The“shuttle effect”of polysulfides hampers the commercialization of lithium-sulfur(Li-S)batteries.Here,a thin molecular sieve film was decorated on the surface of an electrospun cellulose acetate(CA)membrane derived...The“shuttle effect”of polysulfides hampers the commercialization of lithium-sulfur(Li-S)batteries.Here,a thin molecular sieve film was decorated on the surface of an electrospun cellulose acetate(CA)membrane derived from recycled cigarette filters,where the truncated cone structureβ-cyclodextrin(β-CD)was selected as the building block to physically block and chemically trap polysulfides while simultaneously dramatically speeding up ion transport.Furthermore,on theβ-CD free side of the separator facing the cathode,graphite carbon(C)was sputtered as an upper current collector,which barely increases the thickness.These benefits result in an initial discharge performance of 1378.24 mAh g^(−1) and long-term cycling stability of 863.78 mAh g^(−1) after 1000 cycles at 0.2 C for the battery with theβ-CD/CA/C separator,which is more than three times that of the PP separator after 500 cycles.Surprisingly,the funnel-type channel ofβ-CD generates a differential ionic fluid pressure on both sides,speeding up ion transport by up to 69%,and a 65.3%faster charging rate of 9484 mA g^(−1) was achieved.The“funnel effect”of a separator is regarded as a novel and high-efficiency solution for fast charging of Li-S and other lithium secondary batteries.展开更多
A new gas-solid separator dedicated to heavy-oil fast pyrolysis process incorporating inertial and centrifugal separation was designed. Gas and typical fluid catalytic cracking （FCC） catalyst particles （with a dens...A new gas-solid separator dedicated to heavy-oil fast pyrolysis process incorporating inertial and centrifugal separation was designed. Gas and typical fluid catalytic cracking （FCC） catalyst particles （with a density of 1500 kg/m3, and a mean diameter of 45.81 p.m） were used in the study. The inlet gas velocity was kept constant at 13.36 m/s, while the solid loading at the inlet ranged from 0 to 700 g/m3. When the exhaust pipe opening was provided with two narrow-width slots near the inlet without baffles, the solid collection efficiency increased with an increasing solid loading at the inlet and was close to 95% along with a decreasing pressure drop. After increasing the secondary separation structure, the separation efficiency greatly improved. By adjusting the diameter of the secondary exhaust pipe, the separation efficiency and pressure drop could be balanced. Under the experimental conditions, when the diameter of the second exhaust pipe was equal to d=100 mm, the pressure drop was lower than 1400 Pa while the separation efficiency could exceed 99.50%; and when the diameter was equal to d=120 mm, the pressure drop was less than 700 Pa, with the separation efficiency reaching over 99.00%.展开更多
[Objective] This study aimed to establish an efficient process for separation of phycoerythrin by using Q Sepharose Fast Flow resin and verity its feasibility for scale-up. [Method] Elution gradient, sample volume and...[Objective] This study aimed to establish an efficient process for separation of phycoerythrin by using Q Sepharose Fast Flow resin and verity its feasibility for scale-up. [Method] Elution gradient, sample volume and flow rate were optimized to determine the optimal separation condition, under which the scale-up process was verified. [Result] The optimal condition for separation of phycoerythrin by using Q Sepharose FF resin was investigated： 30 ml of laver extract was loaded to the Q Sepharose FF column with a bed volume of 8 ml; subsequently, the column was stepwise eluted with 0-0.10-0.35-1.00 mol/L NaCI solution （pH 6.0） at a constant flow rate of 1 ml/min; the elution peak under 0.35 mol/L NaCI solution was collected, and the recovery rate and purity coefficient （A565/A280） of phycoerythrin were determined as 44.3 and 1.15, respectively. Based on the established process, 75 ml of phycoerythrin extract was loaded to the Q Sepharose FF column with a bed volume of 20 ml for separation, while no significant variation was observed in the separation result. [Conclusion] Phycoerythrin can be well separated from laver extract by using Q Sepharose FF resin and the process is feasible for scale-up.展开更多
The present study was aimed at the inlet particle spatial distribution of a gas-solid separator with high solid loading and investigated its effects on cyclone performance and the inner flow pattern.The flow fields of...The present study was aimed at the inlet particle spatial distribution of a gas-solid separator with high solid loading and investigated its effects on cyclone performance and the inner flow pattern.The flow fields of a cyclone with different rectangular particle flow areas on the inlet surface were numerically simulated using a four-way coupling method.The simulated results indicate that reducing the inlet particle flow area and lowing the inlet particle position can effectively reduce the scattered particles inside the cyclone separator and enhance the separation performance.Vertically gathering the particles to the centerline can also weaken the particle back-mixing.The particles near the roof account for the swirling particle ceiling phenomenon.The inlet particle spatial distribution affects the pressure drop mainly by affecting the gas tangential velocity in the cylinder body.Moreover,compared to the hori-zontal particle distribution on the inlet surface,the vertical particle distribution has greater effects on cyclone performance.展开更多
To meet the requirements for fast and efficient gas-solid separation at the outlet of a gas-solid concurrent downflow fluidized bed(downer),a new horizontal gas-solid rapid separator was designed based on the joint ac...To meet the requirements for fast and efficient gas-solid separation at the outlet of a gas-solid concurrent downflow fluidized bed(downer),a new horizontal gas-solid rapid separator was designed based on the joint action of centrifugal and inertial forces.Under the same experimental conditions,a fluid catalytic cracking(FCC)catalyst was used as the material(with a particle density of 1500 kg/m3 and a mean particle size of 45.8μm)to experimentally investigate the effects of the insertion length of gas outlet pipe,the bypass cylinder,the gas outlet direction,and the secondary separation structure on the separator performance.The results showed that with an inlet gas flow rate of 14.5 m/s and a gas phase solid content of 60―835 g/m3,the downer system achieved a gas-solid separation efficiency of above 99.5%,with the separator’s pressure drop within 1846 Pa(when the separator included a bypass cylinder and a secondary separation structure with a proper insertion length of gas outlet pipe).展开更多
Relaxation and diffusion measurements were carried out on single and binary liquids filling the pore space of controlled porous glass Vycor with an average pore size of about 4 nm.The dispersion of the longitudinal re...Relaxation and diffusion measurements were carried out on single and binary liquids filling the pore space of controlled porous glass Vycor with an average pore size of about 4 nm.The dispersion of the longitudinal relaxation time Tr is discussed as a means to identify liquid-surface interaction based on existing models developed for metal-free glass surfaces.In addition,the change of T1 and T2 with respect to their bulk values is discussed,in particular T2 serves as a probe for the strength of molecular interactions.As the native glass surface is polar and contains a large amount of hydroxyl groups,a pronounced interaction of polar and protic adsorbate liquids is expected;however,the T dispersion,and the corresponding reduction of T2,are also observed for non-polar liquids such as alkanes and cyclohexane.Deuterated liquids are employed for simplifying data analysis in binary systems,but also for separating the respective contributions of intra-and intermolecular interactions to the overall relaxation rate.Despite the lack of paramagnetic impurities in the glass material,H and 2H relaxation dispersions of equivalent molecules are frequently found to differ from each other,suggesting intermolecular relaxation mechanisms for the'H nuclei.The variation of the T dispersion when comparing single and binary systems gives clear evidence for the preferential adsorption of one of the two liquids,suggesting complete phase separation in several cases.Measurement of the apparent tortuosity by self-diffusion experiments supports the concept of a local variation of sample composition within the porespace.展开更多
文章提出了一种有效分离并重构信号的数字化方案。信号A和信号B通过加法器叠加成信号C,对信号C进行快速傅里叶变换,再通过直接数字合成(Direct Digital Synthesizer,DDS)模块分别输出重构信号A′和重构信号B′。测试结果表明:当输入信号...文章提出了一种有效分离并重构信号的数字化方案。信号A和信号B通过加法器叠加成信号C,对信号C进行快速傅里叶变换,再通过直接数字合成(Direct Digital Synthesizer,DDS)模块分别输出重构信号A′和重构信号B′。测试结果表明:当输入信号为1时,V PP的正弦波或者三角波频率在10~100 kHz。所提方案能够有效分离出2路重构信号,重构信号无失真、无漂移,能够调节2路信号相位差。展开更多
基金the Jiangsu Provincial Key Research and Development Program(BE2017060)the China Postdoctoral Science Foundation(169483)the 111 Project(B17021)。
文摘The“shuttle effect”of polysulfides hampers the commercialization of lithium-sulfur(Li-S)batteries.Here,a thin molecular sieve film was decorated on the surface of an electrospun cellulose acetate(CA)membrane derived from recycled cigarette filters,where the truncated cone structureβ-cyclodextrin(β-CD)was selected as the building block to physically block and chemically trap polysulfides while simultaneously dramatically speeding up ion transport.Furthermore,on theβ-CD free side of the separator facing the cathode,graphite carbon(C)was sputtered as an upper current collector,which barely increases the thickness.These benefits result in an initial discharge performance of 1378.24 mAh g^(−1) and long-term cycling stability of 863.78 mAh g^(−1) after 1000 cycles at 0.2 C for the battery with theβ-CD/CA/C separator,which is more than three times that of the PP separator after 500 cycles.Surprisingly,the funnel-type channel ofβ-CD generates a differential ionic fluid pressure on both sides,speeding up ion transport by up to 69%,and a 65.3%faster charging rate of 9484 mA g^(−1) was achieved.The“funnel effect”of a separator is regarded as a novel and high-efficiency solution for fast charging of Li-S and other lithium secondary batteries.
文摘A new gas-solid separator dedicated to heavy-oil fast pyrolysis process incorporating inertial and centrifugal separation was designed. Gas and typical fluid catalytic cracking （FCC） catalyst particles （with a density of 1500 kg/m3, and a mean diameter of 45.81 p.m） were used in the study. The inlet gas velocity was kept constant at 13.36 m/s, while the solid loading at the inlet ranged from 0 to 700 g/m3. When the exhaust pipe opening was provided with two narrow-width slots near the inlet without baffles, the solid collection efficiency increased with an increasing solid loading at the inlet and was close to 95% along with a decreasing pressure drop. After increasing the secondary separation structure, the separation efficiency greatly improved. By adjusting the diameter of the secondary exhaust pipe, the separation efficiency and pressure drop could be balanced. Under the experimental conditions, when the diameter of the second exhaust pipe was equal to d=100 mm, the pressure drop was lower than 1400 Pa while the separation efficiency could exceed 99.50%; and when the diameter was equal to d=120 mm, the pressure drop was less than 700 Pa, with the separation efficiency reaching over 99.00%.
基金Supported by National Natural Science Foundation of China(51143012)Natural Science Foundation of Shandong Province(ZR2009BM006)~~
文摘[Objective] This study aimed to establish an efficient process for separation of phycoerythrin by using Q Sepharose Fast Flow resin and verity its feasibility for scale-up. [Method] Elution gradient, sample volume and flow rate were optimized to determine the optimal separation condition, under which the scale-up process was verified. [Result] The optimal condition for separation of phycoerythrin by using Q Sepharose FF resin was investigated： 30 ml of laver extract was loaded to the Q Sepharose FF column with a bed volume of 8 ml; subsequently, the column was stepwise eluted with 0-0.10-0.35-1.00 mol/L NaCI solution （pH 6.0） at a constant flow rate of 1 ml/min; the elution peak under 0.35 mol/L NaCI solution was collected, and the recovery rate and purity coefficient （A565/A280） of phycoerythrin were determined as 44.3 and 1.15, respectively. Based on the established process, 75 ml of phycoerythrin extract was loaded to the Q Sepharose FF column with a bed volume of 20 ml for separation, while no significant variation was observed in the separation result. [Conclusion] Phycoerythrin can be well separated from laver extract by using Q Sepharose FF resin and the process is feasible for scale-up.
基金supported by the Key Project of the National Fourteen-Five Year Research Program of China(grant No.2022YFB4100303).
文摘The present study was aimed at the inlet particle spatial distribution of a gas-solid separator with high solid loading and investigated its effects on cyclone performance and the inner flow pattern.The flow fields of a cyclone with different rectangular particle flow areas on the inlet surface were numerically simulated using a four-way coupling method.The simulated results indicate that reducing the inlet particle flow area and lowing the inlet particle position can effectively reduce the scattered particles inside the cyclone separator and enhance the separation performance.Vertically gathering the particles to the centerline can also weaken the particle back-mixing.The particles near the roof account for the swirling particle ceiling phenomenon.The inlet particle spatial distribution affects the pressure drop mainly by affecting the gas tangential velocity in the cylinder body.Moreover,compared to the hori-zontal particle distribution on the inlet surface,the vertical particle distribution has greater effects on cyclone performance.
基金The authors gratefully acknowledge the financial support from the National Natural Science Foundation of China(21576294 and 21706287).
文摘To meet the requirements for fast and efficient gas-solid separation at the outlet of a gas-solid concurrent downflow fluidized bed(downer),a new horizontal gas-solid rapid separator was designed based on the joint action of centrifugal and inertial forces.Under the same experimental conditions,a fluid catalytic cracking(FCC)catalyst was used as the material(with a particle density of 1500 kg/m3 and a mean particle size of 45.8μm)to experimentally investigate the effects of the insertion length of gas outlet pipe,the bypass cylinder,the gas outlet direction,and the secondary separation structure on the separator performance.The results showed that with an inlet gas flow rate of 14.5 m/s and a gas phase solid content of 60―835 g/m3,the downer system achieved a gas-solid separation efficiency of above 99.5%,with the separator’s pressure drop within 1846 Pa(when the separator included a bypass cylinder and a secondary separation structure with a proper insertion length of gas outlet pipe).
基金Financial support by the Deutsche Forschungsgemeinschaft(STA 511/15-1 and STA 511/15-2)is gratefully acknowledged。
文摘Relaxation and diffusion measurements were carried out on single and binary liquids filling the pore space of controlled porous glass Vycor with an average pore size of about 4 nm.The dispersion of the longitudinal relaxation time Tr is discussed as a means to identify liquid-surface interaction based on existing models developed for metal-free glass surfaces.In addition,the change of T1 and T2 with respect to their bulk values is discussed,in particular T2 serves as a probe for the strength of molecular interactions.As the native glass surface is polar and contains a large amount of hydroxyl groups,a pronounced interaction of polar and protic adsorbate liquids is expected;however,the T dispersion,and the corresponding reduction of T2,are also observed for non-polar liquids such as alkanes and cyclohexane.Deuterated liquids are employed for simplifying data analysis in binary systems,but also for separating the respective contributions of intra-and intermolecular interactions to the overall relaxation rate.Despite the lack of paramagnetic impurities in the glass material,H and 2H relaxation dispersions of equivalent molecules are frequently found to differ from each other,suggesting intermolecular relaxation mechanisms for the'H nuclei.The variation of the T dispersion when comparing single and binary systems gives clear evidence for the preferential adsorption of one of the two liquids,suggesting complete phase separation in several cases.Measurement of the apparent tortuosity by self-diffusion experiments supports the concept of a local variation of sample composition within the porespace.
文摘文章提出了一种有效分离并重构信号的数字化方案。信号A和信号B通过加法器叠加成信号C,对信号C进行快速傅里叶变换,再通过直接数字合成(Direct Digital Synthesizer,DDS)模块分别输出重构信号A′和重构信号B′。测试结果表明:当输入信号为1时,V PP的正弦波或者三角波频率在10~100 kHz。所提方案能够有效分离出2路重构信号,重构信号无失真、无漂移,能够调节2路信号相位差。
