Proton-gradient-transfer acid complexes and their catalytic performance for the synthesis of geranyl acetate

Special proton-gradient-transfer acid complexes （PGTACs） in which the bonded protons are not equivalent and have gradients in transfer ability, acidity, and reactivity were reported. The acidity gradient of the protons gave the PGTACs excellent catalytic activity and selectivity in the esterifica- tion of terpenols. These PGTACs are ＂reaction-induced self-separation catalysts＂ and can be easily reused. The kinetics with PGTACs as catalyst in the esterification of geraniol were also studied for use in engineering design.

Reasons for and Countermeasures against Gradient Transfer of Rural Population——A Case Study of Chongqing

We take Chongqing as an example to analyze reasons for rural population gradient transfer from such factors as social system,industrial development,urban planning,and living costs.Finally,we present four policies and suggestions,including promoting urban construction,increasing investment in rural areas,pushing forward construction of labor market,and bringing safeguarding function into full play.

Discussion on Calculation Methods of Sensible Heat Flux during GAME/Tibet in 1998

Based on previous research on sensible heat flux, we investigate it from different aspects using GAME/Tibet data measured during 6 June–13 September, 1998. This work consists of the derivation of the surface heat flux equation, analysis on counter-gradient heat transference, comparison between two different methods to compute the sensible heat flux, and investigation on the calculation scheme of sensible heat flux in the Simple Biosphere model 2 (SiB2) with relevant simulation. By improving two previous formulations, an integrated formulation for calculating surface heat flux is given. Secondly, using the measured data, the counter-gradient heat flux is clarified, leading to the fact that buoyancy plays an important role in the sensible heat transfer process. It is concluded that (1) energy imbalance is a common phenomenon resulting from the use of the traditional closure scheme on the heterogeneous underlying surface because the measured ensemble heat fluxes by eddy correlation contain the effect of nonlocal parcel movements; and (2) nonlocal parcel movement deserves more attention in any future heat flux study.

Heat transfer of nanofluidics in hydrophilic pores: Insights from molecular dynamics simulations

Nanofluidics in hydrophilic nanopores is a common issue in many natural and industrial processes. Among all,the mass transport of nanofluidics is most concerned. Besides that, the heat transfer of a fluid flow in nano or micro channels is always considered with adding nanoparticles into the flow, so as to enhance the heat transfer by convection between the fluid and the surface. However, for some applications with around 1 nm channels such as nano filtration or erosion of rocks, there should be no nanoparticles included. Hence, it is necessary to figure out the heat transfer mechanism in the single phase nanofluidics. Via non-equilibrium molecular dynamics simulations, we revealed the heat transfer inside nanofluidics and the one between fluid and walls by setting simulation into extremely harsh condition. It was found that the heat was conducted by molecular motion without temperature gradient in the area of low viscous heat, while it was transferred to the walls by increasing the temperature of fluids. If the condition back to normal, it was found that the viscous heat of nanofluidics could be easily removed by the fluid-wall temperature drop of less than 1 K.