Change in Grain-Size Composition of Lignite under Cyclic Freezing-Thawing and Wetting-Drying

The paper presents the change in grain-size composition of lignite under cyclic freezing-thawing (FTC) and wetting-drying (WDC). The article shows that in the spring and autumn periods the lignites can be subjected to repeated freezing-thawing and wetting-drying, which determines the possibility of changing their grain-size composition and structure. Experimental studies in laboratory conditions on the influence of cyclic freezing-thawing (FTC) and wetting-drying (WDC) on the quality indicators of lignites have been carried out, their granulometric (fractional) composition has been studied. Freezing-thawing cycle conditions are as follows (FTC): minimum exposure temperature: -20°C;maximum: +5°C;relative humidity: 30%;number of processing cycles: 3. Wetting-drying cycles are as follows (WDC): drying temperatures are +20, +40, +60, +80°C, drying time 90 minutes, the coals are further subjected to rain (soaking) for a period of water saturation to humidity of 30% - 40% and dry again. The number of wetting-drying cycles is 3 times. The tests have revealed the destructive effects of FTC and WDC on the samples of lower metamorphic grade coal, and the cycles of wet-dry lead to the much higher yield of fine sizes (-6+0;-13+0 mm) than the cycles of freeze-thaw. Furthermore, it is found that the increase in the yield of fines depends on the heating temperature: coal disintegration proceeds more intensively at a higher temperature of drying.

Numerical Simulation on Climate Effects of Freezing-Thawing Processes Using CCM3

A parameterization of soil freezing-thawing physics for use in the land-surface model of the National Center for Atmospheric Research(NCAR) Community Climate Model(CCM3) is developed and evaluated.The new parameterization scheme has improved the representation of physical processes in the existing land surface model.Numerical simulations using CCM3 with improved land-surface processes and with the original land-surface processes are compared against the NCEP reanalysis.It is found that the CCM3 version using the improved land surface model shows significant improvements in simulating precipitation in China during the summer season,the general circulation over East Asia,and wind fields over the Tibet Plateau.For the summer season,the improved model was able to better simulate the Indian summer monsoon components,including the mean northerly wind in the upper troposphere and mean southerly wind in the lower troposphere.

Shear strength of frozen clay under freezing-thawing cycles using triaxial tests

Using a new low-temperature dynamic triaxial apparatus, the influence law of freezing-thawing cycles on clay shear strength is studied. In this research, the concept of correction coefficients of freezing-thawing cycles on clay static strength, cohesion and internal friction angles is proposed, and the change patterns, correction curves and regressive formulae of clay static strength, cohesion and internal friction angles under freezing-thawing cycles are given. The test results indicate that with increasing numbers of freezing-thawing cycles, the clay static strength and cohesion decrease exponentially but the internal friction angle increases exponentially. The performance of static strength, cohesion and internal friction angles are different with increasing numbers of freezing-thawing cycles, i.e., the static strength decreases constantly until about 30% of the initial static strength prior to the freezing-thawing cycling and then stays basically stable. After 5-7 freezing-thawing cycles, the cohesion decreases gradually to about 70% of the initial cohesion. The internal friction angle increases about 20% after the first freezing-thawing cycle, then increases gradually close to a stable value which is an increase of about 40% of the internal friction angle. The freezing-thawing process can increase the variation of the density of the soil samples; therefore, strict density discreteness standards of frozen soil sample preparation should be established to ensure the reliability of the test results.

Mechanical performances and microstructural characteristics of reactive MgO-carbonated silt subjected to freezing-thawing cycles

The characteristics of reactive magnesia(MgO)-carbonated silt in respect to long-term stability have not been well understood in severely cold climate despite the usage of reactive MgO in enhancing the engineering performances.Under the binder content of 15%and initial water content of 25%,MgO-admixed silt specimens were carbonized for 3 h and 6 h and then subjected to different numbers of freezingthawing(F-T)cycles.After different F-T cycles,the physico-mechanical properties of MgO-carbonated silt were analyzed in comparison with Portland cement(PC)-stabilized silt through physical and unconfined compression tests.Besides,a series of micro tests on MgO-carbonated specimens was performed including X-ray diffraction(XRD),scanning electron microscopy(SEM)and mercury intrusion porosimetry(MIP)tests.The results demonstrate that both mass change ratio and moisture content of carbonated/stabilized silt decrease,and these values of MgO-carbonated silt are significantly lower while the density is higher compared to PC-stabilized silt.The strengths and moduli of MgO-carbonated silt are still two times higher than those of PC-stabilized specimens and the strength change ratio of keeps above0.8 after F-T cycles.There is no visible transformation between nesquehonite and dypingite/hydromagnesite,although the XRD peaks of nesquehonite decrease and the bonding and filling effects weaken slightly.After 6 and 10 F-T cycles,the pore-size characteristics changed from a unimodal distribution to a three-peak and bimodal distribution,respectively.The total,macro and large pore volumes increase obviously while the medium and small pore volumes decrease except for intra-aggregate pore.The findings show better F-T durability of MgO-carbonated silt,which would be helpful for facilitating the application of MgO carbonation in the soil treatment.

Effects of Nitrogen Application on N_2O Flux from Fluvo-Aquic Soil Subject to Freezing-Thawing Process

A lab-incubation experiment was conducted to investigate the effects of different forms of nitrogen application （ammonium, NH4＋-N; nitrate, NO3--N; and amide-N, NH2-N） and different concentrations （40, 200 and 800 mg L-1） on N2O emission from the fluvo-aquic soil subjected to a freezing-thawing cycling. N2O emission sharply decreased at the start of soil freezing, and then showed a smooth line with soil freezing. In subject to soil thawing, N2O emission increased and reached a peak at the initial thawing stage. The average N2O emissions with addition of NH4＋-N, NO3 -N and NH2-N are 119.01, 611.61 and 148. 22 ug m-2 h-1, respectively, at the concentration of 40 mg L-1; 205.28, 1 084.40 and 106.13 ug m2 h-1 at the concentration of 200 mg L-1; and 693.95, 1 820.02 and 49.74 ug m-2 h4 at the concentration of 800 mg L-1. The control is only 100.35 ug m-2 h-1. N2O emissions with addition of NH4＋-N and NO3--N increased with increasing concentration, by ranging from 17.49 to 425.67% for NH4＋-N, and from 563.38 to 1458.6% for NO3--N compared with control. There was a timelag for N2O emission to reach a steady state with an increase of concentration. In contrast, by adding NH2-N to soil, N2O emission decreased with increasing concentration. In sum, NH4＋-N or NO3--N fertilizer incorporated in soil enhanced the cumulative N2O emission from the fluvo-aquic soil relative to amide-N. This study suggested that ammonium and nitrate concentration in overwintering water should be less than 200 and 40 mg L-1 in order to reduce N2O emissions from soil, regardless of amide-N.

Seasonal freezing-thawing process and hydrothermal characteristics of soil on the Loess Plateau, China

In seasonally frozen soil regions,freezing-thawing action and hydrothermal effect have strong influence on physical and mechanical behavior of shallow soil.A field experiment on the Loess Plateau in Northwest China was carried out to analyze the freezing-thawing process and hydrothermal characteristics of shallow soil considering the climate influence.The results show that the maximum seasonal freezing depth under bare ground surface in this area is from 20 cm to 50 cm.The ground temperature shows a similar changing trend with air temperature,but it has lagged behind the air temperature,and the ground temperature amplitude exponentially decreases with the increase of soil depth.The seasonally frozen soil has experienced four typical stages:unfrozen period,alternate freezing period,freezing period and alternate thawing period.The freezing-thawing process is characterized by unidirectional freezing and bidirectional thawing.The water content of shallow soil is significantly affected by air temperature,evaporation and precipitation,and the soil water content shows a"low-high-low"changing trend with the increase of depth.The soil temperature and water content interact with each other,and are often coupled.The variation trend of soil moisture with time is consistent with the change trend of the ground temperature with time in each soil layer,andthe degree of consistency is higher in the near surface soil than that in the lower layer.Also,the spatial-temporal characteristics of soil moisture and temperature is that the volumetric water content and ground temperatureof near surface soil have strong variability,and the range valueKa and coefficient of variation Cvof soil water content and ground temperaturein different seasons show a decreasing trend with the increase of depth.

Response Relationship between the Seasonal Freezing-Thawing Process of Soil and Spatial Factor Changes in the Dayekou Basin of the Qilian Mountains

Objective: In this study, the influence and response relationship between the seasonal freezing-thawing process of soil and the spatial factor changes in the management and utilization of water resource processes were explored. Methods: The monitoring equipment in this study was arranged at different altitudes, gradients, and slope directions, such as the typical forest sample area in the Dayekou Basin of the Qilian Mountains. The spatial variation characteristics of the seasonal freezing-thawing process of the soil were analyzed, and a regression model was established. Results: 1) The results of this study determined that the rate of the soil’s freezing increased with the altitude in a trend of volatility. However, the rate of the thawing of the frozen soil was found to have an opposite trend. The variation degree of the freezing-thawing process increased with the altitude in a trend of volatility. The end time of the approximate soil freezing with altitude increased in a volatility trend ahead of schedule. However, the opposite was observed in the thawing rate of the frozen soil;2) The rate of the soil’s freezing under the mosses of the spruce forest at an altitude of 3028 m was found to be the lowest. However, in the sub-alpine scrub forest at an altitude of 3300 m, a maximum in the spatial ordering was observed, with an average of 1.9 cm·d-1. The thawing rate of the frozen soil in scrub-spruce forest at an altitude of 3300 m was found to be minimal. However, in the sunny slope grassland at an altitude of 2946 m, a maximum in the spatial ordering was observed, with an average of 1.5 cm·d-1. In the spatial ordering of the variation degree of the process of freezing-thawing with an average of 1.2, the scrub-grassland at an altitude of 2518 m was found to be the lowest, and the scrub-spruce forest at an altitude of 3195 m was also low;3) The soil freezing began on approximately October 20th, and the rate of soil freezing gradually became reduced. The arrival time of the frozen soil of up to 150 cm in depth in sub-alpine scrub forest was first observed at an altitude of 3028 m. However, the scrub-spruce forest at an altitude of 3100 m did not become frozen until approximately January 12th on average. Then, the thawing rate of the frozen soil increased gradually. The end time of the thawing was earliest observed in the sunny slope grassland at an altitude of 2946 m. However, the scrub-spruce forest at an altitude of 3100 m was found to be the last to thaw, and averaged approximately July 27th. The average durations of the freezing and thawing of the soil were 77 and 121 days, respectively, and the average duration of the entire process of freezing-thawing was 199 days;4) This study’s established regression models of the duration time of frozen soil’s thaw, and the rate of frozen soil’s thaw, all passed the R test of goodness of fit, F test of variance, and t test. Conclusions: The characteristics of the seasonal freezing-thawing process of the soil with the spatial changes were seasonal. However, the characteristics under the different spatial factor influences were not the same.

Experimental study of coal fracture dynamics under the influence of cyclic freezing-thawing using shear elastic waves

Cyclic freezing-thawing can lead to fracture development in coal,affecting its mechanical and consumer properties.To study crack formations in coal,an ultrasonic sounding method using shear polarized waves was proposed.Samples of three coal types(anthracite,lignite and hard coal)were tested.The research results show that,in contrast to the shear wave velocity,the shear wave amplitude is extremely sensitive to the formation of new cracks at the early stages of cyclic freezing-thawing.Tests also show an inverse correlation between coal compressive strength and its tendency to form cracks under temperature impacts;shear wave attenuation increases more sharply in high-rank coals after the first freezing cycle.Spectral analysis of the received signals also confirmed significant crack formation in anthracite after the first freeze-thaw cycle.The initial anisotropy was determined,and its decrease with an increase in the number of freeze-thaw cycles was shown.The data obtained forms an experimental basis for the development of new approaches to preserve coal consumer properties during storage and transportation under severe natural and climatic conditions.

Effects of freezing-thawing on the engineering performance of core wall soil materials of a dam in the process of construction

The construction of water conservancy projects in cold regions experiences freezing-thawing cycles,which can greatly change the engineering properties of soil and have a significant impact on the construction of projects.Lianghekou Hydropower Station(LHS),is a controlling station with the largest installed capacity among the 7 middle reach projects in the Yalong River,the secondary tributary of the Yangtze River.LHS is located in a seasonally frozen soil area.Based on the measured data of air and ground temperature in winter in the dam core wall,the freezing-thawing variation of gravelly soil and contact clay during the filling process of the core wall are compared and analyzed,then the main impact factors of the freezing-thawing variation of soils are discussed.The results show that under the influence of air temperature,soil freezes unidirectionally from ground surface downward and deepens gradually,and the thawing processes are different at the aspects of thawing direction and rate.Air temperature and physical properties of soil including soil type,moisture content and dry density affect the freezingthawing processes of soils.And the impact of engineering construction is more remarkable than natural factors.The engineering construction affects soil temperature and freezing-thawing process by controlling the initial temperature of soil,the speed and duration of the technological conversion of paving,compaction,and the length of placed duration at night.Due to the long placed duration of soil with the slow construction method,the initial temperature of soil gradually reduces,the heat transfer process inside soil is fast.Then the internal heat of soil releases,the decreasing rate of ground temperature of soil at different depths is fast and the frozen depth deepens.While due to the short placed duration of soil with the rapid construction process,the initial temperature of soil is high,high internal heat of soil is supplied every day,and the heat transfer process inside soil is slow.Then the decreasing rate of temperature of soil at different depths is slow,and the variation amplitude of frozen depth is small.This study provides useful guidance for the freezingthawing prevention during the construction process of core wall dams located at high altitude region in winter.

Experimental research on the development of residual strain in seasonal frozen soil under freezing-thawing and impact type traffic loads

Vehicle load is among the main factors affecting the deformation of subgrade soil.In this research study,the concept of impact type traffic load is introduced to investigate the effects of vehicle load based on the dynamic stress and displacement time histories acquired from seasonal frozen subgrade soils.Using freezing-thawing and dynamic triaxial tests and considering the amplitude and loading sequence of impact type traffic load,the residual deformation characteristics of subgrade soil under impact type traffic loads and freezing-thawing cycles is studied.It was found that under impact type traffic load,the residual deformation of soils increased sharply as the amplitude of impact type traffic load increased.It was also found that the increase in the amplitude of impact type traffic load led to the increase of residual deformation in a scale of power and exponential function.The amplitudes of impact type traffic load affect the development stress-strain path of the residual strain.After the soil experienced the proper amount of pre-vibration of the light load,residual deformation decreased by 15%.After freezing-thawing,the residual strain of soil increased as the amplitude of the impact type traffic loads increased.Also,when the amplification effect of freezing-thawing on the residual strain was basically stable,the residual deformation increased by about 10%.The peak impact type traffic load had a large effect on soil deformation after the freezing-thawing process,leading to the observation that of the earlier the peaks,the stronger the effect of freezing-thawing.After the soil was subjected to preloading with a small load,the influence of the freezing-thawing cycles gradually stabilized.The results may be useful in preventing and controlling the risk of subgrade soil failure when construction takes place spring thaw periods.

Advances in studies on concrete durability and countermeasures against freezing-thawing effects

This paper is a meta-analysis of recent domestic and foreign research on freezing-thawing effects on concrete durability. The main theories on the mechanisms of freeze-thaw damage to concrete are introduced： the hydrostatic pressure theory, the osmotic pressure theory, the critical water saturation degree theory, the dual mechanism theory, and the micro-ice-crystal lens model theory. The influence laws of freezing-thawing on the mechanical properties of concrete are summarized, and countermeasures to improve concrete durability in freezing-thawing circumstances are presented. This work provides valuable references for future engineering constructions in cold regions.

Effect of Freezing-Thawing Process on Wetland Soil Iron

The iron concentrations of snows,semi-melting snows,snowmelts,and ditch waters were observed in four typical microhabitats,Carex lasiocarpa marsh(Ⅰ), Calamagrostis angustifolia wet meadow(Ⅱ),dry land (Ⅲ)and paddy field(Ⅳ),of Sanjiang Plain Wetland, Northeast China.Each sample was collected from three sites of one microhabitat,mixed together, filtrated with 0.45μm membrane,and tested using atomic absorption spectrometry(AAS)for iron measurement.The iron concentrations of soil solutions were investigated as well.Each soil solution was in-situ extracted by negative pressure,filtrated with 0.45μm membrane,and tested using AAS,too. The results showed that the wet precipitation of iron from snow were little to detect.The loss of iron was attributed to the interaction of water and soil surface. The iron concentrations of snowmelts were 7.4,15,

Effect of pH,temperature and freezing-thawing on quantity changes and cellular uptake of exosomes

Exosomes are cup-shaped small(30-150 nm)extracellular vesicles with the structure of lipid bilayer membrane(Tkach and Thery,2016)containing proteins,mRNAs and micro-RNAs that mediate intercellular communication(Valadi et al.,2007).Unlike other extracellular vesicles,exosomes are released into the extracellular space when the multivesicular bodies(MVBs)fuse with the plasma membrane(Colombo et al.,2014).

Development of pot-cover effect apparatus with freezing-thawing cycles

‘Pot-cover effect’ refers to the phenomenon of moisture accumulation beneath the pavement under condensation or desublimation because the vapor transfer in the soil is blocked by the pavement. To study this phenomenon in the laboratory, we have developed the pot-cover effect apparatus with freezing-thawing cycles(PEAFC), which consists of three parts, namely, the vapor transfer system, the temperature control system, and the temperature and water content monitoring system. The major functions of this apparatus include: simulation of both vapor transfer and freezing-thawing cycling in the soil, real-time monitoring of the temperature and the water content in soil samples, and one-dimensional heat and moisture transfer in the samples. The FDR(frequency domain reflectometry) sensors of the apparatus are calibrated and a calibration formula is proposed to eliminate the water content measurement errors induced by temperature changes. Constant temperature difference tests and a freezing-thawing cycling test are conducted with the apparatus. Results indicate that the apparatus can control the water replenishment in the soil samples, monitor the vapor transfer in the samples in real time, and simulate the vapor transfer process under the condition of the freezing-thawing cycling in the soil. These tests verify the effectiveness and reliability of the apparatus, which indicates that the development purpose is achieved.

Durability of Concrete Subjected to the Combined Actions of Flexural Stress,Freeze-thaw Cycles and Bittern Solutions

Freeze-thaw durabilities of three types of concretesnormal portland cement concrete （OPC）, high strength concrete （HSC） and steel fiber reinforced high strength concrete （SFRHSC） were systemically investigated under the attacks of chemical solution, and combination of external flexural stress and chemical solution. Four kinds of bitterns from salt lakes in Sinkiang, Qinghai, Inner Mongolia and Tibet provinces of China were used as chemical attack solutions. The relative dynamic modulus （RDM） was used as an index for evaluating the damage degree during the course of chemical attack and stress corrosion. The experimental results show that the freeze-thaw durability of concrete is visibly reduced in the present of the flexural stress, i e, stress accelerates the damage process. In order to quantify the stress accelerated effect, a stress accelerating coefficient was proposed. The stress accelerating coefficient is closely related with the types of bitterns and the numbers of freeze-thaw cycles is. The more numbers of freeze-thaw cycles is, the greater the stress accelerating coefficient for various concretes will be. In addition, there also exists a critical ratio of external stress to the maximum flexural stress. If the stress ratio exceeds the critical one, the freeze-thaw durability of various concretes will be greatly decreased compared to the responding concretes without applied stress. The critical stress ratio of OPC, HSC and SFRHSC is 0.30, 0.40 and 0.40, respectively, indicating that HSC and SFRHSC have advantages over OPC and are suitable to use in the bittern erosion regions.

Fatigue Property of Basalt Fiber-Modified Asphalt Mixture under Complicated Environment

The fatigue property of asphalt mixtures under complicated environment （low-temperature bending performance, chloride penetration, freezing-thawing cycle and their coupling effect） and the improvement effect for relevant property of basalt fiber-reinforcing asphalt mixture under complicated environment are studied. Two grading types of asphalt mixtures, AC-16I and AC-13I, are chosen, whose optimum asphalt-aggregate ratio and optimum dosage of basalt fiber are determined by the Marshall test. The standard specimens are made firstly, and then the low temperature bending tests of asphalt mixture and basalt fiber-reinforced asphalt mixture under the coupling effect of the chloride erosion and freezing-thawing cycle have been carried out. Finally, the fatigue property tests of asphalt mixture and basalt fiber-reinforced asphalt mixture under complex environment are performed on MTS material testing system. The results indicate that the tensile strength, the maximum curving tensile stress, the curving stiffness modulus, and fatigue properties of asphalt mixture are influenced by the coupling effect of the chloride erosion and freezing-thawing cycle. The low-temperature bending performance and fatigue property of asphalt mixtures under complicated environment can be greatly improved by adding moderate basalt fiber. The dense gradation asphalt mixture possesses stronger ability to resist adverse environmental effects under the same condition.

Effect of Preparation Methods on Mechanical Properties of PVA/HA Composite Hydrogel

Poly(vinyl alcohol) (PVA)/hydroxyapatite (HA) composite hydrogel specimens were prepared with 15% PVA and 1%,2%, 3%, 4% and 5% HA by repeated freezing-thawing. The tests of static and dynamic mechanical properties were carried out todiscuss the influence of different contents of HA and freezing-thawing cycles on the mechanical properties of PVA/HA compositehydrogel. The results of static mechanical tests showed that the PVA/HA composite hydrogel with 3% HA and ninefreezing-thawing cycles had excellent stress relaxation properties, higher relaxation ratio, lower stress equilibrium value andpresented better properties of creep and recovery. The results of dynamic mechanical test showed that the PVA/HA compositehydrogel with nine freezing-thawing cycles had higher storage modulus and loss modulus, so was the PVA/HA compositehydrogel with 3% HA.

Effect of Fly Ash on Frost-Resistance and Chloride Ions Diffusion Properties of Marine Concrete

It is necessary to pay more attention to the durability of concrete undergoing freeze-thaw cycles and seawater attack simultaneously.Investigated are the effects of water-binder ratio,fly ash（FA）contents and air-entraining agent on resistance to frost and chloride diffusion of marine concrete blended with FA in natural seawater.The results show that fly ash does not improve the frost resistance of concrete but can improve its resistance to chloride diffusion by addition of less than 30%.The resistance to frost and chloride diffusion of FA concrete can be improved with the decrease of water-binder ratio,and FA may improve both of them simultaneously only being mixed with air-entraining agent.A ratio（named as R）of the frost-resisting durability factor to chloride diffusion coefficient can be used to evaluate the durability of marine concrete.Scanning electron microscope（SEM）analyses are consistent with the evaluations by the value of R.

Durability of Concrete under Multi-damage Action

Several different experiments,including freezing-thawing,freezing-thawing+drying-wetting,and drying-wetting,in salt solution and in water respectively,were designed to determine the durability of concrete.The durability damage features of concrete in the above experiments were studied.It is demonstrated that the damage extent of concrete under freezing-thawing and freezing-thawing+drying-wetting in salt solution is larger than that in water.Thus,freezing-thawing and freezing-thawing+drying-wetting in salt solution are stricter and more effective methods to evaluate the durability of concrete in salt-existing environment in cold regions.The damage extent of concrete under freezing-thawing+drying-wetting shows an ultra-superposition effect.The order of concrete durability deterioration degree in these experiments is determined.It shows that effects of multi-damage factors are greater than those of single-damage factor.

Processes and mechanisms of multi-collapse of loess roads in seasonally frozen ground regions: A review

Usually, the collapsible loess widely distributed across the world can serve as a type of foundation soil that meets its strength requirement after dense compaction and elimination of collapsibility. However, many problems such as cracks and differential settlement still occur in loess roads in the seasonally frozen ground regions after several years of op- eration. Many studies have demonstrated that these secondary or multiple collapses primarily result from the repeated freezing-thawing, wetting-drying, and salinization-desalinization cycles. Therefore, we conducted a research program to （1） monitor the in-situ ground temperatures and water content in certain loess roads to understand their changes, （2） study the effects of freezing-thawing, wetting-drying, and salinization-desalinization cycles on geotechnical properties and micro-fabrics of compacted loess in the laboratory, and （3） develop mitigative measures and examine their engineered effectiveness, i.e., their thermal insulating and water-proofing effects in field and laboratory tests. Our results and advances are reviewed and some further research needs are proposed. These findings more clearly explain the processes and mechanisms of secondary and multiple collapse of loess roads. We also offer references for further study of the weakening mechanisms of similar structural soils.