Influence of tectonic preservation conditions on the nanopore structure of shale reservoir:A case study of Wufeng-Longmaxi Formation shale in western Hubei area,south China

Tectonism is one of the dominant factors affecting the shale pore structure.However,the control of shale pore structure by tectonic movements is still controversial,which limits the research progress of shale gas accumulation mechanism in the complex tectonic region of southern China.In this study,34 samples were collected from two exploratory wells located in different tectonic locations.Diverse experiments,e.g.,organic geochemistry,XRD analysis,FE-SEM,low-pressure gas adsorption,and high-pressure mercury intrusion,were conducted to fully characterize the shale reservoir.The TOC,Ro,and mineral composition of the shale samples between the two wells are similar,which reflects that the shale samples of the two wells have proximate pores-generating capacity and pores-supporting capacity.However,the pore characteristics of shale samples from two wells are significantly different.Compared with the stabilized zone shale,the porosity,pore volume,and specific surface area of the deformed zone shale were reduced by 60.61%,64.85%,and 27.81%,respectively.Moreover,the macroscopic and fine pores were reduced by 54.01%and 84.95%,respectively.Fault activity and uplift denudation are not conducive to pore preservation,and the rigid basement of Huangling uplift can promote pore preservation.These three factors are important reasons for controlling the difference in pore structure between two wells shales.We established a conceptual model of shale pores evolution under different tectonic preservation conditions.This study is significant to clarify the scale of shale gas formation and enrichment in complex tectonic regions,and helps in the selection of shale sweet spots.

Geological conditions and reservoir characteristics of various shales in major shalehosted regions of China

China is home to shales of three facies:Marine shale,continental shale,and marine-continental transitional shale.Different types of shale gas are associated with significantly different formation conditions and major controlling factors.This study compared the geological characteristics of various shales and analyzed the influences of different parameters on the formation and accumulation of shale gas.In general,shales in China’s several regions exhibit high total organic carbon(TOC)contents,which lays a sound material basis for shale gas generation.Marine strata generally show high degrees of thermal evolution.In contrast,continental shales manifest low degrees of thermal evolution,necessitating focusing on areas with relatively high degrees of thermal evolution in the process of shale gas surveys for these shales.The shales of the Wufeng and Silurian formations constitute the most favorable shale gas reservoirs since they exhibit the highest porosity among the three types of shales.These shales are followed by those in the Niutitang and Longtan formations.In contrast,the shales of the Doushantuo,Yanchang,and Qingshankou formations manifest low porosities.Furthermore,the shales of the Wufeng and Longmaxi formations exhibit high brittle mineral contents.Despite a low siliceous mineral content,the shales of the Doushantuo Formation feature a high carbonate mineral content,which can increase the shales’brittleness to some extent.For marine-continental transitional shales,where thin interbeds of tight sandstone with unequal thicknesses are generally found,it is recommended that fracturing combined with drainage of multiple sets of lithologic strata should be employed to enhance their shale gas production.

Analysis of Reservoir Forming Conditions and Prediction of Continuous Tight Gas Reservoirs for the Deep Jurassic in the Eastern Kuqa Depression,Tarim Basin

The exploration targets in the Kuqa Depression at present are mainly structure traps in Cretaceous-Tertiary.Due to the complexity of mountain distribution and reservoir forming conditions, the exploration of Jurassic in the eastern Kuqa Depression has been in a state of semi-stagnation since the discovery of the Yinan-2 gas reservoir.According to the concept and theory of 'continuous petroleum reservoirs' and the re-analysis of the forming conditions of the Yinan-2 gas reservoir and regional natural gas in the eastern Kuqa Depression,it is believed that the deep Jurassic has good natural gas accumulation conditions as well as geological conditions for forming continuous tight gas reservoirs.The boundary of the Yinan-2 gas reservoir is not controlled by a structural spillpoint.The downdip part of the structure is dominated by gas,while the hanging wall of the fault is filled by water and forming obvious inverted gas and water.The gas reservoir has the normal temperature and ultrahigh pressure which formed in the near source or inner-source.All of these characteristics indicate that the Yinan-2 gas reservoir is different from conventional gas reservoirs.The deep Jurassic in the eastern Kuqa Depression has multisets of source-reservoir-cap assemblages,which comprise interbedded sandstones and mudstones.These assemblages are characterized by a self-generation,self-preserving and self-coverage model.Reservoir sandstones and coal measure mudstones are interbedded with each other at a large scale.As the source rocks,Triassic-Jurassic coal measure mudstones distribute continuously at a large scale and can generate and expel hydrocarbon.Source rocks contact intimately with the overlying sandstone reservoirs.During the late stage of hydrocarbon expulsion,natural gas charged continuously and directly into the neighboring reservoirs.Petroleum migrated mainly in a vertical direction over short distances.With ultra-high pressure and strong charging intensity,natural gas accumulated continuously.Reservoirs are dominated by sandstones of braided delta facies.The sand bodies distribute continuously horizontal.With low porosity and low permeability,the reservoirs are featured by strong heterogeneity.It is hypothesized that the sandstones of the interior depression tend to be relatively tight with increasing depth and structure stress weakness.Thus,it is predicted that continuous tight gas reservoirs of ultra-high pressure may exist in the deep formations of the eastern and even the whole Kuqa Depression.So,it is worth evaluating the exploration potential.

Geological Conditions and Prospect Forecast of Shale Gas Formation in Qiangtang Basin, Qinghai-Tibet Plateau

The presence of shale gas has been confirmed in almost every marine shale distribution area in North America.Formation conditions of shale gas in China are the most favorable for marine,organic-rich shale as well.But there has been little research focusing on shale gas in Qiangtang Basin,Qinghai-Tibet Plateau,where a lot of Mesozoic marine shale formations developed.Based on the survey results of petroleum geology and comprehensive test analysis data for Qinghai-Tibet Plateau,for the first time,this paper discusses characteristics of sedimentary development,thickness distribution,geochemistry,reservoir and burial depth of organic-rich shale,and geological conditions for shale gas formation in Qiangtang Basin.There are four sets of marine shale strata in Qiangtang Basin including Upper Triassic Xiaochaka Formation （T3x）,Middle Jurassic Buqu Formation （J2b）,Xiali Formation （J2x） and Upper Jurassic Suowa Formation （J3s）,the sedimentary types of which are mainly bathyal-basin facies,open platform-platform margin slope facies,lagoon and tidal-fiat facies,as well as delta facies.By comparing it with the indicators of gas shale in the main U.S.basins,it was found that the four marine shale formations in Qiangtang Basin constitute a multi-layer distribution of organic-rich shale,featuring a high degree of thickness and low abundance of organic matter,high thermal evolution maturity,many kinds of brittle minerals,an equivalent content of quartz and clay minerals,a high content of feldspar and low porosity,which provide basic conditions for an accumulation of shale gas resources.Xiaochaka Formation shale is widely distributed,with big thickness and the best gas generating indicators.It is the main gas source layer.Xiali Formation shale is of intermediate thickness and coverage area,with relatively good gas generating indicators and moderate gas formation potential.Buqu Formation shale and Suowa Formation shale are of relatively large thickness,and covering a small area,with poor gas generating indicators,and limited gas formation potential.The shale gas geological resources and technically recoverable resources were estimated by using geologic analogy method,and the prospective areas and potentially favorable areas for Mesozoic marine shale gas in Qiangtang Basin are forecast and analyzed.It is relatively favorable in a tectonic setting and indication of oil and gas,shale maturity,sedimentary thickness and gypsum-salt beds,and in terms of mineral association for shale gas accumulation.But the challenge lies in overcoming the harsh natural conditions which contributes to great difficulties in ground engineering and exploration,and high exploration costs.

Geological conditions of natural gas accumulation and new exploration areas in the Mesoproterozoic to Lower Paleozoic of Ordos Basin, NW China

Based on field outcrop investigation,interpretation and analysis of drilling and seismic data,and consulting on a large number of previous research results,the characteristics of ancient marine hydrocarbon source rocks,favorable reservoir facies belts,hydrocarbon migration direction and reservoir-forming law in the Ordos Basin have been studied from the viewpoints of North China Craton breakup and Qilian-Qinling oceanic basin opening and closing.Four main results are obtained:(1)Controlled by deep-water shelf-rift,there are three suites of source rocks in the Ordos Basin and its periphery:Mesoproterozoic,Lower Cambrian and Middle-Upper Ordovician.(2)Controlled by littoral environment,paleo-uplift and platform margin,four types of reservoirs are developed in the area:Mesoproterozoic-Lower Cambrian littoral shallow sea quartz sandstone,Middle-Upper Cambrian–Ordovician weathering crust and dolomitized reservoir,and Ordovician L-shape platform margin reef and beach bodies.(3)Reservoir-forming assemblages vary greatly in the study area,with"upper generation and lower storage"as the main pattern in the platform,followed by"self-generation and self-storage".There are both"upper generation and lower storage"and"self-generation and self-storage"in the platform margin zone.In addition,in the case of communication between deep-large faults and the Changchengian system paleo-rift trough,there may also exist a"lower generation and upper reservoir"combination between the platform and the margin.(4)There are four new exploration fields including Qingyang paleo-uplift pre-Carboniferous weathering crust,L-shape platform margin zone in southwestern margin of the basin,Ordovician subsalt assemblage in central and eastern parts of the basin,and Mesoproterozoic–Cambrian.Among them,pre-Carboniferous weathering crust and L-shape platform margin facies zone are more realistic replacement areas,and Ordovician subsalt assemblage and the Proterozoic-Cambrian have certain potential and are worth exploring.

The instability conditions of a gas trapped in weak weakly interacting Fermi magnetic field

In this paper the analytical expression of free energy expressed by small parameter r of a weakly interacting Fermi gas trapped in weak magnetic field is derived by using ＇the maximum approximation＇ method and the ensemble theory. Based on the derived expression, the exact instability conditions of a weakly interacting Fermi gas trapped in weak magnetic field at both high and low temperatures are given. From the instability conditions we get the following two results. （1） At the whole low-temperature extent, whether the interactions are repulsive or attractive with （αn-k 4εF/3） （n and εF denote the particle-number density and the Fermi energy respectively, α = 4πah^2/m, and a is s-wave scattering length） positive, there is a lower-limit magnetic field of instability; in addition, there is an upper-limit magnetic field for the system of attractive interactions with （αn ＋ 4εF/3） negative. （2） At the whole high-temperature extent, the system with repulsive interactions is always stable, but for the system with attractive interactions, the greater the scattering length of attractive interactions ｜α｜ is, the stronger the magnetic field is and the larger the particle-number density is, the bigger the possibility of instability in the system will be.

Discussion on "sandwich"structures and preservation conditions of shale gas in the South Yellow Sea Basin

In order to make a breakthrough in Mesozoic-Paleozoic shale gas exploration in the South Yellow Sea Basin,a comparison of the preservation conditions was made within the Barnett shale gas reservoirs in the Fortworth Basin,the Jiaoshiba shale gas reservoirs in Sichuan Basin and potential shale gas reservoirs in Guizhou Province.The results show that the "Sandwich"structure is of great importance for shale gas accumulation.Therein to,the "Sandwich"structure is a kind of special reservoir-cap rock assemblage which consist of limestone or dolomite on the top,mudstone or shale layer in the middle and limestone or dolomite at the bottom.In consideration of the Mesozoic-Paleozoie in the Lower Yangtze,and Laoshan Uplift with weak Paleozoic deformation and thrust fault sealing On both flanks of the Laoshan Uplift,a conclusion can be drawn that the preservation conditions of shale gas probably developed "Sandwich" structures in the Lower Cambrian and Permian,which are key layers for the breakthrough of shale gas in the South Yellow Sea.Moreover,the preferred targets for shale gas drilling probably locate at both flanks of the Laoshan Uplift.

Conditions for the Formation of Oil and Gas Pools in Tertiary Volcanics in the Western Part of the Huimin Sag, Shandong and Their Distribution

Conditions for the Formation of oil and gas pools in Tertiary volcanics in the western part of the Huimin sag, Shandong and then (?)stribution have been studied based on the geological, seismic and well-logging information. In this paper, the types and lithofacies of the volcanic rocks in the western part of the Huimin sag are described; the relationship between rocks and electrical properties, the seismic reflection structures, the development and distribution of the volcanic rocks are expounded; and the fourfold role of the volcanic activities in the formation of the oil and gas pools is also dealt with. It is considered by the authors that the volcanic activities were not destructive to the formation of oil and gas pools but a factor favourable to the accumulation of organic matters and their conversion to hydrocarbon. The volcanic rocks might have served as reservoir rocks and cap rocks, or as a synsedimentary anticline. The prerequisites and important factors for the formation of oil and gas pools and their distribution are pointed out in the paper.

Reservoir Conditions of Central Gas Field in Shaan-Gan-Ning Basin

ＲｅｓｅｒｖｏｉｒＣｏｎｄｉｔｉｏｎｓｏｆＣｅｎｔｒａｌＧａｓＦｉｅｌｄｉｎＳｈａａｎ－Ｇａｎ－ＮｉｎｇＢａｓｉｎ￥ＣｈｅｎＡｎｎｉｎｇ（Ｓｅｎｉｏｒｇｅｏｌｏｇｉｓｔ，Ｅ．＆Ｄ．ＲｅｓｅａｒｃｈＩｎｓｔｉｔｕｔｅ，ＣｈａｎｇｑｉｎｇＰ．Ｅ．Ｂ．）Ｔ...

Thermodynamic Performance Analysis of E/F/H-Class Gas Turbine Combined Cycle with Exhaust Gas Recirculation and Inlet/Variable Guide Vane Adjustment under Part-Load Conditions

Exhaust gas recirculation control(EGRC),an inlet air heating technology,can be utilized in combination with inlet/variable guide vane control(IGV/VGVC) and fuel flow control(FFC) to regulate the load,thereby effectively improving the part-load(i.e.,off-design) performance of the gas turbine combined cycle(GTCC).In this study,the E-,F-,and H-Class EGR-GTCC design and off-design system models were established and validated to perform a comparative analysis of the part-load performance under the EGR-IGV-FFC and conventional IGV-FFC strategies in the E/F/H-Class GTCC.Results show that EGR-IGV-FFC has considerable potential for the part-load performance enhancement and can show a higher combined cycle efficiency than IGV-FFC in the E-,F-,and H-Class GTCCs.However,the part-load performance improvement in the corresponding GTCC was weakened for the higher class of the gas turbine because of the narrower load range of EGR action and the deterioration of the gas turbine performance.Furthermore,EGR-IGV-FFC was inferior to IGV-FFC in improving the performance at loads below 50% for the H-Class GTCC.The results obtained in this paper could help guide the application of EGR-IGV-FFC to enhance the part-load performance of various classes of GTCC systems.

Reservoir Characteristics and Preservation Conditions of Longmaxi Shale in the Upper Yangtze Block, South China

The Upper Ordovician-Lower Silurian Longmaxi Shale in the Upper Yangtze block represents one of the most important shale gas plays in China. The shale composition, porosity, organic thermal maturity, and methane sorption were investigated at the Qilongcun section in the Dingshan area, southeastern Sichuan Basin. The results show that the Upper Ordovician-Lower Silurian Longmaxi Shale contains： （1） sapropelic I organic matter; （2） a 40-m thick bedded sequence where total organic carbon （TOC） content is 〉 2%; （3） a 30-m thick layer at the base of the Longmaxi Shale with a brittle mineral content higher than 50%; and （4） a mean methane adsorption capacity of 1.80 cm3/g （7 MPa pressure）. A positive correlation between TOC and sorbed gas indicates that organic matter content exerts an important control on methane storage capacity. Based on the analysis of the shale reservoir characteristics, the lower member of the Longmaxi Shale can thus be considered a favorable stratum for shale gas exploration and exploitation. It has similar reservoir characteristics with the Longmaxi Shale in the Jiaoshiba area tested with a high-yield industrial gas flow. However, based on tectonic analysis, differences in the level of industrial gas flow between the low-yield study area and the high-yield Jiaoshiba area may result from different tectonic preservation conditions. Evidence from these studies indicates the shale gas potential of the Longmaxi Shale is constrained by the reservoir and preservation conditions.

Generalized δ-entropy condition to Riemann solution for Chaplygin gas in traffic flow

The Riemann problem for the Aw-Rascle model in the traffic flow with the Delta initial data for the Chaplygin gas is studied. The solutions are constructed globally under the generalized Rankine-Hugoniot relations, the δ-entropy conditions, and the generalized δ-entropy conditions. A new Delta wave, which is called a primary Delta wave, is defined in some solutions. The primary Delta wave satisfies the generalized Rankine- Hugoniot relations and the generalized δ-entropy conditions. It generates initially from the Delta initial data, which either evaluates a Delta wave, whose weight becomes stronger and stronger, or disappears at a finite time.

Rock mass response for lined rock caverns subjected to high internal gas pressure

The storage of hydrogen gas in underground lined rock caverns(LRCs)enables the implementation of the first fossil-free steelmaking process to meet the large demand for crude steel.Predicting the response of rock mass is important to ensure that gas leakage due to rupture of the steel lining does not occur.Analytical and numerical models can be used to estimate the rock mass response to high internal pressure;however,the fitness of these models under different in situ stress conditions and cavern shapes has not been studied.In this paper,the suitability of analytical and numerical models to estimate the maximum cavern wall tangential strain under high internal pressure is studied.The analytical model is derived in detail and finite element(FE)models considering both two-dimensional(2D)and three-dimensional(3D)geometries are presented.These models are verified with field measurements from the LRC in Skallen,southwestern Sweden.The analytical model is inexpensive to implement and gives good results for isotropic in situ stress conditions and large cavern heights.For the case of anisotropic horizontal in situ stresses,as the conditions in Skallen,the 3D FE model is the best approach.

A study on periodic boundary condition in direct numerical simulation for gas–solid flow

Direct numerical simulation(DNS) of gas–solid flow at high resolution has been carried out by coupling the lattice Boltzmann method(LBM) for gas flow and the discrete element method(DEM) for solid particles. However,the body force periodic boundary condition(FPBC) commonly used to cut down the huge computational cost of such simulation has faced accuracy concerns. In this study, a novel two-region periodic boundary condition(TPBC) is presented to remedy this problem, with the flow driven in the region with body force and freely evolving in the other region. With simulation cases for simple circulating fluidized bed risers, the validity and advantages of TPBC are demonstrated with more reasonable heterogeneity of the particle distribution as compared to the corresponding case with FPBC.

A statistical method for assessment of the existing correlations of hydrate forming conditions

Hydrate formation in the oil and gas industries has been a serious problem for a long time. It may cause many difficulties for instance in gas pipelines blockages. In order to determine the hydrate forming condition, gas gravity method has been used. Several correlations have been proposed based on gas gravity method. Checking the accuracy of the applied correlations is important. In this paper, the leverage approach is used for this purpose. Leverage approach is a statistical method for detection outliers which identifies the applicability domain （AD） of hydrate data predicting correlations and the quality of the existing data. Moreover, the Williams plot is sketched, which is a graphical depiction for determination of the doubtful points. The obtained results showed the existing correlations are all statistically correct and valid to predict hydrate formation temperature, just one data point is out of the applicability domains, and none of the experimental data can be chosen as outliers.

Study of the Conditions of Formation and Forecast of the Perspective Areas of Hydrogen-Sulfide Water of Surkhandarya Depression

Increase in requirement of hydrosulphuric water for improvement of the population set the task of identification of places of their possible congestion for hydrogeological service. Earlier detection of such congestions was accidental at well-drilling of different function. Therefore, development of new methodical approaches of search and allocation of perspective zones of their formation was required. It was for this purpose necessary to study in what conditions and what factors have an impact on formation of underground hydrosulphuric water. So far, definition of communication attempts only with separate geochemical signs was known. Results of studying of influence on formations of hydrosulphuric water of such factors as lithologic and facial in combination with oil-and-gas content, the geological and structural and hydrodynamic mode are given in this work. It is established that the main sign for formation of hydrosulphuric water is existence of evaporite thickness and hydrocarbon congestions. Besides, it is shown that small depth (up to 2 km) of their bedding has to be an indispensable condition and existence of explosive violation on which there has to be a water infiltration (a geological and structural factor). In the Surkhandarya region, the hydrodynamic mode caused by inclined bedding of aquifers was also one of essential factors. Active water is an exchange process with washing away (oxidation) sulfate of the containing thicknesses and subsequently, its restoration in interaction with hydrocarbons with formation of hydrosulphuric water is described. The technique is developed and the expected card of perspective zones of formation of hydrosulphuric water is constructed.

Enrichment conditions and resource potential of coal-rock gas in Ordos Basin,NW China

To reveal the enrichment conditions and resource potential of coal-rock gas in the Ordos Basin,this paper presents a systematic research on the sedimentary environment,distribution,physical properties,reservoir characteristics,gas-bearing characteristics and gas accumulation play of deep coals.The results show that thick coals are widely distributed in the Carboniferous–Permian of the Ordos Basin.The main coal seams Carboniferous 5~#and Permian 8~#in the Carboniferous–Permian have strong hydrocarbon generation capacity and high thermal evolution degree,which provide abundant materials for the formation of coal-rock gas.Deep coal reservoirs have good physical properties,especially porosity and permeability.Coal seams Carboniferous 5~#and Permian 8~#exhibit the average porosity of 4.1%and 6.4%,and the average permeability of 8.7×10^(-3)μm^(2)and 15.7×10^(-3)μm^(2),respectively.Cleats and fissures are developed in the coals,and together with the micropores,constitute the main storage space.With the increase of evolution degree,the micropore volume tends to increase.The development degree of cleats and fissures has a great impact on permeability.The coal reservoirs and their industrial compositions exhibit significantly heterogeneous distribution in the vertical direction.The bright coal seam,which is in the middle and upper section,less affected by ash filling compared with the lower section,and contains well-developed pores and fissures,is a high-quality reservoir interval.The deep coals present good gas-bearing characteristics in Ordos Basin,with the gas content of 7.5–20.0 m^(3)/t,and the proportion of free gas(greater than 10%,mostly 11.0%–55.1%)in coal-rock gas significantly higher than that in shallow coals.The enrichment degree of free gas in deep coals is controlled by the number of macropores and microfractures.The coal rock pressure testing shows that the coal-limestone and coal-mudstone combinations for gas accumulation have good sealing capacity,and the mudstone/limestone(roof)-coal-mudstone(floor)combination generally indicates high coal-rock gas values.The coal-rock gas resources in the Ordos Basin were preliminarily estimated by the volume method to be 22.38×10^(12)m^(3),and the main coal-rock gas prospects in the Ordos Basin were defined.In the central-east of the Ordos Basin,Wushenqi,Hengshan-Suide,Yan'an,Zichang,and Yichuan are coal-rock gas prospects for the coal seam#8 of the Benxi Formation,and Linxian West,Mizhi,Yichuan-Huangling,Yulin,and Wushenqi-Hengshan are coal-rock gas prospects for the coal seam#5 of the Shanxi Formation,which are expected to become new areas for increased gas reserves and production.

Carbon isotope evidence for shale gas preservation conditions and large methane release over million years:A case study of shale gas reservoirs of Wufeng and Longmaxi Formations in the Sichuan Basin

Although carbon isotope reversal and its reasons in shale gas reservoirs have been widely recognized,the application of the reversal is yet to be investigated.A study on high-maturity shale from Wufeng and Longmaxi Formations in the Sichuan Basin not only reveals the relationship between the degree of isotopes inversion and the production capacity(e.g.,estimated ultimate recovery(EUR))of the gas well but also indicates the preservation conditions of shale gas reservoirs.(1)Although there are differences in gas isotopes in different shale gas reservoirs,the isotope fractionation of shale gas is small during the production stage of gas wells,even when the wellbore pressure drops to zero.The main cause of the difference in carbon isotopes and their inversion degree can be the uplift time during the Yanshan period and the formation pressure relief degree of shale gas reservoirs in distinct structural positions.Thus,carbon isotope inversion is a good indicator of shale gas preservation condition and EUR of shale gas wells.(2)The degree of carbon isotope inversion correlates strongly with shale gas content and EUR.The calculation formula of shale-gas recoverable reserves was established using△δ^(13)C(δC_(1)-δC_(2))and EUR.(3)The gas loss rate and total loss amount can be estimated using the dynamic reserves and isotopic difference values of gas wells in various shale gas fields,which also reflects the current methane loss,thereby demonstrating great potential for evaluating global methane loss in shales.

Behavior of transporting pipeline sections without and with hydrogen exposure based on full-scale tests

Pipeline transport of hydrogen is one of today’s economic and environmental challenges.In order to find safe and reliable application of both existing gas and build new pipelines,it is essential to carry out tests on full-scale pipeline section,including the potentially more dangerous places than the main pipe,the girth welds.For the investigations,pipeline sections of P355NH steel with girth welds were prepared and exposed to pure hydrogen at twice the maximum allowable operating pressure for 41 days.Subsequently,full-scale burst tests were carried out and specimens were cut and prepared from the typical locations of the failed pipeline sections for mechanical,and macro-and microstructural investigations.The results obtained were evaluated and compared with data from previous full-scale tests on pipeline sections without hydrogen exposure.The results showed differences in the behavior of pipeline sections loaded in different ways,with different characteristics of the materials and the welded joints,both in the cases without hydrogen exposure and in the cases exposed to hydrogen.

Ultrafast metal oxide reduction at Pd/PdO_(2) interface enables onesecond hydrogen gas detection under ambient conditions

Here,we report a Pd/PdO_(x) sensing material that achieves 1-s detection of 4% H_(2) gas(i.e.,the lower explosive limit concentration for H_(2))at room temperature in air.The Pd/PdO_(x) material is a network of interconnected nanoscopic domains of Pd,PdO,and PdO_(2).Upon exposure to 4% H_(2),PdO and PdO_(2) in the Pd/PdO_(x) are immediately reduced to metallic Pd,generating over a>90% drop in electrical resistance.The mechanistic study reveals that the Pd/PdO_(2) interface in Pd/PdOx is responsible for the ultrafast PdO_(x) reduction.Metallic Pd at the Pd/PdO_(2) interface enables fast H_(2) dissociation to adsorbed H atoms,significantly lowering the PdO2 reduction barrier.In addition,control experiments suggest that the interconnectivity of Pd,PdO,and PdO2 in our Pd/PdO_(x) sensing material further facilitates the reduction of PdO,which would otherwise not occur.The 1-s response time of Pd/PdO_(x) under ambient conditions makes it an excellent alarm for the timely detection of hydrogen gas leaks.