A computational study on the flow behavior of a gas-solid injector by Eulerian approach was carried out. The gas phase was modeled with k-ε turbulent model and the particle phase was modeled with kinetic theory of gr...A computational study on the flow behavior of a gas-solid injector by Eulerian approach was carried out. The gas phase was modeled with k-ε turbulent model and the particle phase was modeled with kinetic theory of granular flow. The simulations by Eulerian two-fluid model (TFM) were compared with the corresponding results by discrete element method (DEM) and experiments. It was showed that TFM simulated results were in reasonable agreement with the experimental and DEM simulated results. Based on TFM simulations, gas-solid flow pattern, gas velocity, particle velocity and the static pressure under different driving jet velocity, backpressure and convergent section angle were obtained. The results showed that the time average axial gas velocity sharply decreased and then slightly increased to a constant value in the horizontal conveying pipe. The time average axial particle velocity increased initially and then decreased, but in the outlet region of the convergent section the particle velocity remarkably increased once more to the maximal value. As a whole, the static pressure distribution change trends were found to be independent on driving gas velocity, backpressure and convergent section angle. However, the static pressure increased with increase of convergent section angle and gas jet velocities. The difference of static pressure to backpressure increased with increasing backpressure.展开更多
Radio frequency quadrupoles(RFQs),which are crucial components of proton injectors,significantly affect the performance of proton accelerator facilities.An RFQ with a high frequency of 714 MHz dedicated to compact pro...Radio frequency quadrupoles(RFQs),which are crucial components of proton injectors,significantly affect the performance of proton accelerator facilities.An RFQ with a high frequency of 714 MHz dedicated to compact proton injectors for medi-cal applications is designed in this study.The RFQ is designed to accelerate proton beams from 50 keV to 4 MeV within a short length of 2 m and can be matched closely with the downstream drift tube linac to capture more particles through a preliminary optimization.To develop an advanced RFQ,challenging techniques,including fabrication and tuning method,must be evaluated and verified using a prototype.An aluminium prototype is derived from the conceptual design of the RFQ and then redesigned to confirm the radio frequency performance,fabrication procedure,and feasibility of the tuning algorithm.Eventually,a new tuning algorithm based on the response matrix and least-squares method is developed,which yields favorable results based on the prototype,i.e.,the errors of the dipole and quadrupole components reduced to a low level after several tuning iterations.Benefiting from the conceptual design and techniques obtained from the prototype,the formal mechanical design of the 2-m RFQ is ready for the next manufacturing step.展开更多
The nozzle inner-flow characteristic of the“spray G”injector was studied by the computational fluid dynamics(CFD)simulation,and the sensitivity of cycle fuel mass to the conicity and entrance radius of the nozzle ho...The nozzle inner-flow characteristic of the“spray G”injector was studied by the computational fluid dynamics(CFD)simulation,and the sensitivity of cycle fuel mass to the conicity and entrance radius of the nozzle hole were analyzed.Results show that the inner conicity of nozzle hole inhibits the development of cavitation phenomena,and increases the injection rate.While the outer conicity of nozzle hole promotes the diffusion of cavita-tion,leading to reductions of the liquid volume fraction of the nozzle outlet and the local flow resistance of the nozzle hole.The sensitivity of cycle fuel mass to inner-cone nozzle hole is stronger than that of the outer-cone noz-zle,especially at the smaller hole conicity.The increase of injection pressure enhances the sensitivity of the injection characteristics to the nozzle hole structure,in which inner-cone nozzle has higher sensitivity coefficient than the outer-cone nozzle hole.However,the increase of injection pressure aggravates the offset of liquid jet to the nozzle axis of the outer-cone nozzle hole.With the increase of the inner conicity of nozzle,the sensitivity of the injection characteristics to the entrance radius of the hole decreases.With the increase of the outer conicity of nozzle hole,the sensitivity of the injection characteristics to the entrance radius of the hole increases.展开更多
Under the pressure of carbon neutrality,many carbon capture,utilization and storage technologies have witnessed rapid development in the recent years,including oxy-fuel combustion(OFC)technology.However,the convention...Under the pressure of carbon neutrality,many carbon capture,utilization and storage technologies have witnessed rapid development in the recent years,including oxy-fuel combustion(OFC)technology.However,the conventional OFC technology usually depends on the flue gas recirculation system,which faces significant investment,high energy consumption,and potential low-temperature corrosion problem.Considering these deficiencies,the direct utilization of pure oxygen to achieve particle fluidization and fuel combustion may reduce the overall energy consumption and CO_(2)-capture costs.In this paper,the fundamental structure of a self-designed 130 t·h^(-1) pure-oxygen combustion circulating fluidized bed(CFB)boiler was provided,and the computational particle fluid dynamics method was used to analyze the gas-solid flow characteristics of this new-concept boiler under different working conditions.The results indicate that through the careful selection of design or operational parameters,such as average bed-material size and fluidization velocity,the pure-oxygen combustion CFB system can maintain the ideal fluidization state,namely significant internal and external particle circulation.Besides,the contraction section of the boiler leads to the particle backflow in the lower furnace,resulting in the particle suspension concentration near the wall region being higher than that in the center region.Conversely,the upper furnace still retains the classic core-annulus flow structure.In addition to increasing solid circulation rate by reducing the average bed-material size,altering primary gas ratio and bed inventory can also exert varying degrees of influence on the gas-solid flow characteristics of the pure-oxygen combustion CFB boiler.展开更多
The direct conversion of atmospheric CO_(2) into fuel via photocatalysis exhibits significant practical application value in advancing the carbon cycle.In this study,we established an electro-assisted photocatalytic s...The direct conversion of atmospheric CO_(2) into fuel via photocatalysis exhibits significant practical application value in advancing the carbon cycle.In this study,we established an electro-assisted photocatalytic system with dual compartments and interfaces,and coated Ag nanoparticles on the titanium nanotube arrays(TNTAs)by polydopamine modification.In the absence of sacrificial agent and alkali absorption liquid conditions,the stable,efficient and highly selective conversion of CO_(2) to CO at the gas-solid interface in ambient air was realized by photoelectric synergy.Specifically,with the assistance of potential,the CO formation rates reached 194.9μmol h^(−1) m^(−2) and 103.9μmol h^(−1) m^(−2) under ultraviolet and visible light irradiation,respectively;the corresponding CO_(2) conversion rates in ambient air were 30%and 16%,respectively.The excellent catalytic effect is mainly attributed to the formation of P–N heterojunction during the catalytic process and the surface plasmon resonance effect.Additionally,the introduction of solid agar electrolytes effectively inhibits the hydrogen evolution reaction and improves the electron utilization rate.This system promotes the development of photocatalytic technology for practical applications and provides new insights and support for the carbon cycle.展开更多
The quality of crushing,power consumption,and discharging performance of a straw crusher are greatly influenced by the characteristics of its internalflowfield.To enhance the straw crusher’sflowfield properties and improv...The quality of crushing,power consumption,and discharging performance of a straw crusher are greatly influenced by the characteristics of its internalflowfield.To enhance the straw crusher’sflowfield properties and improve the efficiency with which crushed material is discharged,first,the main structural parameters influencing the airflow in the crusher are discussed.Then,the coupled gas-solidflowfield in the straw crusher is numerically calculated through solution of the Navier-Stokes equations and application of the discrete element method(DEM).Finally,the discharge performance index of the crusher is examined through detailed analysis of the crushed material dynamics.Additionally,a multi-island genetic algorithm is used to optimize the structure and operational factors that have significant effects on the discharge performance.With optimization,the accumulation rate of crushed materials in the bottom region of the straw crusher decreases by 20.08%,and the massflow rate at the discharge outlet increases by 11.63%.展开更多
Energetic Semiconductor bridge(ESCB)based on reactive multilayered films(RMFs)has a promising application in the miniature and intelligence of initiator and pyrotechnics device.Understanding the ignition enhancement m...Energetic Semiconductor bridge(ESCB)based on reactive multilayered films(RMFs)has a promising application in the miniature and intelligence of initiator and pyrotechnics device.Understanding the ignition enhancement mechanism of RMFs on semiconductor bridge(SCB)during the ignition process is crucial for the engineering and practical application of advanced initiator and pyrotechnics devices.In this study,a one-dimensional(1D)gas-solid two-phase flow ignition model was established to study the ignition process of ESCB to charge particles based on the reactivity of Al/MoO_(3) RMFs.In order to fully consider the coupled exothermic between the RMFs and the SCB plasma during the ignition process,the heat release of chemical reaction in RMFs was used as an internal heat source in this model.It is found that the exothermal reaction in RMFs improved the ignition performance of SCB.In the process of plasma rapid condensation with heat release,the product of RMFs enhanced the heat transfer process between the gas phase and the solid charge particle,which accelerated the expansion of hot plasma,and heated the solid charge particle as well as gas phase region with low temperature.In addition,it made up for pressure loss in the gas phase.During the plasma dissipation process,the exothermal chemical reaction in RMFs acted as the main heating source to heat the charge particle,making the surface temperature of the charge particle,gas pressure,and gas temperature rise continuously.This result may yield significant advantages in providing a universal ignition model for miniaturized ignition devices.展开更多
Lead-free inorganic copper-silver-bismuth-halide materials have attracted more and more attention due to their environmental friendliness,high element abundance,and low cost.Here,we developed a strategy of one-step ga...Lead-free inorganic copper-silver-bismuth-halide materials have attracted more and more attention due to their environmental friendliness,high element abundance,and low cost.Here,we developed a strategy of one-step gas-solid-phase diffusioninduced reaction to fabricate a series of bandgap-tunable Cu_(a)Agm_(1)Bim_(2)I_(n)/CuI bilayer films due to the atomic diffusion effect for the first time.By designing and regulating the sputtered Cu/Ag/Bi metal film thickness,the bandgap of Cu_(a)Agm_(1)Bim_(2)I_(n)/CuI could be reduced from 2.06 to 1.78 eV.Solar cells with the structure of FTO/TiO_(2)/Cu_(a)Agm_(1)Bim_(2)I_(n)/CuI/carbon were constructed,yielding a champion power conversion efficiency of 2.76%,which is the highest reported for this class of materials owing to the bandgap reduction and the peculiar bilayer structure.The current work provides a practical path for developing the next generation of efficient,stable,and environmentally friendly photovoltaic materials.展开更多
Ruthenium (Ru)‐based catalysts are widely employed in several types of gas‐solid reactions because of their high catalytic activities. This review provides theoretical research on Ru‐based catalysts and an analys...Ruthenium (Ru)‐based catalysts are widely employed in several types of gas‐solid reactions because of their high catalytic activities. This review provides theoretical research on Ru‐based catalysts and an analysis of their basic properties and oxidation behavior. There is particular emphasis on Ru‐catalyzed gas‐solid catalytic reactions, including the catalytic oxidation of VOCs, preferential oxidation of CO, synthesis of ammonia, oxidation of HCl and partial oxidation of CH4. Recent litera‐ture on catalysis is summarized and compared. Finally, we describe current challenges in the field and propose approaches for future development of Ru‐based catalysts.展开更多
The indirect detection method basic principle of rate and concentration,application range and research results on gassolid two phase flow were discussed.The present development situation and the existing problems of r...The indirect detection method basic principle of rate and concentration,application range and research results on gassolid two phase flow were discussed.The present development situation and the existing problems of rate and concentration detection technology were analyzed and summarized.Emphatically analyzed the existing problems in the industrial application and research status of electrostatic method in measuring phase concentration.Design criterion of electrostatic phase concentration sensor is given,the superiority and wide industrial application prospect of the sensor used for phase concentration measurement are clarified.展开更多
基金Supported by the National High Technology Research and Development Program of China (2006AA05A103), the National Natural Science Foundation of China (50706007), Foundation of Graduate Creative Program of Jiangsu (CX08B-060Z), and the Foundation for Excellent Ph.D. Thesis of Southeast University. ACKNOWLEDGEMENTS The authors also expressed sincere gratitude to Professors M. Horio, B. Leckner, A. Kane and E.J. Anthony for constructive advice during their visiting period in Southeast University, which contributed to our research.
文摘A computational study on the flow behavior of a gas-solid injector by Eulerian approach was carried out. The gas phase was modeled with k-ε turbulent model and the particle phase was modeled with kinetic theory of granular flow. The simulations by Eulerian two-fluid model (TFM) were compared with the corresponding results by discrete element method (DEM) and experiments. It was showed that TFM simulated results were in reasonable agreement with the experimental and DEM simulated results. Based on TFM simulations, gas-solid flow pattern, gas velocity, particle velocity and the static pressure under different driving jet velocity, backpressure and convergent section angle were obtained. The results showed that the time average axial gas velocity sharply decreased and then slightly increased to a constant value in the horizontal conveying pipe. The time average axial particle velocity increased initially and then decreased, but in the outlet region of the convergent section the particle velocity remarkably increased once more to the maximal value. As a whole, the static pressure distribution change trends were found to be independent on driving gas velocity, backpressure and convergent section angle. However, the static pressure increased with increase of convergent section angle and gas jet velocities. The difference of static pressure to backpressure increased with increasing backpressure.
基金This work was supported by National Natural Science Foundation of China(No.12222513).
文摘Radio frequency quadrupoles(RFQs),which are crucial components of proton injectors,significantly affect the performance of proton accelerator facilities.An RFQ with a high frequency of 714 MHz dedicated to compact proton injectors for medi-cal applications is designed in this study.The RFQ is designed to accelerate proton beams from 50 keV to 4 MeV within a short length of 2 m and can be matched closely with the downstream drift tube linac to capture more particles through a preliminary optimization.To develop an advanced RFQ,challenging techniques,including fabrication and tuning method,must be evaluated and verified using a prototype.An aluminium prototype is derived from the conceptual design of the RFQ and then redesigned to confirm the radio frequency performance,fabrication procedure,and feasibility of the tuning algorithm.Eventually,a new tuning algorithm based on the response matrix and least-squares method is developed,which yields favorable results based on the prototype,i.e.,the errors of the dipole and quadrupole components reduced to a low level after several tuning iterations.Benefiting from the conceptual design and techniques obtained from the prototype,the formal mechanical design of the 2-m RFQ is ready for the next manufacturing step.
文摘The nozzle inner-flow characteristic of the“spray G”injector was studied by the computational fluid dynamics(CFD)simulation,and the sensitivity of cycle fuel mass to the conicity and entrance radius of the nozzle hole were analyzed.Results show that the inner conicity of nozzle hole inhibits the development of cavitation phenomena,and increases the injection rate.While the outer conicity of nozzle hole promotes the diffusion of cavita-tion,leading to reductions of the liquid volume fraction of the nozzle outlet and the local flow resistance of the nozzle hole.The sensitivity of cycle fuel mass to inner-cone nozzle hole is stronger than that of the outer-cone noz-zle,especially at the smaller hole conicity.The increase of injection pressure enhances the sensitivity of the injection characteristics to the nozzle hole structure,in which inner-cone nozzle has higher sensitivity coefficient than the outer-cone nozzle hole.However,the increase of injection pressure aggravates the offset of liquid jet to the nozzle axis of the outer-cone nozzle hole.With the increase of the inner conicity of nozzle,the sensitivity of the injection characteristics to the entrance radius of the hole decreases.With the increase of the outer conicity of nozzle hole,the sensitivity of the injection characteristics to the entrance radius of the hole increases.
基金supported by the National Key Research and Development Program of China(2022YFB4100305).
文摘Under the pressure of carbon neutrality,many carbon capture,utilization and storage technologies have witnessed rapid development in the recent years,including oxy-fuel combustion(OFC)technology.However,the conventional OFC technology usually depends on the flue gas recirculation system,which faces significant investment,high energy consumption,and potential low-temperature corrosion problem.Considering these deficiencies,the direct utilization of pure oxygen to achieve particle fluidization and fuel combustion may reduce the overall energy consumption and CO_(2)-capture costs.In this paper,the fundamental structure of a self-designed 130 t·h^(-1) pure-oxygen combustion circulating fluidized bed(CFB)boiler was provided,and the computational particle fluid dynamics method was used to analyze the gas-solid flow characteristics of this new-concept boiler under different working conditions.The results indicate that through the careful selection of design or operational parameters,such as average bed-material size and fluidization velocity,the pure-oxygen combustion CFB system can maintain the ideal fluidization state,namely significant internal and external particle circulation.Besides,the contraction section of the boiler leads to the particle backflow in the lower furnace,resulting in the particle suspension concentration near the wall region being higher than that in the center region.Conversely,the upper furnace still retains the classic core-annulus flow structure.In addition to increasing solid circulation rate by reducing the average bed-material size,altering primary gas ratio and bed inventory can also exert varying degrees of influence on the gas-solid flow characteristics of the pure-oxygen combustion CFB boiler.
文摘The direct conversion of atmospheric CO_(2) into fuel via photocatalysis exhibits significant practical application value in advancing the carbon cycle.In this study,we established an electro-assisted photocatalytic system with dual compartments and interfaces,and coated Ag nanoparticles on the titanium nanotube arrays(TNTAs)by polydopamine modification.In the absence of sacrificial agent and alkali absorption liquid conditions,the stable,efficient and highly selective conversion of CO_(2) to CO at the gas-solid interface in ambient air was realized by photoelectric synergy.Specifically,with the assistance of potential,the CO formation rates reached 194.9μmol h^(−1) m^(−2) and 103.9μmol h^(−1) m^(−2) under ultraviolet and visible light irradiation,respectively;the corresponding CO_(2) conversion rates in ambient air were 30%and 16%,respectively.The excellent catalytic effect is mainly attributed to the formation of P–N heterojunction during the catalytic process and the surface plasmon resonance effect.Additionally,the introduction of solid agar electrolytes effectively inhibits the hydrogen evolution reaction and improves the electron utilization rate.This system promotes the development of photocatalytic technology for practical applications and provides new insights and support for the carbon cycle.
基金supported by Basic scientific research funding project of universities directly under the Inner Mongolia Autonomous Region(Grant No.JY20230077)the Natural Science Foundation of Inner Mongolia Funded Project(Grant No.2022FX01)+1 种基金Inner Mongolia Nature Joint Science Fund(Grant No.2023LHMS05023)Qiqihar University Educational Science Research Project(Grant No.GJQTYB202320).
文摘The quality of crushing,power consumption,and discharging performance of a straw crusher are greatly influenced by the characteristics of its internalflowfield.To enhance the straw crusher’sflowfield properties and improve the efficiency with which crushed material is discharged,first,the main structural parameters influencing the airflow in the crusher are discussed.Then,the coupled gas-solidflowfield in the straw crusher is numerically calculated through solution of the Navier-Stokes equations and application of the discrete element method(DEM).Finally,the discharge performance index of the crusher is examined through detailed analysis of the crushed material dynamics.Additionally,a multi-island genetic algorithm is used to optimize the structure and operational factors that have significant effects on the discharge performance.With optimization,the accumulation rate of crushed materials in the bottom region of the straw crusher decreases by 20.08%,and the massflow rate at the discharge outlet increases by 11.63%.
基金supported by the National Natural Science Foundation of China(Grant Nos.22275092,52102107 and 52372084)the Fundamental Research Funds for the Central Universities(Grant No.30923010920)。
文摘Energetic Semiconductor bridge(ESCB)based on reactive multilayered films(RMFs)has a promising application in the miniature and intelligence of initiator and pyrotechnics device.Understanding the ignition enhancement mechanism of RMFs on semiconductor bridge(SCB)during the ignition process is crucial for the engineering and practical application of advanced initiator and pyrotechnics devices.In this study,a one-dimensional(1D)gas-solid two-phase flow ignition model was established to study the ignition process of ESCB to charge particles based on the reactivity of Al/MoO_(3) RMFs.In order to fully consider the coupled exothermic between the RMFs and the SCB plasma during the ignition process,the heat release of chemical reaction in RMFs was used as an internal heat source in this model.It is found that the exothermal reaction in RMFs improved the ignition performance of SCB.In the process of plasma rapid condensation with heat release,the product of RMFs enhanced the heat transfer process between the gas phase and the solid charge particle,which accelerated the expansion of hot plasma,and heated the solid charge particle as well as gas phase region with low temperature.In addition,it made up for pressure loss in the gas phase.During the plasma dissipation process,the exothermal chemical reaction in RMFs acted as the main heating source to heat the charge particle,making the surface temperature of the charge particle,gas pressure,and gas temperature rise continuously.This result may yield significant advantages in providing a universal ignition model for miniaturized ignition devices.
基金supported by National Natural Science Foundation of China(Grant No.52072327,62074052,61874159)Zhongyuan Thousand Talents(Zhongyuan Scholars)Program of Henan Province(202101510004)+6 种基金Higher Education and Teaching Reformation Project(2014SJGLX064)Academic Degrees&Graduate Education Reform Project of Henan Province(2021SJGLX060Y)Key research and development projects of Universities in Henan Province(20A140026)the Scientific Research Innovation Team of Xuchang University(2022CXTD008)Science and Technology Project of Henan Province(222102230009).L.Ding thanks the National Key Research and Development Program of China(2022YFB3803300)the open research fund of Songshan Lake Materials Laboratory(2021SLABFK02)the National Natural Science Foundation of China(21961160720).
文摘Lead-free inorganic copper-silver-bismuth-halide materials have attracted more and more attention due to their environmental friendliness,high element abundance,and low cost.Here,we developed a strategy of one-step gas-solid-phase diffusioninduced reaction to fabricate a series of bandgap-tunable Cu_(a)Agm_(1)Bim_(2)I_(n)/CuI bilayer films due to the atomic diffusion effect for the first time.By designing and regulating the sputtered Cu/Ag/Bi metal film thickness,the bandgap of Cu_(a)Agm_(1)Bim_(2)I_(n)/CuI could be reduced from 2.06 to 1.78 eV.Solar cells with the structure of FTO/TiO_(2)/Cu_(a)Agm_(1)Bim_(2)I_(n)/CuI/carbon were constructed,yielding a champion power conversion efficiency of 2.76%,which is the highest reported for this class of materials owing to the bandgap reduction and the peculiar bilayer structure.The current work provides a practical path for developing the next generation of efficient,stable,and environmentally friendly photovoltaic materials.
基金supported by Beijing Natural Science Foundation (8164063)the Strategic Priority Research Program of the Chinese Academy of Sciences (XDB05050100)~~
文摘Ruthenium (Ru)‐based catalysts are widely employed in several types of gas‐solid reactions because of their high catalytic activities. This review provides theoretical research on Ru‐based catalysts and an analysis of their basic properties and oxidation behavior. There is particular emphasis on Ru‐catalyzed gas‐solid catalytic reactions, including the catalytic oxidation of VOCs, preferential oxidation of CO, synthesis of ammonia, oxidation of HCl and partial oxidation of CH4. Recent litera‐ture on catalysis is summarized and compared. Finally, we describe current challenges in the field and propose approaches for future development of Ru‐based catalysts.
基金Science and Technology on Electronic Test and Measurement Laboratory(No.9140C12040515X)
文摘The indirect detection method basic principle of rate and concentration,application range and research results on gassolid two phase flow were discussed.The present development situation and the existing problems of rate and concentration detection technology were analyzed and summarized.Emphatically analyzed the existing problems in the industrial application and research status of electrostatic method in measuring phase concentration.Design criterion of electrostatic phase concentration sensor is given,the superiority and wide industrial application prospect of the sensor used for phase concentration measurement are clarified.