The DC microgrid has the advantages of high energy conversion efficiency,high energy transmission density,no reactive power flow,and grid-connected synchronization.It is an essential component of the future intelligen...The DC microgrid has the advantages of high energy conversion efficiency,high energy transmission density,no reactive power flow,and grid-connected synchronization.It is an essential component of the future intelligent power distribution system.Constant power load(CPL)will degrade the stability of the DC microgrid and cause system voltage oscillation due to its negative resistance characteristics.As a result,the stability of DC microgrids with CPL has become a problem.At present,the research on the stability of DC microgrid is mainly focused on unipolar DC microgrid,while the research on bipolar DC microgrid lacks systematic discussion.The stability of DC microgrid using CPL was studied first,and then the current stability criteria of DC microgrid were summarized,and its research trend was analyzed.On this basis,aiming at the stability problem caused by CPL,the existing control methods were summarized from the perspective of source converter output impedance and load converter input impedance,and the current control methods were outlined as active and passive control methods.Lastly,the research path of bipolar DC microgrid stability with CPL was prospected.展开更多
In this study we used the deep eutectic solvents (ionic liquids) to investigate the reaction between copper (II) with ethylene diamine (en). Two of the existing methods for analyzing spectrophotometric measurements ha...In this study we used the deep eutectic solvents (ionic liquids) to investigate the reaction between copper (II) with ethylene diamine (en). Two of the existing methods for analyzing spectrophotometric measurements have been applied for establishing, the stoichiometry and whenever possible, the stability constants of the chelates formed. The method of continuous variations was necessary to determine first whether, the metal ion and the ligand ethylene diamine form one or more than one chelate, when more than one chelate formed, the results obtained depend on the wavelength and for meaningful conclusions the wavelengths were carefully selected. The empirical formulae of the chelates were further substantiated by the molar ratio method. The effect of time and temperature on the formation and stability of these chelates in solution is also studied. The stability constants, K1 and K2 for the copper (II) chelates were calculated, though reliable, and are comparable to literature values.展开更多
The cadmium(Ⅱ)-glycine system was studied by the two experimental techniques, ion sensitive electrode (ISE) and differential pulse polarography (DPP), and the experimental data obtained were used by a unified m...The cadmium(Ⅱ)-glycine system was studied by the two experimental techniques, ion sensitive electrode (ISE) and differential pulse polarography (DPP), and the experimental data obtained were used by a unified mathematical treatment to calculate the complex stability constants. The combination of the two techniques is of many advantages as ISE can be performed at low [LT]:[MT] ratios and significantly higher [MT], whereas DPP could be used well at large [LT]:[MT] ratios and much smaller [MT]. This makes it possible to study a metal-ligand system in a relatively broader range of experimental conditions that, in turn, provides more information about the metakligand system of interest. Applying the unified mathematical treatment to the cadmium-glycine system, two new complexes MHL and ML2(OH) as well as three complexes ML, ML2 and ML3, reported in literatures, could be modeled and all their stability constants have been refined.展开更多
Flow-slip damage commonly destabilizes coastal slopes.Finding a slope stabilization method for calcareous sands in the South China Sea is crucial.Microbially induced calcite precipitation is a promising,eco-friendly m...Flow-slip damage commonly destabilizes coastal slopes.Finding a slope stabilization method for calcareous sands in the South China Sea is crucial.Microbially induced calcite precipitation is a promising,eco-friendly method for soil stabilization.This study investigates the effect of microbial treatments,initial relative density,initial cell pressure,and initial stress ratio on the flow-slip stability of calcareous sand specimens by using constant shear drained tests.These tests lay the foundation to study the mechanical instability of sand slopes.Results show that the microbial-treated specimens maintain stable stresses longer,take longer to reach the instability,and withstand larger volumetric strains.Microbial treatment effectively enhances sand stability under constant shear drainage,with improvements amplified by higher initial relative density and initial cell pressure.In addition,a smaller initial stress ratio reduces shear effects on the specimen and increases resistance to flow slides.Microanalysis reveals that the flow-slip stability of calcareous sand slopes is enhanced by contact cementation,particle coating,void filling,and mutual embedment of calcium carbonate crystals.展开更多
The stability constants of the binary complexes of Mn2+ with nicotinamide (NA) were determined from potentiometric pH titrations data at 15.0 , 25.0 and 35.0oC and I = 0.1,0.2,0.4 mol L-1 (NaClO4). The formation of bi...The stability constants of the binary complexes of Mn2+ with nicotinamide (NA) were determined from potentiometric pH titrations data at 15.0 , 25.0 and 35.0oC and I = 0.1,0.2,0.4 mol L-1 (NaClO4). The formation of binary 1:1 , 1:2 NA-Mn complexes at three different temperatures and the influence of three different ionic strength on their stability were reported. The thermodynamic parameters (DGof, DSof, DHof) for the complex formation reaction were estimated from stability constant at different temperatures.展开更多
The influence of particle size and ionic strength on the freeze-thaw(FT) stability of emulsions stabilized by whey protein isolate(WPI) was investigated in this study. The destabilization of emulsions during the FT pr...The influence of particle size and ionic strength on the freeze-thaw(FT) stability of emulsions stabilized by whey protein isolate(WPI) was investigated in this study. The destabilization of emulsions during the FT process could be suppressed in a way by decreasing the particle size of the initial emulsions, which was the result of retarding the coalescence between oil droplets. To further improve the FT stability of emulsions, different amounts of Na Cl were added before emulsification. The emulsions with the ionic strength at 30–50 mmol/L exhibited good FT stability. Notably, the ionic strength in this range would not lower the freezing point of emulsions below the freezing temperature used in this study. Salt addition could improve the structural properties of proteins, which was available to strengthen the rigidity and thickness of interfacial layers, sequentially building up the resistance that the destruction of ice crystals to emulsions. Moreover, stronger flocculation between emulsion droplets could promote the formation of a gel-like network structure dominated by elasticity in the emulsion system, which might effectively inhibit the movement of droplets, and improve the FT stability of emulsions eventually. The result was of great significance for the preparation of emulsion-based foods with improved FT stability.展开更多
China clay was employed as an adsorbent for the removal of Mg 2+ from water at pH 7.0 within the temperature range of 303~328 K. The linearity of the plots indicated Langmuir type isotherms. The reaction was ex...China clay was employed as an adsorbent for the removal of Mg 2+ from water at pH 7.0 within the temperature range of 303~328 K. The linearity of the plots indicated Langmuir type isotherms. The reaction was exothermic. A maximum removal of 35% was obtained at 0.50 mmol L -1 metal concentration and a pH of 7.0 at 303 K. The H + rel /Mg 2+ ads ratio changed from a fractional value to 2.5. Strong chemical bondings took place between oxygen atom of the surface and Mg 2+ , resulting in a surface complex species. Temperature had a significant effect on H + rel , and the stability constants also increased with increasing temperature.展开更多
The stability constants of Sb^5+with Cl−as well as thermodynamics of the Sb−S−Cl−H2O system were calculated.The stability constants of Sb5+with Cl−were obtained by theoretical calculations of the absorbance of a Sb5+-...The stability constants of Sb^5+with Cl−as well as thermodynamics of the Sb−S−Cl−H2O system were calculated.The stability constants of Sb5+with Cl−were obtained by theoretical calculations of the absorbance of a Sb5+-containing solution at different Cl^−concentrations,which was detected by spectrophotometric analysis at certain wavelengths of light(380 nm).The logarithmic values versus 10 of stability constants of Sb^5+with Cl−were 1.795,3.150,4.191,4.955,5.427 and 5.511,respectively,and partly filled the data gaps in the hydrometallurgy of antimony.The presence and distribution of pentavalent antimony compounds under different conditions were analyzed based on equilibrium calculations.Thermodynamic equilibrium calculations were performed for Sb−S−Cl−H2O system,which included the complex behavior of Sb with Cl,and the equilibrium equations of related reactions in this system were integrated into the potential−pH diagram.展开更多
On the example of copper fulvate, it is discussed the method of calculation of stability constants of fulvic complexes. At pH = 8, the complex formation of copper(ll) ions with fulvic acids was studied by the solubi...On the example of copper fulvate, it is discussed the method of calculation of stability constants of fulvic complexes. At pH = 8, the complex formation of copper(ll) ions with fulvic acids was studied by the solubility method. Fulvic acids were separated from the river Mtkvari by the adsorption-chromotographic method. The charcoal (BAU, Russia) was used as a sorbent. The suspension of copper(If) hydroxide was used as the solid phase, on which was added the increasing quantity of standard solution of fulvic acids. In diluted solutions, at pH = 8 the dominant form of copper(lI) is copper dihydroxo complex Cu(OH)^zO. It was established that in the Cu(OH)2 (solid)-Cu(OH)^20 (solution)-FA^2-H20 system, dominates copper dyhydroxo fulvate complex with the structure 1:1, [Cu(OH)2FA]^2. The average stability constant of copper dyhydroxo fulvate complex was calculated based on experimental data fl [Cu(OH)2FAJ^2 = 4.5× l0^5.展开更多
The stepwise stability constants of coordination compounds from sulfonatedsheoak tannin with metal ions have been determined by pH potential method with catechol asmodel compounds at 20℃and constant ionic strength.
A new method,dual-series linear regression method,has been used to study the complexation equilibrium of praseodymium(Pr^(3+))with tribromoarsenazo(TBA)without knowing the accurate concentra- tion of the complexing ag...A new method,dual-series linear regression method,has been used to study the complexation equilibrium of praseodymium(Pr^(3+))with tribromoarsenazo(TBA)without knowing the accurate concentra- tion of the complexing agent TBA.In 1.2 mol/L HCl solution, Pr^(3+)reacts with TBA and forms 1:3 com- plex,the conditional stability constant(lgβ_3)of the complex determined is 15.47,and its molar absorptivity(ε_3^(630))is 1.48×10~5 L·mol^(-1)·cm^(-1).展开更多
The stability constants of the mononuclear complexes of BDBPH-Zn(II), Cd(II) and Mn (II) were determined by the potentiometric equilibrium measurements, and species distributions were also discussed. The metal ions do...The stability constants of the mononuclear complexes of BDBPH-Zn(II), Cd(II) and Mn (II) were determined by the potentiometric equilibrium measurements, and species distributions were also discussed. The metal ions do not combine with the ligand until the first two protons of the ligand have almost been completely neutralized. The main species were mononuclear complexes with the diprotonated ligand, MH,L. The three metal ions also form mono- and noprotonated (fully deprotonated) complexes, MHL, ML. The relative order of stabilities of the mononuclear complexes, ML, is Zn(II) > Cd(II) > Mn(II). The ligand has strong tendency to form mononuclear complexes with Zn(II), Cd(II) and Mn(II), and it can also form dinuclear complexes at high pH.展开更多
The stability constants and species distributions of complexes of two lanthanide ions, Eu(Ⅲ) and Tb(Ⅲ), with a macrocyclic ligand, BDBPH, in 1:1 and 2:lsystem, were determined potentiometrically at 25.0 ℃ and...The stability constants and species distributions of complexes of two lanthanide ions, Eu(Ⅲ) and Tb(Ⅲ), with a macrocyclic ligand, BDBPH, in 1:1 and 2:lsystem, were determined potentiometrically at 25.0 ℃ and I=0.100 mol L^-l. The two metal ions could form deprotonated mono- or dinuclear complexes with BDBPH after the first two protons of the ligand completely neutralized. At higher pH values, Eu(Ⅲ) could not form hydroxy complexes with BDBPH, while Tb(Ⅲ) could form hydroxy complexes in the type of M2L(OH), M2L(OH)2, and M2L(OH)3.展开更多
A new method is proposed for determining the composition and stability constant of coordination compounds of the form M m R n ; it can be used to differentiate mono and poly nuclear coordination compounds. ...A new method is proposed for determining the composition and stability constant of coordination compounds of the form M m R n ; it can be used to differentiate mono and poly nuclear coordination compounds. The equation derived is lg( A i/(A max - A i) m)=n lg c′ R+lg( m·β(c M/A max ) ( m -1) ). The method is based on Bent French limited logarithm method. The demonstration of the proposed method has yielded correct results for Sc 3+ chlorophosphonazo Ⅲ system and Fe 3+ Chromazurol S system.展开更多
There are various applications of the stability theory of the first-order dynamical systems. And the stability of the non-linear control systems can be determined by its linear part. In practice, it is not enough to k...There are various applications of the stability theory of the first-order dynamical systems. And the stability of the non-linear control systems can be determined by its linear part. In practice, it is not enough to know the stability of the dynamical systems. Sometimes we must know the degree of stability of these systems. In this paper, we present some criteria for the degree of stability of the linear constant systems, by using the entries of the coefficient matrix A only.展开更多
The typical loess on high slopes along the BaoLan High-speed Rail, China, was selected as the research object. The influence of the freeze-thaw cycle and dry-wet alternation on the shear-strength parameters of the uns...The typical loess on high slopes along the BaoLan High-speed Rail, China, was selected as the research object. The influence of the freeze-thaw cycle and dry-wet alternation on the shear-strength parameters of the unsaturated loess was investigated by laboratory experimental methods. Moreover, the temperature field, seepage field, and stability of slopes with different gradients were simulated under the effect of the freeze-thaw cycle and dry-wet alternation by using the geotechnical analysis software Geo-Studio. The research results showed(1) when the freeze-thaw cycle was repeated on the slope, with the frozen depth increasing, the melted depth did the same; besides, the closed loop of isotherms formed on the slope;(2) under the action of dry-wet circulation, the negative pore-water pressure and volumetric water content showed an upward tendency. However, owing to the different slope gradients, rainfall infiltration was not the same. As time went by, the differences of the negative pore-water pressure and volumetric water content between the slopes of different gradients continued to increase;(3) with the freeze-thaw cycle and dry-wet alternation increasing, the slope-safety factor decreased. Especially in the early period, the slope-safety factor changed remarkably. For slopes undergoing freeze-thaw action, the slope-safety factor was negatively correlated with the gradient. However, with regard to slopes undergoing dry-wet alternation, the result became more complex because the slope-safety factor was related to both seepage strength and slope grade. Accordingly, further research is needed to study the effect of seepage strength and slope grade on the stability of loess slopes.展开更多
q-axis rotor flux can be chosen to form a model reference adaptive system(MRAS)updating rotor time constant online in induction motor drives.This paper presents a stability analysis of such a system with Popov’s hype...q-axis rotor flux can be chosen to form a model reference adaptive system(MRAS)updating rotor time constant online in induction motor drives.This paper presents a stability analysis of such a system with Popov’s hyperstability concept and small-signal linearization technique.At first,the stability of q-axis rotor flux based MRAS is proven with Popov’s Hyperstability theory.Then,to find out the guidelines for optimally designing the coefficients in the PI controller,acting as the adaption mechanism in the MRAS,small-signal model of the estimation system is developed.The obtained linearization model not only allows the stability to be verified further through Routh criterion,but also reveals the distribution of the characteristic roots,which leads to the clue to optimal PI gains.The theoretical analysis and the resultant design guidelines of the adaptation PI gains are verified through simulation and experiments.展开更多
At pH = 8, the complex formation process of Ni(Ⅱ) ions with FA was studied by the solubility method. FA were separated from the river Mtkvari by the adsorption-chromotographic method. The charcoal (BAU, Russia) w...At pH = 8, the complex formation process of Ni(Ⅱ) ions with FA was studied by the solubility method. FA were separated from the river Mtkvari by the adsorption-chromotographic method. The charcoal (BAU, Russia) was used as a sorbent. The old suspension of Ni(Ⅱ) hydroxide was used as the solid phase, on which was added the increasing quantity of standard solution of FA. In diluted solutions, at pH = 8.0 the dominant form of Ni(Ⅱ) is nickel dihydroxocomplex Ni(OH)2^0. It was established that in the Ni(OH)2(solid)-Ni(OH)2^0(solution)-FA2-H20 system dominates nickel dyhydroxofulvate complex with the structure 1:1, [Ni(OH)2FA]2-. The average stability constant of nickel dyhydroxofulvate complex was calculated based on experimental data flNi(OH)2FA2" = 5.3 × 105.展开更多
The objective of this research was to investigate the effect of Malva nut gum (MG) replacement on the pasting characteristics and freeze-thaw stability of wheat, rice or waxy rice flours. Pasting properties and free...The objective of this research was to investigate the effect of Malva nut gum (MG) replacement on the pasting characteristics and freeze-thaw stability of wheat, rice or waxy rice flours. Pasting properties and freeze-thaw stability of different flours incorporated with 0, 0.5%, 1%, 2%, 3% and 5% of MG were investigated. Pasting temperature (60 ℃-87 ℃) of the pastes significantly decreased with increasing of MG content for wheat and rice flours, but had no significant effect for waxy rice flour. Incorporation of MG into all flours significantly elevated the peak viscosity by about 0.9-2.6 folds when compared to non-MG samples. Hot paste viscosity, breakdown and final viscosity for all flour mixtures significantly increased with increasing of MG which ranged from 81-427, 37-559 and 152-463 RVU, respectively. Freeze-thaw stability measurement demonstrated that higher level of MG in wheat and rice gel mixtures could decrease syneresis. However, MG had no effect on syneresis of waxy rice gel. Presence of MG in flours alters the pasting properties and syneresis effect. It is suggested that higher viscosity and lower syneresis of gels could be modified by MG.展开更多
基金supported by National Natural Science Foundation of China(No.51767015)Key Project of Natural Science Foundation of Gansu Province(No.22JR5RA317)Tianyou Innovation Team Support Program of Lanzhou Jiaotong University(No.TY202009)。
文摘The DC microgrid has the advantages of high energy conversion efficiency,high energy transmission density,no reactive power flow,and grid-connected synchronization.It is an essential component of the future intelligent power distribution system.Constant power load(CPL)will degrade the stability of the DC microgrid and cause system voltage oscillation due to its negative resistance characteristics.As a result,the stability of DC microgrids with CPL has become a problem.At present,the research on the stability of DC microgrid is mainly focused on unipolar DC microgrid,while the research on bipolar DC microgrid lacks systematic discussion.The stability of DC microgrid using CPL was studied first,and then the current stability criteria of DC microgrid were summarized,and its research trend was analyzed.On this basis,aiming at the stability problem caused by CPL,the existing control methods were summarized from the perspective of source converter output impedance and load converter input impedance,and the current control methods were outlined as active and passive control methods.Lastly,the research path of bipolar DC microgrid stability with CPL was prospected.
文摘In this study we used the deep eutectic solvents (ionic liquids) to investigate the reaction between copper (II) with ethylene diamine (en). Two of the existing methods for analyzing spectrophotometric measurements have been applied for establishing, the stoichiometry and whenever possible, the stability constants of the chelates formed. The method of continuous variations was necessary to determine first whether, the metal ion and the ligand ethylene diamine form one or more than one chelate, when more than one chelate formed, the results obtained depend on the wavelength and for meaningful conclusions the wavelengths were carefully selected. The empirical formulae of the chelates were further substantiated by the molar ratio method. The effect of time and temperature on the formation and stability of these chelates in solution is also studied. The stability constants, K1 and K2 for the copper (II) chelates were calculated, though reliable, and are comparable to literature values.
文摘The cadmium(Ⅱ)-glycine system was studied by the two experimental techniques, ion sensitive electrode (ISE) and differential pulse polarography (DPP), and the experimental data obtained were used by a unified mathematical treatment to calculate the complex stability constants. The combination of the two techniques is of many advantages as ISE can be performed at low [LT]:[MT] ratios and significantly higher [MT], whereas DPP could be used well at large [LT]:[MT] ratios and much smaller [MT]. This makes it possible to study a metal-ligand system in a relatively broader range of experimental conditions that, in turn, provides more information about the metakligand system of interest. Applying the unified mathematical treatment to the cadmium-glycine system, two new complexes MHL and ML2(OH) as well as three complexes ML, ML2 and ML3, reported in literatures, could be modeled and all their stability constants have been refined.
基金supported by the Taishan Scholars Program of Shandong Province,China(No.tsqn202306098)supported by the National Natural Science Foundations of China(No.52171282)the Shandong Provincial Key Research and Development Plan,China(No.2021ZLGX04).
文摘Flow-slip damage commonly destabilizes coastal slopes.Finding a slope stabilization method for calcareous sands in the South China Sea is crucial.Microbially induced calcite precipitation is a promising,eco-friendly method for soil stabilization.This study investigates the effect of microbial treatments,initial relative density,initial cell pressure,and initial stress ratio on the flow-slip stability of calcareous sand specimens by using constant shear drained tests.These tests lay the foundation to study the mechanical instability of sand slopes.Results show that the microbial-treated specimens maintain stable stresses longer,take longer to reach the instability,and withstand larger volumetric strains.Microbial treatment effectively enhances sand stability under constant shear drainage,with improvements amplified by higher initial relative density and initial cell pressure.In addition,a smaller initial stress ratio reduces shear effects on the specimen and increases resistance to flow slides.Microanalysis reveals that the flow-slip stability of calcareous sand slopes is enhanced by contact cementation,particle coating,void filling,and mutual embedment of calcium carbonate crystals.
文摘The stability constants of the binary complexes of Mn2+ with nicotinamide (NA) were determined from potentiometric pH titrations data at 15.0 , 25.0 and 35.0oC and I = 0.1,0.2,0.4 mol L-1 (NaClO4). The formation of binary 1:1 , 1:2 NA-Mn complexes at three different temperatures and the influence of three different ionic strength on their stability were reported. The thermodynamic parameters (DGof, DSof, DHof) for the complex formation reaction were estimated from stability constant at different temperatures.
基金financially supported by National Natural Science Foundation of China (31871844 & 31501530)。
文摘The influence of particle size and ionic strength on the freeze-thaw(FT) stability of emulsions stabilized by whey protein isolate(WPI) was investigated in this study. The destabilization of emulsions during the FT process could be suppressed in a way by decreasing the particle size of the initial emulsions, which was the result of retarding the coalescence between oil droplets. To further improve the FT stability of emulsions, different amounts of Na Cl were added before emulsification. The emulsions with the ionic strength at 30–50 mmol/L exhibited good FT stability. Notably, the ionic strength in this range would not lower the freezing point of emulsions below the freezing temperature used in this study. Salt addition could improve the structural properties of proteins, which was available to strengthen the rigidity and thickness of interfacial layers, sequentially building up the resistance that the destruction of ice crystals to emulsions. Moreover, stronger flocculation between emulsion droplets could promote the formation of a gel-like network structure dominated by elasticity in the emulsion system, which might effectively inhibit the movement of droplets, and improve the FT stability of emulsions eventually. The result was of great significance for the preparation of emulsion-based foods with improved FT stability.
文摘China clay was employed as an adsorbent for the removal of Mg 2+ from water at pH 7.0 within the temperature range of 303~328 K. The linearity of the plots indicated Langmuir type isotherms. The reaction was exothermic. A maximum removal of 35% was obtained at 0.50 mmol L -1 metal concentration and a pH of 7.0 at 303 K. The H + rel /Mg 2+ ads ratio changed from a fractional value to 2.5. Strong chemical bondings took place between oxygen atom of the surface and Mg 2+ , resulting in a surface complex species. Temperature had a significant effect on H + rel , and the stability constants also increased with increasing temperature.
基金Projects(51904048,51922108)supported by the National Natural Science Foundation of ChinaProject(2019JJ20031)supported by the Hunan Natural Science Foundation,ChinaProject(gjj170507)supported by the Scientific Research Foundation of Jiangxi Provincial Department of Education,China。
文摘The stability constants of Sb^5+with Cl−as well as thermodynamics of the Sb−S−Cl−H2O system were calculated.The stability constants of Sb5+with Cl−were obtained by theoretical calculations of the absorbance of a Sb5+-containing solution at different Cl^−concentrations,which was detected by spectrophotometric analysis at certain wavelengths of light(380 nm).The logarithmic values versus 10 of stability constants of Sb^5+with Cl−were 1.795,3.150,4.191,4.955,5.427 and 5.511,respectively,and partly filled the data gaps in the hydrometallurgy of antimony.The presence and distribution of pentavalent antimony compounds under different conditions were analyzed based on equilibrium calculations.Thermodynamic equilibrium calculations were performed for Sb−S−Cl−H2O system,which included the complex behavior of Sb with Cl,and the equilibrium equations of related reactions in this system were integrated into the potential−pH diagram.
文摘On the example of copper fulvate, it is discussed the method of calculation of stability constants of fulvic complexes. At pH = 8, the complex formation of copper(ll) ions with fulvic acids was studied by the solubility method. Fulvic acids were separated from the river Mtkvari by the adsorption-chromotographic method. The charcoal (BAU, Russia) was used as a sorbent. The suspension of copper(If) hydroxide was used as the solid phase, on which was added the increasing quantity of standard solution of fulvic acids. In diluted solutions, at pH = 8 the dominant form of copper(lI) is copper dihydroxo complex Cu(OH)^zO. It was established that in the Cu(OH)2 (solid)-Cu(OH)^20 (solution)-FA^2-H20 system, dominates copper dyhydroxo fulvate complex with the structure 1:1, [Cu(OH)2FA]^2. The average stability constant of copper dyhydroxo fulvate complex was calculated based on experimental data fl [Cu(OH)2FAJ^2 = 4.5× l0^5.
文摘The stepwise stability constants of coordination compounds from sulfonatedsheoak tannin with metal ions have been determined by pH potential method with catechol asmodel compounds at 20℃and constant ionic strength.
文摘A new method,dual-series linear regression method,has been used to study the complexation equilibrium of praseodymium(Pr^(3+))with tribromoarsenazo(TBA)without knowing the accurate concentra- tion of the complexing agent TBA.In 1.2 mol/L HCl solution, Pr^(3+)reacts with TBA and forms 1:3 com- plex,the conditional stability constant(lgβ_3)of the complex determined is 15.47,and its molar absorptivity(ε_3^(630))is 1.48×10~5 L·mol^(-1)·cm^(-1).
基金The financial support from the Robert A. Welch Foundation (A-0259) in the U.S and China Scholarship Council (97837086) is gratefully acknowledged.
文摘The stability constants of the mononuclear complexes of BDBPH-Zn(II), Cd(II) and Mn (II) were determined by the potentiometric equilibrium measurements, and species distributions were also discussed. The metal ions do not combine with the ligand until the first two protons of the ligand have almost been completely neutralized. The main species were mononuclear complexes with the diprotonated ligand, MH,L. The three metal ions also form mono- and noprotonated (fully deprotonated) complexes, MHL, ML. The relative order of stabilities of the mononuclear complexes, ML, is Zn(II) > Cd(II) > Mn(II). The ligand has strong tendency to form mononuclear complexes with Zn(II), Cd(II) and Mn(II), and it can also form dinuclear complexes at high pH.
文摘The stability constants and species distributions of complexes of two lanthanide ions, Eu(Ⅲ) and Tb(Ⅲ), with a macrocyclic ligand, BDBPH, in 1:1 and 2:lsystem, were determined potentiometrically at 25.0 ℃ and I=0.100 mol L^-l. The two metal ions could form deprotonated mono- or dinuclear complexes with BDBPH after the first two protons of the ligand completely neutralized. At higher pH values, Eu(Ⅲ) could not form hydroxy complexes with BDBPH, while Tb(Ⅲ) could form hydroxy complexes in the type of M2L(OH), M2L(OH)2, and M2L(OH)3.
文摘A new method is proposed for determining the composition and stability constant of coordination compounds of the form M m R n ; it can be used to differentiate mono and poly nuclear coordination compounds. The equation derived is lg( A i/(A max - A i) m)=n lg c′ R+lg( m·β(c M/A max ) ( m -1) ). The method is based on Bent French limited logarithm method. The demonstration of the proposed method has yielded correct results for Sc 3+ chlorophosphonazo Ⅲ system and Fe 3+ Chromazurol S system.
文摘There are various applications of the stability theory of the first-order dynamical systems. And the stability of the non-linear control systems can be determined by its linear part. In practice, it is not enough to know the stability of the dynamical systems. Sometimes we must know the degree of stability of these systems. In this paper, we present some criteria for the degree of stability of the linear constant systems, by using the entries of the coefficient matrix A only.
基金supported by the National Natural Science Foundation of China (Grant No. 51769013)
文摘The typical loess on high slopes along the BaoLan High-speed Rail, China, was selected as the research object. The influence of the freeze-thaw cycle and dry-wet alternation on the shear-strength parameters of the unsaturated loess was investigated by laboratory experimental methods. Moreover, the temperature field, seepage field, and stability of slopes with different gradients were simulated under the effect of the freeze-thaw cycle and dry-wet alternation by using the geotechnical analysis software Geo-Studio. The research results showed(1) when the freeze-thaw cycle was repeated on the slope, with the frozen depth increasing, the melted depth did the same; besides, the closed loop of isotherms formed on the slope;(2) under the action of dry-wet circulation, the negative pore-water pressure and volumetric water content showed an upward tendency. However, owing to the different slope gradients, rainfall infiltration was not the same. As time went by, the differences of the negative pore-water pressure and volumetric water content between the slopes of different gradients continued to increase;(3) with the freeze-thaw cycle and dry-wet alternation increasing, the slope-safety factor decreased. Especially in the early period, the slope-safety factor changed remarkably. For slopes undergoing freeze-thaw action, the slope-safety factor was negatively correlated with the gradient. However, with regard to slopes undergoing dry-wet alternation, the result became more complex because the slope-safety factor was related to both seepage strength and slope grade. Accordingly, further research is needed to study the effect of seepage strength and slope grade on the stability of loess slopes.
文摘q-axis rotor flux can be chosen to form a model reference adaptive system(MRAS)updating rotor time constant online in induction motor drives.This paper presents a stability analysis of such a system with Popov’s hyperstability concept and small-signal linearization technique.At first,the stability of q-axis rotor flux based MRAS is proven with Popov’s Hyperstability theory.Then,to find out the guidelines for optimally designing the coefficients in the PI controller,acting as the adaption mechanism in the MRAS,small-signal model of the estimation system is developed.The obtained linearization model not only allows the stability to be verified further through Routh criterion,but also reveals the distribution of the characteristic roots,which leads to the clue to optimal PI gains.The theoretical analysis and the resultant design guidelines of the adaptation PI gains are verified through simulation and experiments.
文摘At pH = 8, the complex formation process of Ni(Ⅱ) ions with FA was studied by the solubility method. FA were separated from the river Mtkvari by the adsorption-chromotographic method. The charcoal (BAU, Russia) was used as a sorbent. The old suspension of Ni(Ⅱ) hydroxide was used as the solid phase, on which was added the increasing quantity of standard solution of FA. In diluted solutions, at pH = 8.0 the dominant form of Ni(Ⅱ) is nickel dihydroxocomplex Ni(OH)2^0. It was established that in the Ni(OH)2(solid)-Ni(OH)2^0(solution)-FA2-H20 system dominates nickel dyhydroxofulvate complex with the structure 1:1, [Ni(OH)2FA]2-. The average stability constant of nickel dyhydroxofulvate complex was calculated based on experimental data flNi(OH)2FA2" = 5.3 × 105.
文摘The objective of this research was to investigate the effect of Malva nut gum (MG) replacement on the pasting characteristics and freeze-thaw stability of wheat, rice or waxy rice flours. Pasting properties and freeze-thaw stability of different flours incorporated with 0, 0.5%, 1%, 2%, 3% and 5% of MG were investigated. Pasting temperature (60 ℃-87 ℃) of the pastes significantly decreased with increasing of MG content for wheat and rice flours, but had no significant effect for waxy rice flour. Incorporation of MG into all flours significantly elevated the peak viscosity by about 0.9-2.6 folds when compared to non-MG samples. Hot paste viscosity, breakdown and final viscosity for all flour mixtures significantly increased with increasing of MG which ranged from 81-427, 37-559 and 152-463 RVU, respectively. Freeze-thaw stability measurement demonstrated that higher level of MG in wheat and rice gel mixtures could decrease syneresis. However, MG had no effect on syneresis of waxy rice gel. Presence of MG in flours alters the pasting properties and syneresis effect. It is suggested that higher viscosity and lower syneresis of gels could be modified by MG.