional theory electronic structure heats of formation
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Study on the mechanism of copper-ammonia complex decomposition in struvite formation process and enhanced ammonia and copper removal 被引量:12
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作者 Cong Peng Liyuan Chai +4 位作者 Chongjian Tang Xiaobo Min Yuxia Song Chengshan Duan Cheng Yu 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2017年第1期222-233,共12页
Heavy metals and ammonia are difficult to remove from wastewater,as they easily combine into refractory complexes.The struvite formation method(SFM) was applied for the complex decomposition and simultaneous removal... Heavy metals and ammonia are difficult to remove from wastewater,as they easily combine into refractory complexes.The struvite formation method(SFM) was applied for the complex decomposition and simultaneous removal of heavy metal and ammonia.The results indicated that ammonia deprivation by SFM was the key factor leading to the decomposition of the copper-ammonia complex ion.Ammonia was separated from solution as crystalline struvite,and the copper mainly co-precipitated as copper hydroxide together with struvite.Hydrogen bonding and electrostatic attraction were considered to be the main surface interactions between struvite and copper hydroxide.Hydrogen bonding was concluded to be the key factor leading to the co-precipitation.In addition,incorporation of copper ions into the struvite crystal also occurred during the treatment process. 展开更多
关键词 Copper-ammonia complex Ammonia removal Copper hydroxide Co-precipitation Struvite formation Heavy-metal-containing wastewater
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Chemical equilibrium constants of rare earth nitrates and tri-n-butyl phosphate complex formation
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作者 Kalaya Changkrueng Deacha Chatsiriwech 《Journal of Rare Earths》 SCIE EI CAS CSCD 2011年第9期896-901,共6页
Mixed rare earth nitrates (REi(NO3)3) in the aqueous solution was mixed with tri-n-butyl phosphate (TBP, (n-C4H9O)3PO) dissolved in kerosene for the formation of their corresponding complexes (REi(NO3)3... Mixed rare earth nitrates (REi(NO3)3) in the aqueous solution was mixed with tri-n-butyl phosphate (TBP, (n-C4H9O)3PO) dissolved in kerosene for the formation of their corresponding complexes (REi(NO3)3·ni(n-C4H9O)3PO) at 303 K. The effects of initial concentrations of both TBP and mixed rare earth nitrates on the equilibrium constants of their complex formations were investigated. The complexes were formed almost immediately after mixing. The simultaneous formations reached their chemical equilibria within a few minutes by shaking the mixture at 200 r/min. The chemical equilibrium constants of the complex formations were independent of the initial TBP concentrations. However, they were decreased by reducing the concentration of REi(NO3)3. All equilibrium constants of the simultaneous complex formations were less than 0.7, while the average molar ratio of TBP to REi(NO3)3 of the complexes varied between 1.0 and 1.6. The chemical equilibrium constant for the formation of La(NO3)3·(n-C4H9O)3PO was 0.09, while that of Dy(NO3)3·(n-C4H9O)3PO was 0.68. The ascending sequence of chemical equilibrium constants for the simultaneous formations was La, Ce, Pr, Nd, Eu, Y, Sm, Gd, and Dy. 展开更多
关键词 chemical equilibrium constants TBP rare earth nitrates complex formation
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Linear free energy relationships between reaction rate constants and equilibrium constants of complex compounds——III. Kinetics and mechanisms of ternary complex formation between (5-X-1, 10-phenanthroline)copper(II) and threonine 被引量:1
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作者 CHEN Rong-Ti (Y.T.Chen) +1 位作者 ZHANG Qi-Yan LI Yue-Jin 《Acta Chimica Sinica English Edition》 SCIE CAS CSCD 1989年第4期342-348,共1页
The kinetics of ternary complex formation involving Cu(5-X-1, 10-phen) and threonine (CuAL, A=5-X-1, 10-phen; L=threonine or represented by O-N; X=NO_2, Cl, H, CH_3) has been studied by temperature-jump and stopped-fl... The kinetics of ternary complex formation involving Cu(5-X-1, 10-phen) and threonine (CuAL, A=5-X-1, 10-phen; L=threonine or represented by O-N; X=NO_2, Cl, H, CH_3) has been studied by temperature-jump and stopped-flow methods. The formation rate constants, k_f(M^(-1).s^(-1)), for the complexation reaction, CuA + LCuAL, are as follows; X=NO_2, 8.68×10~8; X=Cl, 7.13×10~8; X=H, 6.12×10~8; X=CH_3, 5.42×10~8. The rate constants for zwitterion attack are nil within experimental error. It has been found that a linear free energy relationship exists between the stability(logK_(CuAL)^(CuA) of the complexes CuAL and log kf as follows: IogK_(CuAL)^(CuA)=0.13 + 0.83 logk_f, r=0.99. It suggested that the formation rate governed the stability of the ternary complexes. The rates of formation of the ternary complexes increased with decreasing electron-donating property of the substituents. A linear relationship was found to exist as expressed by the following equation: log(k_f^R/k_F^O) = 0.097σ, r=0.96. A mechanism involves a rapid equilibrium between CuA and L followed by a slow ring closure of L. 展开更多
关键词 rate Kinetics and mechanisms of ternary complex formation between and threonine phenanthroline)copper II Linear free energy relationships between reaction rate constants and equilibrium constants of complex compounds X-1 III free
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Study on the cocolouration effect in the β-complex formation reactions of rare earths with p-chloro-chlorophosphonazo (CPApC)
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作者 XU, Zhong-Jun (HSU, Chung-Gin) ZHANG, Lan PAN, Jiao-Mai Department of Chemistry, East China Normal University, Shanghai 200062 《Chinese Journal of Chemistry》 SCIE CAS CSCD 1992年第5期424-429,共0页
Terbium- and yttrium-group rare earths form β-complexes with CPApC in acidic medium. The sensitivities for determination of these rare earths by this reaction depend on their ionic radii. Cerium- or terbium-group rar... Terbium- and yttrium-group rare earths form β-complexes with CPApC in acidic medium. The sensitivities for determination of these rare earths by this reaction depend on their ionic radii. Cerium- or terbium-group rare earth in the presence of yttrium-group element produces the cocolouration effect which remarkably sensitizes the reaction. Yb-CPApC-Eu complex has a molar composition of 1:4:2 and gives a molar absorptivity of 2. 02 ×10~5 L·mol^(-1)·cm^(-1) at 746 nm for Eu. It is found that the closer the lengths of ionic radii of the rare earths are, the greater will be the cocolouration effect. 展开更多
关键词 CPApC Study on the cocolouration effect in the complex formation reactions of rare earths with p-chloro-chlorophosphonazo
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Adsorption performance and physicochemical mechanism of MnO_(2)-polyethylenimine-tannic acid composites for the removal of Cu(Ⅱ) and Cr(Ⅵ) from aqueous solution 被引量:2
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作者 Xiaoyan Deng Luxing Wang +6 位作者 Qihui Xiu Ying Wang Hong Han Dongmei Dai Yongji Xu Hongtao Gao Xien Liu 《Frontiers of Chemical Science and Engineering》 SCIE EI CAS CSCD 2021年第3期538-551,共14页
In this work,an adsorbent,which we call MnPT,was prepared by combining MnO_(2),polyethylenimine and tannic acid,and exhibited efficient performance for Cu(Ⅱ) and Cr(VI) removal from aqueous solution.The oxygen/nitrog... In this work,an adsorbent,which we call MnPT,was prepared by combining MnO_(2),polyethylenimine and tannic acid,and exhibited efficient performance for Cu(Ⅱ) and Cr(VI) removal from aqueous solution.The oxygen/nitrogen-containing functional groups on the surface of MnPT might increase the enrichment of metal ions by complexation.The maximum adsorption capacities of MnPT for Cu(Ⅱ) and Cr(Ⅵ) were 121.5 and 790.2 mg·g^(-1),respectively.The surface complexation formation model was used to elucidate the physicochemical interplay in the process of Cu(Ⅱ) and Cr(Ⅵ) co-adsorption on MnPT.Electrostatic force,solvation action,adsorbate-adsorbate lateral interaction,and complexation were involved in the spontaneous adsorption process.Physical electrostatic action was dominant in the initial stage,whereas chemical action was the driving force leading to adsorption equilibrium.It should be noted that after adsorption on the surface of MnPT,Cr(Ⅵ) reacted with some reducing functional groups(hydroxylamine-NH_(2))and was converted into Cr(Ⅲ).The adsorption capacity declined by 12% after recycling five times.Understanding the adsorption mechanism might provide a technical basis for the procedural design of heavy metal adsorbents.This MnPT nanocomposite has been proven to be a low-cost,efficient,and promising adsorbent for removing heavy metal ions from wastewater. 展开更多
关键词 MnO_(2)-polyethylenimine-tannic acid composite surface complexation formation model Cu(Ⅱ) Cr(Ⅵ) physicochemical mechanism
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Investigation of the interaction of ethyl acetoacetate with nano alumina particle as Lewis acid in acetonitrile solvent
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作者 Asadollah FARHADI Mohammad Ali TAKASSI Mandana DAYER 《Frontiers of Chemistry in China》 2011年第3期248-252,共5页
The enol form of ethyl acetoacetate(EAA)displays interesting spectroscopic characteristics;this form of ethyl acetylacetate is very important in condensation reaction.In this investigation,we have studied the interact... The enol form of ethyl acetoacetate(EAA)displays interesting spectroscopic characteristics;this form of ethyl acetylacetate is very important in condensation reaction.In this investigation,we have studied the interactions and the complex formation constants(K_(f))with nano alumina(10–20 nm)particle and alumina(mesh 135)compounds as Lewis acids in the acetonitrile solvent using absorption spectroscopy and related calculations.Furthermore,in this study we calculated the thermodynamic parameters of this reaction.The trend of reactivity of the ethyl acetoacetate(EAA)complexes toward the above Lewis acids,based on the solvent as follows:nano alumina compound>alumina compound. 展开更多
关键词 complex formation constant ethyl acetoacetate nano alumina ALUMINA THERMODYNAMIC
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