Study of the Diffusion Behavior of Seawater Absorption in Multi-Walled Carbon Nanotubes/Halloysite Nanotubes Hybrid Nanofillers Modified Epoxy-Based Glass/Carbon Fiber Composites

In the maritime industry, cost-effective and lightweight Fiber Reinforced Polymer (FRP) composites offer excellent mechanical properties, design flexibility, and corrosion resistance. However, their reliability in harsh seawater conditions is a concern. Researchers address this by exploring three approaches: coating fiber surfaces, hybridizing fibers and matrices with or without nanofillers, and interply rearrangement. This study focuses on evaluating the synergistic effects of interply rearrangement of glass/carbon fibers and hybrid nanofillers, specifically Multi-walled carbon nanotubes (MWCNT) and Halloysite nanotubes (HNT). The aim is to enhance impact properties by minimizing moisture absorption. Hybrid nanocomposites with equal-weight proportions of two nanofillers: 0 wt.%, 1 wt.%, and 2 wt.% were exposed to seawater for 90 days. Experimental data was subjected to modelling through the application of Predictive Fick’s Law. The study found that the hybrid composite containing 2 wt.% hybrid nanofillers exhibited a 22.10% increase in impact performance compared to non-modified counterparts. After 90 days of seawater aging, the material exhibited enhanced resistance to moisture absorption (15.74%) and minimal reduction in impact strength (8.52%) compared to its dry strength, with lower diffusion coefficients.

Numerical Optimization by Finite Element Method of Stainless Steel/Glass-Epoxy Composite Bolted Joint under Tension and Compression

The aim of this study was to optimize the geometry and the design of metallic/composite single bolted joints subjected to tension-compression loading. For this purpose, it was necessary to evaluate the stress state in each component of the bolted join. The multi-material assembly was based on the principle of double lap bolted joint. It was composed of a symmetrical balanced woven glass-epoxy composite material plate fastened to two stainless sheets using a stainless pre-stressed bolt. In order to optimize the design and the geometry of the assembly, ten configurations were proposed and studied: a classical simple bolted joint, two joints with an insert (a BigHeadR insert and a stair one) embedded in the composite, two “waved” solutions, three symmetrical configurations composed of a succession of metallic and composites layers, without a sleeve, with one and with two sleeves, and two non-symmetrical constituted of metallic and composites layers associated with a stair-insert (one with a sleeve and one without). A tridimensional Finite Element Method (FEM) was used to model each configuration mentioned above. The FE models taked into account the different materials, the effects of contact between the different sheets of the assembly and the pre-stress in the bolt. The stress state was analyzed in the composite part. The concept of stress concentration factor was used in order to evaluate the stress increase in the highly stressed regions and to compare the ten configurations studied. For this purpose, three stress concentration factors were defined: one for a monotonic loading in tension, another for a monotonic loading in compression, and the third for a tension-compression cyclic loading. The results of the FEM computations showed that the use of alternative metallic and composite layers associated with two sleeves gived low values of stress concentration factors, smaller than 1.4. In this case, there was no contact between the bolt and the composite part and the most stressed region was not the vicinity of the hole but the end of the longest layers of the metallic inserts.

Innovative dispersion techniques of graphene nanoplatelets(GNPs)through mechanical stirring and ultrasonication:Impact on morphological,mechanical,and thermal properties of epoxy nanocomposites

Graphene nanoplatelets(GNPs)have attracted tremendous interest due to their unique properties and bonding capabilities.This study focuses on the effect of GNP dispersion on the mechanical,thermal,and morphological behavior of GNP/epoxy nanocomposites.This study aims to understand how the dispersion of GNPs affects the properties of epoxy nanocomposite and to identify the best dispersion approach for improving mechanical performance.A solvent mixing technique that includes mechanical stirring and ultrasonication was used for producing the nanocomposites.Fourier transform infrared spectroscopy was used to investigate the interaction between GNPs and the epoxy matrix.The measurements of density and moisture content were used to confirm that GNPs were successfully incorporated into the nanocomposite.The findings showed that GNPs are successfully dispersed in the epoxy matrix by combining mechanical stirring and ultrasonication in a single step,producing well-dispersed nanocomposites with improved mechanical properties.Particularly,the nanocomposites at a low GNP loading of 0.1 wt%,demonstrate superior mechanical strength,as shown by increased tensile properties,including improved Young's modulus(1.86 GPa),strength(57.31 MPa),and elongation at break(4.98).The nanocomposite with 0.25 wt%GNP loading performs better,according to the viscoelastic analysis and flexural properties(113.18 MPa).Except for the nanocomposite with a 0.5 wt%GNP loading,which has a higher thermal breakdown temperature,the thermal characteristics do not significantly alter.The effective dispersion of GNPs in the epoxy matrix and low agglomeration is confirmed by the morphological characterization.The findings help with filler selection and identifying the best dispersion approach,which improves mechanical performance.The effective integration of GNPs and their interaction with the epoxy matrix provides the doorway for additional investigation and the development of sophisticated nanocomposites.In fields like aerospace,automotive,and electronics where higher mechanical performance and functionality are required,GNPs'improved mechanical properties and successful dispersion present exciting potential.

Research on properties of hollow glass microspheres/epoxy resin composites applied in deep rock in-situ temperature-preserved coring

Deep petroleum resources are in a high-temperature environment.However,the traditional deep rock coring method has no temperature preserved measures and ignores the effect of temperature on rock porosity and permeability,which will lead to the distortion of the petroleum resources reserves assessment.Therefore,the hollow glass microspheres/epoxy resin(HGM/EP)composites were innovatively proposed as temperature preserved materials for in-situ temperature-preserved coring(ITP-Coring),and the physical,mechanical,and temperature preserved properties were evaluated.The results indicated that:As the HGM content increased,the density and mechanical properties of the composites gradually decreased,while the water absorption was deficient without hydrostatic pressure.For composites with 50 vol%HGM,when the hydrostatic pressure reached 60 MPa,the water absorption was above 30.19%,and the physical and mechanical properties of composites were weakened.When the hydrostatic pressure was lower than 40 MPa,the mechanical properties and thermal conductivity of composites were almost unchanged.Therefore,the composites with 50 vol%HGM can be used for ITPCoring operations in deep environments with the highest hydrostatic pressure of 40 MPa.Finally,to further understand the temperature preserved performance of composites in practical applications,the temperature preserved properties were measured.An unsteady-state heat transfer model was established based on the test results,then the theoretical change of the core temperature during the coring process was obtained.The above tests results can provide a research basis for deep rock in-situ temperature preserved corer and support accurate assessment of deep petroleum reserves.

Influence of Non-smooth Surface on Tribological Properties of Glass Fiber-epoxy Resin Composite Sliding against Stainless Steel under Natural Seawater Lubrication

With the development of bionics, the bionic non-smooth surfaces are introduced to the field of tribology. Although non-smooth surface has been studied widely, the studies of non-smooth surface under the natural seawater lubrication are still very fewer, especially experimental research. The influences of smooth and non-smooth surface on the frictional properties of the glass fiber-epoxy resin composite（GF/EPR） coupled with stainless steel 316 L are investigated under natural seawater lubrication in this paper. The tested non-smooth surfaces include the surfaces with semi-spherical pits, the conical pits, the cone-cylinder combined pits, the cylindrical pits and through holes. The friction and wear tests are performed using a ring-on-disc test rig under 60 N load and 1000 r/min rotational speed. The tests results show that GF/EPR with bionic non-smooth surface has quite lower friction coefficient and better wear resistance than GF/EPR with smooth surface without pits. The average friction coefficient of GF/EPR with semi-spherical pits is 0.088, which shows the largest reduction is approximately 63.18% of GF/EPR with smooth surface. In addition, the wear debris on the worn surfaces of GF/EPR are observed by a confocal scanning laser microscope. It is shown that the primary wear mechanism is the abrasive wear. The research results provide some design parameters for non-smooth surface, and the experiment results can serve as a beneficial supplement to non-smooth surface study.

Experimental Study on Influence of Dimples on Lubrication Performance of Glass Fiber-epoxy Resin Composite under Natural Seawater Lubrication

Bionic non-smooth surface is widely applied in metal and ceramics materials. In order to introduce this technology to high pressure seawater pump, the influence of bionic non-smooth surface on the engineering plastics used in pump should be investigated. The comparative tests are carried out with a ring-on-disc configuration under 800, 1000, 1200 and 1400 r/min in order to research the influence of the bionic non-smooth surface on glass fiber-epoxy resin composite（GF/EPR） under natural seawater lubrication. The disc surfaces are textured with five kinds of pits, which are semi-spherical, conical, cone-cylinder combined, cylindrical pits and through holes, respectively. A smooth surface is tested as reference. The results show that the lubrication performance of dimpled GF/EPR sample is much better than that of the smooth sample under all rotational speeds. The semi-spherical pits surface has more obvious friction reduction than the others, which shows that the least reduction is approximately 43.29% of smooth surface under 1200 r/rain. However, the wear level is only marginally influenced by dimples. The surface morphology investigations disclose severe modifications caused by abrasive wear primarily. The results are helpful to vary friction properties of GF/EPR by non-smooth surface, or provide references to the design of non-smooth surfaces under certain condition.

Low velocity impact studies of E-glass/epoxy composite laminates at different thicknesses and temperatures

Low velocity impact experiments were carried out on E-glass/epoxy composite laminates having varying thicknesses at sub zero and elevated temperatures using hemi spherical steel impactor of 16 mm diameter with impact energies in the rage of 50-150 J.The performance of the laminates was assessed in terms of energy absorption,maximum displacement,peak force and failure behaviour.Results indicated that the effect of temperature on energy absorption of the laminate is negligible although the laminates are embrittling at sub zero temperatures.However it has influence on failure behaviour and displacement.Peak force has increased linearly with increase in laminate thickness from 5 to 10 mm.However it got reduced by 25% when temperature was increased from-20℃ to 100℃,Based on experimental results,laminate perforation energies were predicted using curve fitting equations.Statistical analysis was carried out using Taguchi method to identify the global effects of various parameters on laminate performance and confirmed that the laminate thickness has significant influence as compared to temperature,for the studied range.

Strain coordination of quasi-plane-hypothesis for reinforced concrete beam strengthened by epoxy-bonded glass fiber reinforced plastic plate

The testing of thirteen reinforeed concrete （RC） beams strengthened by epoxy-bonded glass fiber reinforced plastic plate （GFRP） shows that the RC beam and the GFRP plate with epoxy bonding on it can work fairly well in coordination to eaeh other. But there is relative slipping between RC beam and GFRP plate. And the strain of GFRP and steel rebar of RC beam satisfies the quasi-plane-hypothesis, that is, the strain of longitudinal fiher that parallels to the neutral axis of plated beam within the scope of effective height （ h0 ） of the cross section is in direct proportion to the distance from the fiber to the neutral axis. The strain of GFRP and steel rebar satisfies the equation： εGFRP=Kεsteel.

Mechanical properties of short carbon/glass fiber reinforced high mechanical performance epoxy resins

To research the relationship between epoxy and fiber inherent property and mechanical properties of composite,we prepared a series of composites using three kinds of high mechanical performance epoxy resins as matrices and reinforced by the same volume fraction(5%)of short carbon and glass fiber.Their mechanical properties were investigated from the perspective of chemical structure and volume shrinkage ratio of epoxy.We analyzed their tensile strength and modulus based on the mixing rule and Halpin-Tsai eq...

CONSTITUTIVE MODEL AND DYNAMIC MECHANICAL PROPERTIES OF GLASS-CLOTH/EPOXY LAMINATES AT DIFFERENT TEMPERATURES

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Effect of Ultrasonication on the Properties of Multi-walled Carbon Nanotubes/Hollow Glass Microspheres/Epoxy Syntactic Foam

Multi-walled carbon nanotubes（MWCNTs） reinforced hollow glass microspheres（HGMs）/epoxy syntactic foam was fabricated. The effects of ultrasonication on the density, compression strength, and water absorption properties were studied. Better dispersed MWCNTs can be obtained after ultrasonication treatment, but an increasing viscosity will lead to a larger amount of voids during syntactic foam preparation especially when the content of HGMs is more than 70 vol%. The existing voids will decrease the density of epoxy syntactic foam. However, the ultrasonication does not change the compression strength much. Ultrasonication treatment will decrease the water absorption content due to the better dispersion and hydrophobic properties of MWCNTs. But a significant increase of water absorption content occurs when HGMs is more than 70 vol%, which is attributed to the higher viscosity and larger amount of voids.

Flash X-ray radiography technique to study the high velocity impact of soft projectile on E-glass/epoxy composite material

In the present paper, the high velocity impact of 9 mm soft lead projectile on 10 mm and 30 mm thick Eglass/epoxy composites was studied using a 450 kV Flash X-ray radiography(FXR) system. The basic parameters of FXR imaging, such as effect of ratio of target to film(TF) and source to target(ST) distances and X-ray penetration thickness of the composite material were optimized based on clarity and the actual dimensions of the objects. The optimized parameters were used in the FXR imaging of the ballistic event of 9 mm soft projectile on E-glass/epoxy composite. The real time deformation patterns of both the projectile and composite target during the ballistic impact were captured and studied at different time intervals. The notable failure modes of the 10 mm thick target with time include fibre breakage, bulging on the back side, delamination, recovery of the bulging, reverse bulging and its recovery. However, with increase in thickness of the target to 30 mm the only failure mechanism observed is the breaking of fibres. The ballistic impact event was also numerically simulated using commercially available LS-DYNA software. The numerically simulated deformation patterns of the projectile and target at different time intervals are closely matching with the corresponding radiographic images.

Influence of Nano-Modification on the Interlaminar Shear Strength of Unidirectional Glass Fiber-Reinforced Epoxy Resin

Interlaminar shear properties of the fibre reinforced polymer composites are very important in many structured applications. It has been reported that interlaminar shear strength (ILSS) of fibre reinforced polymer composites may be improved by the modification of the matrix. In this paper, diglycidyl ether of bisphenol A (DGEBA)/triethylene tetramine (TETA) system is used as the starting epoxy matrix. Alumina nanoparticles are employed to modify the epoxy matrix at various concentrations. Unmodified and modified epoxy resins are used along with unidirectional glass fibres for fabricating composite laminates by vaccum bagging method. The interlaminar shear strength of the glass fibre reinforced composites is investigated and the results indicate that introduction of the alumina nanoparticles enhances the ILSS. In particular, the addition of 0.8 wt% alumina nanoparticles leads to maximum enhancement in the ILSS;however, there is a decrease in the value with further addition. The dispersion of alumina nanoparticles and the fracture surfaces of the fibre reinforced composites are examined by the scanning electron microscope. The graphs are employed to explain the results.

Interlaminar Fracture Toughness of Epoxy Glass Fiber Fly Ash Laminate Composite

Epoxy glass fiber laminate composite (PMCs) are finding ever increasing applications in aerospace and automobile industries due to its high strength to weight ratio and resistance to aqueous environment. Additions of particulate reinforcements in the polymer matrix are reported to improve the Interlaminar Shear Strength and Interlaminar Fracture Toughness of the composites. In the present investigation, epoxy glass fiber laminate composites were processed using hand layup and vacuum bagging technique. The particulate reinforcement precipitator fly ash (25 - 45 μm) was added in the epoxy matrix by mechanical mixing up to 10 wt%. The effects of fly ash reinforcement on the mechanical properties and Interlaminar Fracture Toughness were studied before and after exposure to aqueous fog in a salt fog chamber at 45°C. In unexposed condition Mode I interlaminar fracture toughness of epoxy glass fiber laminate composite improved by the addition of fly ash reinforcement 10% (By weight) by 49.43% and when it was subjected to aqueous fog for 10 days the interlaminar fracture toughness improved 58.42%. Exposure to aqueous fog for 10 days causes plasticization of resin matrix and weakening of fiber/matrix interface results in improvement in interlaminar fracture toughness. The fracture surfaces were analyzed using scanning electron microscopy.

Studies on Mechanical Properties of Jute/E-Glass Fiber Reinforced Epoxy Hybrid Composites

Hybrid materials of any class are essential for current demands. This paper deals with the hybrid effect of composites made of jute/E-Glass fibers which are fabricated by hand layup method using LY556 Epoxy resin and HY951 hardener. The properties of this hybrid composite are determined by testing like tensile, flexural, impact, and inter laminar shear strength which are evaluated experimentally according to ASTM standards. The result of the test shows that hybrid composite of jute/ E-glass fiber has far better properties than that of jute fiber composite. However, it is found that the hybrid composite has better strength as compared to jute fiber composite fabricated separately with glass fiber.

Preparation and Characterization of ZnO-CuO-Bi_(2)O_(3)-B_(2)O_(3)-SiO_(2)System Low Melting Sealing Glasses

Lead-free low melting glasses,ZnO-CuO-Bi_(2)O_(3)-B_(2)O_(3)-SiO_(2)system,with fixed contents of 15 mol%CuO and 20 mol%Bi_(2)O_(3),were prepared by using melt cooling method.Structure and thermal properties of the glasses were studied by using X-ray diffractometer(XRD),infrared spectrometer(FIT-IR),thermal dilatometer and differential thermal analyzer(DTA).Chemical durability of the glasses was studied by using dissolution rate method.Wettability of glasses on substrate was tested by using button sintering experiment.It is found that alkaline resistance of the glass solders is lower than that of plate glass and the water resistance is comparable with that of plate glass.The sealing temperatures are Ts=445-490℃,while the average thermal expansion coefficient from room temperature to 300℃is in the range of(65-82)×10^(−7)℃^(−1).At sealing temperature,the glass solders have good wettability on plate glass or alumina substrate.They are not crystallized even sintered at the sealing temperature for 30 min.The solder glasses are suitable for sealing plate glass,alumina and other inorganic non-metallic materials.

Greatly enhanced corrosion/wear resistances of epoxy coating for Mg alloy through a synergistic effect between functionalized graphene and insulated blocking layer

The poor corrosion and wear resistances of Mg alloys seriously limit their potential applications in various industries.The conventional epoxy coating easily forms many intrinsic defects during the solidification process,which cannot provide sufficient protection.In the current study,we design a double-layer epoxy composite coating on Mg alloy with enhanced anti-corrosion/wear properties,via the spin-assisted assembly technique.The outer layer is functionalized graphene(FG)in waterborne epoxy resin(WEP)and the inner layer is Ce-based conversion(Ce)film.The FG sheets can be homogeneously dispersed within the epoxy matrix to fill the intrinsic defects and improve the barrier capability.The Ce film connects the outer layer with the substrate,showing the transition effect.The corrosion rate of Ce/WEP/FG composite coating is 2131 times lower than that of bare Mg alloy,and the wear rate is decreased by~90%.The improved corrosion resistance is attributed to the labyrinth effect(hindering the penetration of corrosive medium)and the obstruction of galvanic coupling behavior.The synergistic effect derived from the FG sheet and blocking layer exhibits great potential in realizing the improvement of multi-functional integration,which will open up a new avenue for the development of novel composite protection coatings of Mg alloys.

Corrosion and in vitro cytocompatibility investigation on the designed Mg-Zn-Ag metallic glasses for biomedical application

In the present work,seven Mg-Zn-Ag alloys with the nominal composition of Mg_(96-x)Zn_(x)Ag_(4)(x=17,20,23,26,29,32,35 in at.%)were prepared by induction melting and single-roller melt-spinning.The X-ray diffraction(XRD)analyses indicate the metallic glasses with three composition of Mg_(73)Zn_(23)Ag_(4),Mg_(70)Zn_(26)Ag_(4),and Mg_(67)Zn_(29)Ag_(4)were obtained successfully.The differential scanning calorimetry(DSC)measurement was used to obtain the characteristic temperature of Mg-Zn-Ag metallic glasses for the glass-forming ability analysis.The maximum glass transition temperature(Trg)was found to be 0.525 with a composition close to Mg_(67)Zn_(29)Ag_(4),which results in the best glass-forming ability.Moreover,the immersion test in simulated body fluid(SBF)demonstrate the relative homogeneous corrosion behavior of the Mg-Zn-Ag metallic glasses.The corrosion rate of Mg-Zn-Ag metallic glasses in SBF solution decreases with the increase of Zn content.The sample Mg_(67)Zn_(29)Ag_(4)has the lowest corrosion rate of 0.19mm/yr,which could meet the clinical application requirement well.The in vitro cell experiments show that the Madin-Darby canine kidney(MDCK)cells cultured in sample Mg_(67)Zn_(29)Ag_(4)and its extraction medium have higher activity.However,the Mg-Zn-Ag metallic glasses exhibit obvious inhibitory effect on human rhabdomyosarcoma(RD)tumor cells.The present investigations on the glass-forming ability,corrosion behavior,cytocompatibility and tumor inhibition function of the Mg-Zn-Ag based metallic glass could reveal their biomedical application possibility.

Assessment of Cutting Parameters Influencing on Thrust Force and Torque during Drilling Particulate Filled Glass Fabric Reinforced Epoxy Composites

Drilling is indispensable process and it cannot be avoided for joining composite structures used in various engineering applications. In this research article, the influence of drilling parameters on thrust force and torque of silica (SiO2) and alumina (Al2O3) filled into glass fabric reinforced epoxy (G-E) composites are analyzed. Drilling experiments are conducted on these composite materials using BATLIBOI make radial drilling machine. Two different drill bits (HSS and cemented carbide) are used for the experimentation. The influence of drilling parameters like cutting speed and feed on thrust force and torque on drilling of particulate filled G-E composites has been carried out. The experimental results indicated that the thrust force and torque were increased with increasing feed and cutting speed for all the composites tested. Further, it is observed that the carbide drill performed better than HSS drill during drilling of particulate filled G-E composites. The drilled surfaces are examined using scanning electron microscopy (SEM) and damage mechanisms are discussed.