Gas expansion caused by significant exhumation in the Sulige gas field in the Ordos Basin since Late Cretaceous and its effects on hydrocarbon accumulation have been investigated systematically based on comprehensive ...Gas expansion caused by significant exhumation in the Sulige gas field in the Ordos Basin since Late Cretaceous and its effects on hydrocarbon accumulation have been investigated systematically based on comprehensive analysis of geochemical,fluid inclusion and production data.The results indicate that gas volume expansion since the Late Cretaceous was the driving force for adjustment and secondary charging of tight sandstone gas reservoirs in the Sulige gas field of the Ordos Basin.The gas retained in the source rocks expanded in volume,resulting in gas re-expulsion,migration and secondary charging into reservoirs,while the gas volume expansion in the tight reservoirs caused the increase of gas saturation,gas-bearing area and gas column height,which worked together to increase the gas content of the reservoir and bring about large-scale gas accumulation events.The Sulige gas field had experienced a two-stage accumulation process,burial before the end of Early Cretaceous and uplifting since the Late Cretaceous.In the burial stage,natural gas was driven by hydrocarbon generation overpressure to migrate and accumulate,while in the uplifting stage,the gas volume expansion drove internal adjustment inside gas reservoirs and secondary charging to form new reservoirs.On the whole,the gas reservoir adjustment and secondary charging during uplifting stage is more significant in the eastern gas field than that in the west,which is favorable for forming gas-rich area.展开更多
An OH radical measurement instrument based on Fluorescence Assay by Gas Expansion(FAGE)has been developed in our laboratory.Ambient air is introduced into a low-pressure fluorescence cell through a pinhole aperture ...An OH radical measurement instrument based on Fluorescence Assay by Gas Expansion(FAGE)has been developed in our laboratory.Ambient air is introduced into a low-pressure fluorescence cell through a pinhole aperture and irradiated by a dye laser at a high repetition rate of 8.5 k Hz.The OH radical is both excited and detected at 308 nm using A-X(0,0)band.To satisfy the high efficiency needs of fluorescence collection and detection,a 4-lens optical system and a self-designed gated photomultiplier(PMT)is used,and gating is actualized by switching the voltage applied on the PMT dynodes.A micro channel photomultiplier(MCP)is also prepared for fluorescence detection.Then the weak signal is accumulated by a photon counter in a specific timing.The OH radical excitation spectrum range in the wavelength of 307.82–308.2 nm is detected and the excited line for OH detection is determined to be Q1(2)line.The calibration of the FAGE system is researched by using simultaneous photolysis of H2O and O2.The minimum detection limit of the instrument using gated PMT is determined to be 9.4×10~5molecules/cm^3,and the sensitivity is 9.5×10^(-7)cps/(OH·cm^(-3)),with a signal-to-noise ratio of 2 and an integration time of 60 sec,while OH detection limit and the detection sensitivity using MCP is calculated to be 1.6×10~5molecules/cm^3and 2.3×10^(-6)cps/(OH·cm^(-3)).The laboratory OH radical measurement is carried out and results show that the proposed system can be used for atmospheric OH radical measurement.展开更多
By analyzing the gas expansion process from the upstream chamber via an orifice and a very rapid-opening ultra-high vacuum(UHV)gate valve to downstream one,the standard pressure analytical model basedon the dvnamic va...By analyzing the gas expansion process from the upstream chamber via an orifice and a very rapid-opening ultra-high vacuum(UHV)gate valve to downstream one,the standard pressure analytical model basedon the dvnamic vacuum calibration apparatus in millisecond range developed by Lanzhou Institute of Physics(LIP)is deduced theoretically and corrected by real gas characteristics and temperature changes.According to the Kuudsen criterion,there is no free molecular fow regime in the area in front of the orifice during the gas expansion,so the chocked fow approximation is adopted to reduce the difficulty of numerical computation Under this anproxiuatiou and the full opening of the rapid valve,the standard pressure expression is calculated theoretically,and the upstream chamber pressure and temperature changes are obtained by numerical simulation during the gas expansion from 100 kPa to 10kPa.Also,experiments are performed using capacitance diaphragmgauges(model CDG045Dhs),The uncertainties between the measured pressure and the simulated and theoretical ones are 10%and 4.65%,respectively,which indicates that the apparatus can generate predictable pressure changes in the millisecond rauge and the conceptual model can better approximate the calibration results.Einally,the orifice conductance,and the correction factors of real gas characteristics and temperature change to the standard pressure are calculated accordins to the simulation results:the corrected staudard pressure expression is obtained.展开更多
The technology of pressure relief gas drainage is one of the most effective and economic for preventing gas emissions in underground mines.Based on current understanding of strata breakage and fracture development in ...The technology of pressure relief gas drainage is one of the most effective and economic for preventing gas emissions in underground mines.Based on current understanding of strata breakage and fracture development in overlying strata,the current study divides the overlying strata into the following three longitudinal zones in terms of the state of gas flow:a turbulent channel zone,a transitional circulation channel zone and a seepage channel zone.According to the key strata discrimination theory of controlling the overlying strata,the calculation method establishes that the step-type expansion of the mining gas channel corresponds to the advancing distance of working face,and this research also confrms the expanding rule that the mining gas channel in overlying strata follows the advancing distance of mining working face.Based on the geological conditions of Xinjing Coal Mine of Yangquan,this paper researches the expanding rule of mining gas channel as well as the control action of the channel acting on the pressure relief flow under the condition of the remote protective layer,and got the distance using inversion that the step-type expanding of mining gas channel is corresponding to the advancing distance of working face,which verifes the accuracy and feasibility of theoretical calculation method proposed in this study.The research provides the theoretical basis for choosing the technology of pressure relief gas drainage and designing the parameters of construction.展开更多
A validated numerical model was established to simulate gas−liquid flow behaviors in the oxygen-enriched side-blown bath furnace.This model included the slip velocity between phases and the gas thermal expansion effec...A validated numerical model was established to simulate gas−liquid flow behaviors in the oxygen-enriched side-blown bath furnace.This model included the slip velocity between phases and the gas thermal expansion effect.Its modeling results were verified with theoretical correlations and experiments,and the nozzle-eroded states in practice were also involved in the analysis.Through comparison,it is confirmed that the thermal expansion effect influences the flow pattern significantly,which may lead to the backward motion of airflow and create a potential risk to production safety.Consequently,the influences of air injection velocity and furnace width on airflow behavior were investigated to provide operating and design guidance.It is found that the thin layer melt,which avoids high-rate oxygen airflow eroding nozzles,shrinks as the injection velocity increases,but safety can be guaranteed when the velocity ranges from 175 to 275 m/s.Moreover,the isoline patterns and heights of thin layers change slightly when the furnace width increases from 2.2 to 2.8 m,indicating that the furnace width shows a limited influence on production safety.展开更多
Coal and gas outburst is a violent disaster driven by released energy from gas desorption.The initial expansion energy of released gas(IEERG)is a new method to predict coal and gas outburst.In this paper,an instrument...Coal and gas outburst is a violent disaster driven by released energy from gas desorption.The initial expansion energy of released gas(IEERG)is a new method to predict coal and gas outburst.In this paper,an instrument for IEERG measurement was developed.Compared with previous setups,the new one which is equipped with three convergent nozzles and quick-release mechanism gets improved in data acquisition and gas sealing and releasing performance.To comprehensively know the effect of gas pressure,particle size,and nozzle area on IEERG,a series of experiments were carried out with this new setup.The variable control test results indicated that the gas pressure-IEERG curves remain the linear trend and the particle size-IEERG curves maintain the negative exponential trend for nozzle areas at 1.13,2.26,and3.39 mm2,respectively.The increase in nozzle area leads to deceases in value of IEERG and absolute value of slope of fitting curves in each test.In addition,the orthogonal experiment showed that the influence of gas pressure,nozzle area,and particle size on IEERG decreases in turn.Only gas pressure had a marked impact on IEERG.This work offers great importance in improving the accuracy of prediction of coal and gas outburst.展开更多
In this work,a flowing material balance equation(FMBE) is established for under saturated coalbed methane(CBM) reservoirs,which considers immobile free gas expansion effect at the dewatering stage.Based on the establi...In this work,a flowing material balance equation(FMBE) is established for under saturated coalbed methane(CBM) reservoirs,which considers immobile free gas expansion effect at the dewatering stage.Based on the established FMBE,five straight-line methods are proposed to determine the control area,initial water reserve,initial free gas reserve,initial adsorbed gas reserve,original gas in place,as well as permeability at the same time.Subsequently,the proposed FMBE methods for undersaturated CBM reservoirs are validated against a reservoir simulation software with and without considering free gas expansion.Finally,the proposed methods are applied in a field case when considering free gas expansion effect.Validation cases show that the straight-line relationships for the proposed five FMBE methods are excellent,and good agreements are obtained among the actual reserves and permeabilities and those evaluated by the proposed five FMBE methods,indicating the proposed five FMBE methods are effective and rational for CBM reservoirs.Results show that a small amount of free gas will result in a great deviation in reserve evaluation;hence,the immobile free gas expansion effect should be considered when establishing the material balance equation of undersaturated CBM reservoirs at the dewatering stage.展开更多
基金Supported by the National Natural Science Foundation of China(41502132)China National Demonstration Project(2016ZX05050).
文摘Gas expansion caused by significant exhumation in the Sulige gas field in the Ordos Basin since Late Cretaceous and its effects on hydrocarbon accumulation have been investigated systematically based on comprehensive analysis of geochemical,fluid inclusion and production data.The results indicate that gas volume expansion since the Late Cretaceous was the driving force for adjustment and secondary charging of tight sandstone gas reservoirs in the Sulige gas field of the Ordos Basin.The gas retained in the source rocks expanded in volume,resulting in gas re-expulsion,migration and secondary charging into reservoirs,while the gas volume expansion in the tight reservoirs caused the increase of gas saturation,gas-bearing area and gas column height,which worked together to increase the gas content of the reservoir and bring about large-scale gas accumulation events.The Sulige gas field had experienced a two-stage accumulation process,burial before the end of Early Cretaceous and uplifting since the Late Cretaceous.In the burial stage,natural gas was driven by hydrocarbon generation overpressure to migrate and accumulate,while in the uplifting stage,the gas volume expansion drove internal adjustment inside gas reservoirs and secondary charging to form new reservoirs.On the whole,the gas reservoir adjustment and secondary charging during uplifting stage is more significant in the eastern gas field than that in the west,which is favorable for forming gas-rich area.
基金supported by the Strategic Priority Research Program of the Chinese Academy of Sciences (Grant No. XDB05040200)the National Natural Science Foundation of China (Grant Nos. 91644107, 61575206, 41305139, 61108031)
文摘An OH radical measurement instrument based on Fluorescence Assay by Gas Expansion(FAGE)has been developed in our laboratory.Ambient air is introduced into a low-pressure fluorescence cell through a pinhole aperture and irradiated by a dye laser at a high repetition rate of 8.5 k Hz.The OH radical is both excited and detected at 308 nm using A-X(0,0)band.To satisfy the high efficiency needs of fluorescence collection and detection,a 4-lens optical system and a self-designed gated photomultiplier(PMT)is used,and gating is actualized by switching the voltage applied on the PMT dynodes.A micro channel photomultiplier(MCP)is also prepared for fluorescence detection.Then the weak signal is accumulated by a photon counter in a specific timing.The OH radical excitation spectrum range in the wavelength of 307.82–308.2 nm is detected and the excited line for OH detection is determined to be Q1(2)line.The calibration of the FAGE system is researched by using simultaneous photolysis of H2O and O2.The minimum detection limit of the instrument using gated PMT is determined to be 9.4×10~5molecules/cm^3,and the sensitivity is 9.5×10^(-7)cps/(OH·cm^(-3)),with a signal-to-noise ratio of 2 and an integration time of 60 sec,while OH detection limit and the detection sensitivity using MCP is calculated to be 1.6×10~5molecules/cm^3and 2.3×10^(-6)cps/(OH·cm^(-3)).The laboratory OH radical measurement is carried out and results show that the proposed system can be used for atmospheric OH radical measurement.
基金the National Natural Science Foundation of China(No.61501212)。
文摘By analyzing the gas expansion process from the upstream chamber via an orifice and a very rapid-opening ultra-high vacuum(UHV)gate valve to downstream one,the standard pressure analytical model basedon the dvnamic vacuum calibration apparatus in millisecond range developed by Lanzhou Institute of Physics(LIP)is deduced theoretically and corrected by real gas characteristics and temperature changes.According to the Kuudsen criterion,there is no free molecular fow regime in the area in front of the orifice during the gas expansion,so the chocked fow approximation is adopted to reduce the difficulty of numerical computation Under this anproxiuatiou and the full opening of the rapid valve,the standard pressure expression is calculated theoretically,and the upstream chamber pressure and temperature changes are obtained by numerical simulation during the gas expansion from 100 kPa to 10kPa.Also,experiments are performed using capacitance diaphragmgauges(model CDG045Dhs),The uncertainties between the measured pressure and the simulated and theoretical ones are 10%and 4.65%,respectively,which indicates that the apparatus can generate predictable pressure changes in the millisecond rauge and the conceptual model can better approximate the calibration results.Einally,the orifice conductance,and the correction factors of real gas characteristics and temperature change to the standard pressure are calculated accordins to the simulation results:the corrected staudard pressure expression is obtained.
基金the National Basic Research Programs of China (No. 2011CB201204)the National Natural Science Foundation of China (Nos. 51074160)+1 种基金the Fundamental Research Funds for the Central Universities (No. 2010QNA03)Project Funded by the Priority Academic Program Development of Jiangsu Higher Education institutions for their support for this project
文摘The technology of pressure relief gas drainage is one of the most effective and economic for preventing gas emissions in underground mines.Based on current understanding of strata breakage and fracture development in overlying strata,the current study divides the overlying strata into the following three longitudinal zones in terms of the state of gas flow:a turbulent channel zone,a transitional circulation channel zone and a seepage channel zone.According to the key strata discrimination theory of controlling the overlying strata,the calculation method establishes that the step-type expansion of the mining gas channel corresponds to the advancing distance of working face,and this research also confrms the expanding rule that the mining gas channel in overlying strata follows the advancing distance of mining working face.Based on the geological conditions of Xinjing Coal Mine of Yangquan,this paper researches the expanding rule of mining gas channel as well as the control action of the channel acting on the pressure relief flow under the condition of the remote protective layer,and got the distance using inversion that the step-type expanding of mining gas channel is corresponding to the advancing distance of working face,which verifes the accuracy and feasibility of theoretical calculation method proposed in this study.The research provides the theoretical basis for choosing the technology of pressure relief gas drainage and designing the parameters of construction.
基金the support from the National Key R&D Program of China(No.2018YFC1901606).
文摘A validated numerical model was established to simulate gas−liquid flow behaviors in the oxygen-enriched side-blown bath furnace.This model included the slip velocity between phases and the gas thermal expansion effect.Its modeling results were verified with theoretical correlations and experiments,and the nozzle-eroded states in practice were also involved in the analysis.Through comparison,it is confirmed that the thermal expansion effect influences the flow pattern significantly,which may lead to the backward motion of airflow and create a potential risk to production safety.Consequently,the influences of air injection velocity and furnace width on airflow behavior were investigated to provide operating and design guidance.It is found that the thin layer melt,which avoids high-rate oxygen airflow eroding nozzles,shrinks as the injection velocity increases,but safety can be guaranteed when the velocity ranges from 175 to 275 m/s.Moreover,the isoline patterns and heights of thin layers change slightly when the furnace width increases from 2.2 to 2.8 m,indicating that the furnace width shows a limited influence on production safety.
基金supported by the National Key Scientific Instruments and Equipment Development Projects of China(No.51427804)the National Science Foundation of Shandong Province(No.ZR2017MEE023)。
文摘Coal and gas outburst is a violent disaster driven by released energy from gas desorption.The initial expansion energy of released gas(IEERG)is a new method to predict coal and gas outburst.In this paper,an instrument for IEERG measurement was developed.Compared with previous setups,the new one which is equipped with three convergent nozzles and quick-release mechanism gets improved in data acquisition and gas sealing and releasing performance.To comprehensively know the effect of gas pressure,particle size,and nozzle area on IEERG,a series of experiments were carried out with this new setup.The variable control test results indicated that the gas pressure-IEERG curves remain the linear trend and the particle size-IEERG curves maintain the negative exponential trend for nozzle areas at 1.13,2.26,and3.39 mm2,respectively.The increase in nozzle area leads to deceases in value of IEERG and absolute value of slope of fitting curves in each test.In addition,the orthogonal experiment showed that the influence of gas pressure,nozzle area,and particle size on IEERG decreases in turn.Only gas pressure had a marked impact on IEERG.This work offers great importance in improving the accuracy of prediction of coal and gas outburst.
基金supported by the National Science and Technology Major Projects of China (No. 2016ZX05042 and No. 2017ZX05039)the National Natural Science Foundation Projects of China (No. 51504269 and No. 51490654)Science Foundation of China University of Petroleum, Beijing (No.C201605) to support part of this work。
文摘In this work,a flowing material balance equation(FMBE) is established for under saturated coalbed methane(CBM) reservoirs,which considers immobile free gas expansion effect at the dewatering stage.Based on the established FMBE,five straight-line methods are proposed to determine the control area,initial water reserve,initial free gas reserve,initial adsorbed gas reserve,original gas in place,as well as permeability at the same time.Subsequently,the proposed FMBE methods for undersaturated CBM reservoirs are validated against a reservoir simulation software with and without considering free gas expansion.Finally,the proposed methods are applied in a field case when considering free gas expansion effect.Validation cases show that the straight-line relationships for the proposed five FMBE methods are excellent,and good agreements are obtained among the actual reserves and permeabilities and those evaluated by the proposed five FMBE methods,indicating the proposed five FMBE methods are effective and rational for CBM reservoirs.Results show that a small amount of free gas will result in a great deviation in reserve evaluation;hence,the immobile free gas expansion effect should be considered when establishing the material balance equation of undersaturated CBM reservoirs at the dewatering stage.