Comparison of the Mutagenicity of Exhaust Emissions From Motor Vehicles Using Leaded and Unleaded Gasoline as Fuel

While Unleaded gasoline has the advantage of eliminating lead from automobile exhaust, its potential to reduce the exhaust gas and particles, merits further examination. In the present studies,the concentrations of hydrocarbons (HC) and earbon monoxides (CO) in emissions were analyzed on Santana engine Dynamometer under a standard test cycle, and total exhaust particles were collected from engines using leaded and unleaded gasoline. It was found that unleaded gasoline reduced the emissions of CO and HC, and decreased the quantity of vehicle exhaust particulate matters by 60%.With the unlead gasoline, only 23 kinds of organic substances, adsorbed in the particles, were identified by gas chromatography/mass spectrometer (GC/MS) while 32 components were detected using the leaded gasoline. The results of in vitro Salmonella/ microsomal test and micronucleus induction assay in CHL cells indicated that both types of gasoline increased the number of histidine-independent colonies and the frequencies of micronucleus induction; no significant differellce was found in their mutagenicity.

Emission profiling of diesel and gasoline cars at a city traffic junction

In congested urban roads, cars must stop at intersections because of city traffic lights. As a result, pedestri- ans and traffic police personnel are exposed to pollutants emanating from the tailpipe of various vehicles at such city trafficjunctions. In this study, various gasoline- and diesel-fueled cars complying with differ- ent emission standards were tested for their emissions in simulated city traffic junction conditions. The engine exhaust from these cars was subjected to physicochemical characterization at different engine speeds under no-load conditions. These engine conditions were chosen because the cars idle at differ- ent engine speeds at a city traffic junction. Gravimetric and real-time measurements were performed for the tailpipe exhaust sampled from these vehicles. Exhaust particles were collected on 47 mm diameter quartz filter papers and subjected to gravimetric analysis for determining the total particulate mass （TPM） and trace metals while the engines were operated at two different engine idling speeds, 1500 rpm （representing low idling） and 2500 rpm （representing high idling）. At similar engine operating condi- tions, TPM and trace metals were lower for the exhaust from gasoline engines compared to the exhaust from diesel engines. Real-time measurements were performed for particle-bound poly-aromatic hydro- carbons （PAHs）, particle number and size distribution, regulated gaseous emissions and smoke opacity of the exhaust at four different engine speeds, 1500, 2000, 2500, and 3000 rpm. Particle-bound PAHs showed a decreasing trend for the vehicles that complied with stricter vehicular emission standards. Higher particle peak number concentrations were observed for diesel exhausts compared to the results for gasoline exhaust. Regulated gaseous emissions were also comoared.

Potential of secondary aerosol formation from Chinese gasoline engine exhaust

Light-duty gasoline vehicles have drawn public attention in China due to their significant primary emissions of particulate matter and volatile organic compounds（VOCs）. However,little information on secondary aerosol formation from exhaust for Chinese vehicles and fuel conditions is available. In this study, chamber experiments were conducted to quantify the potential of secondary aerosol formation from the exhaust of a port fuel injection gasoline engine. The engine and fuel used are common in the Chinese market, and the fuel satisfies the China V gasoline fuel standard. Substantial secondary aerosol formation was observed during a 4–5 hr simulation, which was estimated to represent more than 10 days of equivalent atmospheric photo-oxidation in Beijing. As a consequence, the extreme case secondary organic aerosol（SOA） production was 426 ± 85 mg/kg-fuel, with high levels of precursors and OH exposure. The low hygroscopicity of the aerosols formed inside the chamber suggests that SOA was the dominant chemical composition. Fourteen percent of SOA measured in the chamber experiments could be explained through the oxidation of speciated single-ring aromatics. Unspeciated precursors, such as intermediate-volatility organic compounds and semi-volatile organic compounds, might be significant for SOA formation from gasoline VOCs. We concluded that reductions of emissions of aerosol precursor gases from vehicles are essential to mediate pollution in China.