Construction of 3D porous Cu_(1.81)S/nitrogen-doped carbon frameworks for ultrafast and long-cycle life sodium-ion storage

Transition metal sulfides have great potential as anode mterials for sodium-ion batteries(SIBs)due to their high theoretical specific capacities.However,the inferior intrinsic conductivity and large volume variation during sodiation-desodiation processes seriously affect its high-rate and long-cyde performance,unbeneficial for the application as fast-charging and long-cycling SIBs anode.Herein,the three-dimensional porous Cu_(1.81)S/nitrogen-doped carbon frameworks(Cu_(1.81)S/NC)are synthesized by the simple and facile sol-gel and annealing processes,which can accommodate the volumetric expansion of Cu_(1.81)S nanoparticles and accelerate the transmission of ions and electrons during Na^(+)insertion/extraction processes,exhibiting the excellent rate capability(250.6 mA·g^(-1)at 20.0 A·g^(-1))and outstanding cycling stability(70% capacity retention for 6000 cycles at 10.0 A·g^(-1))for SIBs.Moreover,the Na-ion full cells coupled with Na_(3)V_(2)(PO_(4))_(3)/C cathode also demonstrate the satisfactory reversible specific capacity of 330.5 mAh·g^(-1)at 5.0 A·g^(-1)and long-cycle performance with the 86.9% capacity retention at 2.0 A·g^(-1)after 750 cycles.This work proposes a promising way for the conversionbased metal sulfides for the applications as fast-charging sodium-ion battery anode.

Measuring urban sprawl in Beijing with geo-spatial indices

Concerning about the rapid urban growth in recent China, this study takes Beijing as a case and puts forward that urban sprawl can be measured from spatial configuration, urban growth efficiency and external impacts, and then develops a geo-spatial indices system for measuring sprawl, a total of 13 indicators. In order to calculate these indices, different sources data are selected, including land use maps, former land use planning, land price and floor-area-ratio samples, digitized map of the highways and city centers, population and GDP statistical data, etc. Various GIS spatial analysis methods are used to spatialize these indices into 100mx100m cells. Besides, an integrated urban sprawl index is calculated by weight sum of these 13 indices. The application result indicates that geo-spatial indices system can capture most of the typical features and interior differentia of urban sprawl. Construction land in Beijing has kept fast growing with large amount, low efficiency and disordered spatial configuration, indicating a typical sprawling tendency. The following specific sprawl features are identified by each indicator： （1） typical spatial configuration of sprawling： obvious fragmentation and irregularity of landscape due to unsuccessful enforcement of land use planning, unadvisable pattern of typical discontinuous development, strip development and leapfrog development; （2） low efficiency of sprawl： low development density, low population density and economic output in newly developed area; and （3） negative impacts on agriculture, environment and city life. According to the integrated sprawl index, the sprawling amount in the northern part is larger than that in the southern, but the sprawling extent is in converse case; most sprawling area include the marginal area of the near suburbs and the area between highways, etc. Four sprawling patterns are identified： randomly expansion at urban fringe, strip development along or between highways, scattered development of industrial land, leapfrog development of urban residence and industrial area.

Digital Watermark-based Security Technology for Geo-spatial Graphics Data

The paper presents a set of techniques of digital watermarking by which copyright and user rights messages are hidden into geo-spatial graphics data,as well as techniques of compressing and encrypting the watermarked geo-spatial graphics data.The technology aims at tracing and resisting the illegal distribution and duplication of the geo-spatial graphics data product,so as to effectively protect the data producer＇s rights as well as to facilitate the secure sharing of geo-spatial graphics data.So far in the CIS field throughout the world,few researches have been made on digital watermarking.The research is a novel exploration both in the field of security management of geo-spatial graphics data and in the applications of digital watermarking technique.An application software employing the proposed technology has been developed.A number of experimental tests on the 1：500,000 digital bathymetric chart of the South China Sea and 1：10,000 digital topographic map of Jiangsu Province have been conducted to verify the feasibility of the proposed technology.

Challenges and Opportunities in Preserving Key Structural Features of 3D-Printed Metal/Covalent Organic Framework

Metal-organic framework(MOF)and covalent organic framework(COF)are a huge group of advanced porous materials exhibiting attractive and tunable microstructural features,such as large surface area,tunable pore size,and functional surfaces,which have significant values in various application areas.The emerging 3D printing technology further provides MOF and COFs(M/COFs)with higher designability of their macrostructure and demonstrates large achievements in their performance by shaping them into advanced 3D monoliths.However,the currently available 3D printing M/COFs strategy faces a major challenge of severe destruction of M/COFs’microstructural features,both during and after 3D printing.It is envisioned that preserving the microstructure of M/COFs in the 3D-printed monolith will bring a great improvement to the related applications.In this overview,the 3D-printed M/COFs are categorized into M/COF-mixed monoliths and M/COF-covered monoliths.Their differences in the properties,applications,and current research states are discussed.The up-to-date advancements in paste/scaffold composition and printing/covering methods to preserve the superior M/COF microstructure during 3D printing are further discussed for the two types of 3D-printed M/COF.Throughout the analysis of the current states of 3D-printed M/COFs,the expected future research direction to achieve a highly preserved microstructure in the 3D monolith is proposed.

Parallel Light Fields: A Perspective and A Framework

Dear Editor,Light fields give relatively complete description of scenes from perspective of angles and positions of rays. At present time, most of the computer vision algorithms take 2D images as input which are simplified expression of light fields with depth information discarded. In theory, computer vision tasks may achieve better performance as long as complete light fields are acquired.

Porous framework materials for energy&environment relevant applications:A systematic review

Carbon peaking and carbon neutralization trigger a technical revolution in energy&environment related fields.Development of new technologies for green energy production and storage,industrial energy saving and efficiency reinforcement,carbon capture,and pollutant gas treatment is in highly imperious demand.The emerging porous framework materials such as metal–organic frameworks(MOFs),covalent organic frameworks(COFs)and hydrogen-bonded organic frameworks(HOFs),owing to the permanent porosity,tremendous specific surface area,designable structure and customizable functionality,have shown great potential in major energy-consuming industrial processes,including sustainable energy gas catalytic conversion,energy-efficient industrial gas separation and storage.Herein,this manuscript presents a systematic review of porous framework materials for global and comprehensive energy&environment related applications,from a macroscopic and application perspective.

All‑Covalent Organic Framework Nanofilms Assembled Lithium‑Ion Capacitor to Solve the Imbalanced Charge Storage Kinetics

Free-standing covalent organic framework(COFs)nanofilms exhibit a remarkable ability to rapidly intercalate/de-intercalate Li^(+) in lithium-ion batteries,while simultaneously exposing affluent active sites in supercapacitors.The development of these nanofilms offers a promising solution to address the persistent challenge of imbalanced charge storage kinetics between battery-type anode and capacitor-type cathode in lithium-ion capacitors(LICs).Herein,for the first time,custom-made COFBTMB-TP and COFTAPB-BPY nanofilms are synthesized as the anode and cathode,respectively,for an all-COF nanofilm-structured LIC.The COFBTMB-TP nanofilm with strong electronegative–CF3 groups enables tuning the partial electron cloud density for Li^(+) migration to ensure the rapid anode kinetic process.The thickness-regulated cathodic COFTAPB-BPY nanofilm can fit the anodic COF nanofilm in the capacity.Due to the aligned 1D channel,2D aromatic skeleton and accessible active sites of COF nanofilms,the whole COFTAPB-BPY//COFBTMB-TP LIC demonstrates a high energy density of 318 mWh cm^(−3) at a high-power density of 6 W cm^(−3),excellent rate capability,good cycle stability with the capacity retention rate of 77%after 5000-cycle.The COFTAPB-BPY//COFBTMB-TP LIC represents a new benchmark for currently reported film-type LICs and even film-type supercapacitors.After being comprehensively explored via ex situ XPS,7Li solid-state NMR analyses,and DFT calculation,it is found that the COFBTMB-TP nanofilm facilitates the reversible conversion of semi-ionic to ionic C–F bonds during lithium storage.COFBTMB-TP exhibits a strong interaction with Li^(+) due to the C–F,C=O,and C–N bonds,facilitating Li^(+) desolation and absorption from the electrolyte.This work addresses the challenge of imbalanced charge storage kinetics and capacity between the anode and cathode and also pave the way for future miniaturized and wearable LIC devices.

An Optimal Method for High-Resolution Population Geo-Spatial Data

China' Mainland has a poor distribution of meteorological stations.Existing models’estimation accuracy for creating high-resolution surfaces of meteorological data is restricted for air temperature,and low for relative humidity and wind speed(few studies reported).This study compared the typical generalized additive model(GAM)and autoencoder-based residual neural network(hereafter,residual network for short)in terms of predicting three meteorological parameters,namely air temperature,relative humidity,and wind speed,using data from 824 monitoring stations across China’s mainland in 2015.The performance of the two models was assessed using a 10-fold cross-validation procedure.The air temperature models employ basic variables such as latitude,longitude,elevation,and the day of the year.The relative humidity models employ air temperature and ozone concentration as covariates,while the wind speed models use wind speed coarse-resolution reanalysis data as covariates,in addition to the fundamental variables.Spatial coordinates represent spatial variation,while the time index of the day captures time variation in our spatiotemporal models.In comparison to GAM,the residual network considerably improved prediction accuracy:on average,the coefficient of variation(CV)R2 of the three meteorological parameters rose by 0.21,CV root-mean square(RMSE)fell by 37%,and the relative humidity model improved the most.The accuracy of relative humidity models was considerably improved once the monthly index was included,demonstrating that varied amounts of temporal variables are crucial for relative humidity models.We also spoke about the benefits and drawbacks of using coarse resolution reanalysis data and closest neighbor values as variables.In comparison to classic GAMs,this study indicates that the residual network model may considerably increase the accuracy of national high spatial(1 km)and temporal(daily)resolution meteorological data.Our findings have implications for high-resolution and high-accuracy meteorological parameter mapping in China.

Geo-Spatial Information System for Developing Tourism Industry in Kandy District, Sri Lanka

Tourism is a rapidly growing investment point in Sri Lanka, where huge investment is takeing place. Even though the investment is very massive, the planning, development, and marketing are key components of success in tourism zone enhancement. The main objective of this study was to implement a geo-spatial information system for development of tourism in Kandy district. Primary data collection methods i.e. questionnaire survey, interviews, focus group interviews, and observations were employed for data collection. Google maps with Google API standards which are specially designed for developers and computer programmers were used for implementation of the system. System requirements were identified by interviewing tourists and observations made on tourist sites. Proximity analysis, spatial joint, and network analysis with Google direction application program interface （API） and Google place API were used to analyze data. The study highlights the potential tourist attractions and the accessibility and other required details through a web output. Issues and challenges faced by travelers are mainly lack of specific location information, public transport schedules, and reliable tourist attraction information. Online geo-spatial information system created in this study provides a guide for tourists to fred the destination routes, the service areas, and all necessary details on particular destinations.

Accelerating Oxygen Electrocatalysis Kinetics on Metal-Organic Frameworks via Bond Length Optimization

Metal-organic frameworks(MOFs)have been developed as an ideal platform for exploration of the relationship between intrinsic structure and catalytic activity,but the limited catalytic activity and stability has hampered their practical use in water splitting.Herein,we develop a bond length adjustment strategy for optimizing naphthalene-based MOFs that synthesized by acid etching Co-naphthalenedicarboxylic acid-based MOFs(donated as AE-CoNDA)to serve as efficient catalyst for water splitting.AE-CoNDA exhibits a low overpotential of 260 mV to reach 10 mA cm^(−2)and a small Tafel slope of 62 mV dec^(−1)with excellent stability over 100 h.After integrated AE-CoNDA onto BiVO_(4),photocurrent density of 4.3 mA cm^(−2)is achieved at 1.23 V.Experimental investigations demonstrate that the stretched Co-O bond length was found to optimize the orbitals hybridization of Co 3d and O 2p,which accounts for the fast kinetics and high activity.Theoretical calculations reveal that the stretched Co-O bond length strengthens the adsorption of oxygen-contained intermediates at the Co active sites for highly efficient water splitting.

Overcoming Object Misalignment in Geo-Spatial Datasets

In integrating geo-spatial datasets, sometimes layers are unable to perfectly overlay each other. In most cases, the cause of misalignment is the cartographic variation of objects forming features in the datasets. Either this could be due to actual changes on ground, collection, or storage approaches used leading to overlapping or openings between features. In this paper, we present an alignment method that uses adjustment algorithms to update the geometry of features within a dataset or complementary adjacent datasets so that they can align to achieve perfect integration. The method identifies every unique spatial instance in datasets and their spatial points that define all their geometry;the differences are compared and used to compute the alignment parameters. This provides a uniform geo-spatial features’ alignment taking into consideration changes in the different datasets being integrated without affecting the topology and attributes.

Coastline Security Engineering Using Geo-Spatial Approach: Case of Chabahar Port, Iran

Regarding the special potential of ports located on international coastlines such as Makoran Sea (Iran) for goods and human smuggling, national level of coastline security is very important. They can play a significant role in the development of power and security. Based on military reviews and analyses, police location and monitoring field view in the coastlines are strategic issues in modern security development. This research proposes a tool for development of coastal roads and coastal walking routes in the deployment of police. The main focuses are monitoring field view and accessibility to the strategic coastline. GIS tool plays an essential role in producing important security maps. Chabahar Port in Iran, as the most important port of Makoran Sea, has been selected as the study area, regarding its strategic role in the national economy and security. Research method focused on these major axes: successful establishment of police stations in shoreline for increasing monitoring and coastal security and suitable patrol of patrol police car in the coastal roads. This study adopts a scientific approach to the analysis of the present and future development in urban and security planning in coastal towns in the national and regional levels.

Managing the surge:A comprehensive review of the entire disposal framework for retired lithium-ion batteries from electric vehicles

Anticipating the imminent surge of retired lithium-ion batteries(R-LIBs)from electric vehicles,the need for safe,cost-effective and environmentally friendly disposal technologies has escalated.This paper seeks to offer a comprehensive overview of the entire disposal framework for R-LIBs,encompassing a broad spectrum of activities,including screening,repurposing and recycling.Firstly,we delve deeply into a thorough examination of current screening technologies,shifting the focus from a mere enumeration of screening methods to the exploration of the strategies for enhancing screening efficiency.Secondly,we outline battery repurposing with associated key factors,summarizing stationary applications and sizing methods for R-LIBs in their second life.A particular light is shed on available reconditioning solutions,demonstrating their great potential in facilitating battery safety and lifetime in repurposing scenarios and identifying their techno-economic issues.In the realm of battery recycling,we present an extensive survey of pre-treatment options and subsequent material recovery technologies.Particularly,we introduce several global leading recyclers to illustrate their industrial processes and technical intricacies.Furthermore,relevant challenges and evolving trends are investigated in pursuit of a sustainable end-of-life management and disposal framework.We hope that this study can serve as a valuable resource for researchers,industry professionals and policymakers in this field,ultimately facilitating the adoption of proper disposal practices.

Atomically dispersed Mn-N_(x) catalysts derived from Mn-hexamine coordination frameworks for oxygen reduction reaction

Metal-organic frameworks recently have been burgeoning and used as precursors to obtain various metal-nitrogen-carbon catalysts for oxygen reduction reaction(ORR).Although rarely studied,Mn-N-C is a promising catalyst for ORR due to its weak Fenton reaction activity and strong graphitization catalysis.Here,we developed a facile strategy for anchoring the atomically dispersed nitrogen-coordinated single Mn sites on carbon nanosheets(MnNCS)from an Mn-hexamine coordination framework.The atomically dispersed Mn-N_(4) sites were dispersed on ultrathin carbon nanosheets with a hierarchically porous structure.The optimized MnNCS displayed an excellent ORR performance in half-cells(0.89 V vs.reversible hydrogen electrode(RHE)in base and 0.76 V vs.RHE in acid in half-wave potential)and Zn-air batteries(233 mW cm^(−2)in peak power density),along with significantly enhanced stability.Density functional theory calculations further corroborated that the Mn-N_(4)-C(12)site has favorable adsorption of*OH as the rate-determining step.These findings demonstrate that the metal-hexamine coordination framework can be used as a model system for the rational design of highly active atomic metal catalysts for energy applications.

One stone two birds:electrochemical and colorimetric dual-mode biosensor based on copper peroxide/covalent organic framework nanocomposite for ultrasensentive norovirus detection

Norovirus(NoV)is regarded as one of the most common causes of foodborne diarrhea in the world.It is urgent to identify the pathogenic microorganism of the diarrhea in short time.In this work,we developed an electrochemical and colorimetric dual-mode detection for NoV based on the excellent dual catalytic properties of copper peroxide/COF-NH_(2)nanocomposite(CuO_(2)@COF-NH_(2)).For the colorimetric detection,NoV can be directly detected by the naked eye based on CuO_(2)@COF-NH_(2)as a laccase-like nonazyme using“peptide-NoV-antibody”recognition mode.The colorimetric assay displayed a wide and quality linear detection range from 1 copy/mL to 5000 copies/mL of NoV with a low limit of detection(LOD)of 0.125 copy/mL.For the electrochemical detection of NoV,CuO_(2)@COF-NH_(2)showed an oxidation peak of copper ion from Cu^(+)to Cu^(2+)using“peptide-NoV-antibody”recognition mode.The electrochemical assay showed a linear detection range was 1-5000 copies/mL with a LOD of 0.152 copy/mL.It's worthy to note that this assay does not need other electrical signal molecule,which provide the stable and sensitive electrochemial detection for NoV.The electrochemical and colorimetric dual-mode detection was used to detect NoV in foods and faceal samples,which has the potential for improving food safety and diagnosing of NoV-infected diarrhea.

Covalent Organic Framework with 3D Ordered Channel and Multi-Functional Groups Endows Zn Anode with Superior Stability

Achieving a highly robust zinc(Zn)metal anode is extremely important for improving the performance of aqueous Zn-ion batteries(AZIBs)for advancing“carbon neutrality”society,which is hampered by the uncontrollable growth of Zn dendrite and severe side reactions including hydrogen evolution reaction,corrosion,and passivation,etc.Herein,an interlayer containing fluorinated zincophilic covalent organic framework with sulfonic acid groups(COF-S-F)is developed on Zn metal(Zn@COF-S-F)as the artificial solid electrolyte interface(SEI).Sulfonic acid group(-SO_(3)H)in COF-S-F can effectively ameliorate the desolvation process of hydrated Zn ions,and the three-dimensional channel with fluoride group(-F)can provide interconnected channels for the favorable transport of Zn ions with ion-confinement effects,endowing Zn@COF-S-F with dendrite-free morphology and suppressed side reactions.Consequently,Zn@COF-S-F symmetric cell can stably cycle for 1,000 h with low average hysteresis voltage(50.5 m V)at the current density of 1.5 m A cm^(-2).Zn@COF-S-F|Mn O_(2)cell delivers the discharge specific capacity of 206.8 m Ah g^(-1)at the current density of 1.2 A g^(-1)after 800 cycles with high-capacity retention(87.9%).Enlightening,building artificial SEI on metallic Zn surface with targeted design has been proved as the effective strategy to foster the practical application of high-performance AZIBs.

Unveiling the tailorable electrochemical properties of zeolitic imidazolate framework-derived Ni-doped LiCoO_(2) for lithium-ion batteries in half/full cells

As a prevailing cathode material of lithium-ion batteries(LIBs),LiCoO_(2)(LCO)still encounters the tricky problems of structural collapse,whose morphological engineering and cation doping are crucial for surmounting the mechanical strains and alleviating phase degradation upon cycling.Hereinafter,we propose a strategy using a zeolitic imidazolate framework(ZIF)as the self-sacrificing template to directionally prepare a series of LiNi_(0.1)Co_(0.9)O_(2)(LNCO)with tailorable electrochemical properties.The rational selection of sintering temperature imparts the superiority of the resultant products in lithium storage,during which the sample prepared at 700℃(LNCO-700)outperforms its counterparts in cyclability(156.8 mA h g^(-1)at 1 C for 200 cycles in half cells,1 C=275 mA g^(-1))and rate capability due to the expedited ion/electron transport and the strengthen mechanical robustness.The feasibility of proper Ni doping is also divulged by half/full cell tests and theoretical study,during which LNCO-700(167 mA h g^(-1)at 1 C for 100 cycles in full cells)surpasses LCO-700 in battery performance due to the mitigated phase deterioration,stabilized layered structu re,ameliorated electro nic co nductivity,a nd exalted lithium sto rage activity.This work systematically unveils tailorable electrochemical behaviors of LNCO to better direct their practical application.

A Transfer Learning Framework for Deep Multi-Agent Reinforcement Learning

Dear Editor,This letter presents a new transfer learning framework for the deep multi-agent reinforcement learning(DMARL) to reduce the convergence difficulty and training time when applying DMARL to a new scenario [1], [2].