Thermodynamic Modelling of Ore-Forming Mechanism of the Changkeng Gold-Silver Deposits in Guangdong Province

The Changkeng gold-silver deposits consist of a sediment-hosted, disseminated gold deposit and a replacement-type silver deposit. The mineralizations of gold and silver are zoned and closely related to the silicification of carbonate and clastic rocks, so that siliceous ores dominate in the deposit. The mineralizing temperature ranges mainly from 300 to 170℃, and K+, Na+, Ca2+, Mg2+, and Cl- are the major ions in the ore-forming fluid. Calculations of distribution of metal complexes show that gold is mainly transported by hydrosulphide complexes, but chloride complexes of silver, iron, lead, and zinc, which are transformed into hydroxyl and hydrosulphide complexes under neutral to weak-alkaline circumstances in the late stage, predominate in the ore-forming solutions. Water-rock interaction is confirmed to be the effective mechanism for the formation of silver ores by computer modelling of reaction of hydrothermal solution with carbonate rocks. The solubility analyses demonstrate that the precipitation of gold and silver-bearing minerals taking place under weak-acid conditions and near-neutral to weak-alkaline conditions, respectively, is the main or favourable factor for the ore zonation and separation between gold and silver.

Isotope Tracing and Prospecting Assessment of Gold-Silver Deposits in Zhejiang Province

Three different types of gold and silver deposits in Zhejiang Province(Huangshan gold deposit, Zhilingtou gold-silver deposit and Haoshi silver deposit) showmarked differences in lead and strontium isotopic composition, suggesting three differentsources and geneses of these deposits. The Huangshan gold deposit features low initial Srisotope ratios and low μ values or low content of radiogenic Pb and its ore-forming materialscame primarily from the upper mantle; the Zhilingtou gold-silver deposit shows high initial Srisotope ratios and high μ values or high content of radiogenic Pb and the ore-forming materialswere derived mainly from the upper crust; and the Haoshi silver deposit has its Pb and Srisotope ratios between the above two cases with the ore-forming materials stemming from boththe mantle and the crust. The characteristic Pb isotopic composition may serve as an indicatorfor prospecting for different types of ore deposits.

Geochemistry and metallogenic age of Sishanlinchang gold-silver deposit in Jidong of Heilongjiang

the Sishanlinchang gold-silver deposit is mainly composed of gold-quartz vein type ores. It has many kinds of sulfides and gold in high grade. The Au has a close correlation with As, Pb, Ag and Cu. Geochemi- cally, the deposit is characterized by relatively enrichment in LREE with moderate or lower Eu negative anoma- ly. Sulfur isotopes appear as single and deep source, and lead isotopes indicate the Pb is from the earth＇s mantle and crust, which mainly are orogenic belt Pb, the ore-forming fluid has a temperature of 215~C -350~C and a low salinity with a mixture of characteristics of magmaitc hydrothermal and meteoric water. The ore-forming age is 111. 1 - 111.4 Ma. The deposit is formed in mineralization and precipitation of metallogenie materials caused by the mixture of the magmatic hydrothermal fluid and meteoric water.

Characteristics of Ore-forming Fluid of the Gaoshan Gold-Silver Deposit in the Longquan Area, Zhejiang Province and its Implications for the Ore Genesis

The Gaoshan gold-silver deposit, located between the Yuyao-Lishui Fault and Jiangshan- Shaoxing fault in Longquan Area, occurs in the Suichang-Longquan gold-silver polymetallic metallogenic belt. This study conducted an investigation for ore-forming fluids using microthermometry, D-O isotope and trace element. The results show that two types of fluid inclusions involved into the formation of the deposit are pure liquid phase and gas-liquid phase aqueous inclusions. The homogenization temperature and salinity of major mineralization phase ranges from 156~C to 236~C （average 200~C） and 0.35% to 8.68% （NaCleqv） （average 3.68%）, respectively, indicating that the ore-forming fluid is characteristic of low temperature and low salinity. The ore- forming pressure ranges between in 118.02 to 232.13＂105 pa, and it is estabmiated that the ore- forming depth ranges from 0.39 to 0.77 km, indicating it is a hypabyssal deposit in genesis. The low rare earth elements content in pyrites, widely developed fluorite in late ore-forming stage and lack of chlorargyrite （AgCI）, indicates that the ore-forming fluid is rich in F rather than CI. The ratios of Y/ Ho, Zr/Hf and Nb/Ta of between different samples have little difference, indicating that the later hydrothermal activities had no effects on the former hydrothermal fluid. The chondrite-normalized REE patterns of pyrites from country rocks and ore veins are basically identical, with the characteristics of light REE enrichment and negative Eu anomalies, implying that the ore-forming fluid was oxidative and derived partly from the country rocks. The JD and jlSo of fluid inclusions in quartz formed during the main metallogenic stage range from -105%o to -69 %0 and -6.01%o to -3.81%o, respectively. The D-O isotopic diagram shows that the metallogenic fluid is characterized by the mixing of formation water and meteoric water, without involvement of magmatic water. The geological and geochemical characteristics of the Gaoshan gold-silver deposit are similar to those of continental volcanic hydrothermal deposit, and could be assigned to the continental volcanic hydrothermal gold-silver deposit type.

Genesis of Gold-Silver Deposits in Qingchengzi Ore Field

The gold-silver complex ore field of Qingchengzi is located in Liaohe group of Liaodong rift. The gold-silver ore bodies mainly lie in Dashiqiao group and Gaixian group. which provides ore-forming materials for the mineralization. For taking place multi-period and multi-stage magmatic activities, the ore-forming materials in the formation had had dyna- mothermal metamorphism for a long time and enriched and formed ore bodies after magmatism in Indo-Chinese and Yan- shan epoch. The ore bodies are controlled by stratigraphic formation and stored in the interformational faults and schistosity belts. Silicalite is the most important indicator for searching them. Although the Pb-Zn and the gold-silver deposits are the same series of mineralized products, their positions are different, resulting from the differences of elements nature and mineralized conditions. The gold silver deposits belong to strata-bound and hysterogeneticmesothermal-epithermal de- posit.

Jet formation and penetration performance of a double-layer charge liner with chemically-deposited tungsten as the inner liner

This paper proposes a type of double-layer charge liner fabricated using chemical vapor deposition(CVD)that has tungsten as its inner liner.The feasibility of this design was evaluated through penetration tests.Double-layer charge liners were fabricated by using CVD to deposit tungsten layers on the inner surfaces of pure T2 copper liners.The microstructures of the tungsten layers were analyzed using a scanning electron microscope(SEM).The feasibility analysis was carried out by pulsed X-rays,slug-retrieval test and static penetration tests.The shaped charge jet forming and penetration law of inner tungsten-coated double-layer liner were studied by numerical simulation method.The results showed that the double-layer liners could form well-shaped jets.The errors between the X-ray test results and the numerical results were within 11.07%.A slug-retrieval test was found that the retrieved slug was similar to a numerically simulated slug.Compared with the traditional pure copper shaped charge jet,the penetration depth of the double-layer shaped charge liner increased by 11.4% and>10.8% respectively.In summary,the test results are good,and the numerical simulation is in good agreement with the test,which verified the feasibility of using the CVD method to fabricate double-layer charge liners with a high-density and high-strength refractory metal as the inner liner.

Tumor deposits in axillary adipose tissue in patients with breast cancer:Do they matter?

Tumor deposits(TDs)are defined as discrete,irregular clusters of tumor cells lying in the soft tissue adjacent to but separate from the primary tumor,and are usually found in the lymphatic drainage area of the primary tumor.By definition,no residual lymph node structure should be identified in these tumor masses.At present,TDs are mainly reported in colorectal cancer,with a few reports in gastric cancer.There are very few reports on breast cancer(BC).For TDs,current dominant theories suggest that these are the result of lymph node metastasis of the tumor with complete destruction of the lymph nodes by the tumor tissue.Even some pathologists classify a TD as two lymph node metastases for calculation.Some pathologists also believe that TDs belong to the category of disseminated metastasis.Therefore,regardless of the origin,TDs are an indicator of poor prognosis.Moreover,for BC,sentinel lymph node biopsy is generally used at present.Whether radical axillary lymph node dissection should be adopted for BC with TDs in axillary lymph nodes is still inconclusive.The present commentary of this clinical issue has certain guiding significance.It is aimed to increase the awareness of the scientific community towards this under-recognized problem in BC pathology.

Review on laser directed energy deposited aluminum alloys

Lightweight aluminum(Al)alloys have been widely used in frontier fields like aerospace and automotive industries,which attracts great interest in additive manufacturing(AM)to process high-value Al parts.As a mainstream AM technique,laser-directed energy deposition(LDED)shows good scalability to meet the requirements for large-format component manufacturing and repair.However,LDED Al alloys are highly challenging due to their inherent poor printability(e.g.low laser absorption,high oxidation sensitivity and cracking tendency).To further promote the development of LDED high-performance Al alloys,this review offers a deep understanding of the challenges and strategies to improve printability in LDED Al alloys.The porosity,cracking,distortion,inclusions,element evaporation and resultant inferior mechanical properties(worse than laser powder bed fusion)are the key challenges in LDED Al alloys.Processing parameter optimizations,in-situ alloy design,reinforcing particle addition and field assistance are the efficient approaches to improving the printability and performance of LDED Al alloys.The underlying correlations between processes,alloy innovation,characteristic microstructures,and achievable performances in LDED Al alloys are discussed.The benchmark mechanical properties and primary strengthening mechanism of LDED Al alloys are summarized.This review aims to provide a critical and in-depth evaluation of current progress in LDED Al alloys.Future opportunities and perspectives in LDED high-performance Al alloys are also outlined.

A progress review of black carbon deposition on Arctic snow and ice and its impact on climate change

The rapid warming of the Arctic,accompanied by glacier and sea ice melt,has significant consequences for the Earth’s climate,ecosystems,and economy.Black carbon(BC)deposition on snow and ice can trigger a significant reduction in snow albedo and accelerate melting of snow and ice in the Arctic.By reviewing the published literatures over the past decades,this work provides an overview of the progress in both the measurement and modeling of BC deposition and its impact on Arctic climate change.In summary,the maximum value of BC deposition appears in the western Russian Arctic(26 ng·g^(–1)),and the minimum value appears in Greenland(3 ng·g^(–1)).BC records in the Arctic ice core already peaked in 1920s and 1970s,and shows a regional difference between Greenland and Canadian Arctic.The different temporal variations of Arctic BC ice core records in different regions are closely related to the large variability of BC emissions and transportation processes across the Arctic region.Model simulations usually underestimate the concentration of BC in snow and ice by 2–3 times,and cannot accurately reflect the seasonal and regional changes in BC deposition.Wet deposition is the main removal mechanism of BC in the Arctic,and observations show different seasonal variations in BC wet deposition in Ny-Ålesund and Barrow.This discrepancy may result from varying contributions of anthropogenic and biomass burning(BB)emissions,given the strong influence by BC from BB emissions at Barrow.Arctic BC deposition significantly influences regional climate change in the Arctic,increasing fire activities in the Arctic have made BB source of Arctic BC more crucial.On average,BC in Arctic snow and ice causes an increase of+0.17 W·m^(–2)in radiative forcing and 8 Gt·a^(–1)in runoff in Greenland.As stressed in the latest Arctic Monitoring and Assessment Programme report,reliable source information and long-term and high-resolution observations on Arctic BC deposition will be crucial for a more comprehensive understanding and a better mitigation strategy of Arctic BC.In the future,it is necessary to collect more observations on BC deposition and the corresponding physical processes(e.g.,snow/ice melting,surface energy balance)in the Arctic to provide reliable data for understanding and clarifying the mechanism of the climatic impacts of BC deposition on Arctic snow and ice.

Construction of Dynamic Alloy Interfaces for Uniform Li Deposition in Li-Metal Batteries

It is well accepted that a lithiophilic interface can effectively regulate Li deposition behaviors,but the influence of the lithiophilic interface is gradually diminished upon continuous Li deposition that completely isolates Li from the lithiophilic metals.Herein,we perform in-depth studies on the creation of dynamic alloy interfaces upon Li deposition,arising from the exceptionally high diffusion coefficient of Hg in the amalgam solid solution.As a comparison,other metals such as Au,Ag,and Zn have typical diffusion coefficients of 10-20 orders of magnitude lower than that of Hg in the similar solid solution phases.This difference induces compact Li deposition pattern with an amalgam substrate even with a high areal capacity of 55 mAh cm^(-2).This finding provides new insight into the rational design of Li anode substrate for the stable cycling of Li metal batteries.

Accelerated Sequential Deposition Reaction via Crystal Orientation Engineering for Low-Temperature,High-Efficiency Carbon-Electrode CsPbBr_(3) Solar Cells

Low-temperature,ambient processing of high-quality CsPbBr_(3)films is demanded for scalable production of efficient,low-cost carbon-electrode perovskite solar cells(PSCs).Herein,we demonstrate a crystal orientation engineering strategy of PbBr_(2)precursor film to accelerate its reaction with CsBr precursor during two-step sequential deposition of CsPbBr_(3)films.Such a novel strategy is proceeded by adding CsBr species into PbBr_(2)precursor,which can tailor the preferred crystal orientation of PbBr_(2)film from[020]into[031],with CsBr additive staying in the film as CsPb_(2)Br_(5)phase.Theoretical calculations show that the reaction energy barrier of(031)planes of PbBr_(2)with CsBr is lower about 2.28 eV than that of(O2O)planes.Therefore,CsPbBr_(3)films with full coverage,high purity,high crystallinity,micro-sized grains can be obtained at a low temperature of 150℃.Carbon-electrode PSCs with these desired CsPbBr_(3)films yield the record-high efficiency of 10.27%coupled with excellent operation stability.Meanwhile,the 1 cm^(2)area one with the superior efficiency of 8.00%as well as the flexible one with the champion efficiency of 8.27%and excellent mechanical bending characteristics are also achieved.

Discovery of scheelite in the Zaozigou gold deposit of West Qinling Orogen,Northwest China and its implications for ore genesis

1.Objective The West Qinling Orogen extends east-west over 1500 km and is endowed with dozens of large-super large scale gold deposits.The Zaozigou gold deposit has a proven reserve of 134 t with an average grade of 3.08 g/t thus is one of the largest deposits in the West Qinling Orogen.However,whether the fluid type is metamorphic or magmatichydrothermal and ore-formation processes of the Zaozigou gold deposit are equivocal.Scheelite is a ubiquitous accessory mineral in geologically diverse ore-deposit types and attested to be a strong indicator of ore-forming conditions and oredeposit genesis.

A potential giant gallium deposit hosted in the tailing dam of the Fankou Zn-Pb deposit in northern Guangdong Province, South China

1.Objective The Fankou giant zinc(Zn)-lead(Pb)deposit in Guangdong Province is well-known for its huge reserves of over 10 Mt(million ton)Zn+Pb metals and high ore-grade with Zn+Pb exceeding 15%(Guangdong Fankou Deposit Investigation Group,1980;Zhu XY et al.,2017).After 60 years of exploration and exploitation,the deposit has accumulated millions of tons of tailings.One interesting question is that what components are hosted in these tailings,and whether some key and critical metals such as gallium and germanium are extremely enriched and worth further comprehensive utilization.This motivated us to conduct an integrated set of field investigation,sampling,major-trace element analyses and reserve assessments about the Fankou tailings.In this contribution,we discover that the tailings contain a variety of metal elements such as zinc,lead and gallium with comprehensive utilization potential.These data can act as a scientific guidance for further exploration and utilization of the Fankou tailings,and aid to enhance the utilization efficiency of the key mineral resource in China.Our study also provide demonstration for future green mine construction in China.

Origin of the Yueguang gold deposit in Xinhua, Hunan Province, South China: insights from fl uid inclusion and hydrogen–oxygen stable isotope analysis

The Yueguang gold deposit is located in Fengjia,Xinhua County,Hunan Province,South China.It represents a recently discovered small-scale gold deposit situated in the southwestern region of the Jiangnan Orogenic Belt,west of the Baimashan granitic batholith.In order to discern the characteristics of the ore-formingfluids,the underlying mineralization processes,and establish a foundation for the origin of the Yueguang gold depositfluid inclusion micro-thermometry,as well as quartz hydrogen and oxygen isotope analysis,have been carried out on samples obtained from various stages of mineralization.The hydrothermal miner-alization stages within the Yueguang gold deposit can be categorized into three stages:(i)the barren,pre-ore quartz-pyrite stage(Stage Ⅰ),the quartz-pyrite-gold stage(Stage Ⅱ),and the post-ore quartz-carbonate stage(Stage Ⅲ),with the second stage being the main mineralization stage.Thefluid inclusions identified in samples from the main min-eralization stage can predominantly be described with the NaCl–H_(2)O and CO_(2)–NaCl–H_(2)O systems.These inclusions display homogenization temperatures ranging from 158.8 to 334.9℃,and thefluid salinity ranges from 0.3%to 4.0%(wt.%NaCl equiv.).Laser Raman spectroscopy analysis of individual inclusions further reveals the presence of gas-phases such as CO_(2),CH_(4),and N_(2).Isotopic analysis indicatesδ^(18)Ofluid values ranging from 3.95 to 6.7‰ and δDH_(2)O values ranging from-71.9 to-55.7‰.These results indi-cate that the ore-formingfluid of the Yueguang gold deposit belongs to metamorphic hydrothermalfluids of middle-low temperature and low salinity.In the process of ore formation,gold is transported in the form of Au(HS)2-complexes,with gold deposition being driven byfluid immiscibility.Therefore,the Yueguang gold deposit is categorized as an orogenic gold deposit dominated by metamorphic hydrother-malfluid.It may become a new target for gold exploration in the Baimashan region,central Hunan Province.

Atomic layer deposition in advanced display technologies:from photoluminescence to encapsulation

Driven by the growing demand for next-generation displays,the development of advanced luminescent materials with exceptional photoelectric properties is rapidly accelerating,with such materials including quantum dots and phosphors,etc.Nevertheless,the primary challenge preventing the practical application of these luminescent materials lies in meeting the required durability standards.Atomic layer deposition(ALD)has,therefore,been employed to stabilize luminescent materials,and as a result,flexible display devices have been fabricated through material modification,surface and interface engineering,encapsulation,cross-scale manufacturing,and simulations.In addition,the appropriate equipment has been developed for both spatial ALD and fluidized ALD to satisfy the low-cost,high-efficiency,and high-reliability manufacturing requirements.This strategic approach establishes the groundwork for the development of ultra-stable luminescent materials,highly efficient light-emitting diodes(LEDs),and thin-film packaging.Ultimately,this significantly enhances their potential applicability in LED illumination and backlighted displays,marking a notable advancement in the display industry.

Pinus sylvestris and Picea abies canopy effects on deposition of air pollutants

Tree canopies influence atmospheric pollutant depositions depending on type,ecosystem characteristics,and local climatic conditions.This study investigated the impact of Pinus sylvestris L.and Picea abies(L.)H.Karst.,and a mixture of both,on the chemical composition of pre-cipitation.Three permanent plots within the ICP forest level Ⅱ monitoring network in Lithuania were selected to illustrate typical hemiboreal coniferous forests.The study analysed(1)the concentrations of NO_(2),NH_(3) and SO_(2) in the ambi-ent air;(2)the concentrations of SO_(4)^(2−),NO_(3)^(−),NH_(4)^(+),Na^(+),K^(+),Ca^(2+) and Cl^(-) in throughfall beneath canopies and in precipitation collected in an adjacent field,and(3)S and total N,Na^(+),K^(+),Ca^(2+)and Cl−depositions in throughfall and precipitation over 2006-2022.Results show a signifi-cant decrease in SO_(2) emissions in the ambient air;NO_(2) and NH_(3) emissions also decreased.The canopies reduced the acidity of throughfall,although they led to notably higher concentrations of SO_(4)^(2−),NO_(3)^(−),Na^(+),and particularly K^(+).During the study,low variability in NO_(3)^(-)deposition and a decrease in NH_(4)^(+)deposition occurred.Deposition loads increased by 20-30%when precipitation passed through the canopy.The cumulative deposition of S,Cl,Na,K,Ca,and N was greater under P.abies than under P.sylvestris.How-ever,K deposition in throughfall was considerably lower under P.sylvestris compared to the P.abies or mixed stand.Throughfall S depositions declined across all three coniferous plots.Overall,there was no specific effect of tree species on throughfall chemistry.

Geochemistry and depositional environment of fuchsite quartzites from Sargur Group,western Dharwar Craton,India

Meso-Neoarchean fuchsite quartzites are present in different stratigraphic positions of Dharwar Craton including the oldest(~3.3 Ga)Sargur Group of western Dharwar Craton.The present study deals with the petro-graphic and geochemical characteristics of the fuchsite quartzites from the Ghattihosahalli belt to evaluate their genesis,depositional setting and the enigma involved in the ancient sedimentation history.Their major mineral assemblages include quartz,fuchsite,and feldspars along with accessory kyanite and rutile.The geochemical com-positions are characterized by high SiO_(2),Al_(2)O_(3),low MgO,CaO,strongly enriched Cr(1326–6899 ppm),Ba(1165–3653 ppm),Sr(46–210 ppm),V(107–868 ppm)and Zn(11–158 ppm)contents compared to the upper continental crust(UCC).The UCC normalized rare earth element(REE)patterns are characterized by depleted light REE[(La/Sm)UCC=0.33–0.95]compared to heavy REE[(Gd/Yb)_(UCC)=0.42–1.65]with conspicuous positive Eu-anomalies(Eu/Eu^(*)=1.35–18.27)characteristic of hydrothermal solutions evidenced through the interlayered barites.The overall major and trace element systematics reflect a combined mafic-felsic provenance and suggest their deposition at a passive continental margin environ-ment.The comprehensivefield,petrographic,and geo-chemical studies indicate that these quartzites are infiltrated by Cr-richfluids released during high-grade metamorphism of associated ultramafic rocks.The Sargur and the subse-quent Dharwar orogeny amalgamated diverse lithounits from different tectonic settings,possibly leading to the release of Cr-richfluids and the formation of fuchsite quartzite during or after the orogeny.Thesefindings sug-gest a pre-existing stable crust prior to the Sargur Group and the link between orogenic events and various mineral deposits in the Dharwar Craton.

Depositional process of hyperpycnal flow deposits:A case study on Lower Cretaceous Sangyuan outcrop in the Luanping Basin,Northeast China

Sedimentary process research is of great significance for understanding the distribution and characteristics of sediments.Through the detailed observation and measurement of the Sangyuan outcrop in Luanping Basin,this paper studies the depositional process of the hyperpycnal flow deposits,and divides their depositional process into three phases,namely,acceleration,erosion and deceleration.In the acceleration phase,hyperpycnal flow begins to enter the basin nearby,and then speeds up gradually.Deposits developed in the acceleration phase are reverse.In addition,the original deposits become unstable and are taken away by hyperpycnal flows under the eroding force.As a result,there are a lot of mixture of red mud pebbles outside the basin and gray mud pebbles within the basin.In the erosion phase,the reverse deposits are eroded and become thinner or even disappear.Therefore,no reverse grading characteristic is found in the proximal major channel that is closer to the source,but it is still preserved in the middle branch channel that is far from the source.After entering the deceleration phase,normally grading deposits appear and cover previous deposits.The final deposits in the basin are special.Some are reverse,and others are normal.They are superimposed with each other under the action of hyperpycnal flow.The analysis of the Sangyuan outcrop demonstrates the sedimentary process and distribution of hyperpycnites,and reasonably explain the sedimentary characteristics of hyperpycnites.It is helpful to the prediction of oil and gas exploration targets in gravity flow deposits.

Revolutionizing plasmonic platform via magnetic field-assisted confined ultrafast laser deposition of high-density,uniform,and ultrafine nanoparticle arrays

The remarkable capabilities of 2D plasmonic surfaces in controlling optical waves havegarnered significant attention.However,the challenge of large-scale manufacturing of uniform,well-aligned,and tunable plasmonic surfaces has hindered their industrialization.To address this,we present a groundbreaking tunable plasmonic platform design achieved throughmagnetic field(MF)assisted ultrafast laser direct deposition in air.Through precise control of metal nanoparticles(NPs),with cobalt(Co)serving as the model material,employing an MF,and fine-tuning ultrafast laser parameters,we have effectively converted coarse and non-uniform NPs into densely packed,uniform,and ultrafine NPs(~3 nm).This revolutionary advancement results in the creation of customizable plasmonic‘hot spots,’which play a pivotal role insurface-enhanced Raman spectroscopy(SERS)sensors.The profound impact of this designable plasmonic platform lies in its close association with plasmonic resonance and energyenhancement.When the plasmonic nanostructures resonate with incident light,they generate intense local electromagnetic fields,thus vastly increasing the Raman scattering signal.This enhancement leads to an outstanding 2–18 fold boost in SERS performance and unparalleled sensing sensitivity down to 10^(-10)M.Notably,the plasmonic platform also demonstratesrobustness,retaining its sensing capability even after undergoing 50 cycles of rinsing andre-loading of chemicals.Moreover,this work adheres to green manufacturing standards,making it an efficient and environmentally friendly method for customizing plasmonic‘hot spots’inSERS devices.Our study not only achieves the formation of high-density,uniform,and ultrafine NP arrays on a tunable plasmonic platform but also showcases the profound relation betweenplasmonic resonance and energy enhancement.The outstanding results observed in SERS sensors further emphasize the immense potential of this technology for energy-relatedapplications,including photocatalysis,photovoltaics,and clean water,propelling us closer to a sustainable and cleaner future.

Printability disparities in heterogeneous material combinations via laser directed energy deposition:a comparative study

Additive manufacturing provides achievability for the fabrication of bimetallic and multi-material structures;however,the material compatibility and bondability directly affect the parts’formability and final quality.It is essential to understand the underlying printability of different material combinations based on an adapted process.Here,the printability disparities of two common and attractive material combinations(nickel-and iron-based alloys)are evaluated at the macro and micro levels via laser directed energy deposition(DED).The deposition processes were captured using in situ high-speed imaging,and the dissimilarities in melt pool features and track morphology were quantitatively investigated within specific process windows.Moreover,the microstructure diversity of the tracks and blocks processed with varied material pairs was comparatively elaborated and,complemented with the informative multi-physics modeling,the presented non-uniformity in mechanical properties(microhardness)among the heterogeneous material pairs was rationalized.The differences in melt flow induced by the unlike thermophysical properties of the material pairs and the resulting element intermixing and localized re-alloying during solidification dominate the presented dissimilarity in printability among the material combinations.This work provides an in-depth understanding of the phenomenological differences in the deposition of dissimilar materials and aims to guide more reliable DED forming of bimetallic parts.