Effects of channel wall wettability on gas-liquid dynamics mass transfer under Taylor flow in a serpentine microchannel

The wall wettability of microchannels plays an important role in the gas-liquid mass transfer dynamics under Taylor flow.In this study,we regulated the contact angle of the wall surface through surface chemical grafting polymerization under controlled experimental conditions.The dynamic changes of CO_(2)bubbles flowing along the microchannel were captured by a high-speed video camera mounted on a stereo microscope,whilst a unit cell model was employed to theoretically investigate the gas-liquid mass transfer dynamics.We quantitatively characterized the effects of wall wettability,specifically the contact angle,on the formation mechanism of gas bubbles and mass transfer process experimentally.The results revealed that the gas bubble velocity,the overall volumetric liquid phase mass transfer coefficients(kLa),and the specific interfacial area(a)all increased with the increase of the contact angle.Conversely,gas bubble length and leakage flow decreased.Furthermore,we proposed a new modified model to predict the gas-liquid two-phase mass transfer performance,based on van Baten’s and Yao’s models.Our proposed model was observed to agree reasonably well with experimental observations.

Dilution characteristics of dual buoyant jets in wavy cross-flow environment

Due to the difference in density between the discharge effluent and coastal water,partially treated wastewater is often discharged into the marine environment as a buoyant jet via submarine outfalls with multiport diffusers.The dilution characteristics of effluent discharge(dual buoyant jets)in a wavy cross-flow environment were studied in a laboratory.The planar laser-induced fluorescence technique was used to obtain the concentration data of the jets.The effects of different environmental variables on the diffusion and dilution characteristics of the jets were examined through physical experiments,dimensional analysis,and empirical formulations.It was found that the dilution process of the dual jets could be divided into two components:the original jet component and the effluent cloud component.The jet-to-current velocity ratio was the main parameter affecting the concentration levels of the effluent cloud.The merging of the two jets increased the jet concentration in the flow field.When the jets traveled further downstream,the axial dilution increased gradually and then increased significantly along the axis.Under the effects of strong waves,the concentration contours branched into two peaks,and the mean dilution became more significant than under the effects of weak waves.Therefore,the dilution of the effluent discharge was expected to be significant under strong wave effects because the hydrodynamic force increased.A dilution equation was derived to improve our understanding of the dilution process of buoyant jets in a wavy cross-flow environment.This equation was used to determine the influences of the jet-to-current velocity ratio,wave-to-current velocity ratio,and Strouhal number on the minimum jet dilution.It revealed that the wave and buoyancy effects in effluent discharges were significant.

A New Distribution Method for Wet Steam Injection Optimization

A new approach and a new related distribution system are proposed to address the issue of uneven steam injection caused by the different suction capacities of the used wells during the application of steam“stimulation”methods for enhanced oil recovery.The new distribution system consists of a swirler,spiral dividing baffles,and critical flow nozzles.Numerical simulations are used to analyze the flow-field and degree of steam homogeneity obtained with such an approach.The results indicate that a higher inlet pressure leads to better results.Additionally,the internal flow field becomes more stable,and the deviation from an even distribution reduces to±4.0%even when the resistance of each branch is inconsistent.Furthermore,field tests have yielded satisfactory results.

带非局部边值条件的Gas-Liquid模型正解的渐近性态

应用bootstrap技巧,讨论了带非局部边值条件的Gas-Liquid模型正周期拟解的存在性和一般时变解的渐近性态.

Experimental Study on Coupled Cross-Flow and in-Line Vortex-Induced Vibration of Flexible Risers

In this work, we study the coupled cross-flow and in-line vortex-induced vibration （VIV） of a fixedly mounted flexible pipe, which is free to move in cross-flow （ Y- ） and in-line （ X- ） direction in a fluid flow where the mass and natural frequencies are precisely the same in both X- and Y-direction. The fluid speed varies from low to high with the corresponding vortex shedding frequency varying from below the first natural frequency to above the second natural frequency of the flexible pipe. Particular emphasis was placed on the investigation of the relationship between in-line and cross-flow vibration. The experimental results analyzed by using these measurements exhibits several valuable features.

Experimental Investigation of Vibration Response of A Free-Hanging Flexible Riser Induced by Internal Gas-Liquid Slug Flow

The vibration response of a free-hanging flexible riser induced by internal gas-liquid slug flow was studied experimentally in a small-diameter tube model based on Froude number criterion. The flow regime in a curved riser model and the response displacements of the riser were simultaneously recorded by high speed cameras. The gas superficial velocity ranges from 0.1 m/s to 0.6 m/s while the liquid superficial velocity from 0.06 m/s to 0.3 m/s.Severe slugging type 3, unstable oscillation flow and relatively stable slug flow were observed in the considered flow rates. Severe slugging type 3 characterized by premature gas penetration occurs at relatively low flow rates. Both the cycle time and slug length become shorter as the gas flow rate increases. The pressure at the riser base undergoes a longer period and larger amplitude of fluctuation as compared with the other two flow regimes. Additionally, severe slugging leads to the most vigorous in-plane vibration. However, the responses in the vertical and horizontal directions are not synchronized. The vertical vibration is dominated by the second mode while the horizontal vibration is dominated by the first mode. Similar to the vortex-induced vibration, three branches are identified as initial branch, build-up branch and descending branch for the response versus the mixture velocity of gas-liquid flow.

Experimental Study on Cross-Flow Induced Vibrations in Heat Exchanger Tube Bundle

Vibration in heat exchangers is one of the main problems that the industry has faced over last few decades. Vibration phenomenon in heat exchangers is of major concern for designers and process engineers since it can lead to the tube damage, tube leakage, baffle damage, tube collision damage, fatigue, creep etc. In the present study, vibration response is analyzed on single tube located in the centre of the tube bundle having parallel triangular arrangement （60-） with P/D ratio of 1.44. The experiment is performed for two different flow conditions. This kind of experiment has not been reported in the literature. Under the first condition, the tube vibration response is analyzed when there is no internal flow in the tube and under the second condition, the response is analyzed when the internal tube flow is maintained at a constant value of 0.1 rn/s. The free stream shell side velocity ranges from 0.8 rn/s to 1.3 m/s, the reduced gap velocity varies from 1,80 to 2.66 and the Reynolds number varies from 44500 to 66000. It is observed that the internal tube flow results in larger vibration amplitudes for the tube than that without internal tube flow. It is also established that over the current range of shell side flow velocity, the turbulence is the dominant excitation mechanism for producing vibration in the tube since the amplitude varies directly with the increase in the shell side velocity. Damping has no significant effect on the vibration behavior of the tube for the current velocity range.

Effect of the Inclination Angle on Slippage Loss in Gas-Liquid Two-Phase Flow

The lifting efficiency and stability of gas lift well are affected by the socalled slippage-loss effect in gas-liquid two-phase flow.The existing studies on this subject have generally been based on vertical and horizontal wells.Only a few of them have considered inclined pipes.In the present work a new focused study is presented along these lines.More specifically,we use the non-slip pressure drop model with Flanigan’s fluctuation correction coefficient formula(together with the parameters of slippage density,slippage pressure drop and slippage ratio)to analyze the influence of the inclination angle on slippage loss for different conditions(different gas-liquid superficial velocity and pipe diameters).Moreover,the“standard regression coefficient method”is used for multi-factor sensitivity analysis.The experimental results indicate that slippage loss is affected by multiple factors,and the influence of the inclination angle on slippage loss is less significant than other factors.The change of the slippage pressure drop with the superficial velocity of gas-liquid is similar to that of the total pressure drop.The inclination angles of 45°and 60°have the greatest influence on slippage loss.The correlation between slippage density and slippage ratio is not obvious.Using the so-called slippage ratio seems to be a more accurate option to evaluate the degree of slippage loss.

Evaluation of gas-liquid separation performance of natural gas filters

Fibrous filters are often used to remove contaminants including both dusts and liquid droplets from natural gas. This paper aims to evaluate the gas-liquid separation performance of three types of cartridge filters used in the West-East natural gas transmission project. The comparison of the original pressure drop of clean filters and the evolution of pressure drop as liquid droplets deposited in the filter media are described. The original pressure drops of these filters were similar but the pressure drops at a steady state were different. Fractional efficiency was used to study the separation performance of cartridge filters. Droplets at the outlet of the filters had small diameters, no more than 3 μm, but were very numerous. The effect of filtration velocity on gas-liquid separation performance was analyzed. Higher filtration velocity indicated better gas-liquid separation performance. Finally the quality factor related to pressure drop and filtration efficiency was applied to evaluate the gas-liquid separation performance.

Initial Dilution of A Vertical Round Non-Buoyant Jet in Wavy Cross-Flow Environment

The phenomenon of wastewater discharged into coastal waters can be simplified as a turbulent jet under the effect of waves and currents. Previous studies have been carried out to investigate the jet behaviors under the current only or the wave only environment. To obtain better understanding of the jet behaviors in a realistic situation, a series of physical experiments on the initial dilution of a vertical round jet in the wavy cross-flow environment are conducted. The diluted processes of the jet are recorded by a high-resolution camcorder and the concentration fields of the jet are measured with a peristaltic suction pumping system. When the jet is discharged into the wavy cross-flow environment, a distinctive phenomenon, namely ＂effluent clouds＂, is observed. According to the quantitative measurements, the jet width in the wavy cross-flow environment increases more significantly than that does in the cross-flow only environment, indicating that the waves impose a positive effect on the enhancement of jet initial dilution. In order to generalize the experimental findings, a comprehensive velocity scale ua and a characteristic length scale l are introduced. Through dimensional analysis, it is found that the dimensionless centerline concentration trajectories cy/l is in proportion to 1/3 power of the dimensionless downstream distance x/l, and the dimensionless centerline dilution 2c aS Q/（u l） is proportional to the square of the dimensionless centerline trajectory cy/l. Several empirical equations are then derived by using the Froude number of cross-flow Frc as a reference coefficient. This paper provides a better understanding and new estimations of the jet initial dilution under the combined effect of waves and cross-flow current.

Degradation of tetracycline in water by gas-liquid plasma in conjunction with rGO-TiO_(2) nanocomposite

Tetracycline(TC)is an antibiotic mainly used in livestock production and respiratory infection.Traditional methods are not effective in removing TC from solution.In this study,TC was degraded by gas–liquid plasma in the presence of rGO-TiO_(2)in solution.The rGO-TiO_(2)was prepared by modified hummers and hydrothermal method.The electrical and optical properties of the gas–liquid discharge plasma were studied and the produced long-lived reactive species were analyzed by spectrophotometer.The degradation efficiency of TC was improved by 41.4%after plasma treatment for 12 min in presence of 30 mg l-1 r GO-TiO_(2)compared to that with plasma alone.The degradation efficiency increased with increasing discharge power,but as the initial concentration was increased from 20 to 80 mg l-1,the degradation efficiency of TC decreased.The initial p H had no significant effect on the degradation of TC.The intermediate products were determined by UV–vis spectrophotometry and ESI(+)–MS,and the degradation mechanism was analyzed.The reactive species,including O_(3),·OH,and H_(2)O_(2),etc.,produced in the plasma/catalyst system attracted electron-rich functional groups(amino group,aromatic ring,and double bond).Therefore,the gas–liquid plasma/catalyst system could be an effective and promising method for pharmaceutical wastewater treatment in future.

Low gas-liquid ratio foam flooding for conventional heavy oil

The recovery of heavy oil by water flooding is 10% lower than that of conventional crude oil, so enhanced oil recovery （EOR） is of great significance for heavy oil. In this paper, foam flooding with a gas-liquid ratio （GLR） of 0.2：1 for the Zhuangxi heavy oil （325 mPa.s at 55 ℃） was performed on cores, sand packs and plate model. In sand pack tests, polymer enhanced foam flooding increased oil recovery by 39.8%, which was 11.4% higher than that for alkali/surfactant/polymer （ASP） flooding under the same conditions. Polymer enhanced foam flooding in plate models shows that the low GLR foam flooding increased oil recovery by about 30%, even when the extended water flooding was finished at 90% water cut. Moreover, it was discovered by microscopy that foam was more stable in heavy oil than in light oil. These results confirm that low GLR foam flooding is a promising technology for displacing conventional heavy oil.

Modeling of Continuous Cross-flow Microfiltration Process in an Airlift External-loop Slurry Reactor

New modified combination mathematical models including the pores blocking models and the cake layer models were developed to describe the continuous cross-flow microfiltration in an airlift external loop slurry reactor. The pores blocking models were created based on the standard blocking law and the intermediate blocking law, and then the cake layer models were developed based on the hydrodynamic theory in which the calculation method of porosity of cake layer was newly corrected. The Air-Water-FCC equilibrium catalysts cold model experiment was used to verify the relevant models.Results showed that the calculated values fitted well with experimental data with a relative error of less than 10%.

A novel complex network-based deep learning method for characterizing gas-liquid two-phase flow

Gas-liquid two-phase flow widely exits in production and transportation of petroleum industry.Characterizing gas-liquid flow and measuring flow parameters represent challenges of great importance,which contribute to the recognition of flow regime and the optimal design of industrial equipment.In this paper,we propose a novel complex network-based deep learning method for characterizing gas-liquid flow.Firstly,we map the multichannel measurements to multiple limited penetrable visibility graphs(LPVGs)and obtain their degree sequences as the graph representation.Based on the degree distribution,we analyze the complicated flow behavior under different flow structures.Then,we design a dual-input convolutional neural network to fuse the raw signals and the graph representation of LPVGs for the classification of flow structures and measurement of gas void fraction.We implement the model with two parallel branches with the same structure,each corresponding to one input.Each branch consists of a channel-projection convolutional part,a spatial-temporal convolutional part,a dense block and an attention module.The outputs of the two branches are concatenated and fed into several full connected layers for the classification and measurement.At last,our method achieves an accuracy of 95.3%for the classification of flow structures,and a mean squared error of 0.0038 and a mean absolute percent error of 6.3%for the measurement of gas void fraction.Our method provides a promising solution for characterizing gas-liquid flow and measuring flow parameters.

Study on Separation of Water and Alumina Fine Particles by Cross-Flow Microfiltration

A cross-flow microfiltration process had been developed to separate alumina fine particles from the suspension using a stainless steel membrane tube with a pore size of 10 μm. The influence of cross-flow velocity and trans-membrane pressure on the permeate flux and the solid holdup in permeate had been investigated. It was found that both the permeate flux and the solid holdup in permeate decreased with time. Moreover, the permeate flux increased with an increasing transmembrane pressure but the influence of cross-flow velocity on the permeate flux was quite complex. Both the permeate flux and the solid holdup in permeate in long term filtration had been studied. The operation of cross-flow microfiltration could be carried out stably for 10 hours with the permeate flux values ranging from 520.5 to 936 L/(m^2·h) at rs=1%, while it could continue in 10 hours with the permeate flux values ranging from 226 to 432 L/(m^2·h) at rs=5%. The solid holdup in permeate had been less than 10 mg/L during the whole operating cycle.

Ideality analysis and general laws of bubble swarm microflow for large-scale gas-liquid microreaction processes

The flow ideality of bubbly microflow remains unclear even though it is vital for the design of microreactors,especially the ideality of bubble swarm microflow for large-scale gas-liquid microreaction processes.This work is the first time to report the ideality analysis of the microbubble swarm in a relatively large microchannel.The bubble swarm microflow has undergone two conditions:quasihomogeneous plug flow and liquid phase/gas-liquid qua si-homogeneous phase two-phase laminar flow.Both the deviations of void fraction and bubble velocity from the ideal plug flow can divide into two parts,and the two transition points simultaneously happen at the velocity ratio of 1.25.There exists a critical capillary number to maintain the quasi-homogeneous plug flow,which could be regarded as the general laws for the design of gas-liquid microreactors.Finally,a novel model is developed to predict the bubble velocity.This work could be very helpful for the large-scale gas-liquid microreactors design.

ANALYSIS OF A COMPRESSIBLE GAS-LIQUID MODEL MOTIVATED BY OIL WELL CONTROL OPERATIONS

We are interested in a viscous two-phase gas-liquid mixture model relevant for modeling of well control operations within the petroleum industry. We focus on a simplified mixture model and provide an existence result within an appropriate class of weak solutions. We demonstrate that upper and lower limits can be obtained for the gas and liquid masses which ensure that transition to single-phase regions do not occur. This is used together with appropriate a prior estimates to obtain convergence to a weak solution for a sequence of approximate solutions corresponding to mollified initial data. Moreover, by imposing an additional regularity condition on the initial masses, a uniqueness result is obtained. The framework herein seems useful for further investigations of more realistic versions of the gas-liquid model that take into account different flow regimes.

Numerical Simulation and Experimental Analysis of the Influence of Asymmetric Pressure Conditions on the Splitting of a Gas-Liquid Two-Phase Flow at a T-Junction

Dedicated experiments and numerical simulations have been conducted to investigate the splitting characteristics of a gas-liquid two phase flow at a T junction.The experiments were carried out for different gas-liquid velocities.The flow rates in the two branches were measured accurately to determine how the two considered phases distribute in the two outlets.The experimental results have shown that when the two outlet pressures are asymmetric,the two-phase flow always tends to flow into the outlet which has a lower pressure.As the inlet liquid velocity increases,however,the two-phase flow gradually tends to split evenly.Compared with the experiment results,the pressure difference between the two outlets can be determined more accurately by means of numerical simulation.The trends of experimental results and simulations are in very good agreement.

Activation of peroxydisulfate by gas-liquid pulsed discharge plasma to enhance the degradation of p-nitrophenol

Pulsed discharge in water and over water surfaces generates ultraviolet radiation,local high temperature,shock waves,and chemical reactive species,including hydroxyl radicals,hydrogen peroxide,and ozone.Pulsed discharge plasma（PDP） can oxidize and mineralize pollutants very efficiently,but high energy consumption restricts its application for industrial wastewater treatment.A novel method for improving the energy efficiency of wastewater treatment by PDP was proposed,in which peroxydisulfate（PDS） was added to wastewater and PDS was activated by PDP to produce more strong oxidizing radicals,including sulfate radicals and hydroxyl radicals,leading to a higher oxidation capacity for the PDP system.The experimental results show that the increase in solution conductivity slightly decreased the discharge power of the pulse discharge over the water surface.An increase in the discharge intensity improved the activation of PDS and therefore the degradation efficiency and energy efficiency of p-nitrophenol（PNP）.An increase in the addition dosage of PDS greatly facilitated the degradation of PNP at a molar ratio of PDS to PNP of lower than 80：1,but the performance enhancement was no longer obvious at a dosage of more than 80：1.Under an applied voltage of 20 kV and a gas discharge gap of 2 mm,the degradation efficiency and energy efficiency of the PNP reached 90.7%and45.0 mg kWh^（-1） for the plasma/PDS system,respectively,which was 34%and 18.0 mg kWh^（-1）higher than for the discharge plasma treatment alone.Analysis of the physical and chemical effects indicated that ozone and hydrogen peroxide were important for PNP degradation and UV irradiation and heat from the discharge plasma might be the main physical effects for the activation of PDS.

Measurement of Liquid Concentration Fields Near Interface with Cocurrent Gas-Liquid Flow Absorption Using Holographic Interferometry

Real-time laser holographic interferometry was applied to measure liquid concentrations of CO2 in the vicinity of gas-liquid free interface under the conditions of cocurrent gas-liquid flow for absorption of CO2 by ethanol. The influences of the Reynolds number on the measurable interface concentration and on the film thickness were discussed. The results show that CO2 concentration decreases exponentially along the mass transfer direction, and the concentration gradient increases as Reynolds number of either liquid or gas increases. CO2 concentrations fluctuate slightly along the direction of flow; on the whole, there is an increase in CO2 concentration. The investiga- tion also demonstrated that film thickness decreases with the increase of Reynolds number of either of the two phases. Sherwood number representing the mass transfer coefficient was finally correlated as a function of the hy- drodynamic parameters and the physical properties.