Formation condition of solid solution type high-entropy alloy

Formation condition of high-entropy alloys with solid solution structure was investigated. Seventeen kinds of the high-entropy alloys with different components were prepared, the influencing factors （the comprehensive atomic radius difference δ, the mixing enthalpy AH and the mixing entropy AS） of phase composition of the alloys were calculated, and the microstructure and phase compositions of alloys were analyzed by using SEM and XRD. The result shows that only the systems with δ≤2.77 and △H≥-8.8 kJ/mol will form high entropy alloy with simple solid solution. Otherwise, intermetallic compounds will exist in the alloys. So, selection of the type of element has important effects on microstructure and properties of high entropy alloys.

The Analysis on Comparison of Forming Condition with Abroad Palaeo-Epicontinental Marine Basin and Possibility of Potash Formation in North China

1 Introduction Currently,all six different continents have discovered potash deposits and potash-bearing salt lake saline water.However,the distribution is extremely uneven,which is mostly concentrated in Canada,Russia,Middle-Asia and

Effect of Deformation Condition on Axial Compressive Precision Forming Process of Tube with Curling Die

The effect of the deformation condition on the axial compressive precision forming process of tube with curling die was investigated by using a rigid-plastic FEM. The results show that the forming accuracy depends mainly on geometric condition rp/d0, little on tube material properties and friction condition; the relative gap △/2rp of double-walled tubes obtained decreases with Increasing rp/d0, and there is a parameter k for a given to/do or rp/t0, when rp/d0 >k, △/2rp< 1, otherwise △/2rp>1.

Experimental Study on Formation Conditions of Ammoniojarosite and Its Environmental Significance

Formation conditions of ammoniojarosite in system Fe2（SO4）3-（NH4）2SO4-H2O are investigated in this paper. The results show that ammoniojarosite can be formed rapidly under normal temperature and pressure by controlling suitable pH value and Fe2（SO4）3 and （NH4）2SO4 concentrations. The pH value, temperature and concentration of Fe2（SO4）3 medium are key factors influencing the formation of ammoniojarosite. Under normal temperature, precipitation of ammoniojarosite can be seen within 24 hours at pH values between 2.6-3.1, and a great quantity of ammoniojarosite is formed within 48 hours. At about 90℃, the pH value range forming ammoniojarosite extends to 1.2-3.1, and within this range the rise of pH value is advantageous to the formation of ammoniojarosite and high Fe2（SO4）3 concentration is also advantageous. Relative pure ammoniojarosite is synthesized under high Fe2（SO4）3 concentration （≥0.05 M） and ammoniojarosite containing melanterite and colloid amorphous hydroxide vitriol iron is formed at low Fe2（SO4）3 concentration. The deposition process of ammoniojarosite can be used to harness wastewater from mines and other industries and remove S, Fe and other toxic and harmful elements, such as As, Cr, Hg, Pb in water. Rapid formation of ammoniojarosite and other jarosite analogs under normal temperature and pressure has a good potential prospect for harnessing acid wastewater by means of precipitation of jarosite and its analogs.

Geological Conditions and Prospect Forecast of Shale Gas Formation in Qiangtang Basin, Qinghai-Tibet Plateau

The presence of shale gas has been confirmed in almost every marine shale distribution area in North America.Formation conditions of shale gas in China are the most favorable for marine,organic-rich shale as well.But there has been little research focusing on shale gas in Qiangtang Basin,Qinghai-Tibet Plateau,where a lot of Mesozoic marine shale formations developed.Based on the survey results of petroleum geology and comprehensive test analysis data for Qinghai-Tibet Plateau,for the first time,this paper discusses characteristics of sedimentary development,thickness distribution,geochemistry,reservoir and burial depth of organic-rich shale,and geological conditions for shale gas formation in Qiangtang Basin.There are four sets of marine shale strata in Qiangtang Basin including Upper Triassic Xiaochaka Formation （T3x）,Middle Jurassic Buqu Formation （J2b）,Xiali Formation （J2x） and Upper Jurassic Suowa Formation （J3s）,the sedimentary types of which are mainly bathyal-basin facies,open platform-platform margin slope facies,lagoon and tidal-fiat facies,as well as delta facies.By comparing it with the indicators of gas shale in the main U.S.basins,it was found that the four marine shale formations in Qiangtang Basin constitute a multi-layer distribution of organic-rich shale,featuring a high degree of thickness and low abundance of organic matter,high thermal evolution maturity,many kinds of brittle minerals,an equivalent content of quartz and clay minerals,a high content of feldspar and low porosity,which provide basic conditions for an accumulation of shale gas resources.Xiaochaka Formation shale is widely distributed,with big thickness and the best gas generating indicators.It is the main gas source layer.Xiali Formation shale is of intermediate thickness and coverage area,with relatively good gas generating indicators and moderate gas formation potential.Buqu Formation shale and Suowa Formation shale are of relatively large thickness,and covering a small area,with poor gas generating indicators,and limited gas formation potential.The shale gas geological resources and technically recoverable resources were estimated by using geologic analogy method,and the prospective areas and potentially favorable areas for Mesozoic marine shale gas in Qiangtang Basin are forecast and analyzed.It is relatively favorable in a tectonic setting and indication of oil and gas,shale maturity,sedimentary thickness and gypsum-salt beds,and in terms of mineral association for shale gas accumulation.But the challenge lies in overcoming the harsh natural conditions which contributes to great difficulties in ground engineering and exploration,and high exploration costs.

Prediction of Structure-H Gas Hydrate Formation Conditions for Reservoir Fluids

In this work, a thermodynamic model is developed for prediction of structure H hydrate formation. The model combines the Peng-Robinson equation of state for the vapor, liquid and aqueous phases with the extended Ng-Robinson hydrate model for gas hydrate formation of all three structures. The parameters of 14 structure- H hydrate formers are determined based on the experimental data of structure-H hydrates in the literature. The expression of fugacity of water in the empty hydrate phase is correlated for calculating structure-H hydrate formation conditions in the absence of free water. The model is tested by predicting hydrate formation conditions of a number of structure-H hydrate forming systems which are in good agreement with the experimental data. The proposed model is also applied to the prediction of hydrate formation conditions for various reservoir fluids such as natural gas and gas condensate.

AN ANALYSIS OF THE GEOTECTONICCONDITIONS OF FORMATION OF NONMETALLIC ORES ON THE WESTERN MARGIN OF THE DONGTING DIWA

There is a close relationship between occurrence of nonmetallic minerals and tectonic evolution of geosyncline, platform and diwa (geodepression) on the western margin of the Dongting diwa. Some results that (1) diwa tectonics is berfeficial for formation and preservation of nonmetallic minerals and (2) volcano-sedimentary altered ore deposits, saline deposits and organo-sedimentary ore deposits can be often found in diwa basins are gained.

Geothermal resources formation conditions and preferred target areas in a certain county of Western Sichuan, China

The geothermal resource is a form of "green" and renewable energy with huge development potential in terms of both environmental protection and economy. It was concluded that the exposed hot springs were mostly produced when fluids derived from atmospheric precipitation were heated deep and recurrently under the ground, developed banded geothermal reservoir in the pores of fault damage zones, fissure zones, hornification zones and dikes, and then moved upward with analyzing the geological and hydrogeological data as well as hydrochemical types of the naturally exposed hot springs in the studied region so as to ascertain the accumulation conditions of geothermal resources in a particular county in Western Sichuan and opt for suitable target areas for exploring geothermal resources. Four areas where geothermal resources are potentially located were proposed with analysis of their formation conditions based on this notion, and the "epsilon-shaped" structure in Zhimulin, the "epsilon-shaped" structure in Jiaochang, the vortex structure in Rewugou and the arcuate structure in Shidaguan were analyzed in this paper offering a reference for developing and exploiting the geothermal resources in the region as well as studying the development patterns of other hot springs in this region.

Study of the Conditions of Formation and Forecast of the Perspective Areas of Hydrogen-Sulfide Water of Surkhandarya Depression

Increase in requirement of hydrosulphuric water for improvement of the population set the task of identification of places of their possible congestion for hydrogeological service. Earlier detection of such congestions was accidental at well-drilling of different function. Therefore, development of new methodical approaches of search and allocation of perspective zones of their formation was required. It was for this purpose necessary to study in what conditions and what factors have an impact on formation of underground hydrosulphuric water. So far, definition of communication attempts only with separate geochemical signs was known. Results of studying of influence on formations of hydrosulphuric water of such factors as lithologic and facial in combination with oil-and-gas content, the geological and structural and hydrodynamic mode are given in this work. It is established that the main sign for formation of hydrosulphuric water is existence of evaporite thickness and hydrocarbon congestions. Besides, it is shown that small depth (up to 2 km) of their bedding has to be an indispensable condition and existence of explosive violation on which there has to be a water infiltration (a geological and structural factor). In the Surkhandarya region, the hydrodynamic mode caused by inclined bedding of aquifers was also one of essential factors. Active water is an exchange process with washing away (oxidation) sulfate of the containing thicknesses and subsequently, its restoration in interaction with hydrocarbons with formation of hydrosulphuric water is described. The technique is developed and the expected card of perspective zones of formation of hydrosulphuric water is constructed.

Spectroscopic Features and Formation Conditions of Sphalerite in the Lead-Zinc Deposit, Guangdong,China

Electron paramagnetic resonance spectra, absorption spectra, cathodoluminescence spectra and infrared spectra of sphalerite from the Lechang remoulded sedimentary lead-zinc deposit have been studied so as to provide microscopic evidence for the formation conditions and mineralization stages of the deposit as well as the geochemical processes of mineralization. On the basis of thermodynamic calculations, the stable fields of sphalerite from different mineralization stages were determined and are shown in logfs_2-logfo_2 diagrams; furthermore. the physico-chemical conditions of mineralization and the properties of mineralization solutions are discussed so that reliability of the genetic information provided by the spectroscopy of sphalerite may also be verified. It is suggested that the temperature and pH value of the mineralization system decrease, and so do the fugacities of O_2, S_2, H_2. and H_2S and the activities of HS^- and SO_4^(2-) from the early to late stages of minerahzation.

CONDITIONS FOR INCIPIENT CAVITATION FORMATION

The growth, equilibrium and stabilization of free gas nucleus are analyzed. It is shown that the cavitation results from growth of free gas nucleus to critical radius and conditions of cavitation have been derived.

Conditions for the Formation of Oil and Gas Pools in Tertiary Volcanics in the Western Part of the Huimin Sag, Shandong and Their Distribution

Conditions for the Formation of oil and gas pools in Tertiary volcanics in the western part of the Huimin sag, Shandong and then (?)stribution have been studied based on the geological, seismic and well-logging information. In this paper, the types and lithofacies of the volcanic rocks in the western part of the Huimin sag are described; the relationship between rocks and electrical properties, the seismic reflection structures, the development and distribution of the volcanic rocks are expounded; and the fourfold role of the volcanic activities in the formation of the oil and gas pools is also dealt with. It is considered by the authors that the volcanic activities were not destructive to the formation of oil and gas pools but a factor favourable to the accumulation of organic matters and their conversion to hydrocarbon. The volcanic rocks might have served as reservoir rocks and cap rocks, or as a synsedimentary anticline. The prerequisites and important factors for the formation of oil and gas pools and their distribution are pointed out in the paper.

In situ formation of an intimate solid-solid interface by reaction between MgH_(2) and Ti to stabilize metal hydride anode with high active material content

MgH_(2) and TiH_(2) have been extensively studied as potential anode materials due to their high theoretical specific capacities of 2036 and 1024 mAh/g,respectively.However,the large volume changes that these compounds undergo during cycling affects their performance and limits practical applications.The present work demonstrates a novel approach to limiting the volume changes of active materials.This effect is based on mechanical support from an intimate interface generated in situ via the reaction between MgH_(2) and Ti within the electrode prior to lithiation to form Mg and TiH_(2).The resulting Mg can be transformed back to MgH_(2) by reaction with LiH during delithiation.In addition,the TiH_(2) improves the reaction kinetics of MgH_(2) and enhances electrochemical performance.The intimate interface produced in this manner is found to improve the electrochemical properties of a MgH_(2)-Ti-LiH electrode.An exceptional reversible capacity of 800 mAh/g is observed even after 200 cycles with a high current density of 1 mA/cm^(2) and a high proportion of active material(90 wt.%)at an operation temperature of 120℃.This study therefore showcases a new means of improving the performance of electrodes by limiting the volume changes of active materials.

Analysis of Reservoir Forming Conditions and Prediction of Continuous Tight Gas Reservoirs for the Deep Jurassic in the Eastern Kuqa Depression,Tarim Basin

The exploration targets in the Kuqa Depression at present are mainly structure traps in Cretaceous-Tertiary.Due to the complexity of mountain distribution and reservoir forming conditions, the exploration of Jurassic in the eastern Kuqa Depression has been in a state of semi-stagnation since the discovery of the Yinan-2 gas reservoir.According to the concept and theory of 'continuous petroleum reservoirs' and the re-analysis of the forming conditions of the Yinan-2 gas reservoir and regional natural gas in the eastern Kuqa Depression,it is believed that the deep Jurassic has good natural gas accumulation conditions as well as geological conditions for forming continuous tight gas reservoirs.The boundary of the Yinan-2 gas reservoir is not controlled by a structural spillpoint.The downdip part of the structure is dominated by gas,while the hanging wall of the fault is filled by water and forming obvious inverted gas and water.The gas reservoir has the normal temperature and ultrahigh pressure which formed in the near source or inner-source.All of these characteristics indicate that the Yinan-2 gas reservoir is different from conventional gas reservoirs.The deep Jurassic in the eastern Kuqa Depression has multisets of source-reservoir-cap assemblages,which comprise interbedded sandstones and mudstones.These assemblages are characterized by a self-generation,self-preserving and self-coverage model.Reservoir sandstones and coal measure mudstones are interbedded with each other at a large scale.As the source rocks,Triassic-Jurassic coal measure mudstones distribute continuously at a large scale and can generate and expel hydrocarbon.Source rocks contact intimately with the overlying sandstone reservoirs.During the late stage of hydrocarbon expulsion,natural gas charged continuously and directly into the neighboring reservoirs.Petroleum migrated mainly in a vertical direction over short distances.With ultra-high pressure and strong charging intensity,natural gas accumulated continuously.Reservoirs are dominated by sandstones of braided delta facies.The sand bodies distribute continuously horizontal.With low porosity and low permeability,the reservoirs are featured by strong heterogeneity.It is hypothesized that the sandstones of the interior depression tend to be relatively tight with increasing depth and structure stress weakness.Thus,it is predicted that continuous tight gas reservoirs of ultra-high pressure may exist in the deep formations of the eastern and even the whole Kuqa Depression.So,it is worth evaluating the exploration potential.

Bulging in incremental sheet forming of cold bonded multi-layered Cu clad sheet: Influence of forming conditions and bending

Bulge is a defect that causes geometrical inaccuracy and premature failure in the innovative incremental sheet forming (ISF) process. This study has two-fold objectives:(1) knowing the bulging behavior of a Cu clad tri-layered steel sheet as a function of forming conditions, and (2) analyzing the bending effect on bulging in an attempt to identify the associated mechanism. A series of ISF tests and bending analysis are performed to realize these objectives. From the cause-effect analysis, it is found that bulge formation in the layered sheet is sensitive to forming conditions in a way that bulging can be minimized utilizing annealed material and performing ISF with larger tool diameter and step size. The bending under tension analysis reveals that the formation of bulge is an outgrowth of bending moment that the forming tool applies on the sheet during ISF. Furthermore, the magnitude of bending moment depending upon the forming conditions varies from 0.046 to 10.24 N·m/m and causes a corresponding change in the mean bulge height from 0.07 to 0.91 mm. The bending moment governs bulging in layered sheet through a linear law. These findings lead to a conclusion that the bulge defect can be overcome by controlling the bending moment and the formula proposed can be helpful in this regards.

Forming Condition and Geology Prediction Techniques of Deep Clastic Reservoirs

1 Introduction As new exploration domain for oil and gas,reservoirs with low porosity and low permeability have become a hotspot in recent years(Li Daopin,1997).With the improvement of technology,low porosity and low

FEM simulation and experimental verification of roll forming and springback process under complex contact conditions

The application of advanced high strength steel （AHSS） has an important significance in the development of the lightweight of automobile, but the parts made of AHSS usually have defects, such as fracture and large amount of springback, etc. In this paper, a model of multi-pass roll form- ing and springback process of AHSS is established with finite element software ABAQUS. Then a roll forming experiment is performed, and simulation and experimental results have been compared and analyzed. The model is established under complex contact conditions, including self-contact condi- tion. The results shows that during the process of sheet bending, large Mises stresses appear at ben- ding corners. The smaller the bending radius is, the larger the Mises stress and strain are. Thick- ness of sheet metal changes exceeds a certain limit, the differently if the bending radius is different. When the bending radius change tendency of the sheet thickness turns from increase to decrease.

Ore-forming Conditions and Prospecting in the West Kunlun Area,Xinjiang, China

The West Kunlun ore-forming belt is located between the northwestern Qinghai-Tibet Plateau and southwestern Tarim Basin. It situated between the Paleo-Asian Tectonic Domain and Tethyan Tectonic Domain. It is an important component of the giant tectonic belt in central China (the Kunlun-Qilian-Qinling Tectonic Belt or the Central Orogenic Belt). Many known ore-forming belts such as the Kunlun-Qilian Qinling ore-forming zone, Sanjiang (or Three river) ore-forming zone, Central Asian ore-forming zone, etc. pass through the West Kunlun area. Three ore-forming zones and seven ore-forming subzones were classified, and eighteen mineralization areas were marked. It is indicated that the West Kunlun area is one of the most favorable region for finding out large and superlarge ore deposits.

A statistical method for assessment of the existing correlations of hydrate forming conditions

Hydrate formation in the oil and gas industries has been a serious problem for a long time. It may cause many difficulties for instance in gas pipelines blockages. In order to determine the hydrate forming condition, gas gravity method has been used. Several correlations have been proposed based on gas gravity method. Checking the accuracy of the applied correlations is important. In this paper, the leverage approach is used for this purpose. Leverage approach is a statistical method for detection outliers which identifies the applicability domain （AD） of hydrate data predicting correlations and the quality of the existing data. Moreover, the Williams plot is sketched, which is a graphical depiction for determination of the doubtful points. The obtained results showed the existing correlations are all statistically correct and valid to predict hydrate formation temperature, just one data point is out of the applicability domains, and none of the experimental data can be chosen as outliers.