Insights into measurements of water-soluble ions in PM_(2.5)and their gaseous precursors in Beijing

To better understand the characteristics and transformation mechanisms of secondary inorganic aerosols,hourly mass concentrations of water-soluble inorganic ions(WSIIs)in PM_(2.5)and their gaseous precursors were measured online from 2016 to 2018 at an urban site in Beijing.Seasonal and diurnal variations in water-soluble ions and gaseous precursors were discussed and their gas-particle conversion and partitioning were also examined,some related parameters were characterized.The(TNH_(3))Rich was also defined to describe the variations of the excess NH_(3)in different seasons.In addition,a sensitivity test was carried out by using ISORROPIA II to outline the driving factors of gas-particle partitioning.In Beijing,the relative contribution of nitrate to PM_(2.5)has increased markedly in recent years,especially under polluted conditions.In the four seasons,only a small portion of NO_(2)in the atmosphere was converted into total nitrate(TNO_(3)),and more than 80%of TNO_(3)occurred in the form of nitrate due to the abundant ammonia.The concentration of total ammonia(TNH_(3))was much higher than that required to neutralize acid gases,and most of the TNH_(3)occurred as gaseous NH_(3).The nitrous acid(HONO)concentration was highly correlated with NH_(3)concentration and had increased significantly in Beijing compared with previous studies.The total chloride(TCl)was the highest in winter,andε(Cl^(-))was more sensitive to variations in the ambient temperature(T)and relative humidity(RH)thanε(NO_(3)^(-)).

Evolution and meteorological causes of fine particulate explosive growth events in Beijing, China, from 2013 to 2017

Based on online observations of fine particulate matter(PM2.5) for five consecutive years from January 2013 to December 2017 in Beijing, combined with simultaneous measurement of gaseous precursors and meteorological parameters, the evolution and meteorological causes of fineparticle explosive growth(FPEG) events were analyzed. During the 5-year observation period,132 FPEG events were observed and these events were further divided into three types(3-, 6-, and 9-h events) according to their evolution duration. The majority of FPEG events were observed in winter under the conditions of higher gas precursor concentrations and unfavorable meteorological conditions. The average concentration of PM2.5 during winter FPEG events changed little from 2013 to 2016, whereas it decreased significantly in 2017, in accordance with the similar variation of gaseous species(SO2, NO2, and CO). In addition, the higher wind speeds and lowest relative humidity observed in 2017 were also conducive to the decrease in PM2.5. The evolutions of FPEG events and normal haze episodes were analyzed, revealing that the rate of increase in NO2 was much greater than that of SO2, suggesting more of a contribution from mobile sources than stationary sources. The polar Plot results suggest that the transportation from the southeast area of Beijing plays a major role in the formation of 3-h events, whereas local emissions is the main contributory factor for 9-h events and normal haze episodes. However, further quantitative analysis regarding the contributions of these factors is still needed.

Aqueous synthesis of CdSe and CdSe/CdS quantum dots with controllable introduction of Se and S sources

A new and convenient route is developed to synthesize CdSe and core-shell CdSe/CdS quantum dots（QDs） in aqueous solution.The gaseous precursors,H2Se and H2S,generated on-line by reducing SeO 3 2à with NaBH 4 and the reaction between Na 2 S and diluted H2SO 4,are used to form high-quality CdSe and CdSe/CdS QDs,respectively.The synthesized water-soluble CdSe and CdSe/CdS QDs possess high quantum yield（3% and 20%） and narrow full-width-at-half-maximum（43 nm and 38 nm）.The synthesis process is easily reproducible with simple apparatus and low-toxic chemicals,and can be readily extended to the large-scale aqueous synthesis of QDs.