Prediction of Leakage Rates Through Sealing Connections with Nonmetallic Gaskets

在这个工作，通过非金属的垫板的煤气的漏的一个模型被开发以便预言封上连接的垫板的漏率。模型被垫板的二种类型的漏实验验证：压缩非石棉纤维垫板和与 tanged 金属表增强的灵活石墨垫板。在漏率公式的系数被试验性的数据的回归为垫板的每种类型获得。模型被另外的研究人员也对试验性的漏数据验证并且出现生产精确断言。而且，模型在服务被用于一个固定 flanged 连接以便估计连接的紧密。

Optimization of sensor deployment sequences for hazardous gas leakage monitoring and source term estimation

Nowadays, chemical safety has attracted considerable attention, and chemical gas leakage monitoring and source term estimation(STE) have become hot spots. However, few studies have focused on sensor layouts in scenarios with multiple potential leakage sources and wind conditions, and studies on the risk information(RI) detection and prioritization order of sensors have not been performed. In this work, the monitoring area of a chemical factory is divided into multiple rectangles with a uniform mesh. The RI value of each grid node is calculated on the basis of the occurrence probability and normalized concentrations of each leakage scenario. A high RI value indicates that a sensor at a grid node has a high chance of detecting gas concentrations in different leakage scenarios. This situation is beneficial for leakage monitoring and STE. The methods of similarity redundancy detection and the maximization of sensor RI detection are applied to determine the sequence of sensor locations. This study reveals that the RI detection of the optimal sensor layout with eight sensors exceeds that of the typical layout with 12 sensors. In addition, STE with the optimized placement sequence of the sensor layout is numerically simulated. The statistical results of each scenario with various numbers of sensors reveal that STE is affected by sensor number and scenarios(leakage locations and winds). In most scenarios, appropriate STE results can be retained under the optimal sensor layout even with four sensors. Eight or more sensors are advised to improve the performance of STE in all scenarios. Moreover, the reliability of the STE results in each scenario can be known in advance with a specific number of sensors. Such information thus provides a reference for emergency rescue.

Growth rate of CO_(2) hydrate film on water-oil and water-gaseous CO_(2) interface

It is known that injection of carbon dioxide into the petroleum reservoir(CO_(2) flooding) is one of the effective methods for enhanced oil recovery. CO_(2) flooding may be complicated by formation of CO_(2) hydrate plugs. It makes topical investigation of CO_(2) hydrate formation in the system gaseous CO_(2)-oil-water. In this work, the growth rates of carbon dioxide hydrate films at the water-oil as well as the water-gas interface are studied in the pressure range of 2.30-3.04 MPa and at temperatures between -5.4 and 5.0℃. It is found that the growth rate for the water-oil interface is 3.5 times lower than that for the water-gas interface with carbon dioxide. It is hypothesised that the observed decrease in the growth rate is related to the mechanical resistance of the oil components adsorbed on the interface to the growth of the hydrate film. The growth rate of the film has been shown to depend on the experimental procedure,most likely due to the different initial concentrations of carbon dioxide in the aqueous solutions.

Gas-Water Production of a Continental Tight-Sandstone Gas Reservoir under Different Fracturing Conditions

A numerical model of hydraulic fracture propagation is introduced for a representative reservoir(Yuanba continental tight sandstone gas reservoir in Northeast Sichuan).Different parameters are considered,i.e.,the interlayer stress difference,the fracturing discharge rate and the fracturing fluid viscosity.The results show that these factors affect the gas and water production by influencing the fracture size.The interlayer stress difference can effectively control the fracture height.The greater the stress difference,the smaller the dimensionless reconstruction volume of the reservoir,while the flowback rate and gas production are lower.A large displacement fracturing construction increases the fracture-forming efficiency and expands the fracture size.The larger the displacement of fracturing construction,the larger the dimensionless reconstruction volume of the reservoir,and the higher the fracture-forming efficiency of fracturing fluid,the flowback rate,and the gas production.Low viscosity fracturing fluid is suitable for long fractures,while high viscosity fracturing fluid is suitable for wide fractures.With an increase in the fracturing fluid viscosity,the dimensionless reconstruction volume and flowback rate of the reservoir display a non-monotonic behavior,however,their changes are relatively small.

Microscopic experiment on efficient construction of underground gas storages converted from water-invaded gas reservoirs

Based on the microfluidic technology,a microscopic visualization model was used to simulate the gas injection process in the initial construction stage and the bottom water invasion/gas injection process in the cyclical injection-production stage of the underground gas storage(UGS)rebuilt from water-invaded gas reservoirs.Through analysis of the gas-liquid contact stabilization mechanism,flow and occurrence,the optimal control method for lifecycle efficient operation of UGS was explored.The results show that in the initial construction stage of UGS,the action of gravity should be fully utilized by regulating the gas injection rate,so as to ensure the macroscopically stable migration of the gas-liquid contact,and greatly improve the gas sweeping capacity,providing a large pore space for gas storage in the subsequent cyclical injection-production stage.In the cyclical injection-production stage of UGS,a constant gas storage and production rate leads to a low pore space utilization.Gradually increasing the gas storage and production rate,that is,transitioning from small volume to large volume,can continuously break the hydraulic equilibrium of the remaining fluid in the porous media,which then expands the pore space and flow channels.This is conducive to the expansion of UGS capacity and efficiency for purpose of peak shaving and supply guarantee.

Analysis of Maximum Liquid Carrying Capacity Based on Conventional Tubing Plunger Gas Lift

China’s unconventional gas fields have a large number of low-productivity and low-efficiency wells, many of whichare located in remote and environmentally harsh mountainous areas. To address the long-term stable productionof these gas wells, plunger-lift technology plays an important role. In order to fully understand and accurately graspthe drainage and gas production mechanisms of plunger-lift, a mechanical model of plunger-liquid column uplift inthe plunger-lift process was established, focusing on conventional plunger-lift systems and representative wellboreconfigurations in the Linxing region. The operating casing pressure of the plunger-lift process and the calculationmethod for the maximum daily fluid production rate based on the work regime with the highest fluid recovery ratewere determined. For the first time, the critical flow rate method was proposed as a constraint for the maximumliquid-carrying capacity of the plunger-lift, and liquid-carrying capacity charts for conventional plunger-lift withdifferent casing sizes were developed. The results showed that for 23/8 casing plunger-lift, with a well depth ofshallower than 808 m, the maximum drainage rate was 33 m3/d;for 27/8 casing plunger-lift, with a well depth ofshallower than 742 m, the maximum drainage rate was 50.15 m3/d;for 31/2 casing plunger-lift, with a well depthof shallower than 560 m, the maximum drainage rate was 75.14 m3/d. This research provides a foundation for thescientific selection of plunger-lift technology and serves as a decision-making reference for developing reasonableplunger-lift work regimes.

RECENT ADVANCES IN HYDRATE-BASED TECHNOLOGIES FOR NATURAL GAS STORAGE——A REVIEW

Interest in the possibility of storing and transporting natural gas in the form of clathrate hydrates has been increasing in recent years, particularly in some gas-importing and exporting countries.The technologies necessary for realizing this possibility may be classified into those relevant to the four serial processes (a) the formation of a hydrate, (b) the processing (dewatering, pelletizing, etc. ) of the formed hydrate, (c) the storage and transportation of the processed hydrate, and (d) the regasification (dissociation) of the hydrate. The technological development of any of these processes is still at an early stage. For hydrate formation, for example, various rival operations have been proposed. However,many of them have never been subjected to actual tests for practical use. More efforts are required for examining the different hydrate-formation technologies and for rating them by comparison. The general design of the processing of the formed hydrate inevitably depends on both the hydrate-formation process and the storage/transportation process, hence it has a wide variability. The major uncertainty in the storage-process design lies in the as-yet unclarified utility of the "self-preservation" effect of the naturalgas hydrates. The process design as well as the relevant cost evaluation should strongly depend on whether the hydrates are well preserved at atmospheric pressure in large-scale storage facilities. The regasification process has been studied less extensively than the former processes. The state of the art of the technological development in each of the serial processes is reviewed, placing emphasis on the hydrate formation process.

Leakage and Stiffness Characteristics of Bionic Cluster Spiral Groove Dry Gas Seal

Spiral groove dry gas seal(S?DGS), the most widely used DGS in the world, encounters the problem of high leakage rate and inferior film stability when used in high?speed machinery equipment, which could not be well solved by optimization of geometrical parameters and molded line of spiral groove. A new type of bionic cluster spiral groove DGS(CS?DGS) is proved to have superior film stability than S?DGS at the condition of high?speed and low?pressure numerically. A bionic CS?DGS is experimentally investigated and compared with common S?DGS in order to provide evidence for theoretical study. The film thickness and leakage rate of both bionic spiral groove and common spiral groove DGS are measured and compared with each other and with theoretical values under different closing force at the condition of static pressure, high?speed and low?pressure, and the film stiffness and stiffness?leakage ratio of these two face seals are derived by the relationship between closing force and film thickness at the steady state. Experimental results agree well with the theory that the leakage and stiffness of bionic CS?DGS are superior to that of common S?DGS under the condition of high?speed and low?pressure, with the decreasing amplitude of 20% to 40% and the growth amplitude of 20%, respectively. The opening performance and stiffness characteristics of bionic CS?DGS are inferior to that of common S?DGS when rotation speed equals to 0 r/min. The proposed research provides a new method to measure the axis film stiffness of DGS, and validates the superior performance of bionic CS?DGS at the condition of high?speed and low?pressure experimentally.

A study of hydrate plug formation in a subsea natural gas pipeline using a novel high-pressure flow loop

The natural gas pipeline from Platform QKI8-1 in the southwest of Bohai Bay to the onshore processing facility is a subsea wet gas pipeline exposed to high pressure and low temperature for a long distance. Blockages in the pipeline occur occasionally. To maintain the natural gas flow in the pipeline, we proposed a method for analyzing blockages and ascribed them to the hydrate formation and agglomeration. A new high-pressure flow loop was developed to investigate hydrate plug formation and hydrate particle size, using a mixture of diesel oil, water, and natural gas as experimental fluids. The influences of pressure and initial flow rate were also studied. Experimental results indicated that when the flow rate was below 850 kg/h, gas hydrates would form and then plug the pipeline, even at a low water content （10%） of a water/oil emulsion. Furthermore, some practical suggestions were made for daily management of the subsea pipeline.

Preliminary results of environmental monitoring of the natural gas hydrate production test in the South China Sea

Natural gas hydrate (NGH)is considered as one of the new clean energy sources of the 21st century with the highest potential.The environmental issues of NGH production have attracted the close attention of scientists in various countries.From May 10 to July 9,2017,the first offshore NGH production test in the South China Sea (SCS)was conducted by the China Geological Survey.In addition,environmental security has also been effectively guaranteed via a comprehensive environmental monitoring system built during the NGH production test.The monitoring system considered sea-surface atmosphere methane and carbon dioxide concentrations,dissolved methane in the sea water column,and the seafloor physical oceanography and marine chemistry environment.The whole process was monitored via multiple means, in multiple layers,in all domains,and in real time.After the production test,an environmental investigation was promptly conducted to evaluate the environmental impact of the NGH production test. The monitoring results showed that the dissolved methane concentration in seawater and the near-seabed environment characteristics after the test were consistent with the background values,indicating that the NGH production test did not cause environmental problems such as methane leakage.

Experimental Study on Preparation of Natural Gas Hydrate by Crystallization

In this paper, the saturated solution crystallization method is proposed to promote the formation of hydrate by means of the known similarities between the hydrate formation process and the crystallization process. In this method,adding the second phase crystals was used to replace the spontaneous formation of hydrate crystal nuclei to form hydrate.The effects of saturated Na_2SO_4, MgSO_4, NH_4HCO_3 and CuSO_4 solutions on the formation rates of natural gas hydrate and gas storage capacity were investigated. The results showed that the saturated solution had an influence on the hydrate formation process. Under the given experimental conditions, the saturated Na_2SO_4 solution showed a highest increase in the hydrate formation rate, and the average hydrate formation rate in its presence was 11.8 times higher than that obtained in the deionized water. Moreover, the largest formation rate of gas hydrates observed in the saturated Na_2SO_4 solution was 386 times bigger than that in the deionized water, and the gas storage capacity increased by 10 times. In addition, the average hydrate formation rate in the saturated Mg SO_4 solution was faster than that in water by 20 times. The largest formation rate of gas hydrates in the saturated MgSO_4 solution was 165 times faster than that obtained in the deionized water, and the gas storage capacity increased by 6.2 times. The saturated NH_4HCO_3 and saturated CuSO_4 solutions also influenced the formation process of hydrate. Therefore, the crystallization method of saturated solution can be used to achieve a highefficiency preparation of natural gas hydrates, which provides theoretical guidance for the storage of natural gas in the form of hydrate.

Effects of Four Types of Pre-swirls on the Leakage, Flow Field, and Fluid-Induced Force of the Rotary Straight-through Labyrinth Gas Seal

The labyrinth seal in turbomachinery is a key element that restricts leakage flow among rotor-stator clearances from high-pressure regions to low-pressure regions. The fluid-induced forces on the rotor from seals during machine operation must be accurately quantified to predict their dynamic behavior effectively. To understand the fluid-induced force characteristics of the labyrinth seal more fully, the effects of four types of pre-swirls on the leakage, flow field, and fluid-induced force of a rotary straight-through labyrinth gas seal (RSTLGS) were numerically investigated using the proposed steady computational fluid dynamics (CFD) method based on the three-dimensional models of the RSTLGS. The leakage, flow field, and fluid-induced force of the RSTLGS for six axial pre-swirl velocities, four radial preswirl angles, four circumferential positive pre-swirl angles, and four circumferential negative pre-swirl angles were computed under the same geometrical parameters and operational conditions. Mesh analysis ensures the accuracy of the present steady CFD method. The numerical results show that the four types of pre-swirls influence the leakage, flow field, and fluid-induced force of the RSTLGS. The axial pre-swirl velocity remarkably inhibits the fluid-induced force, and the circumferential positive pre-swirl angle and circumferential negative pre-swirl angle remarkably promote the fluid-induced force. The effects of the radial pre-swirl angle on the fluid-induced force are complicated, and the pressure forces and viscous forces show the maximum or minimum values at a specific radial pre-swirl angle. The pre-swirl has a negligible impact on the leakage. The four types of pre-swirls affect the leakage, flow field, and fluidinduced force of the RSTLGS to varying degrees. The pre-swirl is the influence factor affecting the leakage, flow field, and fluid-induced force of the RSTLGS. The conclusions will help to understand the fluid-induced force of labyrinth seals more fully, by providing helpful suggestions for engineering practices and a theoretical basis to analyze the fluid–structure interaction of the seal-rotor system in future research.

Leakage Rate Model of Urban Water Supply Networks Using Principal Component Regression Analysis

To analyze the factors affecting the leakage rate of water distribution system, we built a macroscopic "leakage rate–leakage factors"(LRLF) model. In this model, we consider the pipe attributes(quality, diameter,age), maintenance cost, valve replacement cost, and annual average pressure. Based on variable selection and principal component analysis results, we extracted three main principle components—the pipe attribute principal component(PAPC), operation management principal component, and water pressure principal component. Of these, we found PAPC to have the most influence. Using principal component regression, we established an LRLF model with no detectable serial correlations. The adjusted R2 and RMSE values of the model were 0.717 and 2.067, respectively.This model represents a potentially useful tool for controlling leakage rate from the macroscopic viewpoint.

Numerical study on effects of the cofferdam area in liquefied natural gas storage tank on the leakage and diffusion characteristics of natural gas

The leakage and diffusion characteristics of natural gas were investigated in the condition of the leakage of liquefied natural gas(LNG) in the storage tank.Fluent was adopted to simulate the process in a series of three-dimension unsteady state calculations.The effects of different heights of the cofferdam(1.0 m, 2.0 m and 3.0 m),wind directions,ambient temperature,leakage location,leakage volume on the diffusion process of natural gas were investigated.The diffusion characteristics of the natural gas clouds over cofferdam were found.Under windless condition,when the gas clouds met,the gas clouds rose due to the collision,which made them easier to cross the cofferdam and spread out.The higher the ambient temperature was,the higher the gas concentration around the cofferdam was,and the smaller the gas concentration difference was.When the leakage occurred,the higher coffe rdam was more beneficial to delay the outward diffusion of gas clouds.However,when the leaka ge stopped,the higher cofferdam went against the dissipation of gas clouds.Under windy condition,the time to form stable leakage flow field was faster than that of windless,and the lower cofferdam further reduced this time.Therefore,considering the effect of barrier and dissipation,it was suggested that the rational height of cofferdam should be designed in the range of 1.0 m to 2.0 m.In case of emergency,the leakage of gas should be deduced reasonably by combining the measurement of gas concentration with the rolling of gas clouds.When windless,the leakage area should be entered between the overflows of gas clouds.

CFD numerical simulation of dispersion law of indoor gas leakage based on weather conditions

The calculation model was established by k-ε turbulence stress which reflects the change of indoor gas leak's volume fraction,and the CFD software was used to numerically simulate the volume fraction of gas after the gas of continuity leakage,at the same time the changes of gas leak were studied. The results show that the process of gas leakage is different with the change of conditions of indoor and outdoor. Because of the different influencing factors,when the gas leak reaches a certain stable value,the volume fraction,velocity and the explosion of regional are different in the same state indoor. In some regions the gas will explode which meets the fire even if the mean volume fraction of the gas cannot achieve the explosion limit.

Gas leakage recognition for CO2 geological sequestration based on the time series neural network

The leakage of stored and transported CO2 is a risk for geological sequestration technology. One of the most challenging problems is to recognize and determine CO2 leakage signal in the complex atmosphere background. In this work, a time series model was proposed to forecast the atmospheric CO2 variation and the approximation error of the model was utilized to recognize the leakage. First, the fitting neural network trained with recently past CO2 data was applied to predict the daily atmospheric CO2. Further, the recurrent nonlinear autoregressive with exogenous input(NARX) model was adopted to get more accurate prediction. Compared with fitting neural network, the approximation errors of NARX have a clearer baseline, and the abnormal leakage signal can be seized more easily even in small release cases. Hence, the fitting approximation of time series prediction model is a potential excellent method to capture atmospheric abnormal signal for CO2 storage and transportation technologies.

VISUAL OBSERBATION OF HCFC141b GAS HYDRATE FORMATION/DECOMPOSITION PROCESS OUTSIDE OF A TUBE

In order to design a kind of heat exchanger suitable to the indirect-touched gas hydrate cool storage vessel, a visual observation of HCFC141b gas hydrate formation/decomposition process was presented through a self-designed small-scale visualization apparatus of gas hydrate cool storage. Based on the shooted photos and recorded temperatures, the formation/decomposition process of HCFC141b are described, some characteristics are concluded, and some suggestions of designing heat exchanger are indicated according to the specific characteristics of HCFC141b gas hydrate formation/decomposition process.

Characteristics of Leakage Pollution of Longpan Road Gas Station and Its Enlightenment

Geological penetrating radar combined with drilling and chemical analysis has been applied to investigate leakage pollution of Longpan Road gas station in Nanjing, China. The results indicate that radar images show strong reflection anomalies along the northeast to the gas station, characterized by contaminants or contaminant plumes spreading downstream and below. The drilling results confirmed the contents of monocyclic and polycyclic aromatic hydrocarbons contained in the layers of fine sands ranging from 0.60 m to 6.0 m beneath the surface mostly exceed Chinese standard severely, such as toluene and isobutylbenzene with high content at 2738 μg/kg and 64505 μg/kg, respectively. Therefore, it is considered that geological penetrating radar can be employed to investigate leakage contamination of gas stations, and remediation and administration should be conducted in the polluted soil layers and aquifers.

Rotational failure analysis of spherical-cylindrical shell pressure controllers related to gas hydrate drilling investigations

In situ pressure-preserved coring(IPP-Coring)technology is considered one of the most efficient methods for assessing resources.However,seal failure caused by the rotation of pressure controllers greatly affects the success of pressure coring.In this paper,a novel spherical-cylindrical shell pressure controller was proposed.The finite element analysis model was used to analyze the stress distribution and deformation characteristics of the pressure controller at different rotation angles.The seal failure mechanism caused by the rotation of the pressure controller was discussed.The stress deviation rate was defined to quantitatively characterize the stress concentration.Based on the test equipment designed in this laboratory,the ultimate bearing strength of the pressure controller was tested.The results show that the rotation of the valve cover causes an increase in the deformation on its lower side.Furthermore,the specific sealing pressure in the weak zone is greatly reduced by a statistically significant amount,resulting in seal failure.When the valve cover rotates 5°around the major axis,the stress deviation rate is-92.6%.To prevent rotating failure of the pressure controller,it is necessary to control the rotation angle of the valve cover within 1°around the major axis.The results of this research can help engineers reduce failure-related accidents,provide countermeasures for pressure coring,and contribute to the exploration and evaluation of deep oil and gas resources.

Simplified graphical correlation for determining flow rate in tight gas wells in the Sulige gas field

The Sulige tight gas reservoir is characterized by low-pressure, low-permeability and lowabundance. During production, gas flow rate and reservoir pressure decrease sharply; and in the shut- in period, reservoir pressure builds up slowly. Many conventional methods, such as the indicative curve method, systematic analysis method and numerical simulation, are not applicable to determining an appropriate gas flow rate. Static data and dynamic performance show permeability capacity, kh is the most sensitive factor influencing well productivity, so criteria based on kh were proposed to classify vertical wells. All gas wells were classified into 4 groups. A multi-objective fuzzy optimization method, in which dimensionless gas flow rate, period of stable production, and recovery at the end of the stable production period were selected as optimizing objectives, was established to determine the reasonable range of gas flow rate. In this method, membership functions of above-mentioned optimizing factors and their weights were given. Moreover, to simplify calculation and facilitate field use, a simplified graphical illustration （or correlation） was given for the four classes of wells. Case study illustrates the applicability of the proposed method and graphical correlation, and an increase in cumulative gas production up to 37% is achieved and the well can produce at a constant flow rate for a long time.