Capacitive energy storage from single pore to porous electrode identified by frequency response analysis

Rate capability,peak power,and energy density are of vital importance for the capacitive energy storage(CES)of electrochemical energy devices.The frequency response analysis(FRA)is regarded as an efficient tool in studying the CES.In the present work,a bi-scale impedance transmission line model(TLM)is firstly developed for a single pore to a porous electrode.Not only the TLM of the single pore is reparameterized but also the particle packing compactness is defined in the bi-scale.Subsequently,the CES properties are identified by FRA,focused on rate capability vs.characteristic frequency,peak power vs.equivalent series resistance,and energy density vs.low frequency limiting capacitance for a single pore to a porous electrode.Based on these relationships,the CES properties are numerically simulated and theoretically predicted for a single pore to a porous electrode in terms of intra-particle pore length,intra-particle pore diameter,inter-particle pore diameter,electrolyte conductivity,interfacial capacitance&exponent factor,electrode thickness,electrode apparent surface area,and particle packing compactness.Finally,the experimental diagnosis of four supercapacitors(SCs)with different electrode thicknesses is conducted for validating the bi-scale TLM and gaining an insight into the CES properties for a porous electrode to a single pore.The calculating results suggest,to some extent,the inter-particle pore plays a more critical role than the intra-particle pore in the CES properties such as the rate capability and the peak power density for a single pore to a porous electrode.Hence,in order to design a better porous electrode,more attention should be given to the inter-particle pore.

HF-VHF dual-channel multifunctional radio astronomy terminal system

The high frequency-very high frequency(HF-VHF)frequency band is of significant importance in astronomical observations,with applications studying various phenomena such as space weather,solar radio emissions,planetary eruptions in the solar system,pulsars,transient sources,and reionization of the early universe.This article introduces the HF-VHF frequency band multifunctional radio astronomical terminal system based on a dual-channel high-speed acquisition board with a frequency observation range of 1-250 MHz and a sampling rate of 500 Msps(Mega samples per second).The maximum quantization bit of the system is 14 bits,with a maximum time resolution of 0.1 s and a maximum spectral resolution of 16 kHz.The system combines spectral analysis of solar radio signals and recording of time-domain data of signals interfering with long baselines,and adopts a server-client separation mode to allow remote operation with separate permissions.It is used in the China-Malaysia joint astronomy project,which can carry out single-site observation of solar radio signals as well as interferometric observation of signals from multiple sites.

Frequency Features Based Fuzzy System for Rotating Machinery Vibration Analysis Using Smartphones Low-Cost MEMS Sensors

Smart devices have become an important entity for many applications in daily life activities. These devices have witnessed a rapid improvement in its technology to fulfill the increasingly diverse usage demands. In the meanwhile, rotating machinery vibration analysis based on low-cost sensors has gained a considerable attraction over the last few years. For a long time, the vibration analysis of machines has been accepted as an effective solution to detect and prevent failures in complex systems to avoid the sudden malfunction. The objective of this work is to use MEMS accelerometer measurements to monitor the different level of vibration of a machine. This work presents a new technique for rotating machinery vibration analysis. It uses Fast Fourier Transformation as a feature extraction algorithm and Fuzzy Logic System (FLS) as the classifier algorithm. A smartphone accelerometer is used to collect the data from the vibrating machine. The performance of the proposed technique is tested using data from different vibration resources at a different speed of operations. The results are discussed to illustrate the various vibration levels.

High-precision frequency attenuation analysis and its application

Based on seismic attenuation theory in a fluid-filled porous medium, we improve conventional methods of low-frequency shadow analysis （LFSA） and energy absorption analysis （EAA） and propose a high-precision frequency attenuation analysis technology. First, we introduce the method of three-parameter wavelet transform and the time-frequency focused criterion and develop a high-precision time-frequency analysis method based on an adaptive three-parameter wavelet transform, which has high time-frequency resolution with benefit to LFSA and can obtain a single-peaked spectrum with narrow side-lobes with benefit to EAA. Second, we correctly compute absorption coefficient by curve fitting based on the nonlinear Nelder-Mead algorithm and effectively improve EAA precision. Practical application results show that the proposed frequency attenuation analysis technology integrated with LFSA and EAA can effectively predict favorable zones of carbonate oolitic reservoir. Furthermore, reservoir prediction results based on LFSA correspond with EAA. The new technology can effectively improve reservoir prediction reliability and reduce exploration risk.

Frequency spectrum analysis on micro-seismic signal of rock bursts induced by dynamic disturbance

Blasting and breaking of hard roof are main inducing causes of rock bursts in coal mines with danger of rock burst,and it is important to find out the frequency spectrum distribution laws of these dynamic stress waves and rock burst waves for researching the mechanism of rock burst.In this paper,Fourier transform as a micro-seismic signal conversion method of amplitude-time character to amplitude-frequency character is used to analyze the frequency spectrum characters of micro-seismic signal of blasting,hard roof breaking and rock bursts induced by the dynamic disturbance in order to find out the difference and relativity of different signals.The results indicate that blasting and breaking of hard roof are high frequency signals,and the peak values of dominant frequency of the signals are single.However,the results indicate that the rock bursts induced by the dynamic disturbance are low frequency signals,and there are two obvious peak values in the amplitude-frequency curve witch shows that the signals of rock bursts are superposition of low frequency signals and high frequency signals.The research conclusions prove that dynamic disturbance is necessary condition for rock bursts,and the conclusions provide a new way to research the mechanism of rock bursts.

Frequency domain stability criteria for fractional-order control systems

This paper concerns about the frequency domain stability criteria for fractional-order control systems. On the base of characteristics of the fractional-order equations solutions, we consider the Nyquist stability criterion in a wider sense and obtain a more common means to analyze the stability of fractional-order systems conveniently. Finally, this paper illustrates the generalized stability criteria with an example to show the effect of the parameters variation on the fractional-order control systems.

Regional Frequency Analysis of Observed Sub-Daily Rainfall Maxima over Eastern China

Based on hourly rainfall observational data from 442 stations during 1960-2014, a regional frequency analysis of the annual maxima （AM） sub-daily rainfall series （1-, 2-, 3-, 6-, 12-, and 24-h rainfall, using a moving window approach） for eastern China was conducted. Eastern China was divided into 13 homogeneous regions： Northeast （NE1, NE2）, Central （C）, Central North （CN1, CN2）, Central East （CE1, CE2, CE3）, Southeast （SE1, SE2, SE3, SE4）, and Southwest （SW）. The generalized extreme value performed best for the AM series in regions NE, C, CN2, CE1, CE2, SE2, and SW, and the generalized logistic distribution was appropriate in the other regions. Maximum return levels were in the SE4 region, with value ranges of 80-270 mm （1-h to 24-h rainfall） and 108-390 mm （1-h to 24-h rainfall） for 20- and 100 yr, respectively. Minimum return levels were in the CN1 and NE1 regions, with values of 37-104 mm and 53-140 mm for 20 and 100 yr, respectively. Comparing return levels using the optimal and commonly used Pearson-III distribution, the mean return-level differences in eastern China for 1-24-h rainfall varied from -3-4 mm to -23-11 mm （- 10%-10%） for 20-yr events, reaching -6-26 mm （-10%-30%） and -10-133 mm （-10%-90%） for 100-yr events. In view of the large differences in estimated return levels, more attention should be given to frequency analysis of sub-daily rainfall over China, for improved water management and disaster reduction.

DEVELOPMENT OF VIRTUAL INSTRUMENT IN CHARACTERISTIC ANALYSIS OF ROTATING MACHINERY BASED ON INSTANTANEOUS FREQUENCY ESTIMATION

Based on the recently quick-developing time-frequency analysis (TFA)technique and virtual instrument (VI) technique, a virtual instrument in characteristic analysis ofrotating machinery is researched and developed successfully. By utilizing instantaneous frequencyestimation (IFE) theoretics of TFA technique, and based on IFE of peak searching on thetime-frequency spectrum, order analysis (OA) functions is put forward and implemented, such as orderspectrum, order spectrum matrix, order tracking, order tracking filtering, and order componentextraction, etc. Unlike the home and abroad existing popular characteristic analyzers, which needkey phasing devices such as shaft encoder, phase-locked loop (PLL), phase-locked multiple frequency,tachometer, etc, to implement constant angle sampling directly or indirectly, whereas thisinstrument only uses the vibration signal of rotating machinery to carry out OA. This instrumentmakes up the shortage of these traditional instruments in analyzing the non-stationary signal ofrun-up and run-down process of rotating machinery. Therefore, it is a great breakthrough for theexisting order analyzers.

Adaptive Fourier Decomposition Based Time-Frequency Analysis

The attempt to represent a signal simultaneously in time and frequency domains is full of challenges. The recently proposed adaptive Fourier decomposition （AFD） offers a practical approach to solve this problem. This paper presents the principles of the AFD based time-frequency analysis in three aspects： instantaneous frequency analysis, frequency spectrum analysis, and the spectrogram analysis. An experiment is conducted and compared with the Fourier transform in convergence rate and short-time Fourier transform in time-frequency distribution. The proposed approach performs better than both the Fourier transform and short-time Fourier transform.

Prediction of Intraoperative Fracture by Hammering Sound Frequency Analysis and Stress Estimation during Total Hip Arthroplasty

When a stem is inserted into the femur during total hip arthroplasty, sufficient fixation depends on the surgeon’s experience. An objective method of evaluating whether the stem has been correctly fixed may aid clinicians in their decision. We examined the relationship between the sound frequency caused by hammering the stem and the internal stress in artificial femurs, and evaluated the utility of sound frequency analysis to prevent intraoperative fracture. Surgeons inserted one of two types of cementless stems (SL-PLUS and modified CLS) using routine operational procedures into 13 artificial femurs. These are the standard Zweymüllers used in Europe. The difference is the lateral shape;SL-PLUS has holes for removal and the modified CLS has fins to prevent rotation. We estimated stress in the femur via finite element analysis, measured the hammering force, and recorded the sound of hammering for frequency analysis. Finite element analysis revealed that the hammering sound frequency decreased as the maximum stress increased. A decrease in frequency suggested that fixation was sufficient and that continued hammering would increase the risk of fracture. Thus, evaluation of the change in sound frequency during stem insertion may indicate when the hammering force should be reduced, thereby preventing intraoperative periprosthetic fractures. Further frequency change may also predict fractures prior to visual confirmation. We concluded that sound frequency analysis has potential as an objective evaluation method to help prevent intraoperative periprosthetic fractures during stem insertion.

Analysis of Frequency Characteristics and Sensitivity of Compliant Mechanisms

Based on a modified pseudo-rigid-body model,the frequency characteristics and sensitivity of the large-deformation compliant mechanism are studied.Firstly,the pseudo-rigid-body model under the static and kinetic conditions is modified to enable the modified pseudo-rigid-body model to be more suitable for the dynamic analysis of the compliant mechanism.Subsequently,based on the modified pseudo-rigid-body model,the dynamic equations of the ordinary compliant four-bar mechanism are established using the analytical mechanics.Finally,in combination with the finite element analysis software ANSYS,the frequency characteristics and sensitivity of the compliant mechanism are analyzed by taking the compliant parallel-guiding mechanism and the compliant bistable mechanism as examples.From the simulation results,the dynamic characteristics of compliant mechanism are relatively sensitive to the structure size,section parameter,and characteristic parameter of material on mechanisms.The results could provide great theoretical significance and application values for the structural optimization of compliant mechanisms,the improvement of their dynamic properties and the expansion of their application range.

Local and regional flood frequency analysis based on hierarchical Bayesian model in Dongting Lake Basin,China

This study developed a hierarchical Bayesian(HB)model for local and regional flood frequency analysis in the Dongting Lake Basin,in China.The annual maximum daily flows from 15 streamflow-gauged sites in the study area were analyzed with the HB model.The generalized extreme value(GEV)distribution was selected as the extreme flood distribution,and the GEV distribution location and scale parameters were spatially modeled through a regression approach with the drainage area as a covariate.The Markov chain Monte Carlo(MCMC)method with Gibbs sampling was employed to calculate the posterior distribution in the HB model.The results showed that the proposed HB model provided satisfactory Bayesian credible intervals for flood quantiles,while the traditional delta method could not provide reliable uncertainty estimations for large flood quantiles,due to the fact that the lower confidence bounds tended to decrease as the return periods increased.Furthermore,the HB model for regional analysis allowed for a reduction in the value of some restrictive assumptions in the traditional index flood method,such as the homogeneity region assumption and the scale invariance assumption.The HB model can also provide an uncertainty band of flood quantile prediction at a poorly gauged or ungauged site,but the index flood method with L-moments does not demonstrate this uncertainty directly.Therefore,the HB model is an effective method of implementing the flexible local and regional frequency analysis scheme,and of quantifying the associated predictive uncertainty.

Hammering Sound Frequency Analysis to Fix an Acetabular Cup during Total Hip Arthroplasty: Clinical Trials and Biomechanical Studies

Failure during total hip arthroplasty may lead to bedridden of the elderly. Since the acetabulum cup fix in an anatomically deep region, failures, such as loosening and fracture, occur three times more frequently compared with failures of the stem fix in the femur. We investigated the possibility of evaluating whether fixation was acquired by frequency analysis of the hammering sound of implanting a cup into the acetabulum. The subjects were 11 patients (11 joints) who underwent total hip arthroplasty, biomechanical test materials, and orthopedic models. Surgeries and experiments were performed by orthopedists specialized in the hip. A system was constructed with a tablet PC and directional microphone, the peak frequency at which the amplitude reached the maximum was determined, and judgment processing (stable, unstable) of cup fixability was performed in real time. The stable maximum peak frequency observed in the clinical trials was 4.42 ± 4.02 kHz. The mean stable maximum peak frequency in the biomechanical tests was 4.46 ± 1.19 kHz in biomechanical test materials and 4.56 ± 2.02 kHz in orthopaedicmodels. When hammering was continued, the frequency leading to fracture decreased in both biomechanical test materials and orthopaedicmodels. In conclusion, in clinical trials and biomechanical studies, variation of the maximum peak frequency decreased when fixation was acquired and the frequency stabilized. It was suggested that this method can serve as a fixability evaluation method of acetabular cups because analysis can be performed in real time during surgery, for which prevention of intraoperative fracture can be expected.

A Priority-aware Frequency Domain Polling MAC Protocol for OFDMA-based Networks in Cyber-physical Systems

Wireless networking in cyber-physical systems (CPSs) is characteristically different from traditional wireless systems due to the harsh radio frequency environment and applications that impose high real-time and reliability constraints. One of the fundamental considerations for enabling CPS networks is the medium access control protocol. To this end, this paper proposes a novel priority-aware frequency domain polling medium access control (MAC) protocol, which takes advantage of an orthogonal frequency-division multiple access (OFDMA) physical layer to achieve instantaneous priority-aware polling. Based on the polling result, the proposed work then optimizes the resource allocation of the OFDMA network to further improve the data reliability. Due to the non-polynomial-complete nature of the OFDMA resource allocation, we propose two heuristic rules, based on which an efficient solution algorithm to the OFDMA resource allocation problem is designed. Simulation results show that the reliability performance of CPS networks is significantly improved because of this work. © 2014 Chinese Association of Automation.

Frequency Analysis on the Data of Field Fertilizer Efficiency Test and Fertilization Decision-making

To solve the problems of abnormal larger, abnormal lower or even negative of target yield and fertilizing amount recommended by part of non-typical fertilizer effect equations using agricultural experiments and statistical analysis software,Yangzhou analyzer（2.2）, regression analysis of Excel, which objected to local actual production, the study adopted the principle and method of basic knowledge and the frequency of using probability theory, and carried out statistical analysis on the rape field fertilizer experiment data by frequency analysis method, the rape yield after optimizing fertilizing amount was 1 732.4 kg/hm^2, the ranges of N, P and K optimal combinations were： N=210.36-149.64 kg/hm^2,P2O5=81.89-58.11 kg/hm^2, K2O=81.89-58.11 kg/hm^2,which was consistent with local actual production. This study was based on frequency analysis, using weighted average method to determine the production combinations of different yield objectives, hereinto, the combinations with high yield, high frequency of occurrence（dependable crop） and fertilizer-saving were viewed as the optimizing production measures, and they had the merits of increasing fertilization decision-making information, reducing or avoiding the risk of small probability event. The results of this study can solve the problem of abnormal values fertilizing amount and target yield recommended by non-typical fertilizer effect function, which did not accord with local actual production, caused by Yangzhou analyzer（2.2）, regression analysis of Excel, and DPS statistical analysis software. For the fertilizer effect function equation established by regression analysis which did not reach significance level using variance analysis, whether the method can be adapted to for carrying out fertilization decision-making, recommending optimization combinations of N, P and K fertilizers and yield under optimized fertilizing amount should be further researched in future working practice.

Analysis of active patents to investigate the frequency and patterns of Chinese herbal extract combinations claiming to treat heart disease

Objective:Using Chinese patents in force to investigate the frequency and patterns of Chinese herbal extract combinations claiming to treat heart disease.Methods:Patent documents were retrieved from the official website of the State Intellectual Property Office of the People’s Republic China.Cluster,frequency,and fuzzy cluster analyses were applied.Results:A high number of patents in force included high-frequency herbs such as Salvia miltiorrhiza,Panax ginseng,and Panax notoginseng,as well as high-frequency herbal families such as Araliaceae,Leguminosae,Labiatae,and Umbelliferae.Herb pairs such as P.ginsengþOphiopogon japonicus,S.miltiorrhizaþDalbergia odorifera,and P.ginsengþSchisandra chinensis are also commonly used,as well as herbal family pairs such as AraliaceaeþLiliaceae,LauraceaeþLeguminosae,and AraliaceaeþSchisandraceae.Traditional treatment principles for preventing and treating heart diseases was most-commonly based on simultaneously treating the liver and heart and treating the lung and spleen secondarily for choosing herbal combinations.Conclusion:Most of the high-frequency Chinese herbs in the patents investigated belong to the high-frequency herbal families,and herb pairs were commonly selected to coincide with the commonly-used herbal family pairs.Low-frequency Chinese herbs were also used,but generally belonged to the high-frequency herbal families,and were therefore similar to the highfrequency herbs in terms of traditional categories of taste and channel entered.The results reflect the use of traditional principles of formula composition,and suggest that these principles may indeed be an effective guide for further research and development of Chinese herbal extract combinations to prevent and treat heart diseases.

Combined spatial frequency spectroscopy analysis with visible resonance Raman for optical biopsy of human brain metastases of lung cancers

The purpose of this study is to examine optical spatial frequency spectroscopy analysis(SFSA)combined with visible resonance Raman(VRR)spectroscopic method,for thefirst time,to discriminate human brain metastases of lung cancers adenocarcinoma(ADC)and squamous cell carcinoma(SCC)from normal tissues.A total of 31 label-free micrographic images of three type of brain tissues were obtained using a confocal micro-Raman spectroscopic system.VRR spectra of the corresponding samples were synchronously collected using excitation wavelength of 532 nm from the same sites of the tissues.Using SFSA method,the difference in the randomness of spatial frequency structures in the micrograph images was analyzed using Gaussian functionfitting.The standard deviations,calculated from the spatial frequencies of the micrograph images were then analyzed using support vector machine(SVM)classifier.The key VRR biomolecularfingerprints of carotenoids,tryptophan,amide II,lipids and proteins(methylene/methyl groups)were also analyzed using SVM classifier.All three types of brain tissues were identified with high accuracy in the two approaches with high correlation.The results show that SFSA–VRR can potentially be a dual-modal method to provide new criteria for identifying the three types of human brain tissues,which are on-site,real-time and label-free and may improve the accuracy of brain biopsy.

Regional Frequency Analysis of Significant Wave Heights Based onL-moments

L-moments are defined as linear combinations of probability-weighted moments, They are, virtually unbiased for small samples, and perform well in parameter estimation, choice of the distribution type and regional analysis. The traditional methods of determining the design wave heights for planning marine structures use data only from the site of interest. Regional frequency analysis gives a new approach to estimate quantile by use of the homogeneous neighborhood informatian. A regional frequency analysis based on L-moments with a case study of the California coast is presented. The significant wave height data for the California coast is offered by NDBC. A 6-site region without 46023 is considered to be a homogeneous region, whose optimal regional distribution is Pearson Ⅲ. The test is conducted by a simulation process. The regional quantile is compared with the at-site quantile, and it is shown that efficient neighborhood information can be used via regional frequency analysis to give a reasonable estimation of the site without enough historical data.

Unsupervised FIR adaptive filtering and its frequency domain analysis

An unsupervised minimum mean square error FIR adaptive filtering （UAF） algorithm is proposed to estimate the system＇ s input signal. The algorithm only uses the system＇ s output signal and noise variance without requiring knowledge of a reference signal. The frequency analysis shows that the UAF is a multi-spot bandpass filter with passing frequency determined by the system＇ s input signal. Namely, the UAF chooses the expected frequency and extremely restricts the unwanted fre- quency signal by using weight-updating scheme in time domain. However, the UAF presents the Gibbs phenomenon since the ideal filter is infinitely long which is unrealizable. The simulation and experimental results show that the UAF could effectively reduce the amplitude of the noise and im- prove the signal to noise ratio.

Error Analysis in Frequency Domain for Linear Multipass Algorithms

Error analysis methods in frequency domain are developed in this paper for determining the characteristic root and transfer function errors when the linear multipass algorithms are used to solve linear differential equations. The relation between the local truncation error in time domain and the error in frequency domain is established, which is the basis for developing the error estimation methods. The error estimation methods for the digital simulation model constructed by using the Runge-Kutta algorithms and the linear multistep predictor-corrector algorithms are also given.