The objectives of this research were to understand the process of converting toluene into phenol in a one-step process directly from a water–toluene mixture using the plasma in-liquid method.Experiments were conducte...The objectives of this research were to understand the process of converting toluene into phenol in a one-step process directly from a water–toluene mixture using the plasma in-liquid method.Experiments were conducted using 27.12 MHz radio frequency（RF） in-liquid plasma to decompose a solution of 30% toluene. Based on the experimental results as evaluated using gas chromatography–mass spectrometry（GC–MS）, along with additional analysis by the Gaussian calculation, density functional theory（DFT） hybrid exchange–correlational functional（B3LYP）and 6-311 G basis, the phenol generated from toluene was quantified including any by-products.In the experiment, it was found that OH radicals from water molecules produced using RF inliquid plasma play a significant role in the chemical reaction with toluene. The experimental results suggest that phenol can be directly produced from a water–toluene mixture. The maximum phenol yields were 0.0013% and 0.0038% for irradiation times of 30s and 60s,respectively, at 120 W.展开更多
Train-to-train(T2T)communication can provide protection for existing train-to-ground private network communication,and its channel characteristics directly affect the application of upper-layer communication technolog...Train-to-train(T2T)communication can provide protection for existing train-to-ground private network communication,and its channel characteristics directly affect the application of upper-layer communication technologies.In this study,based on the spatial distribution structure of railway operation scenarios and Fresnel zone theory,we propose a frequency allocation scheme for direct communication between tracking trains in flatland and long straight tunnel scenario.Then we use the estimation method of radio wave attenuation caused by rainfall to analyze the large-scale path loss fading of multi-band wireless channels.Furthermore,we derive the calculation equation of max Doppler frequency shift suitable for T2T communication and describe the multipath wave in the tunnel by ray tracing method to analyze small-scale fading.Simulation analysis shows that the Doppler shift value of T2T communication low frequency band is significantly lower than the frequency shift value of the train-to-ground communication under the same speed conditions.展开更多
基金partially supported by JSPS KAKENHI Grant Number 15K05833
文摘The objectives of this research were to understand the process of converting toluene into phenol in a one-step process directly from a water–toluene mixture using the plasma in-liquid method.Experiments were conducted using 27.12 MHz radio frequency（RF） in-liquid plasma to decompose a solution of 30% toluene. Based on the experimental results as evaluated using gas chromatography–mass spectrometry（GC–MS）, along with additional analysis by the Gaussian calculation, density functional theory（DFT） hybrid exchange–correlational functional（B3LYP）and 6-311 G basis, the phenol generated from toluene was quantified including any by-products.In the experiment, it was found that OH radicals from water molecules produced using RF inliquid plasma play a significant role in the chemical reaction with toluene. The experimental results suggest that phenol can be directly produced from a water–toluene mixture. The maximum phenol yields were 0.0013% and 0.0038% for irradiation times of 30s and 60s,respectively, at 120 W.
基金National Natural Science Foundation of China(No.61763023)Lanzhou Jiaotong University-Tianjin University Innovation Fund(No.20180519)。
文摘Train-to-train(T2T)communication can provide protection for existing train-to-ground private network communication,and its channel characteristics directly affect the application of upper-layer communication technologies.In this study,based on the spatial distribution structure of railway operation scenarios and Fresnel zone theory,we propose a frequency allocation scheme for direct communication between tracking trains in flatland and long straight tunnel scenario.Then we use the estimation method of radio wave attenuation caused by rainfall to analyze the large-scale path loss fading of multi-band wireless channels.Furthermore,we derive the calculation equation of max Doppler frequency shift suitable for T2T communication and describe the multipath wave in the tunnel by ray tracing method to analyze small-scale fading.Simulation analysis shows that the Doppler shift value of T2T communication low frequency band is significantly lower than the frequency shift value of the train-to-ground communication under the same speed conditions.
