Synthesis and Coloring Mechanism of Metallic Glaze in R_(2)O-RO-Al_(2)O_(3)-SiO_(2)-P_(2)O_(5)System

A copper-red and silver-white metallic glaze of R_(2)O-RO-Al_(2)O_(3)-SiO_(2)-P_(2)O_(5)system was synthesized by adjusting the firing temperature and glaze components.The coloration mechanism of the metallic glaze was revealed via investigation of the microstructure of the glaze.Our research reveals that the metallic glaze with different colors is mainly due to the amount of Fe_(2)O_(3).The metallic glaze shows a silver-white luster due to a structural color ofα-Fe_(2)O_(3)crystals with a good orientation when the sample contains 0.0939 mol of Fe_(2)O_(3),maintaining temperatures at 1150℃for 0.5 h.The metallic glaze is copper-red which is dominated by the coupling of chemical and structural color ofα-Fe_(2)O_(3)crystals when the sample contains 0.0783 mol of Fe_(2)O_(3).After testing the amount of SiO_(2),we find that 4.0499 mol is the optimal amount to form the ceramic network,and 0.27 mol AlPO_(4)is the best amount to promote phase separation.

The Impact of Sun Radiation on the Thermal Comfort in Highly Glazed Buildings Equipped with Floor Heating Systems

Occupants of highly glazed buildings often suffer from thermal discomfort during the mid-seasons when no shadings are used in such buildings,especially when inertial heating systems are used.The present study is devoted to evaluating the impact of long solar beam exposure on the internal thermal discomfort in glazed spaces when heating is implemented through a floor system.A comprehensive experimental study is carried out using an experimental bi-climatic chamber which is fully monitored and controlled,allowing realistic simulations of the dynamic movement of the sun patch on a heated slab.The findings show that a period of discomfort as long as 8 h can occur,and persist far after the sunbeam exposure stops.During this period,the heating slab’s surface temperature,considered from an average point of view,can attain 34°C while the indoor temperature reaches 26°C.Simulations conducted using a previously developed model display a good fit with the measurements.

The Glazed Tile Techniques of the Seljuk and Beylik Periods

The word ＂tile＂ originates from Persian and means ＂China＂ or ＂Chinese work＂. In the Ottoman language, the word ＂tile＂ also means ＂Chinese work＂, or ＂belonging to China＂. The art of Turkish tiles occupies a place of prominence in the history of Islamic art. Its roots can be traced at least as far back as the Uygurs of the eighth and ninth centuries. Its subsequent development was influenced by the Karakhanids, the Ghaznavids, and （especially） Iranian Seljuk art. With the Seljuks＇ victory over the Byzantines at Malazgirt in 1071, the art followed them into Anatolia and embarked upon a new period of strong development fostered by the Anatolian Seljuk sultanate. The first major development in the art of tile-making occurred primarily in Anatolian Seljuk architecture. Various techniques have been used in the art of tiles which gave hundreds of samples for centuries. This study explores the glazed tile techniques used in the production of the S elj uk and Beylik periods.

The effect of single-horn glaze ice on the vortex structures in the wake of a horizontal axis wind turbine

The present study experimentally investigated the effect of a simulated single-horn glaze ice accreted on ro- tor blades on the vortex structures in the wake of a hori- zontal axis wind turbine by using the stereoscopic particle image velocimetry （Stereo-PIV） technique. During the ex- periments, four horizontal axis wind turbine models were tested, and both ＂free-run＂ and ＂phase-locked＂ Stereo-PIV measurements were carried out. Based on the ＂free-run＂ measurements, it was found that because of the simulated single-horn glaze ice, the shape, vorticity, and trajectory of tip vortices were changed significantly, and less kinetic en- ergy of the airflow could be harvested by the wind turbine. In addition, the ＂phase-locked＂ results indicated that the pres- ence of simulated single-horn glaze ice resulted in a dramatic reduction of the vorticity peak of the tip vortices. Moreover, as the length of the glaze ice increased, both root and tip vortex gaps were found to increase accordingly.

Effect of Fly Ash on Drying Shrinkage of Thermal Insulation Mortar with Glazed Hollow Beads

Drying shrinkage of thermal insulation mortar with glazed hollow beads was measured by a vertical length comparator, and the influences of fly ash with different contents（0, 18%, 36%, and 54% were used） on the long-term drying shrinkage were discussed. The mass loss was measured by the weighting method and the pore structure was characterized using three different methods, including the light microscopy, the mercury intrusion porosimetry（MIP）, and the nitrogen adsorption/desorption（NAD） experiments, and the correlations among them were researched. The results show that drying shrinkage process of thermal insulation mortar includes three steps with increasing curing time： the acceleration period（before 7 d）, the deceleration period（7-365 d）, and the metastable period（after 365 d）. Drying shrinkage in the first stage（7 d before） increases quickly owing to the fast water loss, and its development in the last two stages is attributed to the increment of the pore volume of mortar with the radius below 50 nm, especially the increment of the pore volume fraction of the pore radius within the size range between 7.3 nm and 12.3 nm. There is no change in the drying shrinkage development trend of mortar with fly ash addition, and three steps in the service life, but fly ash addition in the mortar restrains its value. There is a linear relationship between the drying shrinkage and fly ash content, which means that drying shrinkage reduces with fly ash addition.

A Novel Infrared Radiant Glaze Exhibiting Antibacterial and Antifungal Functions

Infrared radiant powder was synthesized by conventional ceramic processing techniques by using Fe2 O3, MnO2, CuO, Co2 O3 and kaolin as raw materials. A novel infrared radant glaze was developed by introducing the infrared radiant powder into glazing as a functional additive. Infrared radiant characteristics of the powder and the glaze were investigated. The optimum content of infrared radiant powder in glazing was ascertained to be 5% . The infrared radiant glaze exhibits significant antibacterial and antifungal Junctions due to the thermal effect of infrared radiation. Antibacterial percentages of the glaze reach 91% - 100% when Escherichia coli, Staphylococcus aureus and Bacillus subtilis are used as model bacterium respectively, while antifungal percentage of the glaze exceeds 95% when Penicillum citrinum is used as model fungus.

Preparation of Lead-free Base Glaze Suitable for Pearlescent Pigments by Low-temperature Solid-phase Reaction with Alkali Waste

A lead-free base glaze suitable for pearlescent pigments was prepared by a low-temperature solid-phase reaction with alkali waste.Tests were performed to evaluate the effects of the sintering conditions and alkali waste composition on the prepared base glaze and pearlescent glaze.The experimental results show that partially replacing SiO_(2) with B_(2)O_(3) effectively reduced the sintering temperature and time to form a glass network,but the network structure becomes disconnected as the B_(2)O_(3) content increases.An amorphous base glaze was obtained when soda ash was replaced with a small amount of alkali waste,but increasing the addition of NaCl further was adverse to base glaze formation by resulting in crystallization of the base glaze and a decrease in the bridging oxygen content.The pearlescent pigment was thermally stable in the glaze at 750℃,while higher temperatures caused the crystalline phase of NaAlSiO_(4) to appear and adhere to the surface of pigment granules,which degraded the pearlescent effect of the glaze.

Complex Impedance Spectra Analysis of SnO_2-glaze Composites

SnO2-glaze composites were prepared by Sb-doped SnO2 and SiO2-CaO-Al2O3-B2O3 glaze. The composites changed from an electrical insulator to a conductor as the SnO2 content increased from Owt% to 90 wt% . The complex impedance spectra of the fabricated composites were investigated in the frequency range of 100Hz-40 MHz and three kinds of typical shape of complex impedance spectra were recorded and analyzed. The ,spectrum is quite close to the model of conduction via nonohmic contactiug when the SnO2 content is relatively low, In high loading region, the spectrum shows the conduction pattern through ohmic contact chains . In the moderate loading region, the model is a mixture of the above two models. Equivalent circuit of the composite changes from resistor-capacitor circuit to resistor-inductor circuit as the content of SnO2 increases.

Application of cetylpyridinium chloride in dispersion of antibacterial ceramic glaze

The adsorption of cetylpyridinium chloride(CPC)onto a ceramic glaze mixture composed of limestone,feldspar,quartz,kaolin,and antibacterial agent was studied.Both adsorption isothermals and the average particle zeta potential were investigated in order to understand the suspension stability as a function of pH,ionic strength,and surfactant concentration.The results show that under the optimal conditions such as pH value of 7 or 9,0.01 mol/L of ionic strength and around critical micelle concentration(CMC)of surfactant,antibacterial ceramic glaze acquires fine dispersion stability.The adsorption of CPC on ceramic glaze particles is in accordance with Langmuir model in 0.01mol/L at pH=7 and pH=9.The adsorption of small amounts of cationic CPC onto the primarily negatively charged surfaces of the particles in the pH range of 7?9 produces strong attraction and flocculation due to hydrophobic interactions.High concentration of surfactant under 0.01 mol/L of salt provides high zeta potential,which produces a high stability.

A New Ceramic Substrate Glaze with High Resistance to Molten Aluminum

Corrosion resistance of ceramic substrate glazes to molten aluminum was studied in this paper. The glazes can spread slightly in aluminum alloy according to SEM examination of solidified interface between the glazes and aluminum alloy. The components of B2O3-P2O5 glazes were not detected with electron probe at the side of aluminum alloy near the interface, but the components of boron-free glaze were detected. It is shown that borophosphate glazes can resist the corrosion of molten aluminum.

Influence of Rare Earth Composite Phosphate on Surface Free Energy of Ceramic Glaze

Rare earth composite phosphate (RECP) was doped into the ceramic glazes. The contact angle and surface free energy were characterized by the OCA-30 automatism contact angle test system. Through studied the influence of RECP on the surface free energy of ceramic glaze and movement modality of oil on the ceramic glaze in the water, the results show that the ceramic surface free energy increase obviously after dope RECP. Analysis and calculation show that the surface free energy increase mainly profited from the surface hydroxyl groups increase.

A Study of Ca-Mg Silicate Crystalline Glazes——An Analysis on Forms of Crystals

In the study on Ca-Mg silicate crystalline glazes, we found some disequilibrated crystallization phenomena, such as non-crystallographic small angle forking and spheroidal growth, parasitism and wedging-form of crystals, dendritic growth, secondary nucleation, etc. Those phenomena possibly resulted from two factors: (1) partial temperature gradient, which is caused by heat asymmetry in the electrical resistance furnace, when crystals crystalize from silicate melt; (2) constitutional supercooling near the surface of crystals. The disparity of disequilibrated crystallization phenomena in different main crystalline phases causes various morphological features of the crystal aggregates. At the same time, disequilibrated crystallization causes great stress retained in the crystals, which results in cracks in glazes when the temperature drops. According to the results, the authors analyzed those phenomena and displayed correlative figures and data.

Effect of heat treatment temperature of the glaze lager on the structure and the formaldehyde removal performance of an interior wall tile

With the improvement of people’s living standards,a large number of petroleum products,daily necessities and decorations that can produce volatile organic compounds are used in decoration,which seriously affects the indoor air quality.Interior decoration materials have become a research hotspot in recent years.The purpose of this paper is to develop a kind of interior wall material with good indoor formaldehyde removal effect,easily using,and low cost.In this paper,combining different heat treatment temperatures of the glaze layer,tourmaline/diatomite-based interior wall tiles were prepared by ultrafine grinding,solid sintering,and low temperature calcination.The glaze layer under different heat treatment temperatures was characterized by thermogravimetric-differential thermal analysis,X-ray diffraction,and scanning electron microscope.The influences of heat treatment temperature on the microscopic morphology and structure of the glaze layer were analyzed.Taking formaldehyde as the target degradation product,the effects of tourmaline/diatomite-based interior wall tiles on the removal of formaldehyde under different heat treatment temperatures of the glaze layer were investigated.The results showed that with the increase in heat treatment temperature,the original pores of diatomite decreased,the specific surface area decreased,and the structure of tourmaline changed.At 850℃,the surface structure of the material was slightly damaged,the strength was increased,and the removal effect of formaldehyde was better.In a 1 m^(3) environmental chamber,the formaldehyde removal rate reached 73.6%in 300 min.When the temperature was increased to 950℃ and above,diatomite and the structure of tourmaline were destroyed,and the ability of the material to adsorb and degrade formaldehyde decreased.

Research on the Application in Glazed Tile Heating of the Low-Carbon Catalytic Combustion Furnace of Natural Gas

This experiment aims to summarize the regular pattern of low-carbon catalytic combustion furnace of natural gas used in glazed tile heating. The tiles used for decorating which are heated by catalytic combustion furnace are more fine and glossy than the conventional ones, moreover, pollutant emission produced in productive process is much less than before. This conclusion may provide a new way to glazed tile heating industry, and at the same time, provide a general method of using the catalytic combustion furnace.

Lime-Barium and Lime-Zinc Raw Glazes with Raw Materials from Tanzania and Cameroon

In the paper, the lime-barium and lime-zinc glazes used in Southern and Eastern Africa Mineral Center (SEAMIC) ceramic unit in Tanzania were investigated for the production of high temperature raw glazes in Cameroon. The base Seger formula used was 0.3KNaO, 0.3CaO, 0.4ZnO or BaO;xAl2O3 and ySiO2. Different Al2O3/SiO2 formula ratios for glossy and matt glazes were tested with raw materials from Cameroon and Tanzania. In the Cameroonian glazes, a local pegmatite (quartz, microcline, albite) with low coloured oxides replaced an albitic feldspar in the Tanzanian glazes. The other materials were kaolin, limestone, silica and barium carbonate or zinc oxide. The glazes were tested at Seger Cone 7 (1240℃) on stoneware slabs (made up of the same feldspathic glaze material: 18%, silica sand or quartz 27%, ball clay 40% and kaolin 15%) from both Tanzania and Cameroon materials. From results obtained, zinc oxide acted as a more vigorous flux than barium carbonate at cone 7, which is obvious in the glazes with pegmatite (with high quartz content). At a Seger formula of Al2O3/SiO21:10, transparent glazes were obtained. In these glazes the alumina content was lower and when increased to higher Seger ratios 1:4.7 - 8.7, the gloss was lowered to matt-luster due to fine crystal formation.

Creating Matte and Opaque Stable Colored Glazes on Local Omani Earthenware Pottery: Testing White Zircon Borax Frit Glaze Recipes

The ability of Omani local pottery earthenware to accept low- and medium-temperature fired glazes can face technical difficulties. The impurities included in the clays extracted from local fields, especially iron oxide, are a noted weakness that affects painting the local pottery with shiny, opaque, or matte glazes. Previously published research conducted by the researcher on Omani earthenware clays focused on finding a special transparent, shiny, and stable glazing recipe, but few studies have provided matte and opaque glazing recipes that are technically suitable for local Omani clays. By using laboratory-based experimental methodology, this research will investigate the possibility of using White Zircon Borax Frit (WZBF) to develop matte and opaque stable glazes that are suitable with local Omani pottery clay bodies. In the end of this experimental research, the purpose of this project is to develop applicable glazing recipes to be used for painting pots made by Omani clays.

Investigation of the Effects of Glazed Balconies uponThermal Comfort in Hot Tropical Region

The balcony is responsible to a series of effects on the environmental behavior of a building,mainly in relation of thermal comfort and air distribution to their indoor spaces.Currently a very common practice in several metropolitan areas is the closing with retractable glass panels in balcony openings.This work analyzed the effects of glazed balconies upon thermal comfort in a hot tropical region.Environmental parameters were carried out in a flat alternating the conditions of retractable glass panels to balconies.Thermal simulations were performed considering closing or not the glass door that divides the balcony room;the building material used on the balcony sill;and the use of curtains or shading devices.The results show the maximum mean hourly temperatures recorded on the balcony during the period when the retractable glass panels were closed,reaching peaks between 31.7 and 39.2°C,above the comfort range recommended by ASHRAE 55.All situations simulated show the thermal discomfort prevails in the use of the closed glass panels reaching DhTD of 94.55°C/day.Thus,this practice of using most of the closed retractable glass panels in the balconies presents disadvantages and inefficiencies especially in hot and humid tropical climate regions.

Fabrication of Multilayer Optical interference Filter as Colored Glazed Buildings Fa（;ades for Thermal Solar Collectors Using MgF2/SiO2

A simple idea to obtain a desired color that hiding the black color, and the visibility of tubes and corrugations of the metal sheet （absorber） of the thermal solar collectors which is consider the main obstacle to facade integration buildings of solar thermal collectors will be presented in this study by designing a multilayer optical interference filter during RF magnetron sputtering process. This filter work as antireflection coating in the near IR region and also includes a high colored reflectance at a specific wavelength in the visible region, this is to gain an esthetic aspect for the thermal solar collector which can be used as building facades by employing appropriate dielectric materials with high refractive index （H） like SiO2 and low refractive index （L） such as MgF2 which they deposited on glass substrate for quarterwave thickness and for the optical model air//HL//glass.