From the mathematical principles, the generalized potential theory can be employed to create constitutive model of geomaterial directly. The similar Cam-clay model, which is created based on the generalized potential ...From the mathematical principles, the generalized potential theory can be employed to create constitutive model of geomaterial directly. The similar Cam-clay model, which is created based on the generalized potential theory, has less assumptions,clearer mathematical basis, and better computational accuracy. Theoretically, it is more scientific than the traditional Cam-clay models. The particle flow code PFC3 D was used to make numerical tests to verify the rationality and practicality of the similar Cam-clay model. The verification process was as follows: 1) creating the soil sample for numerical test in PFC3 D, and then simulating the conventional triaxial compression test, isotropic compression test, and isotropic unloading test by PFC3D; 2)determining the parameters of the similar Cam-clay model from the results of above tests; 3) predicting the sample's behavior in triaxial tests under different stress paths by the similar Cam-clay model, and comparing the predicting results with predictions by the Cam-clay model and the modified Cam-clay model. The analysis results show that the similar Cam-clay model has relatively high prediction accuracy, as well as good practical value.展开更多
In this paper we consider that the momentum of a free particle motion withhigh-level speed presenting nonlinear effects may be expanded by using Laurent seriesand then obtain the complete expression of nonlinear and u...In this paper we consider that the momentum of a free particle motion withhigh-level speed presenting nonlinear effects may be expanded by using Laurent seriesand then obtain the complete expression of nonlinear and unsteady momentum. These nonlinear and unsieady phenoniena of high-level speed may further expand to the theory of kinematics and it may be determined by Fredholm's integral equation of the first kind. In addition, according to the nonlinear and unsteady momentum obtained the relations of the nonlinear mechanics equations .work and energy, mass and energymay be derived.Finaly .this paper also calculates those experimental results which done in particle physics for mu-mesons u±and fast neutrons n, these results are in agreement with data perfectly.展开更多
This paper deals with the solution of a parametric equation with generalized boundary condiiton in transport theory. It gives the distribution of parameter (so called delta-eigenvalue [1]) with which the equation has ...This paper deals with the solution of a parametric equation with generalized boundary condiiton in transport theory. It gives the distribution of parameter (so called delta-eigenvalue [1]) with which the equation has non-zero solution. A necessary and sufficient condition for the existence of; he control critical eigenvalue delta0 is established.展开更多
In this article,studies on the multimode excitation problem of waveguides and antennas,the balance/unbalance mech-anism and the balanced feeding techniques in dipole antenna systems are first briefly historically revi...In this article,studies on the multimode excitation problem of waveguides and antennas,the balance/unbalance mech-anism and the balanced feeding techniques in dipole antenna systems are first briefly historically reviewed.In this context,general-ized odd-even mode theory is advanced to quantitatively and approximately describe the mutual coupling effect between a feed line and an antenna.As is mathematically deduced and demonstrated,the modal parity mismatch between the feed line and the antenna should ultimately dominate the unbalance phenomenon in antenna systems.Thus,an elegant,closed-form formula is derived to ap-proximately calculate the“unbalance degree”of a straight dipole off-center fed by a symmetric twin-wire line.Design approaches for the simplest,linear,1-D multimode resonant antennas are introduced.Moreover,the“falling tone excitation”law gauged based on prototype dipoles is revealed and used to develop a mode synthesis design approach for microstrip patch antennas(MPAs)and 2-D sectorial electric dipole antennas.Design examples with distinctive radiation performance are presented and discussed.Finally,possible development trends of multimode resonant antennas are prospected.展开更多
Direct coal liquefaction(DCL)is an important and effective method of converting coal into high-valueadded chemicals and fuel oil.In DCL,heating the direct coal liquefaction solvent(DCLS)from low to high temperature an...Direct coal liquefaction(DCL)is an important and effective method of converting coal into high-valueadded chemicals and fuel oil.In DCL,heating the direct coal liquefaction solvent(DCLS)from low to high temperature and pre-hydrogenation of the DCLS are critical steps.Therefore,studying the dissolution of hydrogen in DCLS under liquefaction conditions gains importance.However,it is difficult to precisely determine hydrogen solubility only by experiments,especially under the actual DCL conditions.To address this issue,we developed a prediction model of hydrogen solubility in a single solvent based on the machine-learning quantitative structure–property relationship(ML-QSPR)methods.The results showed that the squared correlation coefficient R^(2)=0.92 and root mean square error RMSE=0.095,indicating the model’s good statistical performance.The external validation of the model also reveals excellent accuracy and predictive ability.Molecular polarization(a)is the main factor affecting the dissolution of hydrogen in DCLS.The hydrogen solubility in acyclic alkanes increases with increasing carbon number.Whereas in polycyclic aromatics,it decreases with increasing ring number,and in hydrogenated aromatics,it increases with hydrogenation degree.This work provides a new reference for the selection and proportioning of DCLS,i.e.,a solvent with higher hydrogen solubility can be added to provide active hydrogen for the reaction and thus reduce the hydrogen pressure.Besides,it brings important insight into the theoretical significance and practical value of the DCL.展开更多
Due to the influence of deep-sea environment,deep-sea sediments are usually heterogeneous,and their moduli of elasticity and density change as depth changes.Combined with the characteristics of deep-sea sediments,the ...Due to the influence of deep-sea environment,deep-sea sediments are usually heterogeneous,and their moduli of elasticity and density change as depth changes.Combined with the characteristics of deep-sea sediments,the thermo-hydro-mechanical coupling dynamic response model of heterogeneous saturated porous sediments can be established to study the influence of elastic modulus,density,frequency,and load amplitude changes on the model.Based on the Green-Lindsay generalized thermoelasticity theory and Darcy’s law,the thermo-hydro-mechanical coupled dynamic response model and governing equations of heterogeneous deep-sea sediments with nonlinear elastic modulus and density are established.The analytical solutions of dimensionless vertical displacement,vertical stress,excess pore water pressure,and temperature are obtained by means of normal modal analysis,which are depicted graphically.The results show that the changes of elastic modulus and density have few effects on vertical displacement,vertical stress,and temperature,but have great effects on excess pore water pressure.When the mining machine vibrates,the heterogeneity of deep-sea sediments has great influence on vertical displacement,vertical stress,and excess pore water pressure,but has few effects on temperature.In addition,the vertical displacement,vertical stress,and excess pore water pressure of heterogeneous deep-sea sediments change more gently.The variation trends of physical quantities for heterogeneous and homogeneous deep-sea sediments with frequency and load amplitude are basically the same.The results can provide theoretical guidance for deep-sea mining engineering construction.展开更多
We propose a method for mOdeling azimuthal AVO responses from a fractured i reflector. The method calculates the integrated reflected wavetrains, and the wavetrains contain elastodynamic information including the con...We propose a method for mOdeling azimuthal AVO responses from a fractured i reflector. The method calculates the integrated reflected wavetrains, and the wavetrains contain elastodynamic information including the contrast in impedance and anelasticity i across interfaces, the intemal anisotropic propagation, the dispersion and attenuation along i the wave path, and tuning and interference. The results suggest that for large angles of incidence, the velocity dispersion and attenuation increase the amplitudes of PP waves from the top and decrease those from the bottom. For azimuthal responses at specific angles of incidence, the reflected wavetrains of PP waves tend to have longer duration with increasing azimuth. In contrast, model-converted PSV and PSH reflections show stable azimuthal features and are less affected by the reflector thickness. The amplitudes of PSV reflections increase with increasing azimuth; moreover, the waves have no reflection energy at 0° and 90° azimuth and maximum amplitude at 45° azimuth.展开更多
Based on the test data of frictional materials and previous research achievements in this field, a generalized non-linear strength theory (GNST) is proposed. It describes non-linear strength properties on the π-plane...Based on the test data of frictional materials and previous research achievements in this field, a generalized non-linear strength theory (GNST) is proposed. It describes non-linear strength properties on the π-plane and the meridian plane using a unified formula, and it includes almost all the present non-linear strength theories, which can be used in just one material. The shape of failure function of the GNST is a smooth curve between the SMP criterion and the Mises criterion on the π-plane, and an exponential curve on the meridian plane. Through the transformed stress space based on the GNST, the combination of the GNST and various constitutive models using p and q as stress parameters can be realized simply and rationally in three-dimensional stress state. Keywords generalized non-linear strength theory (GNST) - transformed stress - constitutive model - application展开更多
The behavior of soil-structure interface plays a major role in the definition of soil-structure interaction. In this paper a bi-potential surface elasto-plastic model for soil-structure interface is proposed in order ...The behavior of soil-structure interface plays a major role in the definition of soil-structure interaction. In this paper a bi-potential surface elasto-plastic model for soil-structure interface is proposed in order to describe the interface deformation behavior,including strain softening and normal dilatancy. The model is formulated in the framework of generalized potential theory,in which the soil-structure interface problem is regard as a two-dimensional mathematical problem in stress field,and plastic state equations are used to replace the traditional field surface. The relation curves of shear stress and tangential strain are fitted by a piecewise function composed by hyperbolic functions and hyperbolic secant functions,while the relation curves of normal strain and tangential strain are fitted by another piecewise function composed by quadratic functions and hyperbolic secant functions. The approach proposed has the advantage of deriving an elastoplastic constitutive matrix without postulating the plastic potential functions and yield surface. Moreover,the mathematical principle is clear,and the entire model parameters can be identified by experimental tests. Finally,the predictions of the model have been compared with experimental results obtained from simple shear tests under normal stresses,and results show the model is reasonable and practical.展开更多
Porous materials can be found in a variety of geophysical and engineering applications.The existence of thermal contact resistance at the interface between bilayered saturated porous strata would result in a significa...Porous materials can be found in a variety of geophysical and engineering applications.The existence of thermal contact resistance at the interface between bilayered saturated porous strata would result in a significant temperature difference at the interface.An attempt is made to study the thermo-hydro-mechanical coupling dynamic response of bilayered saturated porous strata with thermal contact resistance and elastic wave impedance.The corresponding analytical solutions for the dynamic response of bilayered saturated porous strata under a harmonic thermal load are derived by the operator decomposition method,and their rationality is verified by comparing them with existing solutions.The influences of thermal contact resistance,thermal conductivity ratio,and porosity ratio on the dynamic response of bilayered saturated porous strata are systematically investigated.Outcomes disclose that with the increase of thermal contact resistance,the displacement,pore water pressure and stress decrease gradually,and the temperature jump at the interface between two saturated porous strata increases.展开更多
By systematically studying seismic strengthening areas before 85 earthquakes with M>=6.0 in China, some results have been extracted. 1) Earthquake active strengthening area exists universally before strong shock o...By systematically studying seismic strengthening areas before 85 earthquakes with M>=6.0 in China, some results have been extracted. 1) Earthquake active strengthening area exists universally before strong shock or great earthquake; 2) The size of the strengthening area and its appearing time will increase when the earthquake magnitude increases; 3) The rate between the size of seismic strengthening area and the size of the source region decreases when earthquake magnitude increases; 4) The appearing time of the earthquake active strengthening region in the eastern part of China is longer than that in the western part of China. The above characteristics have been preliminarily explained qualitatively and half-quantitatively by applying the strong body earthquake generating model and the hard inclusion theory. Then applying the seismic strengthening area, we have obtained long-term predictions of 2 earthquakes, so the seismic strengthening area before strong earthquake or great earthquakes is a universal phenomenon, which has some mechanical base.展开更多
The excessive deformation of deep-sea sediments caused by the vibration of the mining machine will adversely affect the efficiency and safety of mining.Combined with the deep-sea environment,the coupled thermo-hydro-m...The excessive deformation of deep-sea sediments caused by the vibration of the mining machine will adversely affect the efficiency and safety of mining.Combined with the deep-sea environment,the coupled thermo-hydro-mechanical problem for saturated porous deep-sea sediments subject to the vibration of the mining vehicle is investigated.Based on the Green-Lindsay(G-L)generalized thermoelastic theory and Darcy’s law,the model of thermo-hydro-mechanical dynamic responses for saturated porous deep-sea sediments under the vibration of the mining vehicle is established.We obtain the analytical solutions of non-dimensional vertical displacement,excess pore water pressure,vertical stress,temperature,and change in the volume fraction field with the normal mode analysis method,and depict them graphically.The normal mode analysis method uses the canonical coordinate transformation to solve the equation,which can quickly decouple the equation by ignoring the modal coupling effect on the basis of the canonical mode.The results indicate that the vibration frequency has obvious influence on the vertical displacement,excess pore water pressure,vertical stress,and change in volume fraction field.The loading amplitude has a great effect on the physical quantities in the foundation,and the changes of the physical quantities increase with the increase in loading amplitude.展开更多
The mechanical behaviors of the interface between coarse-grained soil and concrete were investigated by simple shear tests under condition of mixed soil slurry (bentonite mixed with cement grout).For comparison,the in...The mechanical behaviors of the interface between coarse-grained soil and concrete were investigated by simple shear tests under condition of mixed soil slurry (bentonite mixed with cement grout).For comparison,the interfaces both without slurry and with bentonite slurry were analyzed.The experimental results show that different slurries exert much influence on the strength and deformation of soil/structure interface.Under mixed soil slurry,strain softening and shear dilatation are observed,while shear dilatation appears under the small normal stress of the interface without slurry,and shear contraction is significant under the condition of the bentonite slurry.The thickness of the interface was determined by analyzing the disturbed height of the sample with both simple shear test and particle flow code (PFC).An elasto-plastic constitutive model incorporating strain softening and dilatancy for thin layer element of interface was formulated in the framework of generalized potential theory.The relation curves of shear stress and shear strain,as well as the relation curves of normal strain and shear strain,were fitted by a piecewise function composed by hyperbolic functions and resembling normal functions.The entire model parameters can be identified by tests.The new model is verified by comparing the measured data of indoor cut-off wall model tests with the predictions from finite element method (FEM).The FEM results indicate that the stress of wall calculated by using Goodman element is too large,and the maximum deviation between the test data and prediction is about 45%.While the prediction from the proposed model is close to the measured data,and the error is generally less than 10%.展开更多
At present, associated flow rule of traditional plastic theory is adopted in the slip line field theory and upper bound method of geotechnical materials. So the stress characteristic line conforms to the velocity line...At present, associated flow rule of traditional plastic theory is adopted in the slip line field theory and upper bound method of geotechnical materials. So the stress characteristic line conforms to the velocity line. It is proved that geotechnical materials do not abide by the associated flow rule. It is impossible for the stress characteristic line to conform to the velocity line. Generalized plastic mechanics theoretically proved that plastic potential surface intersects the Mohr-Coulomb yield surface with an angle, so that the velocity line must be studied by non-associated flow rule. According to limit analysis theory, the theory of slip line field is put forward in this paper, and then the ultimate beating capacity of strip footing is obtained based on the associated flow rule and the non-associated flow nile individually. These two results are identical since the ultimate bearing capacity is independent of flow role. On the contrary, the velocity fields of associated and non-associated flow rules are different which shows the velocity field based on the associat- ed flow rule is incorrect.展开更多
Based on nonlocal thermoelastic theory, this article studies the reflection of waves in nanometersemi-conductor media. Firstly, the governing equations are established based on couplednonlocal elasticity theory, pl...Based on nonlocal thermoelastic theory, this article studies the reflection of waves in nanometersemi-conductor media. Firstly, the governing equations are established based on couplednonlocal elasticity theory, plasma diffusion equation, and moving equation. Then, using theharmonic method, the solution of the dissipation equation and the analytic expression of thereflection coefficient rate are obtained. Finally, the influences of nonlocal parameters on wavevelocities are showed graphically. It is found that after the introduction of nonlocal effect, thephase and group velocities all show the attenuation, and as the frequency increases, the nonlocalparameter is bigger, and the decay rate is faster. The reflection coefficient rate varies greatly withdifferent theories, with different reflection coefficient rates depending on the incident angle.展开更多
Thailand has currently enhanced and promoted intensive trade and investment liberalization and implemented long-term growth policy according with current regional economic integration, WTO obligations and globalizatio...Thailand has currently enhanced and promoted intensive trade and investment liberalization and implemented long-term growth policy according with current regional economic integration, WTO obligations and globalization. Nevertheless, several recent internal and external factors e.g. the massive SARS and avian flu outbreaks, the Indian Ocean tsunami devastation, the Asia financial crisis and domestic policy reforms (ICSEAD, 2006) have also impeded this policy. While the issues are important for Thailand and developing countries in Asia, only limited research has been undertaken to investigate them. The paper conducts a substantive quantitative study to contribute to these trade and development policy issues. A new econometric modelling policy method, namely the generalized gravity theory (Tran Van Hoa, 2004) is used to develop a simple flexible simultaneous-equation econometric model of Thailand's openness model with its seven major trade partners (ASEAN-4, Australia, the USA, the EU, China, Japan and India). Using data from the ICSEAD, the World Development Indicators and the Bank of Thailand databases, the paper reveals efficient and reliable empirical findings on trade-growth causality, trade determination including the impact of shocks and policy reform on trade and growth between Thailand and its major trade partners over the past two decades. The paper also provides evidence on the linkages between trade in goods, FDI and services and regional economic integration for more credible policy implications.展开更多
The biexponential distributions of open times are observed in various types of ion channels. In this paper, by discussing a simple channel model, we show that there are two different schemes to understand the biexpone...The biexponential distributions of open times are observed in various types of ion channels. In this paper, by discussing a simple channel model, we show that there are two different schemes to understand the biexponential distribution of open times. One scheme is mathematically strict based on generator matrix theory, while the other one has a clear physical explanation according to an approximation process with numerical simulation of Markovian channel dynamics. Our comparison results suggest that even for biologically complex channels, in addition to carrying out a stochastic simulation, the strict theoretical analysis should be considered to understand the multiple exponential distributions of open times.展开更多
The effect of thermal wave at the initial stage for non-conductive Al_2 O_3 powders compact in field assisted sintering technique(FAST) was investigated. The Lord and Shulman type generalized thermoselastic theory was...The effect of thermal wave at the initial stage for non-conductive Al_2 O_3 powders compact in field assisted sintering technique(FAST) was investigated. The Lord and Shulman type generalized thermoselastic theory was introduced to describe the influence of thermal-mechanical interaction, as well as the heat transport and thermal focusing caused by thermal wave propagation. The expression of vacancy concentration difference of the particles was deduced by considering transient thermal stress. Subsequently, the relationship between activation energy and vacancy concentration difference was obtained. The mechanism of surface diffusion, volume diffusion, simultaneous surface and volume diffusion was analyzed. The numerical simulations indicate that low sintering temperature can obtain high local temperature by the superposition effect of thermal wave. Vacancy concentration differences were improved during FAST compared with hot-pressure and pressureless sintering, thereby decreasing the sintering time. By contrast, the activation energy declined with the decrease of vacancy concentration difference in the neck growth process.展开更多
A nonlinear explicit dynamic finite element formulation based on the generalized beam theory(GBT)is proposed and developed to simulate the dynamic responses of prismatic thin-walled steel members under transverse impu...A nonlinear explicit dynamic finite element formulation based on the generalized beam theory(GBT)is proposed and developed to simulate the dynamic responses of prismatic thin-walled steel members under transverse impulsive loads.Considering the rate strengthening and thermal softening effects on member impact behavior,a modified Cowper-Symonds model for constructional steels is utilized.The element displacement field is built upon the superposition of GBT cross-section deformation modes,so arbitrary deformations such as cross-section distortions,local buckling and warping shear can all be involved by the proposed model.The amplitude function of each cross-section deformation mode is approximated by the cubic non-uniform B-spline basis functions.The Kirchhoff s thin-plate assumption is utilized in the construction of the bending related displacements.The Green-Lagrange strain tensor and the second Piola-Kirchhoff(PK2)stress tensor are employed to measure deformations and stresses at any material point,where stresses are assumed to be in plane-stress state.In order to verify the effectiveness of the proposed GBT model,three numerical cases involving impulsive loading of the thin-walled parts are given.The GBT results are compared with those of the Ls-Dyna shell finite element.It is shown that the proposed model and the shell finite element analysis has equivalent accuracy in displacement and stress.Moreover,the proposed model is much more computationally efficient and structurally clearer than the shell finite elements.展开更多
The droplet size, size distribution, refractive index, and temperature can be measured simultaneously by the rainbow technique. In the present work, the rainbow scattering diagram for a spherical droplet in the second...The droplet size, size distribution, refractive index, and temperature can be measured simultaneously by the rainbow technique. In the present work, the rainbow scattering diagram for a spherical droplet in the secondary rainbow region is simulated by the use of the generalized Lorenz-Mie theory. For achieving high spatial resolution in denser droplet sprays, a focused Gaussian beam is used. For droplet characterization, different inversion algorithms are investigated, which includes trough-trough (<em>θ</em><sub>min1</sub> and <em>θ</em><sub>min2</sub>) method and inflection-inflection (<em>θ</em><sub>inf1</sub> and <em>θ</em><sub>inf2</sub>) method. For the trough-trough algorithm, the absolute error of the refractive index is between −6.4 × 10<sup>−4</sup> and 1.7 × 10<sup>−4</sup>, and the error of the droplet radius is only between −0.55% and 1.77%. For the inflection-inflection algorithm, the maximum absolute error of the inverted refractive index is less than −1.1 × 10<sup>−3</sup>. The error of the droplet radius is between −0.75% and 5.67%.展开更多
基金Projects(51378131,51378403)supported by the National Natural Science Foundation of ChinaProject(2012210020203)supported by the Fundamental Research Funds for the Central Universities,China
文摘From the mathematical principles, the generalized potential theory can be employed to create constitutive model of geomaterial directly. The similar Cam-clay model, which is created based on the generalized potential theory, has less assumptions,clearer mathematical basis, and better computational accuracy. Theoretically, it is more scientific than the traditional Cam-clay models. The particle flow code PFC3 D was used to make numerical tests to verify the rationality and practicality of the similar Cam-clay model. The verification process was as follows: 1) creating the soil sample for numerical test in PFC3 D, and then simulating the conventional triaxial compression test, isotropic compression test, and isotropic unloading test by PFC3D; 2)determining the parameters of the similar Cam-clay model from the results of above tests; 3) predicting the sample's behavior in triaxial tests under different stress paths by the similar Cam-clay model, and comparing the predicting results with predictions by the Cam-clay model and the modified Cam-clay model. The analysis results show that the similar Cam-clay model has relatively high prediction accuracy, as well as good practical value.
文摘In this paper we consider that the momentum of a free particle motion withhigh-level speed presenting nonlinear effects may be expanded by using Laurent seriesand then obtain the complete expression of nonlinear and unsteady momentum. These nonlinear and unsieady phenoniena of high-level speed may further expand to the theory of kinematics and it may be determined by Fredholm's integral equation of the first kind. In addition, according to the nonlinear and unsteady momentum obtained the relations of the nonlinear mechanics equations .work and energy, mass and energymay be derived.Finaly .this paper also calculates those experimental results which done in particle physics for mu-mesons u±and fast neutrons n, these results are in agreement with data perfectly.
基金Project supported by the National Natural Science Foundation of China.
文摘This paper deals with the solution of a parametric equation with generalized boundary condiiton in transport theory. It gives the distribution of parameter (so called delta-eigenvalue [1]) with which the equation has non-zero solution. A necessary and sufficient condition for the existence of; he control critical eigenvalue delta0 is established.
基金supported by the National Key Research and Development Program of China(Grant No.2021YFE0205900)the Key Technologies R&D Program of Jiangsu(Prospective and Key Technologies for Industry)(Grant Nos.BE2022067 and BE2022067-2)。
文摘In this article,studies on the multimode excitation problem of waveguides and antennas,the balance/unbalance mech-anism and the balanced feeding techniques in dipole antenna systems are first briefly historically reviewed.In this context,general-ized odd-even mode theory is advanced to quantitatively and approximately describe the mutual coupling effect between a feed line and an antenna.As is mathematically deduced and demonstrated,the modal parity mismatch between the feed line and the antenna should ultimately dominate the unbalance phenomenon in antenna systems.Thus,an elegant,closed-form formula is derived to ap-proximately calculate the“unbalance degree”of a straight dipole off-center fed by a symmetric twin-wire line.Design approaches for the simplest,linear,1-D multimode resonant antennas are introduced.Moreover,the“falling tone excitation”law gauged based on prototype dipoles is revealed and used to develop a mode synthesis design approach for microstrip patch antennas(MPAs)and 2-D sectorial electric dipole antennas.Design examples with distinctive radiation performance are presented and discussed.Finally,possible development trends of multimode resonant antennas are prospected.
基金the financial support from the National Key Research and Development Program of China(2022YFB4101302-01)the National Natural Science Foundation of China(22178243)the science and technology innovation project of China Shenhua Coal to Liquid and Chemical Company Limited(MZYHG-22-02).
文摘Direct coal liquefaction(DCL)is an important and effective method of converting coal into high-valueadded chemicals and fuel oil.In DCL,heating the direct coal liquefaction solvent(DCLS)from low to high temperature and pre-hydrogenation of the DCLS are critical steps.Therefore,studying the dissolution of hydrogen in DCLS under liquefaction conditions gains importance.However,it is difficult to precisely determine hydrogen solubility only by experiments,especially under the actual DCL conditions.To address this issue,we developed a prediction model of hydrogen solubility in a single solvent based on the machine-learning quantitative structure–property relationship(ML-QSPR)methods.The results showed that the squared correlation coefficient R^(2)=0.92 and root mean square error RMSE=0.095,indicating the model’s good statistical performance.The external validation of the model also reveals excellent accuracy and predictive ability.Molecular polarization(a)is the main factor affecting the dissolution of hydrogen in DCLS.The hydrogen solubility in acyclic alkanes increases with increasing carbon number.Whereas in polycyclic aromatics,it decreases with increasing ring number,and in hydrogenated aromatics,it increases with hydrogenation degree.This work provides a new reference for the selection and proportioning of DCLS,i.e.,a solvent with higher hydrogen solubility can be added to provide active hydrogen for the reaction and thus reduce the hydrogen pressure.Besides,it brings important insight into the theoretical significance and practical value of the DCL.
基金Project supported by the National Natural Science Foundation of China(Nos.12072309,61603322)。
文摘Due to the influence of deep-sea environment,deep-sea sediments are usually heterogeneous,and their moduli of elasticity and density change as depth changes.Combined with the characteristics of deep-sea sediments,the thermo-hydro-mechanical coupling dynamic response model of heterogeneous saturated porous sediments can be established to study the influence of elastic modulus,density,frequency,and load amplitude changes on the model.Based on the Green-Lindsay generalized thermoelasticity theory and Darcy’s law,the thermo-hydro-mechanical coupled dynamic response model and governing equations of heterogeneous deep-sea sediments with nonlinear elastic modulus and density are established.The analytical solutions of dimensionless vertical displacement,vertical stress,excess pore water pressure,and temperature are obtained by means of normal modal analysis,which are depicted graphically.The results show that the changes of elastic modulus and density have few effects on vertical displacement,vertical stress,and temperature,but have great effects on excess pore water pressure.When the mining machine vibrates,the heterogeneity of deep-sea sediments has great influence on vertical displacement,vertical stress,and excess pore water pressure,but has few effects on temperature.In addition,the vertical displacement,vertical stress,and excess pore water pressure of heterogeneous deep-sea sediments change more gently.The variation trends of physical quantities for heterogeneous and homogeneous deep-sea sediments with frequency and load amplitude are basically the same.The results can provide theoretical guidance for deep-sea mining engineering construction.
基金sponsored by the National Natural Science Foundation of China(under Grant Nos.41404090 and U1262208
文摘We propose a method for mOdeling azimuthal AVO responses from a fractured i reflector. The method calculates the integrated reflected wavetrains, and the wavetrains contain elastodynamic information including the contrast in impedance and anelasticity i across interfaces, the intemal anisotropic propagation, the dispersion and attenuation along i the wave path, and tuning and interference. The results suggest that for large angles of incidence, the velocity dispersion and attenuation increase the amplitudes of PP waves from the top and decrease those from the bottom. For azimuthal responses at specific angles of incidence, the reflected wavetrains of PP waves tend to have longer duration with increasing azimuth. In contrast, model-converted PSV and PSH reflections show stable azimuthal features and are less affected by the reflector thickness. The amplitudes of PSV reflections increase with increasing azimuth; moreover, the waves have no reflection energy at 0° and 90° azimuth and maximum amplitude at 45° azimuth.
基金the National Natural Science Foundation of China ( Grant No. 10272010) the Ministry of Science and Technology of China (Grant No. 2002CCC00200).
文摘Based on the test data of frictional materials and previous research achievements in this field, a generalized non-linear strength theory (GNST) is proposed. It describes non-linear strength properties on the π-plane and the meridian plane using a unified formula, and it includes almost all the present non-linear strength theories, which can be used in just one material. The shape of failure function of the GNST is a smooth curve between the SMP criterion and the Mises criterion on the π-plane, and an exponential curve on the meridian plane. Through the transformed stress space based on the GNST, the combination of the GNST and various constitutive models using p and q as stress parameters can be realized simply and rationally in three-dimensional stress state. Keywords generalized non-linear strength theory (GNST) - transformed stress - constitutive model - application
基金supported by the National Natural Science Foundation of ChinaYalona River Hydropower Development of Ertan Hydropower Development Company (No.50639050)
文摘The behavior of soil-structure interface plays a major role in the definition of soil-structure interaction. In this paper a bi-potential surface elasto-plastic model for soil-structure interface is proposed in order to describe the interface deformation behavior,including strain softening and normal dilatancy. The model is formulated in the framework of generalized potential theory,in which the soil-structure interface problem is regard as a two-dimensional mathematical problem in stress field,and plastic state equations are used to replace the traditional field surface. The relation curves of shear stress and tangential strain are fitted by a piecewise function composed by hyperbolic functions and hyperbolic secant functions,while the relation curves of normal strain and tangential strain are fitted by another piecewise function composed by quadratic functions and hyperbolic secant functions. The approach proposed has the advantage of deriving an elastoplastic constitutive matrix without postulating the plastic potential functions and yield surface. Moreover,the mathematical principle is clear,and the entire model parameters can be identified by experimental tests. Finally,the predictions of the model have been compared with experimental results obtained from simple shear tests under normal stresses,and results show the model is reasonable and practical.
基金Projects(52108347,52178371)supported by the National Natural Science Foundation of ChinaProject(LQ22E080010)supported by the Exploring Youth Project of Zhejiang Natural Science Foundation,China。
文摘Porous materials can be found in a variety of geophysical and engineering applications.The existence of thermal contact resistance at the interface between bilayered saturated porous strata would result in a significant temperature difference at the interface.An attempt is made to study the thermo-hydro-mechanical coupling dynamic response of bilayered saturated porous strata with thermal contact resistance and elastic wave impedance.The corresponding analytical solutions for the dynamic response of bilayered saturated porous strata under a harmonic thermal load are derived by the operator decomposition method,and their rationality is verified by comparing them with existing solutions.The influences of thermal contact resistance,thermal conductivity ratio,and porosity ratio on the dynamic response of bilayered saturated porous strata are systematically investigated.Outcomes disclose that with the increase of thermal contact resistance,the displacement,pore water pressure and stress decrease gradually,and the temperature jump at the interface between two saturated porous strata increases.
文摘By systematically studying seismic strengthening areas before 85 earthquakes with M>=6.0 in China, some results have been extracted. 1) Earthquake active strengthening area exists universally before strong shock or great earthquake; 2) The size of the strengthening area and its appearing time will increase when the earthquake magnitude increases; 3) The rate between the size of seismic strengthening area and the size of the source region decreases when earthquake magnitude increases; 4) The appearing time of the earthquake active strengthening region in the eastern part of China is longer than that in the western part of China. The above characteristics have been preliminarily explained qualitatively and half-quantitatively by applying the strong body earthquake generating model and the hard inclusion theory. Then applying the seismic strengthening area, we have obtained long-term predictions of 2 earthquakes, so the seismic strengthening area before strong earthquake or great earthquakes is a universal phenomenon, which has some mechanical base.
基金the National Natural Science Foundation of China(No.12072309)the Youth Fund Foundation of Education Bureau of Hunan Province of China(No.19B546)the High-Level Talent Gathering Project in Hunan Province of China(No.2019RS1059)。
文摘The excessive deformation of deep-sea sediments caused by the vibration of the mining machine will adversely affect the efficiency and safety of mining.Combined with the deep-sea environment,the coupled thermo-hydro-mechanical problem for saturated porous deep-sea sediments subject to the vibration of the mining vehicle is investigated.Based on the Green-Lindsay(G-L)generalized thermoelastic theory and Darcy’s law,the model of thermo-hydro-mechanical dynamic responses for saturated porous deep-sea sediments under the vibration of the mining vehicle is established.We obtain the analytical solutions of non-dimensional vertical displacement,excess pore water pressure,vertical stress,temperature,and change in the volume fraction field with the normal mode analysis method,and depict them graphically.The normal mode analysis method uses the canonical coordinate transformation to solve the equation,which can quickly decouple the equation by ignoring the modal coupling effect on the basis of the canonical mode.The results indicate that the vibration frequency has obvious influence on the vertical displacement,excess pore water pressure,vertical stress,and change in volume fraction field.The loading amplitude has a great effect on the physical quantities in the foundation,and the changes of the physical quantities increase with the increase in loading amplitude.
基金Project(20110094110002) supported by the Specialized Research Fund for the Doctoral Program of Higher Education of ChinaProject(200801014) supported by the Ministry of Water Resources of ChinaProject(50825901) supported by the National Natural Science Foundation of China
文摘The mechanical behaviors of the interface between coarse-grained soil and concrete were investigated by simple shear tests under condition of mixed soil slurry (bentonite mixed with cement grout).For comparison,the interfaces both without slurry and with bentonite slurry were analyzed.The experimental results show that different slurries exert much influence on the strength and deformation of soil/structure interface.Under mixed soil slurry,strain softening and shear dilatation are observed,while shear dilatation appears under the small normal stress of the interface without slurry,and shear contraction is significant under the condition of the bentonite slurry.The thickness of the interface was determined by analyzing the disturbed height of the sample with both simple shear test and particle flow code (PFC).An elasto-plastic constitutive model incorporating strain softening and dilatancy for thin layer element of interface was formulated in the framework of generalized potential theory.The relation curves of shear stress and shear strain,as well as the relation curves of normal strain and shear strain,were fitted by a piecewise function composed by hyperbolic functions and resembling normal functions.The entire model parameters can be identified by tests.The new model is verified by comparing the measured data of indoor cut-off wall model tests with the predictions from finite element method (FEM).The FEM results indicate that the stress of wall calculated by using Goodman element is too large,and the maximum deviation between the test data and prediction is about 45%.While the prediction from the proposed model is close to the measured data,and the error is generally less than 10%.
文摘At present, associated flow rule of traditional plastic theory is adopted in the slip line field theory and upper bound method of geotechnical materials. So the stress characteristic line conforms to the velocity line. It is proved that geotechnical materials do not abide by the associated flow rule. It is impossible for the stress characteristic line to conform to the velocity line. Generalized plastic mechanics theoretically proved that plastic potential surface intersects the Mohr-Coulomb yield surface with an angle, so that the velocity line must be studied by non-associated flow rule. According to limit analysis theory, the theory of slip line field is put forward in this paper, and then the ultimate beating capacity of strip footing is obtained based on the associated flow rule and the non-associated flow nile individually. These two results are identical since the ultimate bearing capacity is independent of flow role. On the contrary, the velocity fields of associated and non-associated flow rules are different which shows the velocity field based on the associat- ed flow rule is incorrect.
基金supported by the National Natural Science Foundation of China (11672224)
文摘Based on nonlocal thermoelastic theory, this article studies the reflection of waves in nanometersemi-conductor media. Firstly, the governing equations are established based on couplednonlocal elasticity theory, plasma diffusion equation, and moving equation. Then, using theharmonic method, the solution of the dissipation equation and the analytic expression of thereflection coefficient rate are obtained. Finally, the influences of nonlocal parameters on wavevelocities are showed graphically. It is found that after the introduction of nonlocal effect, thephase and group velocities all show the attenuation, and as the frequency increases, the nonlocalparameter is bigger, and the decay rate is faster. The reflection coefficient rate varies greatly withdifferent theories, with different reflection coefficient rates depending on the incident angle.
文摘Thailand has currently enhanced and promoted intensive trade and investment liberalization and implemented long-term growth policy according with current regional economic integration, WTO obligations and globalization. Nevertheless, several recent internal and external factors e.g. the massive SARS and avian flu outbreaks, the Indian Ocean tsunami devastation, the Asia financial crisis and domestic policy reforms (ICSEAD, 2006) have also impeded this policy. While the issues are important for Thailand and developing countries in Asia, only limited research has been undertaken to investigate them. The paper conducts a substantive quantitative study to contribute to these trade and development policy issues. A new econometric modelling policy method, namely the generalized gravity theory (Tran Van Hoa, 2004) is used to develop a simple flexible simultaneous-equation econometric model of Thailand's openness model with its seven major trade partners (ASEAN-4, Australia, the USA, the EU, China, Japan and India). Using data from the ICSEAD, the World Development Indicators and the Bank of Thailand databases, the paper reveals efficient and reliable empirical findings on trade-growth causality, trade determination including the impact of shocks and policy reform on trade and growth between Thailand and its major trade partners over the past two decades. The paper also provides evidence on the linkages between trade in goods, FDI and services and regional economic integration for more credible policy implications.
基金Project supported by the National Natural Science Foundations of China(Grant Nos.11504214,31370830,and 11675134)the 111 Project,China(Grant No.B16029)the China Postdoctoral Science Foundation(Grant No.2016M602071)
文摘The biexponential distributions of open times are observed in various types of ion channels. In this paper, by discussing a simple channel model, we show that there are two different schemes to understand the biexponential distribution of open times. One scheme is mathematically strict based on generator matrix theory, while the other one has a clear physical explanation according to an approximation process with numerical simulation of Markovian channel dynamics. Our comparison results suggest that even for biologically complex channels, in addition to carrying out a stochastic simulation, the strict theoretical analysis should be considered to understand the multiple exponential distributions of open times.
基金Funded by the National Natural Science Foundation of China(No.11602042)the Chongqing Research Program of Basic Research and Frontier Technology(No.cstc2016jcyjA0259)the Scientific and Technological Research Program of Chongqing Municipal Education Commission(No.KJ1601304)
文摘The effect of thermal wave at the initial stage for non-conductive Al_2 O_3 powders compact in field assisted sintering technique(FAST) was investigated. The Lord and Shulman type generalized thermoselastic theory was introduced to describe the influence of thermal-mechanical interaction, as well as the heat transport and thermal focusing caused by thermal wave propagation. The expression of vacancy concentration difference of the particles was deduced by considering transient thermal stress. Subsequently, the relationship between activation energy and vacancy concentration difference was obtained. The mechanism of surface diffusion, volume diffusion, simultaneous surface and volume diffusion was analyzed. The numerical simulations indicate that low sintering temperature can obtain high local temperature by the superposition effect of thermal wave. Vacancy concentration differences were improved during FAST compared with hot-pressure and pressureless sintering, thereby decreasing the sintering time. By contrast, the activation energy declined with the decrease of vacancy concentration difference in the neck growth process.
基金The National Natural Science Foundation of China(No.51078229)the Specialized Research Fund for the Doctoral Program of Higher Education(o.20100073110008)
文摘A nonlinear explicit dynamic finite element formulation based on the generalized beam theory(GBT)is proposed and developed to simulate the dynamic responses of prismatic thin-walled steel members under transverse impulsive loads.Considering the rate strengthening and thermal softening effects on member impact behavior,a modified Cowper-Symonds model for constructional steels is utilized.The element displacement field is built upon the superposition of GBT cross-section deformation modes,so arbitrary deformations such as cross-section distortions,local buckling and warping shear can all be involved by the proposed model.The amplitude function of each cross-section deformation mode is approximated by the cubic non-uniform B-spline basis functions.The Kirchhoff s thin-plate assumption is utilized in the construction of the bending related displacements.The Green-Lagrange strain tensor and the second Piola-Kirchhoff(PK2)stress tensor are employed to measure deformations and stresses at any material point,where stresses are assumed to be in plane-stress state.In order to verify the effectiveness of the proposed GBT model,three numerical cases involving impulsive loading of the thin-walled parts are given.The GBT results are compared with those of the Ls-Dyna shell finite element.It is shown that the proposed model and the shell finite element analysis has equivalent accuracy in displacement and stress.Moreover,the proposed model is much more computationally efficient and structurally clearer than the shell finite elements.
文摘The droplet size, size distribution, refractive index, and temperature can be measured simultaneously by the rainbow technique. In the present work, the rainbow scattering diagram for a spherical droplet in the secondary rainbow region is simulated by the use of the generalized Lorenz-Mie theory. For achieving high spatial resolution in denser droplet sprays, a focused Gaussian beam is used. For droplet characterization, different inversion algorithms are investigated, which includes trough-trough (<em>θ</em><sub>min1</sub> and <em>θ</em><sub>min2</sub>) method and inflection-inflection (<em>θ</em><sub>inf1</sub> and <em>θ</em><sub>inf2</sub>) method. For the trough-trough algorithm, the absolute error of the refractive index is between −6.4 × 10<sup>−4</sup> and 1.7 × 10<sup>−4</sup>, and the error of the droplet radius is only between −0.55% and 1.77%. For the inflection-inflection algorithm, the maximum absolute error of the inverted refractive index is less than −1.1 × 10<sup>−3</sup>. The error of the droplet radius is between −0.75% and 5.67%.