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NUMERICAL METHOD OF MIXED FINITE VOLUME-MODIFIED UPWIND FRACTIONAL STEP DIFFERENCE FOR THREE-DIMENSIONAL SEMICONDUCTOR DEVICE TRANSIENT BEHAVIOR PROBLEMS 被引量:5
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作者 袁益让 杨青 +1 位作者 李长峰 孙同军 《Acta Mathematica Scientia》 SCIE CSCD 2017年第1期259-279,共21页
Transient behavior of three-dimensional semiconductor device with heat conduc- tion is described by a coupled mathematical system of four quasi-linear partial differential equations with initial-boundary value conditi... Transient behavior of three-dimensional semiconductor device with heat conduc- tion is described by a coupled mathematical system of four quasi-linear partial differential equations with initial-boundary value conditions. The electric potential is defined by an ellip- tic equation and it appears in the following three equations via the electric field intensity. The electron concentration and the hole concentration are determined by convection-dominated diffusion equations and the temperature is interpreted by a heat conduction equation. A mixed finite volume element approximation, keeping physical conservation law, is used to get numerical values of the electric potential and the accuracy is improved one order. Two con- centrations and the heat conduction are computed by a fractional step method combined with second-order upwind differences. This method can overcome numerical oscillation, dispersion and decreases computational complexity. Then a three-dimensional problem is solved by computing three successive one-dimensional problems where the method of speedup is used and the computational work is greatly shortened. An optimal second-order error estimate in L2 norm is derived by using prior estimate theory and other special techniques of partial differential equations. This type of mass-conservative parallel method is important and is most valuable in numerical analysis and application of semiconductor device. 展开更多
关键词 three dimensional transient behavior of heat conduction problem mixed finitevolume element modified upwind fractional step difference second-order error
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FINITE DIFFERENCE FRACTIONAL STEP METHODS FOR THE TRANSIENT BEHAVIOR OF A SEMICONDUCTOR DEVICE 被引量:4
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作者 袁益让 《Acta Mathematica Scientia》 SCIE CSCD 2005年第3期427-438,共12页
Characteristic finite difference fractional step schemes are put forward. The electric potential equation is described by a seven-point finite difference scheme, and the electron and hole concentration equations are t... Characteristic finite difference fractional step schemes are put forward. The electric potential equation is described by a seven-point finite difference scheme, and the electron and hole concentration equations are treated by a kind of characteristic finite difference fractional step methods. The temperature equation is described by a fractional step method. Thick and thin grids are made use of to form a complete set. Piecewise threefold quadratic interpolation, symmetrical extension, calculus of variations, commutativity of operator product, decomposition of high order difference operators and prior estimates are also made use of. Optimal order estimates in l2 norm are derived to determine the error of the approximate solution. The well-known problem is thorongley and completely solred. 展开更多
关键词 General region semiconductor device 3-dimensional heat conduction characteristic finite difference parallel fractional steps l^2 error estimate.
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THEORY AND APPLICATION OF FRACTIONAL STEP CHARACTERISTIC FINITE DIFFERENCE METHOD IN NUMERICAL SIMULATION OF SECOND ORDER ENHANCED OIL PRODUCTION 被引量:1
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作者 袁益让 程爱杰 +1 位作者 羊丹平 李长峰 《Acta Mathematica Scientia》 SCIE CSCD 2015年第6期1547-1565,共19页
A kind of second-order implicit fractional step characteristic finite difference method is presented in this paper for the numerically simulation coupled system of enhanced (chemical) oil production in porous media.... A kind of second-order implicit fractional step characteristic finite difference method is presented in this paper for the numerically simulation coupled system of enhanced (chemical) oil production in porous media. Some techniques, such as the calculus of variations, energy analysis method, commutativity of the products of difference operators, decomposition of high-order difference operators and the theory of a priori estimates are introduced and an optimal order error estimates in l^2 norm is derived. This method has been applied successfully to the numerical simulation of enhanced oil production in actual oilfields, and the simulation results ate quite interesting and satisfactory. 展开更多
关键词 enhanced (chemical) oil production three-dimensional porous coupled system second-order implicit characteristic fractional step differences optimal order l^2 estimate application in actual oilfields
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Fractional four-step finite element method for analysis of thermally coupled fluid-solid interaction problems 被引量:1
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作者 A. MALATIP N. WANSOPHARK P. DECHAUMPHAI 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2012年第1期99-116,共18页
An integrated fluid-thermal-structural analysis approach is presented. In this approach, the heat conduction in a solid is coupled with the heat convection in the viscous flow of the fluid resulting in the thermal str... An integrated fluid-thermal-structural analysis approach is presented. In this approach, the heat conduction in a solid is coupled with the heat convection in the viscous flow of the fluid resulting in the thermal stress in the solid. The fractional four-step finite element method and the streamline upwind Petrov-Galerkin (SUPG) method are used to analyze the viscous thermal flow in the fluid. Analyses of the heat transfer and the thermal stress in the solid axe performed by the Galerkin method. The second-order semi- implicit Crank-Nicolson scheme is used for the time integration. The resulting nonlinear equations are lineaxized to improve the computational efficiency. The integrated analysis method uses a three-node triangular element with equal-order interpolation functions for the fluid velocity components, the pressure, the temperature, and the solid displacements to simplify the overall finite element formulation. The main advantage of the present method is to consistently couple the heat transfer along the fluid-solid interface. Results of several tested problems show effectiveness of the present finite element method, which provides insight into the integrated fluid-thermal-structural interaction phenomena. 展开更多
关键词 fluid-solid interaction finite element method fractional four-step method
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Characteristic fractional step finite difference method for nonlinear section coupled system
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作者 袁益让 李长峰 +1 位作者 孙同军 刘允欣 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2014年第10期1311-1330,共20页
For the section coupled system of multilayer dynamics of fluids in porous media, a parallel scheme modified by the characteristic finite difference fractional steps is proposed for a complete point set consisting of c... For the section coupled system of multilayer dynamics of fluids in porous media, a parallel scheme modified by the characteristic finite difference fractional steps is proposed for a complete point set consisting of coarse and fine partitions. Some tech- niques, such as calculus of variations, energy method, twofold-quadratic interpolation of product type, multiplicative commutation law of difference operators, decomposition of high order difference operators, and prior estimates, are used in theoretical analysis. Optimal order estimates in 12 norm are derived to show accuracy of the second order approximation solutions. These methods have been used to simulate the problems of migration-accumulation of oil resources. 展开更多
关键词 three-dimensional section coupled system complete nonlinear equation characteristic fractional step CONVERGENCE numerical simulation
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GENERALIZED UPWIND SCHEME WITH FRACTIONAL STEPS FOR 3-D PROBLEM OF CONVECTION DOMINATING GROUNDWATER TRANSPORT
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作者 姚磊华 《Journal of Coal Science & Engineering(China)》 1997年第2期68-72,共5页
A generalized upwind scheme with fractional steps for 3-D mathematical models of convection dominating groundwater quality is suggested. The mass transport equation is split into a convection equation and a dispersive... A generalized upwind scheme with fractional steps for 3-D mathematical models of convection dominating groundwater quality is suggested. The mass transport equation is split into a convection equation and a dispersive equation. The generalized upwind scheme is used to solve the convection equation and the finite element method is used to compute the dispersive equation.These procedures which not only overcome the phenomenon of the negative concentration and numerical dispersion appear frequently with normal FEM or FDM to solve models of convection dominating groundwater transport but also avoid the step for computing each node velocity give a more suitable method to calculate the concentrations of the well points. 展开更多
关键词 3-D problem of groundwater transport convection dominating fractional step generalized upwind scheme
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Numerical Solution of the Rotating Shallow Water Flows with Topography Using the Fractional Steps Method
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作者 Hossam S. Hassan Khaled T. Ramadan Sarwat N. Hanna 《Applied Mathematics》 2010年第2期104-117,共14页
The two-dimensional nonlinear shallow water equations in the presence of Coriolis force and bottom topography are solved numerically using the fractional steps method. The fractional steps method consists of splitting... The two-dimensional nonlinear shallow water equations in the presence of Coriolis force and bottom topography are solved numerically using the fractional steps method. The fractional steps method consists of splitting the multi-dimensional matrix inversion problem into an equivalent one dimensional problem which is successively integrated in every direction along the characteristics using the Riemann invariant associated with the cubic spline interpolation. The height and the velocity field of the shallow water equations over irregular bottom are discretized on a fixed Eulerian grid and time-stepped using the fractional steps method. Effects of the Coriolis force and the bottom topography for particular initial flows on the velocity components and the free surface elevation have been studied and the results are plotted. 展开更多
关键词 Shallow Water Equations fractional steps METHOD RIEMANN INVARIANTS Bottom TOPOGRAPHY Cubic SPLINE Interpolation
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The Theory and Application of Upwind Finite Difference Fractional Steps Procedure for Seawater Intrusion
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作者 Yirang Yuan Hongxing Rui +1 位作者 Dong Liang Changfeng Li 《International Journal of Geosciences》 2012年第5期972-991,共20页
Numerical simulation and theoretical analysis of seawater intrusion is the mathematical basis for modern environmental science. Its mathematical model is the nonlinear coupled system of partial differential equations ... Numerical simulation and theoretical analysis of seawater intrusion is the mathematical basis for modern environmental science. Its mathematical model is the nonlinear coupled system of partial differential equations with initial-boundary problems. For a generic case of a three-dimensional bounded region, two kinds of finite difference fractional steps pro- cedures are put forward. Optimal order estimates in norm are derived for the error in the approximation solution. The present method has been successfully used in predicting the consequences of seawater intrusion and protection projects. 展开更多
关键词 Seawater INTRUSION Three-Dimensional Region UPWIND fractionAL stepS NORM ESTIMATE Numerical Simulation
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基于IECSDE算法的PEMFC改进分数阶子空间辨识模型
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作者 秦灏 戚志东 +1 位作者 于灵芝 童新 《计算机工程》 CAS CSCD 北大核心 2024年第6期346-357,共12页
为准确描述质子交换膜燃料电池(PEMFC)在其发电过程中的特性及变量影响关系,提出一种基于信息交流布谷鸟搜索差分进化(IECSDE)算法的改进分数阶子空间辨识方法来建立PEMFC分数阶模型。首先基于状态空间方程建立PEMFC模型,为了描述PEMFC... 为准确描述质子交换膜燃料电池(PEMFC)在其发电过程中的特性及变量影响关系,提出一种基于信息交流布谷鸟搜索差分进化(IECSDE)算法的改进分数阶子空间辨识方法来建立PEMFC分数阶模型。首先基于状态空间方程建立PEMFC模型,为了描述PEMFC的分数阶特性,将分数阶微分理论融入到模型中,引入Poisson滤波函数预处理实验数据,解决数据多阶不可导的问题,同时引入变步长记忆法处理分数阶微分时的权系数,提高子空间辨识精度。其次在辨识过程中的参数对于建模效果具有重大影响,因此基于IECSDE算法并对其进行优化,对布谷鸟搜索(CS)算法中的控制参数进行自适应处理,受到粒子群优化(PSO)算法的启发,改进随机游走方式提高收敛精度和速度,并引入差分进化(DE)算法与改进CS算法分别对种群进行优化,同时在寻优过程中进行信息交流提高种群的多样性和算法的鲁棒性。仿真结果表明,IECSDE算法的寻优能力在8种测试函数下比其他5种优化算法至少提升了10倍;通过对PEMFC测控平台收集到的实验数据进行模型辨识,所建立的模型将误差缩小到基于短记忆法的分数阶子空间辨识方法误差的20%,输出功率误差控制在0~0.1之间,输出电压误差控制在0~0.2之间,能够精准地模拟PEMFC发电过程。 展开更多
关键词 质子交换膜燃料电池 分数阶子空间辨识 变步长记忆法 优化算法 信息交流
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3Dmesh包覆仪表板副驾气囊区域分步弱化方法研究
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作者 苌占波 李成 +2 位作者 陈婧 于来水 王慧焕 《汽车科技》 2024年第1期38-42,共5页
本文简要叙述了3Dmesh包覆的仪表板副驾气囊区域常见的弱化方法,重点分析了分步弱化方案中,表皮、3Dmesh及骨架的设计要点及关键工艺要求。并根据实际项目经验,总结了常见弱化缺陷产生的原因及相应解决方案,为后续项目开发提供了参考。
关键词 仪表板 3Dmesh 分步弱化法 弱化线 设计要点
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Criteria for Response Monotonicity Preserving in Approximation of Fractional Order Systems
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作者 Mohammad Saleh Tavazoei 《IEEE/CAA Journal of Automatica Sinica》 SCIE EI 2016年第4期422-429,共8页
In approximation of fractional order systems,a significant objective is to preserve the important properties of the original system.The monotonicity of time/frequency responses is one of these properties whose preserv... In approximation of fractional order systems,a significant objective is to preserve the important properties of the original system.The monotonicity of time/frequency responses is one of these properties whose preservation is of great importance in approximation process.Considering this importance,the issues of monotonicity preservation of the step response and monotonicity preservation of the magnitude-frequency response are independently investigated in this paper.In these investigations,some conditions on approximating filters of fractional operators are found to guarantee the preservation of step/magnitude-frequency response monotonicity in approximation process.These conditions are also simplified in some special cases.In addition,numerical simulation results are presented to show the usefulness of the obtained conditions. 展开更多
关键词 fractional order system APPROXIMATION step response magnitude-frequency response MONOTONICITY
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用于中间相沥青制备的两种催化裂化油浆组成分析 被引量:1
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作者 张彪 董森 +6 位作者 唐亚昆 刘浪 刘宏博 李杨俊迪 何平 刘景梅 马凤云 《新疆大学学报(自然科学版)(中英文)》 CAS 2023年第6期704-708,723,共6页
中间相沥青作为制备高性能碳材料的重要前驱体,研究影响中间相沥青结构的因素(原料组成和制备工艺)对推动碳材料发展具有重要意义.以新疆两种催化裂化油浆为原料,经凝胶渗透色谱(GPC)、核磁共振氢谱(^(1)H-NMR)、元素分析、气相色谱-质... 中间相沥青作为制备高性能碳材料的重要前驱体,研究影响中间相沥青结构的因素(原料组成和制备工艺)对推动碳材料发展具有重要意义.以新疆两种催化裂化油浆为原料,经凝胶渗透色谱(GPC)、核磁共振氢谱(^(1)H-NMR)、元素分析、气相色谱-质谱联用(GC-MS)等系统表征,明晰了其组成与结构特点.针对油浆高饱和分特性(>47%),一改传统原料溶剂精制策略,采用先热解优化原料组成,再热缩聚两步法制得软化点为290℃的广域型中间相沥青. 展开更多
关键词 催化裂化油浆 中间相沥青 高饱和分 两步法
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多步浸提法在碳酸盐岩Sr同位素分析中的对比及优化 被引量:2
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作者 潘旭 孙子威 +4 位作者 高继苇 龚红梅 王晓红 段梦 肖媛媛 《岩矿测试》 CAS CSCD 北大核心 2023年第4期691-706,共16页
海相沉积碳酸盐岩是记录海水信息的重要载体,其中碳酸盐岩的Sr同位素比值(87Sr/86Sr)可以反映大陆地壳和地幔对海水组成的相对贡献,其长期变化趋势可用于反演地球历史上的全球构造事件、风化速率变化和生物地球化学循环以及确定海相沉... 海相沉积碳酸盐岩是记录海水信息的重要载体,其中碳酸盐岩的Sr同位素比值(87Sr/86Sr)可以反映大陆地壳和地幔对海水组成的相对贡献,其长期变化趋势可用于反演地球历史上的全球构造事件、风化速率变化和生物地球化学循环以及确定海相沉积地层年龄等。然而,现存古老地层中的碳酸盐岩常不同程度地保留有非碳酸盐组分,并受到后期蚀变影响,从而使碳酸盐岩全岩的Sr同位素组成不等同于原生碳酸盐组分的Sr同位素组成。为了获取可以反映当时的海水组成的原生碳酸盐组分,需要建立一种有效的浸提方法。本文基于已有的两种碳酸盐岩多步浸提方法,探讨了其适用性,并简化了预浸步骤、缩短了流程时间,明确了不同种类的碳酸盐岩的浸提方法。结果表明:碳酸盐纯度≥85%的灰岩适用于采用浸提液为1%乙酸的9步浸提法,目标步骤为L7~L9;纯度≥65%的白云岩样品适用于采用浸提液为0.25%~10%乙酸的14步浸提法,目标步骤为D13~D14,采用多接收电感耦合等离子体质谱仪(MC-ICP-MS)对纯化后的目标浸提液进行Sr同位素测试。通过此方法获得中国灰岩标准物质GBW03105a原生碳酸盐组分的87Sr/86Sr比值为0.708930±0.000015(n=12,2SD),与前人研究结果(0.708879±0.000013)相吻合;并报道了欧洲钢铁标准化委员会(ECISS)白云岩标准物质ECRM-782-1原生碳酸盐组分的^(87)Sr/^(86)Sr比值为0.707868±0.000034(n=12,2SD),为后续地球化学分析提供了方法和数据支持。 展开更多
关键词 碳酸盐岩 SR同位素 多步浸提法 原生碳酸盐组分 MC-ICP-MS
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基于ASGSO的数控机床进给伺服系统分数阶控制 被引量:1
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作者 张俊男 付华 +1 位作者 陆鹏 付强 《机床与液压》 北大核心 2023年第6期142-148,共7页
为满足数控机床对加工精度的要求,针对交流永磁同步电机驱动的进给伺服系统在不同工况下存在的扰动、摩擦、变负载、惯性力矩等非线性问题,设计一种自适应步长的萤火虫算法(ASGSO)优化的分数阶PID控制器(ASGSO-FOPID)。FOPID控制器相比... 为满足数控机床对加工精度的要求,针对交流永磁同步电机驱动的进给伺服系统在不同工况下存在的扰动、摩擦、变负载、惯性力矩等非线性问题,设计一种自适应步长的萤火虫算法(ASGSO)优化的分数阶PID控制器(ASGSO-FOPID)。FOPID控制器相比传统控制器动态性能突出,能够对非线性环节进行更好的控制。利用ASGSO算法全局搜索能力,获得最优数控机床进给伺服系统分数阶PID控制器参数。建立数控机床进给伺服系统模型,分别采用PSO-FOPID、状态转移STA-FOPID、ASGSO-FOPID控制进给伺服系统进行对比。仿真和实验结果表明:提出的ASGSO-FOPID控制器具有跟踪速度快、抗干扰能力强、精度高等优点,该方法能够有效地提高数控机床的定位精度和加工精度。 展开更多
关键词 数控机床 永磁同步电机 伺服系统 分数阶PID控制器 自适应步长萤火虫算法
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求解Ericksen-Leslie方程的一阶精度、线性稳定的数值格式
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作者 韩宇倩 牛丽芳 贾宏恩 《数学杂志》 2023年第1期86-94,共9页
本文研究了液晶流不可压缩动力学方程组的数值求解问题.利用鞍点方法构造泛函,并对泛函进行变分,提出了一个具有一阶精度的解耦数值格式.通过数值模拟结合理论分析,得出所提方法可以准确描述液晶中的缺陷、分子分布规律以及符合动力学... 本文研究了液晶流不可压缩动力学方程组的数值求解问题.利用鞍点方法构造泛函,并对泛函进行变分,提出了一个具有一阶精度的解耦数值格式.通过数值模拟结合理论分析,得出所提方法可以准确描述液晶中的缺陷、分子分布规律以及符合动力学规律的结论.丰富了求解液晶动力学模型的内容. 展开更多
关键词 向量液晶 有限元方法 鞍点结构 增量投影法
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分数阶非线性四阶反应扩散方程变步长L 1格式的能量稳定 被引量:1
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作者 孙红 《南京工程学院学报(自然科学版)》 2023年第1期79-83,共5页
基于非均匀L1公式对时间分数阶非线性四阶反应扩散方程建立时间方向变步长的有限差分格式.利用离散互补卷积核,得到非均匀L1公式系数核的梯度分解,从而证明该差分格式在任意非均匀时间网格上保持变分能量耗散率.数值算例验证了格式的精... 基于非均匀L1公式对时间分数阶非线性四阶反应扩散方程建立时间方向变步长的有限差分格式.利用离散互补卷积核,得到非均匀L1公式系数核的梯度分解,从而证明该差分格式在任意非均匀时间网格上保持变分能量耗散率.数值算例验证了格式的精度和有效性. 展开更多
关键词 分数阶非线性反应扩散方程 CAPUTO导数 变步长 有限差分 能量耗散率
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深井岩巷分步联合支护技术应用 被引量:11
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作者 罗立强 王卫军 +2 位作者 屈延嗣 陈旭 王东洋 《广西大学学报(自然科学版)》 CAS 北大核心 2013年第1期228-234,共7页
通过现场调查、实验室试验、理论分析及现场监测等手段,得出了高应力巷道围岩的蠕变及支护方式的不合理是导致曲江矿大巷围岩失稳的主要原因,并提出了锚梁网喷一次支护,帮锚、注浆二次支护的分步联合支护方案。结合现场对巷道两帮收敛... 通过现场调查、实验室试验、理论分析及现场监测等手段,得出了高应力巷道围岩的蠕变及支护方式的不合理是导致曲江矿大巷围岩失稳的主要原因,并提出了锚梁网喷一次支护,帮锚、注浆二次支护的分步联合支护方案。结合现场对巷道两帮收敛速率的监测,确定了锚索支护的合理时机。现场实践表明:金属网,梁及喷层的护表作用能加强锚杆支护对围岩应力的改善,并使围岩应力得到一定程度的释放;锚杆锚索支护有效结合形成的叠加拱承载结构在很大程度上提高了围岩的自我承载能力,且底角锚索可以有效地切断塑性滑移线,起到很好控制底鼓的作用;注浆能够提高围岩的残余强度,修复和加固围岩。分步联合支护技术能使各支护在时间及空间上实现有效的结合,并成功应用于曲江矿东大巷支护。 展开更多
关键词 深井岩巷 蠕变 分步联合支护 叠加拱承载结构 支护时机
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结晶分级技术在支化聚乙烯研究中的应用 被引量:34
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作者 宋士杰 冯嘉春 +2 位作者 武培怡 杨玉良 乔金梁 《高分子通报》 CAS CSCD 2008年第3期15-28,共14页
介绍了近年发展起来的几种结晶分级技术及其在支化聚乙烯结构表征及性能研究方面的应用。利用升温淋洗分级技术(TREF),可根据结晶特性的不同将高分子分离成多个分布较窄的级份,通过分别表征各级份的链结构,从而可获得高分子链结构方面... 介绍了近年发展起来的几种结晶分级技术及其在支化聚乙烯结构表征及性能研究方面的应用。利用升温淋洗分级技术(TREF),可根据结晶特性的不同将高分子分离成多个分布较窄的级份,通过分别表征各级份的链结构,从而可获得高分子链结构方面较为准确的信息。基于差示扫描量热技术(DSC)发展起来的两类热分级技术,主要包括逐步结晶热分级(SC)和连续自成核退火分级(SSA)技术,虽然不能从物理上对高分子进行分级,但通过选择适当的操作参数,也能得到一系列与升温淋洗分级实验类似的链结构信息,并且具有设备简单、操作方便、样品用量少、耗时短等优点。本文结合我们自己的工作,对各种分级技术的原理、实验操作及应用进行了系统综述,并展望了结晶分级技术发展的某些可能趋势。 展开更多
关键词 支化聚乙烯 升温淋洗分级 逐步结晶 连续自成核退火
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不可压流体自由表面流动的SPH数值模拟 被引量:19
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作者 李梅娥 周进雄 《机械工程学报》 EI CAS CSCD 北大核心 2004年第3期5-9,共5页
根据SPH方法的原理提出了一套模拟流体自由表面流动的方法,场变量及其导数通过核函数插值求取,不需进行差分,也不需要网格,时间积分采用分数步长法,避免了不可压条件带来的压力计算不稳定问题。对流项通过粒子的运动求解,完全消除了数... 根据SPH方法的原理提出了一套模拟流体自由表面流动的方法,场变量及其导数通过核函数插值求取,不需进行差分,也不需要网格,时间积分采用分数步长法,避免了不可压条件带来的压力计算不稳定问题。对流项通过粒子的运动求解,完全消除了数值扩散和自由表面模糊问题。可以模拟飞溅、融合等复杂自由表面现象,并对水坝坍塌这一典型自由表面流动问题进行了模拟,模拟结果与试验吻合良好。 展开更多
关键词 不可压流体流动 自由表面 光滑质点流体动力学 分数步长法 数值模拟
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无硫膨胀石墨的制备及微观组织分析 被引量:8
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作者 王振廷 殷力佳 王洋 《非金属矿》 CAS CSCD 北大核心 2013年第5期36-38,共3页
针对传统方法制得的膨胀石墨含硫量高的问题,以有机酸乙酸为插层剂,氯酸钾和硝酸为氧化剂,0.18mm天然鳞片石墨为原料,采用先氧化后插层的分步法制备了无硫膨胀石墨。研究了制备过程中不同因素对膨胀体积的影响,并对膨胀石墨的微观组织... 针对传统方法制得的膨胀石墨含硫量高的问题,以有机酸乙酸为插层剂,氯酸钾和硝酸为氧化剂,0.18mm天然鳞片石墨为原料,采用先氧化后插层的分步法制备了无硫膨胀石墨。研究了制备过程中不同因素对膨胀体积的影响,并对膨胀石墨的微观组织结构进行了初步分析。确定最佳工艺条件为:m(石墨)∶V(CH3COOH)∶V(HNO3)∶m(KClO3)为1(g)∶2(mL)∶1.8(mL)∶0.8(g),氧化反应和插层反应时间各30 min,反应温度45℃。膨胀石墨膨胀体积达325 mL/g。 展开更多
关键词 膨胀石墨 分步法 膨胀体积 乙酸
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