Role of Ordering Energy in Formation of Grain Structure and Special Boundaries Spectrum in Ordered Alloys with L12 Superstructure

It was revealed that an average energy of special boundaries is proportional to APB energy in the alloys with the L12 superstructure. This fact proves the appearance of the GAPBs in the planes of location of special boundaries in coincidence sites of ordered alloys. It was determined that the more energy of special boundaries in ordered alloys, the more energy of complex stacking fault. There is a correlation between the distribution of special boundaries as a function its relative energy and ordering energy: the more ordering energy, the more degree of washed away of distribution. The correlation between average relative energy of special boundaries and ordering energy was detected: the more ordering energy, the more average energy of special boundaries. The reverse dependence between ordering energy and average number of special boundaries in grains limited by boundaries of general type was discovered.

Role of Disclinations and Nanocrystalline State in the Formation of Quasicrystalline Phases on Mechanical Alloying of Cu-Fe Powders

Elemental powders of Cu and Fe were ball milled for various time durations up to 100 h. The various stages of forced alloying by ball milling, leading to instability of elemental crystalline phases and formation of quasicrystalline phases were monitored using X-ray diffraction. Diffusion of Fe into the Cu matrix is proposed as the cause which triggers the instability of crystalline phases and leads to the formation of quasicrystalline phases after 10 h of milling. Milling for 100 h resulted in two different quasicrystalline phases with different lattice constants. Role of the nanocrystalline microstructure as an important criterion for the destabilisation of crystalline phases is explained. It is suggested that the formation of nanocrystalline microstructure and their subsequent transformation into quasicrystalline phases may be associated with a continuous increase in the disclination content of the system, which had formed as a result of continued milling and mechanical deformation.

The Role of Topography and Diabatic Heating in the Formation of Dipole Blocking in the Atmosphere

In this paper, the nonlinear stationary waves forced by topography and diabatic heating are investigated. It is pointed out that (1) the nonlinear interaction of different stationary waves forced only by topography might form dipole blocking in the atmosphere, this might explain the dipole blocking appeared in the Pacific and Atlantic regions; (2) the dipole blocking could not be caused by the nonlinear interaction of the different stationary waves forced by the diabatic heating alone; (3) the nonlinear interaction of the diffferent stationary waves forced by both topography and diabatic heating could initiate dipole blocking in the atmosphere. In winter, the dipole blocking mainly occurs in the west regions of the Pacific and the Atlantic, and the heat source over the western part of the two oceans is advantageous to the formation of dipole blocking in the west of two oceans. However, in summer, the dipole blocking could be formed in the east part of the two oceans, and the heat source over the eastern part of two continents is favourable for the formation of dipole blocking in the east regions of two oceans.

Sulfate formation and its key role in severe haze development over China

Subject Code:B07With the financial support by the National Natural Science Foundation of China and the Chinese Academy of Sciences,Prof.Wang Gehui(王格慧)at the State Key Laboratory of Loess and Quaternary,Institute of Earth Environment,Chinese Academy of Sciences,and the researchers from China,USA and other countries have revealed a key role of sulfate in the developing process of Chinese haze,which

The role of the sulfur 3d orbitals in bond formation in sulfur-containing compounds

The role of the sulfur 3d orbitals in bond formation is discussed by taking into account the influence of the environment on the orbitals of the sulfur atom in the molecules. The ca cula- tion results of a series of prototype molecules containing sulfur such as SF_2, SF_4, NSF_3, SF_1, H_2S are reported. It is convincingly shown that in highly electronegative environment the energy levels of the sulfur 3d orbitals are reduced to the vicinity of those of the ligand valence orbitals and their spatial distributions are contracted to the bonding area, and therefore they can participate in bond formation to a certain extent, which is enhanced by the formation of the d-p π back bonds. It seems that the result reported in this paper is helpful for the solution of the long-standing debate about the sulfur 3d orbital participation in bond formation.