In studies on the extraction chemistry of gold, the extractants of alcohols, ethers, ketones and amines are widely used. The neutral extractants tributylphosphate (TBP) and trioctylphosphine oxide (TPPO) have been wid...In studies on the extraction chemistry of gold, the extractants of alcohols, ethers, ketones and amines are widely used. The neutral extractants tributylphosphate (TBP) and trioctylphosphine oxide (TPPO) have been widely applied. A few experiments on the synthesis of solid complexes of transition metal ions with TPPO have been car-展开更多
The solid-phase extraction（SPE） technique applied to the extraction of organic compound was creatively used as the extraction of inorganic gold in the paper.Two types of techniques were proposed and explored,namely ...The solid-phase extraction（SPE） technique applied to the extraction of organic compound was creatively used as the extraction of inorganic gold in the paper.Two types of techniques were proposed and explored,namely the SPE and the liquid–liquid extraction（LLE） of the quaternary ammonium surfactant [cetytrimethyl ammonium bromide（CTMAB）,cetyl pyridine bromide（CPB）,benzyl dimethyl dodecyl ammonium chloride（BDMDAC）,and dodecyl trimethyl ammonium chloride（DTMAC）].The surfactant could react with Au（CN）2^- to form the ionic complex,and the compound could be extracted by SPE column of reversed-phase bonded silica gel.Hence,a new method of SPE was proposed to extract gold with these features of the high selectivity,the reliability,and the simplicity.The experimental result shows that the recovery rate of gold is more than 98 %,and the solid-phase extraction column is not easily damaged and it can be repeatedly used.The new method can be used as the extraction process of gold from alkaline cyanide solution as well.Besides,the paper also puts forward a new process of gold extraction.展开更多
基金Project supported by the Science Fund of the Academia Sinica
文摘In studies on the extraction chemistry of gold, the extractants of alcohols, ethers, ketones and amines are widely used. The neutral extractants tributylphosphate (TBP) and trioctylphosphine oxide (TPPO) have been widely applied. A few experiments on the synthesis of solid complexes of transition metal ions with TPPO have been car-
基金financially supported by the National Natural Science Foundation of China (No.20471051.)
文摘The solid-phase extraction（SPE） technique applied to the extraction of organic compound was creatively used as the extraction of inorganic gold in the paper.Two types of techniques were proposed and explored,namely the SPE and the liquid–liquid extraction（LLE） of the quaternary ammonium surfactant [cetytrimethyl ammonium bromide（CTMAB）,cetyl pyridine bromide（CPB）,benzyl dimethyl dodecyl ammonium chloride（BDMDAC）,and dodecyl trimethyl ammonium chloride（DTMAC）].The surfactant could react with Au（CN）2^- to form the ionic complex,and the compound could be extracted by SPE column of reversed-phase bonded silica gel.Hence,a new method of SPE was proposed to extract gold with these features of the high selectivity,the reliability,and the simplicity.The experimental result shows that the recovery rate of gold is more than 98 %,and the solid-phase extraction column is not easily damaged and it can be repeatedly used.The new method can be used as the extraction process of gold from alkaline cyanide solution as well.Besides,the paper also puts forward a new process of gold extraction.
