Simulating the coupling effect brought by freeze-thaw and carbonation environment, we experimentally investigated concrete durability, the variation characteristics of both concrete dynamic elastic modulus, and its ne...Simulating the coupling effect brought by freeze-thaw and carbonation environment, we experimentally investigated concrete durability, the variation characteristics of both concrete dynamic elastic modulus, and its neutralization depth. The influences imposed by carbonation on the freeze-thaw damage of concrete was studied as well and vise versa so as to shed light on the influencing mechanism together with the mutual interaction between them. The experimental results show that the damage caused by the coupling effect of freeze-thaw and carbonation on concrete is severer than any single effect of them two could bring. This provides certain theoretical references and paves down foundations for the further study in concrete durability related by the coupling environmental effect.展开更多
At subzero temperature, the startup capability and performance of polymer electrolyte membrane fuel cell PEMFC deteriorates markedly. The object of this work is to study the degradation mechanism of key compo- nents o...At subzero temperature, the startup capability and performance of polymer electrolyte membrane fuel cell PEMFC deteriorates markedly. The object of this work is to study the degradation mechanism of key compo- nents of PEMFC—membrane-electrode assembly MEA and seek feasible measures to avoid degradation. The ef- fect of freezethaw cycles on the structure of MEA is investigated based on porosity and SEM measurement. The performance of a single cell was also tested before and after repetitious freezethaw cycles. The experimental results indicated that the performance of a PEMFC decreased along with the total operating time as well as the pore size distribution shifting and micro configuration changing. However, when the redundant water had been removed by gas purging, the performance of the PEMFC stack was almost resumed when it experienced again the same subzero temperature test. These results show that it is necessary to remove the water in PEMFCs to maintain stable per- formance under subzero temperature and gas purging is proved to be the effective operation.展开更多
基金Funded by the National Natural Science Foundation of China (No.50538060)
文摘Simulating the coupling effect brought by freeze-thaw and carbonation environment, we experimentally investigated concrete durability, the variation characteristics of both concrete dynamic elastic modulus, and its neutralization depth. The influences imposed by carbonation on the freeze-thaw damage of concrete was studied as well and vise versa so as to shed light on the influencing mechanism together with the mutual interaction between them. The experimental results show that the damage caused by the coupling effect of freeze-thaw and carbonation on concrete is severer than any single effect of them two could bring. This provides certain theoretical references and paves down foundations for the further study in concrete durability related by the coupling environmental effect.
基金the National Natural Science Foundation of China (No.20206030) Ministry of Science and Technology 863Hi-Technology Research and Development Program of China (2005AA501660)
文摘At subzero temperature, the startup capability and performance of polymer electrolyte membrane fuel cell PEMFC deteriorates markedly. The object of this work is to study the degradation mechanism of key compo- nents of PEMFC—membrane-electrode assembly MEA and seek feasible measures to avoid degradation. The ef- fect of freezethaw cycles on the structure of MEA is investigated based on porosity and SEM measurement. The performance of a single cell was also tested before and after repetitious freezethaw cycles. The experimental results indicated that the performance of a PEMFC decreased along with the total operating time as well as the pore size distribution shifting and micro configuration changing. However, when the redundant water had been removed by gas purging, the performance of the PEMFC stack was almost resumed when it experienced again the same subzero temperature test. These results show that it is necessary to remove the water in PEMFCs to maintain stable per- formance under subzero temperature and gas purging is proved to be the effective operation.
