Experimental investigation on coal pore-fracture variation and fractal characteristics synergistically affected by solvents for improving clean gas extraction

Chemical solvents instead of pure water being as hydraulic fracturing fluid could effectively increase permeability and improve clean methane extraction efficiency.However,pore-fracture variation features of lean coal synergistically affected by solvents have not been fully understood.Ultrasonic testing,nuclear magnetic resonance analysis,liquid phase mass spectrometry was adopted to comprehensively analyze pore-fracture change characteristics of lean coal treated by combined solvent(NMP and CS_(2)).Meanwhile,quantitative characterization of above changing properties was conducted using geometric fractal theory.Relationship model between permeability,fractal dimension and porosity were established.Results indicate that the end face fractures of coal are well developed after CS2and combined solvent treatments,of which,end face box-counting fractal dimensions range from 1.1227 to 1.4767.Maximum decreases in ultrasonic longitudinal wave velocity of coal affected by NMP,CS_(2)and combined solvent are 2.700%,20.521%,22.454%,respectively.Solvent treatments could lead to increasing amount of both mesopores and macropores.Decrease ratio of fractal dimension Dsis 0.259%–2.159%,while permeability increases ratio of NMR ranges from 0.1904 to 6.4486.Meanwhile,combined solvent could dissolve coal polar and non-polar small molecules and expand flow space.Results could provide reference for solvent selection and parameter optimization of permeability-enhancement technology.

Nonequilibrium Atmospheric Pressure Ar/O_2 Plasma Jet:Properties and Application to Surface Cleaning

In this study an atmospheric pressure Ar/O_2 plasma jet is generated to study the effects of applied voltage and gas flux rate to the behavior of discharge and the metal surface cleaning.The increase in applied voltage leads to increases of the root mean square（rms） current,the input power and the gas temperature.Furthermore,the optical emission spectra show that the emission intensities of metastable argon and atomic oxygen increase with increasing applied voltage.However,the increase in gas flux rate leads to a reduction of the rms current,the input power and the gas temperature.Furthermore,the emission intensities of metastable argon and atomic oxygen decrease when gas flux rate increases.Contact angles are measured to estimate the cleaning performance,and the results show that the increase of applied voltage can improve the cleaning performance.Nevertheless,the increase of gas flux rate cannot improve the cleaning performance.Contact angles are compared for different input powers and gas flux rates to search for a better understanding of the major mechanism for surface cleaning by plasma jets.

Analysis of China＇s Oil and Gas Policies in 2016

Guided by President Xi Jinping's key speech about energy revolution— "Four Revolutions and One Cooperation"-the Chinese oil and gas industry continued to accelerate its pace of reform in 2016.China has deepened its supply-side structural reforms,prevented and resolved the problem of excess production capacity,increased the effective supply of clean energy such as natural gas,and formed an energy innovation system.It has pushed forward the reform of pricing mechanisms with significant adjustments in the pricing mechanisms of oil products,pipeline transportation,gas storage and gas used for fertilizer production.It has also accelerated market access reform and encouraged various investors to enter into the fields of exploration & production,pipeline transportation and crude oil imports.China has sped up the legislative process of environmental protection to promote green and low-carbon development.It has accelerated oil & gas industry institutional reform,with some provinces initiating the pilot reform of oil and gas.

A Novel Approach to Reduce the Environmental Footprint of Maritime Shipping

Maritime shipping is a strategic sector with a strong international vocation and management.The need to define regulations valid for many different countries without generating disparities of treatment slowed down the formulation of environmental regulations,especially for atmospheric emissions.In particular,regulations pertaining to the reduction of sulphur compounds allowed two distinct approaches:the use of low-sulphur fuels or exhaust gas cleaning systems,the so-called Scrubbers.The actual implementation of these solutions presents specific concerns either related to the toxicity of atmospheric by-products and to the fuel cost or to the generation of polluting washwaters that may need treatment before discharge.In this paper we analyzed the potential environmental benefit deriving from the use of a distillate fuel,not compliant with current IMO Sulphur Regulations,together with a Scrubber.The pilot-scale experimental results indicated that a limited amount of water and/or scrubber volume is needed to reduce sulphur emissions below regulations on maritime shipping,especially with the addition of NaOH reaching a water-saving between 25%-33%compared to the use of pure seawater.Experiments indicated that scrubber washwater PAHs emissions are within the available water quality standards indicated by EU and USA guidelines.A bottom-up analysis on heavy metals concentration shed light on the prominent role of metal-parts corrosion on the washwater emissions.Taking into account for corrosion phenomena,the actual heavy metals concentration in the washwater deriving from scrubbing was normally below the water quality standards.

Preparation of La_(0.9)K_ (0.1)CoO_3 Perovskite Composite Oxide

Two methods for preparing La0.9K0.1CoO3 perovskite composite oxides.traditional solid state reaction method and sol-gel method.were compared.The characteristics of the powders,such as purity.particle diameter,BET surface area,pore diameter,were inrestigated by using TG-DTA,XRD,SEM and BET methods.The experimental results shou that La0.9K0.1CoO3 perorskite composite oxide can be obtained by using the two methods.The purity of La0.9K0.1CoO3 powders can be increased by raising the calcining temperature while the particle diameter increased and BET surface area decreased.At the same calcining temperature,the properties of the La0.9K0.1CoO3 powders synthesized by the sol-gel method are superior to those synthesized by the solid state reaction method.such as purer phase,smaller particle diameter,which can be used as a satisfactory catalyst in diesel waste gas cleaning.

Removal of NO_x and Diesel Soot Particulates Catalyzed byPerovskite-type Oxide La_(0.9)K_(0.1)CoO_3

The catalytic performance of perovskite composite oxide catalyst La0.9 K0.1 CoO3 coated on catalyst supports by traditional solid state reaction method and sol-gel method were investigated by a series of experiments. The restdt shows that the catalytic performance of the La0.9 K0.1 CoO3 perovskite composite oxide catalyst synthesized by sol-gel method is superior to that synthesized by solid state reaction method, having lower ignition temperature of the diesel soot particulates, lower start temperature of NOx treatment, and lower concentration of byproduct CO.

Mechanism Research of Hg^0 Oxidation by Pulse Corona Induced Plasma Chemical Process

The oxidation of Hg^0 by Pulse Corona Induced Plasma Chemical Process （PPCP） was investigated through changing discharge voltage, pulse frequency and gas compositions. Experimental results indicate that active radicals including O, O3 and OH can contribute to the oxidation of elemental mercury. 10 kV is the onset voltage, and the higher voltage the better removal efficiency. While with the increase of pulse frequency, the Hg^0 concentration falls rapidly at first but then rises rapidly. The best oxidation condition is at 12 kV and 600-800 PPS. Adding O2 can significantly promote oxidation. With NO and SO2 existed, there is an inhibition of mercury oxidation, and NO has a greater influence. Addition of HCl can promote oxidation slightly but affect the initial concentration of mercury significantly. Little moisture content can promote oxidation, while too much H2O can not only resist the oxidation, but also affect the initial concentration of mercury. The mercury oxidation rate can increase to 97.95% at 12 kV/800 PPS with the system of 10% 02/3% H2O/50 ppm HCI. However, mercury oxidation efficiency can reduce down to 20% with 100 ppm NO added.

Clean Coal Technology and Market in China

This paper briefs the current clean production and consumption levels of coal in China and the pollution harmbrought to the atmospheric environment, present status and orientation of clean coal technology development in Chinacoal industry, progress and perspective of clean coal power generation technology in China, as well as application andmarket of flue gas desulphurization technology in coal-fired power plants.[

Gas separation using porous cement membrane

Gas separation is a key issue in various industrial fields. Hydrogen has the potential for application in clean fuel technologies. Therefore, the separation and purification of hydrogen is an important research subject. CO2 capture and storage have important roles in ＂green chemistry＂. As an effective clean technology, gas separation using inorganic membranes has attracted much attention in the last several decades. Membrane processes have many applications in the field of gas separation. Cement is one type of inorganic material, with the advantages of a lower cost and a longer lifespan. An experimental setup has been created and improved to measure twenty different cement membranes. The purpose of this work was to investigate the influence of gas molecule properties on the material transport and to explore the influence of operating conditions and membrane composition on separation efficiency. The influences of the above parameters are determined, the best conditions and membrane type are found, it is shown that cementitious material has the ability to separate gas mixtures, and the gas transport mechanism is studied.

Dynamic flowsheet simulation of re-entrainment from particle layers formed inside electrostatic precipitators

Electrostatic precipitators clean away the particulate matter of exhaust gases in manifold industrial processes.Parameter studies of particle separation in the size range of several 100 nm to 25μm is of particular interest for the prediction of precipitation efficiencies and emissions.Models typically cover the transport of particles towards walls of the precipitator.However,no model yet covers the possible re-entrainment of particles from layers formed at the walls back into the gas flow.This study presents the implementation of a new time-resolving model for electrostatic precipitation utilizing a re-entrainment model.Experimental data support the results of modelling.The model uses a statistical approach based on properties of the particulate layer forming at the precipitator walls.The model is used for the analysis of the redispersion of particles in a laboratory-scale electrostatic precipitator(Sander,Gawor,&Fritsching,2018).Results show reduced precipitation efficiencies for particles larger than 5μm as particles have higher kinetic impact energies and lower bounding energy at the layer surface.Time dynamics reveal a steady-state behavior of the separation for CaCO3(limestone,trademark"Ulmer WeissR")while Al2O3(trademark"Pural NFR")precipitation is affected by layer buildup at the walls increasing over several minutes.

HEAVY METAL PARTITIONING IN A NUCLEAR WASTE TREATMENT PLANT

The fate of different trace elements and radio nuclides in the new ZWILAG nuclear waste treatment plant （Switzerland） has been modelled, in order to predict and check the transport behaviour of the volatile species and their distribution in the plant. Calculations show that for active waste from medicine, industry, research （MIR waste） only Zn and Cs have stable gaseous species at 1200℃. The investigations confirm the efficiency of the examined flue gas cleaning system.