Catalytic reduction systems of 2-furancarboxylic acid(FCA)and 2,5-furandicarboxylic acid(FDCA)with H 2 without reduction of the carboxyl groups are reviewed.FCA and FDCA are produced from furfural and 5-hydroxymethylf...Catalytic reduction systems of 2-furancarboxylic acid(FCA)and 2,5-furandicarboxylic acid(FDCA)with H 2 without reduction of the carboxyl groups are reviewed.FCA and FDCA are produced from furfural and 5-hydroxymethylfurfural which are important platform chemicals in biomass conversions.Furan ring hydrogenation to tetrahydrofuran-2-carboxylic acid(THFCA)and tetrahydrofuran-2,5-dicarboxylic acid(THFDCA)easily proceeds over Pd catalysts.Hydrogenolysis of one C–O bond in the furan ring produces 5-hydroxyvaleric acid(5-HVA)and 2-hydroxyadipic acid.2-Hydroxyvaleric acid is not produced in the reported systems.5-HVA can be produced as the lactone form(δ-valerolactone;DVL)or as the esters depending on the solvent.These reactions proceed over Pt catalysts with good yields(~70%)at optimized conditions.Hydrogenolysis of two C–O bonds in the furan ring produces valeric acid and adipic acid,the latter of which is a very important chemical in industry and its production from biomass is of high importance.Adipic acid from FDCA can be produced directly over Pt-MoO_(x) catalyst,indirectly via hydrogenation and hydrodeoxygenation as one-pot reaction using the combination of Pt and acid catalysts such as Pt/niobium oxide,or indirectly via two-step reaction composed of hydrogenation catalyzed by Pd and hydrodeoxygenation catalyzed by iodide ion in acidic conditions.Only the two-step method can give good yield of adipic acid at present.展开更多
A novel phenanthro[2,3-b]furan 1,named(3-hydroxy-9-(4′-hydroxy-3′-methoxypheny1)-11-methoxy-5,6,9,10-tetrahydro- phenanthro[2,3-b]furan-10-yl)methyl acetate,and two known phenolic compounds were isolated from the tu...A novel phenanthro[2,3-b]furan 1,named(3-hydroxy-9-(4′-hydroxy-3′-methoxypheny1)-11-methoxy-5,6,9,10-tetrahydro- phenanthro[2,3-b]furan-10-yl)methyl acetate,and two known phenolic compounds were isolated from the tubers of Pleione bulbocodioides(Franch.)Rolfe.Their structures were elucidated by spectroscopic methods.展开更多
基于高效液相色谱法建立了同时定量分析芒草60Coγ辐照降解副产物(包括酚类、呋喃类和有机酸等9种)的方法。结果表明,采用C18色谱柱,柱温25℃,以乙腈–0.01 mol(NH4)2HPO4(用磷酸调节p H至2.7)为流动相,梯度洗脱,流速为0.8 m L/min,多...基于高效液相色谱法建立了同时定量分析芒草60Coγ辐照降解副产物(包括酚类、呋喃类和有机酸等9种)的方法。结果表明,采用C18色谱柱,柱温25℃,以乙腈–0.01 mol(NH4)2HPO4(用磷酸调节p H至2.7)为流动相,梯度洗脱,流速为0.8 m L/min,多波长紫外检测,可实现对目标化合物的有效分离和测定,相对标准偏差为1.5%~2.3%,最低检出限为0.10~0.89 mg/L。在该条件下对经1 200 k Gy 60Coγ辐照处理的芒草水提液进行检测,检测出水提液中目标化合物对羟基苯甲酸、香草酸、丁香酸、4–羟基苯甲醛、香草醛、对香豆酸、糠醛、甲酸、乙酸的质量浓度分别为17.78、12.43、3.26、15.40、10.18、16.42、2.52、102.29、86.24 mg/L。展开更多
基金This work was financially supported by New Energy and Industrial Technology Development Organization(NEDO)under the program of Extensive Support for Young Promising Researchers.
文摘Catalytic reduction systems of 2-furancarboxylic acid(FCA)and 2,5-furandicarboxylic acid(FDCA)with H 2 without reduction of the carboxyl groups are reviewed.FCA and FDCA are produced from furfural and 5-hydroxymethylfurfural which are important platform chemicals in biomass conversions.Furan ring hydrogenation to tetrahydrofuran-2-carboxylic acid(THFCA)and tetrahydrofuran-2,5-dicarboxylic acid(THFDCA)easily proceeds over Pd catalysts.Hydrogenolysis of one C–O bond in the furan ring produces 5-hydroxyvaleric acid(5-HVA)and 2-hydroxyadipic acid.2-Hydroxyvaleric acid is not produced in the reported systems.5-HVA can be produced as the lactone form(δ-valerolactone;DVL)or as the esters depending on the solvent.These reactions proceed over Pt catalysts with good yields(~70%)at optimized conditions.Hydrogenolysis of two C–O bonds in the furan ring produces valeric acid and adipic acid,the latter of which is a very important chemical in industry and its production from biomass is of high importance.Adipic acid from FDCA can be produced directly over Pt-MoO_(x) catalyst,indirectly via hydrogenation and hydrodeoxygenation as one-pot reaction using the combination of Pt and acid catalysts such as Pt/niobium oxide,or indirectly via two-step reaction composed of hydrogenation catalyzed by Pd and hydrodeoxygenation catalyzed by iodide ion in acidic conditions.Only the two-step method can give good yield of adipic acid at present.
文摘A novel phenanthro[2,3-b]furan 1,named(3-hydroxy-9-(4′-hydroxy-3′-methoxypheny1)-11-methoxy-5,6,9,10-tetrahydro- phenanthro[2,3-b]furan-10-yl)methyl acetate,and two known phenolic compounds were isolated from the tubers of Pleione bulbocodioides(Franch.)Rolfe.Their structures were elucidated by spectroscopic methods.
