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Formation mechanism of nanopores in dense films of anodic alumina
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作者 Peng-ze LI Yu ZHANG +5 位作者 Jia-zheng ZHANG Lin LIU Shi-yi WANG Rui LIU Ye SONG Xu-fei ZHU 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2024年第9期2918-2927,共10页
Constant-current anodization of pure aluminum was carried out in non-corrosive capacitor working electrolytes to study the formation mechanism of nanopores in the anodic oxide films.Through comparative experiments,nan... Constant-current anodization of pure aluminum was carried out in non-corrosive capacitor working electrolytes to study the formation mechanism of nanopores in the anodic oxide films.Through comparative experiments,nanopores are found in the anodic films formed in the electrolytes after high-temperature storage(HTS)at 130°C for 240 h.A comparison of the voltage-time curves suggests that the formation of nanopores results from the decrease in formation efficiency of anodic oxide films rather than the corrosion of the electrolytes.FT-IR and UV spectra analysis shows that carboxylate and ethylene glycol in electrolytes can easily react by esterification at high temperatures.Combining the electronic current theory and oxygen bubble mold effect,the change in electrolyte composition could increase the electronic current in the anodizing process.The electronic current decreases the formation efficiency of anodic oxide films,and oxygen bubbles accompanying electronic current lead to the formation of nanopores in the dense films.The continuous electronic current and oxygen bubbles are the prerequisites for the formation of porous anodic oxides rather than the traditional field-assisted dissolution model. 展开更多
关键词 anodic alumina formation mechanism NANOPORES formation efficiency electronic current oxygen bubble
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Geometry and formation mechanism of tension gashes and their implication on the hydrocarbon accumulation in the deep-seated strata of sedimentary basin:A case from Shunnan area of Tarim Basin
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作者 Yan-Nan Du Kong-You Wu +4 位作者 Yin Liu Yan-Ying Li Zi-Cheng Cao You-Wei Cui Jun Liu 《Petroleum Science》 SCIE EI CAS CSCD 2024年第1期87-99,共13页
With the theoretical and technological developments related to cratonic strike-slip faults,the Shuntuoguole Low Uplift in the Tarim Basin has attracted considerable attention recently.Affected by multi-stage tectonic ... With the theoretical and technological developments related to cratonic strike-slip faults,the Shuntuoguole Low Uplift in the Tarim Basin has attracted considerable attention recently.Affected by multi-stage tectonic movements,the strike-slip faults have controlled the distribution of hydrocarbon resources owing to the special fault characteristics and fault-related structures.In contrast,the kinematics and formation mechanism of strike-slip faults in buried sedimentary basins are difficult to investigate,limiting the discussion of these faults and hydrocarbon accumulation.In this study,we identified the characteristics of massive sigmoidal tension gashes(STGs)that formed in the Shunnan area of the Tarim Basin.High-resolution three-dimensional seismic data and attribute analyses were used to investigate their geometric and kinematic characteristics.Then,the stress state of each point of the STGs was calculated using seismic curvature attributes.Finally,the formation mechanism of the STGs and their roles in controlling hydrocarbon migration and accumulation were discussed.The results suggest that:(1)the STGs developed in the Shunnan area have a wide distribution,with a tensile fault arranged in an enéchelon pattern,showing an S-shaped bending.These STGs formed in multiple stages,and differential rotation occurred along the direction of strike-slip stress during formation.(2)Near the principal displacement zone of the strike-slip faults,the stress value of the STGs was higher,gradually decreasing at both ends.The shallow layer deformation was greater than the deep layer deformation.(3)STGs are critical for connecting source rocks,migrating oil and gas,sealing horizontally,and developing efficient reservoirs.This study not only provides seismic evidence for the formation and evolution of super large STGs,but also provides certain guidance for oil and gas exploration in this area. 展开更多
关键词 Tarim Basin Sigmoidal tension gashes Seismic attributes Shear stress calculation formation mechanism Reservoir control
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Formation of Tianwen-1 landing crater and mechanical properties of Martian soil near the landing site
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作者 Xinshuo Chen Zhaobin Zhang +7 位作者 Juan Li Shouding Li Tao Xu Bo Zheng Xiukuo Sun Yanfang Wu Yiming Diao Xiao Li 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2024年第9期1293-1303,共11页
After landing in the Utopia Planitia,Tianwen-1 formed the deepest landing crater on Mars,approximately 40 cm deep,exposing precious information about the mechanical properties of Martian soil.We established numerical ... After landing in the Utopia Planitia,Tianwen-1 formed the deepest landing crater on Mars,approximately 40 cm deep,exposing precious information about the mechanical properties of Martian soil.We established numerical models for the plume-surface interaction(PSI)and the crater formation based on Computational Fluid Dynamics(CFD)methods and the erosion model modified from Roberts’Theory.Comparative studies of cases were conducted with different nozzle heights and soil mechanical properties.The increase in cohesion and internal friction angle leads to a decrease in erosion rate and maximum crater depth,with the cohesion having a greater impact.The influence of the nozzle height is not clear,as it interacts with the position of the Shock Diamond to jointly control the erosion process.Furthermore,we categorized the evolution of landing craters into the dispersive and the concentrated erosion modes based on the morphological characteristics.Finally,we estimated the upper limits of the Martian soil’s mechanical properties near Tianwen-1 landing site,with the cohesion ranging from 2612 to 2042 Pa and internal friction angle from 25°to 41°. 展开更多
关键词 Tianwen-1 Plume-surface interaction Landing crater formation Martian soil mechanical properties Numerical simulation
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Additive manufacturing of Ni-based superalloys: Residual stress, mechanisms of crack formation and strategies for crack inhibition 被引量:9
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作者 Chuan Guo Gan Li +8 位作者 Sheng Li Xiaogang Hu Hongxing Lu Xinggang Li Zhen Xu Yuhan Chen Qingqing Li Jian Lu Qiang Zhu 《Nano Materials Science》 EI CAS CSCD 2023年第1期53-77,共25页
The additive manufacturing(AM)of Ni-based superalloys has attracted extensive interest from both academia and industry due to its unique capabilities to fabricate complex and high-performance components for use in hig... The additive manufacturing(AM)of Ni-based superalloys has attracted extensive interest from both academia and industry due to its unique capabilities to fabricate complex and high-performance components for use in high-end industrial systems.However,the intense temperature gradient induced by the rapid heating and cooling processes of AM can generate high levels of residual stress and metastable chemical and structural states,inevitably leading to severe metallurgical defects in Ni-based superalloys.Cracks are the greatest threat to these materials’integrity as they can rapidly propagate and thereby cause sudden and non-predictable failure.Consequently,there is a need for a deeper understanding of residual stress and cracking mechanisms in additively manufactured Ni-based superalloys and ways to potentially prevent cracking,as this knowledge will enable the wider application of these unique materials.To this end,this paper comprehensively reviews the residual stress and the various mechanisms of crack formation in Ni-based superalloys during AM.In addition,several common methods for inhibiting crack formation are presented to assist the research community to develop methods for the fabrication of crack-free additively manufactured components. 展开更多
关键词 Additive manufacturing Ni-based superalloys Residual stress mechanisms of crack formation Methods of crack inhibition
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Mechanism of carbonate cementation and its influence on reservoir in Pinghu Formation of Xihu Sag 被引量:3
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作者 Haiqiang Bai Xiaojun Xie +5 位作者 Gongcheng Zhang Ying Chen Ziyu Liu Lianqiao Xiong Jianrong Hao Xin Li 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2023年第3期65-75,共11页
Carbonate cements are the most abundant authigenic mineral and impact on physical properties greatly in sandstone reservoir.In this paper,Pinghu Formation of Xihu Sag was taken as a target.Characteristics,distribution... Carbonate cements are the most abundant authigenic mineral and impact on physical properties greatly in sandstone reservoir.In this paper,Pinghu Formation of Xihu Sag was taken as a target.Characteristics,distribution and formation of carbonate cements were investigated via optical microscopy,cathodoluminescence(CL),electron probe and in-situ carbon-oxygen isotope.The results showed that carbonate cements varied in types and shapes.Calcite/dolomite mainly present as poikilotopic cements,while ferrocalcite/ferrodolomite/ankerite generally present as pore-filling cements.Carbon isotope(δ^(13)C)values of carbonate cements were ranging from–7.77‰to–2.67‰,with an average of–4.52‰,while oxygen isotope(δ^(18)O)values were ranging from–18.94‰to–12.04‰,with an average of–14.86‰.Theδ^(13)C/δ^(18)O indicated that the paleo-fluid of carbonate cement was mainly freshwater.Organic carbon mainly came from organic matter within mature source rocks,and inorganic carbon came from dissolution of carbonate debris and early carbonate cements.Distinctiveδ^(13)C/δ^(18)O values manifest that carbonate cements with different types formed in different periods,which make different contributions to the reservoir properties.Calcite/dolomite formed during eodiagenesis(70–90℃)and early mesodiagenesis stage(90–120℃),and were favorable to reservoir owing to their compacted resistance and selective dissolution.Ferrocalcite/ferrodolomite/ankerite formed during middle-late mesodiagenetic stage(above 120℃),and were unfavorable to reservoir due to cementing the residual intergranular pores.Hence,in order to evaluate the reservoir characteristics,it is of significantly important to distinguish different types of carbonate cements and explore their origins. 展开更多
关键词 carbonate cements genesis mechanism Xihu Sag Pinghu formation
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Formation mechanisms of ethyl acetate and organic acids in Kluyveromyces marxianus L1-1 in Chinese acid rice soup 被引量:1
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作者 Na Liu Likang Qin +1 位作者 Laili Hu Song Miao 《Food Science and Human Wellness》 SCIE CSCD 2023年第1期45-56,共12页
This study aims to explore the formation mechanism of ethyl acetate and organic acids in acid rice soup(rice-acid soup)inoculated with Kluyveromyces marxianus L1-1 through the complementary analysis of transcriptome a... This study aims to explore the formation mechanism of ethyl acetate and organic acids in acid rice soup(rice-acid soup)inoculated with Kluyveromyces marxianus L1-1 through the complementary analysis of transcriptome and proteome.The quantity of K.marxianus L1-1 varied significantly in the fermentation process of rice-acid soup and the first and third days were the two key turning points in the growth phase of K.marxianus L1-1.Importantly,the concentrations of ethyl acetate,ethanol,acetic acid,and L-lactic acid increased from day 1 to day 3.At least 4231 genes and 2937 proteins were identified and 610 differentially expressed proteins were annotated to 30 Kyoto Encyclopedia of Genes and Genomes(KEGG)pathways based on the analysis results of transcriptome and proteome.The key genes and proteins including up-regulated alcohol dehydrogenase family,alcohol O-acetyltransferase,acetyl-CoA C-acetyltransferase,acyl-coenzyme A thioester hydrolase,and down-regulated aldehyde dehydrogenase family were involved in glycolysis/gluconeogenesis pathways,starch and sucrose metabolism pathways,amino sugar and nucleotide sugar metabolism pathways,tricarboxylic acid(TCA)cycle,and pyruvate metabolism pathways,thus promoting the formation of ethyl acetate,organic acids,alcohols,and other esters.Our results revealed the formation mechanisms of ethyl acetate and organic acids in rice-acid soup inoculated with K.marxianus L1-1. 展开更多
关键词 Kluyveromyces marxianus Fermented rice soup Ethyl acetate Organic acid formation mechanism
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Ground fissure development regularity and formation mechanism of shallow buried coal seam mining with Karst landform in Jiaozi coal mine: a case study 被引量:1
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作者 ZHU Heng-zhong 《Journal of Mountain Science》 SCIE CSCD 2023年第10期3101-3120,共20页
A comprehensive study was undertaken at Jiaozi coal mine to investigate the development regularity of ground fissures in shallow buried coal seam mining with Karst landform,shedding light on the development type,geogr... A comprehensive study was undertaken at Jiaozi coal mine to investigate the development regularity of ground fissures in shallow buried coal seam mining with Karst landform,shedding light on the development type,geographical distribution,dynamic development process,and failure mechanism of these ground fissures by employing field monitoring,numerical simulation,and theoretical analysis.The findings demonstrate that ground fissure development has an obvious feature of subregion,and its geographical distribution is significantly affected by topography.Tensile type,open type,and stepped type are three different categories of ground fissure.Ground fissures emerge dynamically as the panel advances,and they typically develop with a distance of less than periodic weighting step distance in advance of panel advancing position.Ground fissures present the dynamic development feature,temporary fissure has the ability of self-healing.The dynamic development process of ground fissure with closed-distance coal seam repeated mining is expounded,and the development scale is a dynamic development stage of“closure→expansion→stabilized”on the basis of the original development scale.From the perspective of topsoil deformation,the computation model considering two points movement vectors towards two directions of the gob and the ground surface is established,the development criterion considering the critical deformation value of topsoil is obtained.The mechanical model of hinged structure of inclined body is proposed to clarify the ground fissure development,and the interaction between slope activity and ground fissure development is expounded.These research results fulfill the gap of ground fissures about development regularity and formation mechanism,and can contribute to ground fissure prevention and treatment with Karst landform. 展开更多
关键词 Karst landform Shallow buried coal seam Development regularity formation mechanism Ground fissure Repeated mining
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Formation mechanism of co-axial grain boundaries in a Mg alloy
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作者 Zhen Peng Yi Liu +7 位作者 Lirong Xiao Yue Yang Bo Gao Mengning Xu Zhaohua Hu Yandong Yu Xuefei Chen Hao Zhou 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2023年第3期1094-1101,共8页
Due to the insufficient slip systems in hexagonal close-packed structure,twinning is frequently activated to support stable plastic deformation of Mg alloy.In this work,we found four typical twin-like interfaces with ... Due to the insufficient slip systems in hexagonal close-packed structure,twinning is frequently activated to support stable plastic deformation of Mg alloy.In this work,we found four typical twin-like interfaces with misorientations of 102°,109°,142°and 149°,respectively,which had not only a shared[1120]zone axis of neighboring grains,but also overlapped diffraction spots similar to twins.However,highresolution transmission electron microscope(HRTEM)analysis revealed that the interfaces in real space deviated from the supposed twinning planes in reciprocal space,i.e.their overlapped diffraction spots.We clarified that the incoherent interfaces were co-axial grain boundaries(CGBs).Additionally,a special angle ofθ,close to 90°,between the interface and one side of basal plane,was frequently formed in CGBs.We proposed that interaction of multiple twinning contributes to the formation of CGBs,and theθis formed due to alternative tensile and compression twinning under a uniaxial loading. 展开更多
关键词 INTERFACE TWINNING Tilt boundaries TEM formation mechanism
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Formation mechanism and criterion of linear segregation in ZL205A alloy 被引量:10
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作者 王晔 吴士平 +3 位作者 薛祥 陈瑞润 张建兵 肖文峰 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2014年第11期3632-3638,共7页
The experiments and numerical simulation were conducted for ZL205A aluminum alloy cylindrical shell casting. The formation mechanism of the linear segregation produced by the low pressure die casting (LPDC) process wa... The experiments and numerical simulation were conducted for ZL205A aluminum alloy cylindrical shell casting. The formation mechanism of the linear segregation produced by the low pressure die casting (LPDC) process was investigated. And the heat transfer of the casting during solidification process was analyzed by simulation technique, resulting from the information of linear segregation obtained by plenty of experiments. The new linear segregation criterion was proposed through the simulation and experimental results. It was found that the melting metal with high Cu contents was feeding the crack shrinkage formed by the tearing under the effect of feeding pressure during the later solidification, which led to the formation of linear segregation. The control methods for the linear segregation were suggested based on the proposed mechanism. Finally, the criterion of linear segregation was confirmed by the production of the actual castings. 展开更多
关键词 cylindrical shell casting linear segregation formation mechanism CRITERION control method
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Formation mechanism of MgB_2 in 2LiBH_4+MgH_2 system for reversible hydrogen storage 被引量:5
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作者 寇化秦 肖学章 +2 位作者 陈立新 李寿权 王启东 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2011年第5期1040-1046,共7页
The formation conditions of MgB2 in 2LiBH4 + MgH2 system during dehydrogenation were investigated and its mechanism was discussed. The results show that direct decomposition of LiBH4 is suppressed under relative high... The formation conditions of MgB2 in 2LiBH4 + MgH2 system during dehydrogenation were investigated and its mechanism was discussed. The results show that direct decomposition of LiBH4 is suppressed under relative higher initial dehydrogenation pressure of 4.0×10^5 Pa, wherein LiBH4 reacts with Mg to yield MgB2, and 9.16% (mass fraction) hydrogen is released within 9.6 h at 450 ℃. However, under relatively lower initial dehydrogenation pressure of 1.0×10^2 Pa, LiBH4 decomposes independently instead of reacting with Mg, resulting in no formation of MgB2, and 7.91% hydrogen is desorbed within 5.2 h at 450 ℃. It is found that the dehydrogenation of 2LiBH4 + MgH2 system proceeds more completely and more hydrogen desorption amount can be obtained within a definite time by forming MgB2. Furthermore, it is proposed that the formation process of MgB2 includes incubation period and nucleus growth process. Experimental results show that the formation process of MgB2, especially the incubation period, is promoted by increasing initial dehydrogenation pressure at constant temperature, and the incubation period is also influenced greatly by dehydrogenation temperature. 展开更多
关键词 complex hydride LiBH4 MGB2 hydrogen storage formation mechanism
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Microstructures and formation mechanism of headstand pyrocarbon cones developed by electromagnetic-field-assisted CVD 被引量:3
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作者 涂川俊 黄启忠 +2 位作者 张明瑜 赵新奇 陈江华 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2012年第10期2569-2577,共9页
Novel headstand pyrocarbon cones (HPCs) with hollow structure were developed on the surfaces of pyrocarbon layers of the carbon/carbon (C/C) composites at 650-750 °C by the electromagnetic-field-assisted chem... Novel headstand pyrocarbon cones (HPCs) with hollow structure were developed on the surfaces of pyrocarbon layers of the carbon/carbon (C/C) composites at 650-750 °C by the electromagnetic-field-assisted chemical vapor deposition in the absence of catalysts. The fine microstructures of the HPCs were characterized by high-resolution transmission electron microscopy. The results show that the textural features of the HPCs directly transfer from turbostratic structure in roots to a well-ordered high texture in stems. And the degree of high texture ordering decreases gradually from the stem to the tail of the HPCs. The formation mechanism of the HPCs was inferred as the comprehensive effect of polarization induction on electromagnetic fields and particle-filler property under disruptive discharge. 展开更多
关键词 headstand pyrocarbon cones chemical vapor deposition electromagnetic-field-assisted method fine microstructure formation mechanism
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Formation mechanism and organizational controlling of ultra-fine-grain copper processed by asymmetrical accumulative rolling-bond and annealing 被引量:2
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作者 王军丽 徐瑞东 +2 位作者 王绍华 钱天才 史庆南 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2012年第11期2672-2678,共7页
The initial copper with large grain sizes of 60-100 μm was processed by six passes asymmetrical accumulative rolling-bond (AARB) and annealing, the ultra-fine-grained (UFG) copper with grain size of 200 nm was ob... The initial copper with large grain sizes of 60-100 μm was processed by six passes asymmetrical accumulative rolling-bond (AARB) and annealing, the ultra-fine-grained (UFG) copper with grain size of 200 nm was obtained, and the microstructures and properties were studied. The results show that there are large sub-structures and also texture component C for the UFG copper obtained by six passes AARB, possessing high strength and microhardness in company with poor elongation and conductivity. Thereafter, the UFG copper was annealed at 220 °C for 35 min, in which the sub-structures disappear, the grain boundaries are composed of big angle grain boundaries, and the textures are composed of a variety of texture components and parts of twins. Compared with the UFG copper obtained by six passes AARB, the tensile strength and yield strength for the UFG copper obtained by six passes AARB and annealing at 220 °C for 35 min are decreased slightly, the elongation and conductivity are improved obviously. 展开更多
关键词 ultra-fine-grain copper asymmetrical accumulative rolling-bond ANNEALING formation mechanism organizational controlling elongation conductivity
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Preparation, formation mechanism and mechanical properties of multilayered TiO_2-organic nanocomposite film 被引量:2
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作者 牟文宁 翟玉春 石双志 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第4期1128-1134,共7页
Ti O2-organic multilayered nanocomposite films were deposited on a self-assembled monolayer-coated silicon substrate based on layer-by-layer technique and chemical bath deposition method by a hydrolysis of Ti Cl4 in a... Ti O2-organic multilayered nanocomposite films were deposited on a self-assembled monolayer-coated silicon substrate based on layer-by-layer technique and chemical bath deposition method by a hydrolysis of Ti Cl4 in an acid aqueous solution. The chemical compositions, surface morphologies and mechanical properties of the films were investigated by X-ray photoelectron spectrometer(XPS), scanning electron microscopy(SEM) and nanoindentation depth-sensing technique, respectively. The results indicate that the major chemical compositions of the films are Ti and O. The principal mechanism for the nucleation and growth of the films is homogeneous nucleation, and the layer number of films has great influence on the surface morphology and roughness of the films. In addition, mechanical nanoindentation testing presents a significant increase in hardness and fracture toughness of titanium dioxide multilayered films compared with single-layer titanium dioxide thin film. 展开更多
关键词 titanium dioxide multilayered film self-assembly monolayer formation mechanism mechanical properties
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Differences in and factors controlling organic matter enrichment in the Ziliujing Formation shale in the Sichuan Basin
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作者 Peng Li Zhong-Bao Liu +4 位作者 He Bi Tao Jiang Rui-Kang Bian Peng-Wei Wang Xiao-Yu Shang 《Petroleum Science》 SCIE EI CAS CSCD 2024年第1期77-86,共10页
Lacustrine shale oil and gas are important fields for unconventional exploration and development in China,and organic-rich shale deposition lays down the critical foundation for hydrocarbon generation.There are two se... Lacustrine shale oil and gas are important fields for unconventional exploration and development in China,and organic-rich shale deposition lays down the critical foundation for hydrocarbon generation.There are two sets of shale,the Dongyuemiao and Da’anzhai Members,in the Ziliujing Formation in the Sichuan Basin.To identify the differential enrichment characteristics of organic matter and clarify its controlling factors,geochemical analyses of organic and inorganic geochemical analyses were performed.The results showed that the total organic carbon content of the Dongyuemiao shale(1.36%)is slightly higher than that of the Da’anzhai shale(0.95%).The enrichment of organic matter in the two shales resulted from the comprehensive controls of paleoproductivity,paleoenvironment,and terrigenous input,but different factors have different effects.In addition,driven by climate,the change in the sulfate concentration in the bottom water further led to the different intensities of bacterial sulfate reduction in early diagenesis.This made a great difference regarding organic matter accumulation in the two members.In general,climate may have played a dominant role in organic matter enrichment in the two sets of shale. 展开更多
关键词 Lacustrine shale Ziliujing formation Sichuan Basin Enrichment mechanism of organic matter
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Adaptive Event-Triggered Time-Varying Output Group Formation Containment Control of Heterogeneous Multiagent Systems
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作者 Lihong Feng Bonan Huang +2 位作者 Jiayue Sun Qiuye Sun Xiangpeng Xie 《IEEE/CAA Journal of Automatica Sinica》 SCIE EI CSCD 2024年第6期1398-1409,共12页
In this paper,a class of time-varying output group formation containment control problem of general linear hetero-geneous multiagent systems(MASs)is investigated under directed topology.The MAS is composed of a number... In this paper,a class of time-varying output group formation containment control problem of general linear hetero-geneous multiagent systems(MASs)is investigated under directed topology.The MAS is composed of a number of tracking leaders,formation leaders and followers,where two different types of leaders are used to provide reference trajectories for movement and to achieve certain formations,respectively.Firstly,compen-sators are designed whose states are estimations of tracking lead-ers,based on which,a controller is developed for each formation leader to accomplish the expected formation.Secondly,two event-triggered compensators are proposed for each follower to evalu-ate the state and formation information of the formation leaders in the same group,respectively.Subsequently,a control protocol is designed for each follower,utilizing the output information,to guide the output towards the convex hull generated by the forma-tion leaders within the group.Next,the triggering sequence in this paper is decomposed into two sequences,and the inter-event intervals of these two triggering conditions are provided to rule out the Zeno behavior.Finally,a numerical simulation is intro-duced to confirm the validity of the proposed results. 展开更多
关键词 Adaptive control event-triggered mechanisms for-mation containment(FC) heterogeneous multiagent systems time-varying group formation.
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Porosity, permeability and rock mechanics of Lower Silurian Longmaxi Formation deep shale under temperature-pressure coupling in the Sichuan Basin, SW China 被引量:3
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作者 SUN Chuanxiang NIE Haikuan +5 位作者 SU Haikun DU Wei LU Ting CHEN Yalin LIU Mi LI Jingchang 《Petroleum Exploration and Development》 2023年第1期85-98,共14页
To investigate the porosity, permeability and rock mechanics of deep shale under temperature-pressure coupling, we selected the core samples of deep shale from the Lower Silurian Longmaxi Formation in the Weirong and ... To investigate the porosity, permeability and rock mechanics of deep shale under temperature-pressure coupling, we selected the core samples of deep shale from the Lower Silurian Longmaxi Formation in the Weirong and Yongchuan areas of the Sichuan Basin for porosity and permeability experiments and a triaxial compression and sound wave integration experiment at the maximum temperature and pressure of 120 ℃ and 70 MPa. The results show that the microscopic porosity and permeability change and the macroscopic rock deformation are mutually constrained, both showing the trend of steep and then gentle variation. At the maximum temperature and pressure, the porosity reduces by 34%–71%, and the permeability decreases by 85%–97%. With the rising temperature and pressure, deep shale undergoes plastic deformation in which organic pores and clay mineral pores are compressed and microfractures are closed, and elastic deformation in which brittle mineral pores and rock skeleton particles are compacted. Compared with previous experiments under high confining pressure and normal temperature,the experiment under high temperature and high pressure coupling reveals the effect of high temperature on stress sensitivity of porosity and permeability. High temperature can increase the plasticity of the rock, intensify the compression of pores due to high confining pressure, and induce thermal stress between the rock skeleton particles, allowing the reopening of shale bedding or the creation of new fractures along weak planes such as bedding, which inhibits the decrease of permeability with the increase of temperature and confining pressure. Compared with the triaxial mechanical experiment at normal temperature, the triaxial compression experiment at high temperature and high pressure demonstrates that the compressive strength and peak strain of deep shale increase significantly due to the coupling of temperature and pressure. The compressive strength is up to 435 MPa and the peak strain exceeds 2%, indicating that high temperature is not conducive to fracture initiation and expansion by increasing rock plasticity. Lithofacies and mineral composition have great impacts on the porosity, permeability and rock mechanics of deep shale. Shales with different lithologies are different in the difficulty and extent of brittle failure. The stress-strain characteristics of rocks under actual geological conditions are key support to the optimization of reservoir stimulation program. 展开更多
关键词 Sichuan Basin Longmaxi formation deep shale gas POROSITY PERMEABILITY rock mechanics high temperature and high pressure triaxial compression
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Integrative analysis of bone-formation associated genes and immune cell infiltration in osteoporosis, and the prediction of active ingredients in targeted traditional Chinese medicine
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作者 WANG Kai DONG Ping GUO Hongzhang 《Digital Chinese Medicine》 CAS CSCD 2024年第2期160-170,共11页
Objective To explore the differential expression and mechanisms of bone formation-related genes in osteoporosis(OP)leveraging bioinformatics and machine learning methodologies;and to predict the active ingredients of ... Objective To explore the differential expression and mechanisms of bone formation-related genes in osteoporosis(OP)leveraging bioinformatics and machine learning methodologies;and to predict the active ingredients of targeted traditional Chinese medicine(TCM)herbs.Methods The Gene Expression Omnibus(GEO)and GeneCards databases were employed to conduct a comprehensive screening of genes and disease-associated loci pertinent to the pathogenesis of OP.The R package was utilized as the analytical tool for the identification of differentially expressed genes.Least absolute shrinkage and selection operator(LASSO)logis-tic regression analysis and support vector machine-recursive feature elimination(SVM-RFE)algorithm were employed in defining the genetic signature specific to OP.Gene Ontology(GO)and Kyoto Encyclopedia of Genes and Genomes(KEGG)pathway enrichment analyses for the selected pivotal genes were conducted.The cell-type identification by estimating rela-tive subsets of RNA transcripts(CIBERSORT)algorithm was leveraged to examine the infiltra-tion patterns of immune cells;with Spearman’s rank correlation analysis utilized to assess the relationship between the expression levels of the genes and the presence of immune cells.Coremine Medical Database was used to screen out potential TCM herbs for the treatment of OP.Comparative Toxicogenomics Database(CTD)was employed for forecasting the TCM ac-tive ingredients targeting the key genes.AutoDock Vina 1.2.2 and GROMACS 2020 softwares were employed to conclude analysis results;facilitating the exploration of binding affinity and conformational dynamics between the TCM active ingredients and their biological targets.Results Ten genes were identified by intersecting the results from the GEO and GeneCards databases.Through the application of LASSO regression and SVM-RFE algorithm;four piv-otal genes were selected:coat protein(CP);kallikrein 3(KLK3);polymeraseγ(POLG);and transient receptor potential vanilloid 4(TRPV4).GO and KEGG pathway enrichment analy-ses revealed that these trait genes were predominantly engaged in the regulation of defense response activation;maintenance of cellular metal ion balance;and the production of chemokine ligand 5.These genes were notably associated with signaling pathways such as ferroptosis;porphyrin metabolism;and base excision repair.Immune infiltration analysis showed that key genes were highly correlated with immune cells.Macrophage M0;M1;M2;and resting dendritic cell were significantly different between groups;and there were signifi-cant differences between different groups(P<0.05).The interaction counts of resveratrol;curcumin;and quercetin with KLK3 were 7;3;and 2;respectively.It shows that the interac-tions of resveratrol;curcumin;and quercetin with KLK3 were substantial.Molecular docking and molecular dynamics simulations further confirmed the robust binding affinity of these bioactive compounds to the target genes.Conclusion Pivotal genes including CP;KLK3;POLG;and TRPV4;exhibited commendable significant prognostic value;and played a crucial role in the diagnostic assessment of OP.Resveratrol;curcumin;and quercetin;natural compounds found in TCM;showed promise in their potential to effectively modulate the bone-forming gene KLK3.This study provides a sci-entific basis for the interpretation of the pathogenesis of OP and the development of clinical drugs. 展开更多
关键词 OSTEOPOROSIS Bone formation Differentially expressed genes Biological information Traditional Chinese medicine(TCM) Active ingredients Molecular mechanism
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MECHANISM OF MICROBAND FORMATION IN COLD ROLLED INTERSTITIAL-FREE STEEL
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作者 沈凯 DUGGAN B J 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI 2005年第4期344-350,共7页
The mechanism of the shear band formation in the high cold rolled BCC metal is analyzed. Based on the plastic deformation theory, the shear distribution in the deformed grain is calculated by using the Taylor constrai... The mechanism of the shear band formation in the high cold rolled BCC metal is analyzed. Based on the plastic deformation theory, the shear distribution in the deformed grain is calculated by using the Taylor constraint model and the Bishop & Hill maximum work principle. Results show that when the rolling direction (RD) is parallel to a certain direction of a grain, the large localized shear occurs on one slip plane, thus generating microbands in the grain because of the high localized shear strain. The angle between the RD and the shear band is about 30°. The plate-like structure of the microband is formed because of the dislocation double cross slip. The transmission electron microscope (TEM) observation of the microband in the cold rolled BCC metal confirms the formation mechanism of the microband. 展开更多
关键词 microband plastic deformation formation mechanism transmission electron microscope
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Formation mechanism and crystal simulation of Na_2O-doped calcium aluminate compounds 被引量:2
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作者 田勇攀 潘晓林 +1 位作者 于海燕 涂赣峰 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2016年第3期849-858,共10页
Calcium aluminate clinkers doped with Na2O were synthesized using analytically pure reagents CaCO3, Al2O3, SiO2 and Na2CO3. The effects of Na2O-doping on the formation mechanism of calcium aluminate compounds and the ... Calcium aluminate clinkers doped with Na2O were synthesized using analytically pure reagents CaCO3, Al2O3, SiO2 and Na2CO3. The effects of Na2O-doping on the formation mechanism of calcium aluminate compounds and the crystal property of 12CaO·7Al2O3 (C12A7) cell were studied. The results show that the minerals containing Na2O mainly include 2Na2O·3CaO·5Al2O3 and Na2O·Al2O3, when the Na2O content in clinkers is less than 4.26% (mass fraction). The rest of Na2O is mainly doped in 12CaO·7Al2O3, which results in the decrease of the crystallinity of 12CaO·7Al2O3. The crystallinity of 2Na2O·3CaO·5Al2O3 is also inversely proportional to the Na2O content in clinkers. The formation processes of 2Na2O·3CaO·5Al2O3 and 12CaO·7Al2O3 can be divided into two ways, which are the direct reactions of raw materials and the transformation of CaO·Al2O3, respectively. The simulation shows that the covalency of O-Na bond in Na2O-doped 12CaO·7Al2O3 cell is weaker than those of O-Ca and O-Al bonds. The free energy of the unit cell increases because of Na2O doping, which results in the improvement of chemical activity of 12CaO·7Al2O3. The leaching efficiency of Al2O3 in clinker is improved from 34.81% to 88.17% when the Na2O content in clinkers increases from 0 to 4.26%. 展开更多
关键词 calcium aluminate Na_2O-doping formation mechanism crystal structure SINTERING computer simulation
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Reservoir characteristics,formation mechanisms and petroleum exploration potential of volcanic rocks in China 被引量:13
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作者 Zhi-Guo Mao Ru-Kai Zhu +4 位作者 Jing-Lan Luo Jing-Hong Wang Zhan-Hai Du Ling Su Shao-Min Zhang 《Petroleum Science》 SCIE CAS CSCD 2015年第1期54-66,共13页
Characterized by complex lithology and strong heterogeneity, volcanic reservoirs in China developed three reservoir space types: primary pores, secondary pores and fractures. The formation of reservoir space went thr... Characterized by complex lithology and strong heterogeneity, volcanic reservoirs in China developed three reservoir space types: primary pores, secondary pores and fractures. The formation of reservoir space went through the cooling and solidification stage (including blast fragmentation, crystallization differentiation and solidification) and the epidiagenesis stage (including metasomatism, filling, weathering and leaching, formation fluid dissolution and tectonism). Primary pores were formed at the solidification stage, which laid the foundation for the development and transformation of effective reservoirs. Secondary pores were formed at the epidiagenesis stage, with key factors as weathering and leaching, formation fluid dissolution and tectonism. In China, Mesozoic-Cenozoic volcanic rocks developed in the Songliao Basin and Bohai Bay Basin in the east and Late Paleozoic volcanic rocks developed in the Junggar Basin, Santanghu Basin and Ta- rim Basin in the west. There are primary volcanic reser- voirs and secondary volcanic reservoirs in these volcanic rocks, which have good accumulation conditions and great exploration potential. 展开更多
关键词 Volcanic reservoirs DIAGENESIS formation mechanism Hydrocarbon exploration
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