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气相色-质联用法测定食品中腐霉利残留量 被引量:17
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作者 卢晓宇 陈跃 +2 位作者 王金花 杜振霞 徐超一 《北京化工大学学报(自然科学版)》 EI CAS CSCD 北大核心 2008年第3期35-38,共4页
建立了气相色谱-质谱法测定食品中腐霉利的快速分析方法。样品用乙腈提取,通过石墨化碳固相萃取柱净化,经DB-5 ms气相色谱柱分离,正电子电离(EI^+)、选择离子监测模式(SIM)为定量离子和定性离子进行MS测定。结果表明,腐霉利添加水... 建立了气相色谱-质谱法测定食品中腐霉利的快速分析方法。样品用乙腈提取,通过石墨化碳固相萃取柱净化,经DB-5 ms气相色谱柱分离,正电子电离(EI^+)、选择离子监测模式(SIM)为定量离子和定性离子进行MS测定。结果表明,腐霉利添加水平为0.010、0.020和0.040 mg/kg时,回收率为102.8%-111.3%,相对标准偏差小于10%,最低检出限为0.005 mg/kg。本方法具有很高的灵敏度和准确度,能够满足食品中腐霉利残留量的快速、高灵敏检测分析。 展开更多
关键词 腐霉利 气相色谱-质谱联用 农药残留 食品安全
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Chemical composition and antimicrobial activity of the essential oil of Cacalia tangutica (Maxim.) Hand.-Mazz
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作者 Yang YANG Shunying ZHU +4 位作者 Xiaoqiang CAI Lifei TANG Deqing LIU Jinghua HUANG Guolin ZOU 《Frontiers in Biology》 CSCD 2008年第4期402-407,共6页
Essential oil of the subterranean part of Cacalia tangutica(Maxim.)Hand.-Mazz was analyzed by gas chromatography(GC)-mass spectrum(MS)technique in two different capillary columns of different polarities.Thirty-one com... Essential oil of the subterranean part of Cacalia tangutica(Maxim.)Hand.-Mazz was analyzed by gas chromatography(GC)-mass spectrum(MS)technique in two different capillary columns of different polarities.Thirty-one components were identified in the oil and the main compounds were a-zingiberene(13.49%),germacrene D(10.76%),α-pinene(8.54%),caryophyllene(Z-)(6.36%),linalool(6.16%),β-myrcene(4.89%),β-ocimene(Z-)(4.40%)and ocimenone(Z-)(3.58%).The antimicrobial activity of the oil was evaluated against 2 fungi and 12 bacteria including 6 clinically isolated strains using the agar disc diffusion and broth microdilution methods.The results show that the oil presented a broad antimicrobial spectrum and had better antimicrobial activity against yeast and gram-positive bacteria.The minimum inhibitory concentration values were 0.16–5.00 g/L and minimum bactericidal concentration values were 0.16–5.00 g/L. 展开更多
关键词 Cacalia tangutica antimicrobial activity essential oil gas chromatography(gc)-mass spectrum(MS)
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