Differences and identification on multi-time hydrocarbon generation of carboniferous-permian coaly source rocks in the Huanghua Depression,Bohai Bay Basin

Coal is a solid combustible mineral,and coal-bearing strata have important hydrocarbon generation potential and contribute to more than 12%of the global hydrocarbon resources.However,the deposition and hydrocarbon evolution process of ancient coal-bearing strata is characterized by multiple geological times,leading to obvious distinctions in their hydrocarbon generation potential,geological processes,and production,which affect the evaluation and exploration of hydrocarbon resources derived from coaly source rocks worldwide.This study aimed to identify the differences on oil-generated parent macerals and the production of oil generated from different coaly source rocks and through different oil generation processes.Integrating with the analysis of previous tectonic burial history and hydrocarbon generation history,high-temperature and high-pressure thermal simulation experiments,organic geochemistry,and organic petrology were performed on the Carboniferous-Permian(C-P)coaly source rocks in the Huanghua Depression,Bohai Bay Basin.The oil-generated parent macerals of coal's secondary oil generation process(SOGP)were mainly hydrogen-rich collotelinite,collodetrinite,sporinite,and cutinite,while the oil-generated parent macerals of tertiary oil generation process(TOGP)were the remaining small amount of hydrogen-rich collotelinite,sporinite,and cutinite,as well as dispersed soluble organic matter and unexhausted residual hydrocarbons.Compared with coal,the oil-generated parent macerals of coaly shale SOGP were mostly sporinite and cutinite.And part of hydrogen-poor vitrinite,lacking hydrocarbon-rich macerals,and macerals of the TOGP,in addition to some remaining cutinite and a small amount of crude oil and bitumen from SOGP contributed to the oil yield.The results indicated that the changes in oil yield had a good junction between SOGP and TOGP,both coal and coaly shale had higher SOGP aborted oil yield than TOGP starting yield,and coaly shale TOGP peak oil yield was lower than SOGP peak oil yield.There were significant differences in saturated hydrocarbon and aromatic parameters in coal and coaly shale.Coal SOGP was characterized by a lower Ts/Tm and C31-homohopane22S/(22S+22R)and a higher Pr/n C17compared to coal TOGP,while the aromatic parameter methyl dibenzothiophene ratio(MDR)exhibited coaly shale TOGP was higher than coaly shale SOGP than coaly TOGP than coaly SOGP,and coal trimethylnaphthalene ratio(TNR)was lower than coaly shale TNR.Thus,we established oil generation processes and discriminative plates.In this way,we distinguished the differences between oil generation parent maceral,oil generation time,and oil production of coaly source rocks,and therefore,we provided important support for the evaluation,prediction,and exploration of oil resources from global ancient coaly source rocks.

Analysis of Energy Characteristics in the Process of Freak Wave Generation

The energy characteristics in the evolution of the wave train are investigated to understand the inherent cause of the freak wave generation. The Morlet wavelet spectrum method is employed to analyze the numerical, laboratory and field evolution data of this generation process. Their energy distributions and variations are discussed with consideration of corresponding surface elevations. Through comparing the energy characteristics of three cases, it is shown that the freak wave generation depends not only on the continuous transfer of wave train energy to a certain region where finally the maximum energy occurs, but also on the distinct shift of the converged energy to high-frequency components in a very short time. And the typical energy characteristics of freak waves are also given.

Rapid Service-Oriented Business Process Generation Method Based on Ontology

Service-oriented business process generation is a key activity in the ServiceOriented Architecture(SOA)business lifecycle,and most of the other activities such as application execution depend on the business process being developed.After the business requirements are acquired,a developer has to use specific programming technologies to orchestrate web services to generate a deployable business process.It is time-consuming to specify all the business processes from lowlevel web services,especially for an enterprise that focuses on a series of similar businesses.This paper proposes a rapid service-oriented business process generation method with domain-specific assets specified in ontology systems.Assets with different levels of granularity are reused to refine the high level business process framework for executable business processes using the Business Process Executional Language(BPEL).The new methodology significantly simplifies service-oriented business process generation by reusing assets to construct business processes.A business process generation tool is also implemented to support the efficient visual design of SOA processes with the proposed method.This paper verifies the proposed method using a shipment tracking case.The studies show that the number of reusable assets increases significantly as these projects progress,and the business process generation speed also increases at the same time.

The influence of intensity and properties of tectonic stress on the process of coalification

Through the research on stress metamorphism character of the II1 coal seam in Ludian gliding structure, the stress effecting factors of metamorphism and hydrocarbon generation process of tectonic coal were studied. It is shown that different tectonic stress has different coal evolution effects. Compared with tensional stress, compressive stress, which has apparent anisotropic characteristics, has greater stimulative effect against the increase of coal metamorphic degree, the abscission of functional group and side chains of basic structural unit, and the formation of gas primarily composed of methane.

Formation, preservation and connectivity control of organic pores in shale

In view of strong heterogeneity and complex formation and evolution of organic pores,field emission scanning electron microscopy(FESEM),Raman spectrum and fluid injection+CT/SEM imaging technology were used to study the macerals,organic pores and connectivity of organic pores in the lower Paleozoic organic-rich shale samples from Southern China.Combined with the mechanism of hydrocarbon generation and expulsion and pore forming mechanism of organic matter-based activated carbon,the relationships between organic pore development and the organic matter type,hydrocarbon generation process,diagenesis and pore pressure were explored to reveal the controlling factors of the formation,preservation and connectivity of organic pores in shale.(1)The generation of organic pores goes on through the whole hydrocarbon generation process,and is controlled by the type,maturity and decomposition of organic matter;the different hydrocarbon generation components and differential hydrocarbon-generation evolution of kerogen and solid asphalt lead to different pore development characteristics;organic pores mainly develop in solid bitumen and hydrogen-rich kerogen.(2)The preservation of organic pores is controlled by maturity and diagenesis,including the steric hindrance effect of in-situ hydrocarbon retention,rigid mineral framework formed by recrystallization,the coupling mechanism of pore-fluid pressure and shale brittleness-ductility transition.(3)The Ro of 4.0%is the maturity threshold of organic pore extinction,the shale layers with Ro larger than 3.5%have high risk for shale gas exploration,these shale layers have low gas contents,as they were in an open state before uplift,and had high hydrocarbon expulsion efficiency and strong aromatization,thus having the"congenital deficiency"of high maturity and pore densification.(4)The pores in the same organic matter particle have good connectivity;and the effective connectivity between different organic matter pores and inorganic pores and fractures depends on the abundance and distribution of organic matter,and development degree of pores and fractures in the shale;the accumulation,preservation and laminar distribution of different types of organic matter in high abundance is the prerequisite for the development and connection of organic pores,grain margin fractures and bedding fractures in reservoir.

Slope runoff study in situ using rainfall simulator in mountainous area of North China

Simulated rainfall is a valid tool to examine the runoff generation on the slope.13 simulated rainfall experiments with different rainfall intensities and durations are completed in a 5 m ×10 m experimental plot in mountainous area of North China.Simultaneously,rainfall,surface runoff,soil-layer flow,mantel-layer flow and soil moisture are monitored respectively.From the results,it is found that the hydrographs in all layers have the characteristics of rapid rise and fall.The recessions of surface flow and soil-layer flow are much faster than that of mantel-layer flow.Surface flow,the main contributor,makes up more than 60% of the total runoff in the study area.It even exceeds 90% in the cases of high intensity rainfall events.Runoff coefficient(ratio of total runoff to rainfall amount) is mainly influenced by rainfall amount,rainfall intensity and antecedent soil moisture,and the relationship can be well expressed by a multiple linear regression function α = 0.002P + 0.182i + 4.88Wa-0.821.The relation between the rainfall intensity and the lag time of three flows(surface runoff,soil-layer flow and mantel-layer flow) is shown to be exponential.Then,the result also shows that the recession constant is 0.75 for surface runoff,is 0.94 for soil-layer and mantel-layer flow in this area.In this study area,the dominant infiltration excess runoff is simulated by Horton model.About 0.10 mm/min percolation is observed under the condition of different rainfall intensities,therefore the value is regarded as the steady infiltration rate of the study area.

Review on theory and applications of wavefront recording plane framework in generation and processing of digital holograms

The wavefront recording plane （WRP）, subsequently generalized to be known as the virtual diffraction plane （VDP）, is a recent concept that has been successfully deployed in fast generation and processing of digital holograms. In brief, the WRP and its extension, the VDP, is a hypothetical plane that is located between the hologram and the object scene, and which is at close proximity to the latter. As such, the fringe patterns on the hypothetical plane are carrying the holistic information of the hologram, as well as the local optical properties of the object scene. This important property enables a hologram to be processed with classical image processing techniques that are normally unsuitable for handling holographic information. In this paper we shall review a number of works, that have been developed based on the framework of the WRP and the VDP.

A new process to improve short-chain fatty acids and bio-methane generation from waste activated sludge

As an important intermediate product, short-chain fatty acids（SCFAs） can be generated after hydrolysis and acidification from waste activated sludge, and then can be transformed to methane during anaerobic digestion process. In order to obtain more SCFA and methane,most studies in literatures were centered on enhancing the hydrolysis of sludge anaerobic digestion which was proved as un-efficient. Though the alkaline pretreatment in our previous study increased both the hydrolysis and acidification processes, it had a vast chemical cost which was considered uneconomical. In this paper, a low energy consumption pretreatment method, i.e. enhanced the whole three stages of the anaerobic fermentation processes at the same time, was reported, by which hydrolysis and acidification were both enhanced, and the SCFA and methane generation can be significantly improved with a small quantity of chemical input. Firstly, the effect of different pretreated temperatures and pretreatment time on sludge hydrolyzation was compared. It was found that sludge pretreated at 100°C for 60 min can achieve the maximal hydrolyzation. Further, effects of different initial p Hs on acidification of the thermal pretreated sludge were investigated and the highest SCFA was observed at initial p H 9.0with fermentation time of 6 d, the production of which was 348.63 mg COD/g VSS（6.8 times higher than the blank test） and the acetic acid was dominant acid. Then, the mechanisms for this new pretreatment significantly improving SCFA production were discussed. Finally,the effect of this low energy consumption pretreatment on methane generation was investigated.

Laser ultrasonic generation and optical detection and processing

History, present situation and importancy of the laser-generated ultrasonic technique are presented. Basic principles and some experimental results of laser ultrasonic generation and optical detection and processing are discussed. Several problems about applying this technique to NDT are also discussed in this paper.

A Prototype Expert System for Automatic Generation of Image Processing Programs

A prototype expert system for generating image processing programs using the subroutine pack- age SPIDER is described in this paper.Based on an interactive dialog,the system can generate a complete application program using SPIDER routines.

Thermodynamic behaviors of SiCl_2 in silicon deposition by gas phase zinc reduction of silicon tetrachloride

The modified Siemens process,which is the major process of producing polycrystalline silicon through current technologies,is a high temperature,slow,semi-batch process and the product is expensive primarily due to the large energy consumption.Therefore,the zinc reduction process,which can produce solar-grade silicon in a cost effective manner,should be redeveloped for these conditions.The SiCl2 generation ratio,which stands for the degree of the side reactions,can be decomposed to SiCl4 and ZnCl2 in gas phase zinc atmosphere in the exit where the temperature is very low.Therefore,the lower SiCl2 generation ratio is profitable with lower power consumption.Based on the thermodynamic data for the related pure substances,the relations of the SiCl2 generation ratio and pressure,temperature and the feed molar ratio（n（Zn）/n（SiCl4） are investigated and the graphs thereof are plotted.And the diagrams of Kpθ-T at standard atmosphere pressure have been plotted to account for the influence of temperature on the SiCl2 generation ratio.Furthermore,the diagram of Kpθ-T at different pressures have also been plotted to give an interpretation of the influence of pressure on the SiCl2 generation ratio.The results show that SiCl2 generation ratio increases with increasing temperature,and the higher pressure and excess gas phase zinc can restrict SiCl2 generation ratio.Finally,suitable operational conditions in the practical process of polycrystalline silicon manufacture by gas phase zinc reduction of SiCl4 have been established with 1200 K,0.2 MPa and the feed molar ratio（n（Zn） /n（SiCl4）） of 4 at the entrance.Under these conditions,SiCl2 generation ratio is very low,which indicates that the side reactions can be restricted and the energy consumption is reasonable.

CW blue light generation at 429 nm by utilizing second harmonic process with KNbO_3

Continuous-wave blue light at 429 nm from a second harmonic process has been investigated at room temperature with Potassium Niobate (KNbO3) crystal. Optimum parameters for nonlinear conversion in our designing single-resonant, external ring cavity pumped by the Ti:sapphire laser are established. 39% of maximum overall conversion efficiency is obtained and factors that limit the conversion efficiency is discussed.

Integration system research and development for three-dimensional laser scanning information visualization in goaf

An integration processing system of three-dimensional laser scanning information visualization in goaf was developed. It is provided with multiple functions, such as laser scanning information management for goaf, cloud data de-noising optimization, construction, display and operation of three-dimensional model, model editing, profile generation, calculation of goaf volume and roof area, Boolean calculation among models and interaction with the third party soft ware. Concerning this system with a concise interface, plentiful data input/output interfaces, it is featured with high integration, simple and convenient operations of applications. According to practice, in addition to being well-adapted, this system is favorably reliable and stable.

All-Optical Signal Processing with Super-Continuum Generated from Optical Fibers

Super-continuum (SC) generated from optical fibers has many attractive applications in optical communication systems. Discussing the mechanism of wideband and flat SC generation, we describe all-optical signal processing that employs the SC.

Data signal processing via manchester coding-decoding method using chaotic signals generated by PANDA ring resonator

We investigate the nonlinear behaviors of light recognized as chaos during the propagation of Gaussian laser beam inside a nonlinear polarization maintaining and absorption reducing （PANDA） ring resonator system. It aims to generate the nonlinear behavior of light to obtain data in binary logic codes for transmission in fiber optics communication. Effective parameters, such as refractive indices of a silicon waveguide, coupling coefficients （~）, and ring radius ring （R）, can be properly selected to operate the nonlinear behavior. Therefore, the binary coded data generated by the PANDA ring resonator system can be decoded and converted to Manchester codes, where the decoding process of the transmitted codes occurs at the end of the transmission link. The simulation results show that the original codes can be recovered with a high security of signal transmission using the Manchester method.