The effects of five amendments such as acetic acid（AA）, citric acid （CA）, ethylenediamine tetraacetic acid （EDTA）, sepiolite and phosphogypsum on growth and metal uptake of giant reed （Arundo donax L.） grown o...The effects of five amendments such as acetic acid（AA）, citric acid （CA）, ethylenediamine tetraacetic acid （EDTA）, sepiolite and phosphogypsum on growth and metal uptake of giant reed （Arundo donax L.） grown on soil contaminated by arsenic （As）, cadmium （Cd） and lead （Pb） were studied. The results showed that the shoot biomass of giant reed was enhanced by 24.8% and 15.0%, while superoxide mutase and catalase activities slightly varied when adding 5.0 mmol/kg CA and 2.5 mol/kg EDTA to soil as compared to the control, respectively. The concentrations of As, Cd and Pb in shoots were remarkably increased by the addition of 2.5 mmol/kg AA and CA, 5.0 mmol/kg EDTA, and 4.0 g/kg sepiolite as compared to the control. The accumulations of As and Cd were also significantly enhanced in the above condition, while the shoot Pb accumulation was noticeably enhanced by amending with 4.0 g/kg sepiolite and 8.0 g/kg phosphogysum, respectively. The results suggested that AA, CA and sepiolite could be used as optimum soil amendments for giant reed remediation system.展开更多
The pyrolysis of phytoremediated giant reed(Arundo donax)biomass could cause secondary pollution of heavy metals.The stabilization of heavy metals in the pyrolysis process with external materials such as Al2O3,CaCO3,F...The pyrolysis of phytoremediated giant reed(Arundo donax)biomass could cause secondary pollution of heavy metals.The stabilization of heavy metals in the pyrolysis process with external materials such as Al2O3,CaCO3,FeCl3and NaOH,wasstudied.The results showed that37%As and97%Cd in biochar were stabilized when giant reed powder was pyrolyzed at250°Cwith5%Al2O3for2h.Furthermore,59%Pb in biochar was stabilized at400°C with5%CaCO3for1h.Under biochar produced inoptimized pyrolysis conditions,Cd mainly existed in a residual fraction,while Pb and As mainly existed in oxidizable fraction inBCR analysis.In XRD analysis,As was only found in Ca2As2O7;Cd in biochar mainly existed in Cd(AlCl4)2,CdPbO3or CdSO3;and Pb mainly existed as Pb3O2SO4.展开更多
A greenhouse experiment was conducted to elucidate the growth changes and tissues anatomical characteristics of giant reed(Arundo donax L.),a perennial rhizomatous grass,which was cultivated for 70 d in soils contamin...A greenhouse experiment was conducted to elucidate the growth changes and tissues anatomical characteristics of giant reed(Arundo donax L.),a perennial rhizomatous grass,which was cultivated for 70 d in soils contaminated with As,Cd and Pb.The results show that giant reed rapidly grows with big biomass of shoots in contaminated soil,possessing strong metal-tolerance with limited metal translocation from roots to shoots.When As,Cd and Pb concentrations in the soil are less than 254,76.1 and 1 552 mg/kg,respectively,plant height and dried biomass are slightly reduced,the accumulation of As,Cd and Pb in shoots of giant reed is low while metal concentration in roots is high,and the anatomical characteristics of stem tissues are thick and homogeneous according to SEM images.However,plant height and dried biomass are significantly reduced and metal concentration in plant shoots and roots are significantly increased(P<0.05),the stems images become heterogeneous and the secretion in vascular bundles increases significantly when As,Cd and Pb concentrations in the soil exceed 334,101 and 2 052 mg/kg,respectively.The giant reed is a promising,naturally occurring plant with strong metal-tolerance,which can be cultivated in soils contaminated with multiple metals for ecoremediation purposes.展开更多
基金Project (2012BAC09B04) supported by National Key Technology Research and Development Program of the Ministry of Science and Technology of ChinaProject (2010-277-027) supported by Science and Technology Foundation of Environmental Protection in Hunan Province,ChinaProject (2011SK3262) supported by Science and Technology Planning of Hunan Province,China
文摘The effects of five amendments such as acetic acid（AA）, citric acid （CA）, ethylenediamine tetraacetic acid （EDTA）, sepiolite and phosphogypsum on growth and metal uptake of giant reed （Arundo donax L.） grown on soil contaminated by arsenic （As）, cadmium （Cd） and lead （Pb） were studied. The results showed that the shoot biomass of giant reed was enhanced by 24.8% and 15.0%, while superoxide mutase and catalase activities slightly varied when adding 5.0 mmol/kg CA and 2.5 mol/kg EDTA to soil as compared to the control, respectively. The concentrations of As, Cd and Pb in shoots were remarkably increased by the addition of 2.5 mmol/kg AA and CA, 5.0 mmol/kg EDTA, and 4.0 g/kg sepiolite as compared to the control. The accumulations of As and Cd were also significantly enhanced in the above condition, while the shoot Pb accumulation was noticeably enhanced by amending with 4.0 g/kg sepiolite and 8.0 g/kg phosphogysum, respectively. The results suggested that AA, CA and sepiolite could be used as optimum soil amendments for giant reed remediation system.
基金Projects(21577176,41271330) supported by the National Natural Science Foundation of China
文摘The pyrolysis of phytoremediated giant reed(Arundo donax)biomass could cause secondary pollution of heavy metals.The stabilization of heavy metals in the pyrolysis process with external materials such as Al2O3,CaCO3,FeCl3and NaOH,wasstudied.The results showed that37%As and97%Cd in biochar were stabilized when giant reed powder was pyrolyzed at250°Cwith5%Al2O3for2h.Furthermore,59%Pb in biochar was stabilized at400°C with5%CaCO3for1h.Under biochar produced inoptimized pyrolysis conditions,Cd mainly existed in a residual fraction,while Pb and As mainly existed in oxidizable fraction inBCR analysis.In XRD analysis,As was only found in Ca2As2O7;Cd in biochar mainly existed in Cd(AlCl4)2,CdPbO3or CdSO3;and Pb mainly existed as Pb3O2SO4.
基金Project(20507022) supported by the National Natural Science Foundation of China
文摘A greenhouse experiment was conducted to elucidate the growth changes and tissues anatomical characteristics of giant reed(Arundo donax L.),a perennial rhizomatous grass,which was cultivated for 70 d in soils contaminated with As,Cd and Pb.The results show that giant reed rapidly grows with big biomass of shoots in contaminated soil,possessing strong metal-tolerance with limited metal translocation from roots to shoots.When As,Cd and Pb concentrations in the soil are less than 254,76.1 and 1 552 mg/kg,respectively,plant height and dried biomass are slightly reduced,the accumulation of As,Cd and Pb in shoots of giant reed is low while metal concentration in roots is high,and the anatomical characteristics of stem tissues are thick and homogeneous according to SEM images.However,plant height and dried biomass are significantly reduced and metal concentration in plant shoots and roots are significantly increased(P<0.05),the stems images become heterogeneous and the secretion in vascular bundles increases significantly when As,Cd and Pb concentrations in the soil exceed 334,101 and 2 052 mg/kg,respectively.The giant reed is a promising,naturally occurring plant with strong metal-tolerance,which can be cultivated in soils contaminated with multiple metals for ecoremediation purposes.
