To obtain the influence laws of the fine gangue rate on the properties of coal gangue cementitious paste, the slump, divergence, stratification, bleeding, setting time and mechanical strength with the change of fine g...To obtain the influence laws of the fine gangue rate on the properties of coal gangue cementitious paste, the slump, divergence, stratification, bleeding, setting time and mechanical strength with the change of fine gangue rate were studied on the basis of keeping the amount of cementing material and slurry concentration unchanged. The porosity and the distribution of pore diameter of the filling specimen for curing 28 d were tested by a mercury injection instrument under different fine gangue rate conditions. It was shown that the slump, divergence, setting time and compressive strength of the paste firstly increased and then decreased with increasing fine gangue rate. The stratification and bleeding rate decreased with increasing fine gangue rate. The smaller the critical pore size of the paste was, the smaller the porosity was, the smaller the average pore size was. When the fine gangue rate was 40%, the maximum critical pore diameter of the paste was 55.79 μm, and the corresponding porosity was 17.54%, and the properties of filling paste were the best. When the fine gangue rate further increased, the aggregate surface area increased, and the reaction product of cementitious materials could not effectively fill the pores. It weakened the agglomeration effect. The particles surface of coal gangue was fragmental and flake deposit with irregular shape and uneven fold morphology. It was easy to be bonded with the surface of other filling material. The hydration products of coal gangue cementitious material were a large number of C-S-H gel with fibrous shape and ettringite（AFt） with compact block structure. The theoretical reference was provided for the preparation of low cost gangue cemented filling materials in coal mines.展开更多
Coal seam CO_(2) sequestration is an important option to address global warming.A better knowledge on coal pore structure evolution during gas adsorption can provide guidance for coal seams CO_(2) seques-tration.Howev...Coal seam CO_(2) sequestration is an important option to address global warming.A better knowledge on coal pore structure evolution during gas adsorption can provide guidance for coal seams CO_(2) seques-tration.However,few investigations on the pore structure evolution differences between the deep and shallow coal were conducted during gas adsorption.In this study,based on the real-time synchrotron radiation small-angle X-ray scattering(SAXS)observation,the average pore diameter and pore surface fractal dimension evolution differences between deep and shallow coal were investigated from the as-pects of coal compositions and stress history.Two types of coal deformation(inner-swelling and outer-swelling)coexist during gas adsorption.Coal compositions have significant impact on the dominance of deformation type.The dominance of inner-swelling in deep coal is induced by the higher ash contents,and there is the decrease of average pore diameter during gas adsorption.The impact of stress-history(burial depth)on adsorption-induced deformation is more prominent than that of gas adsorption ca-pacity.In deep coal,the surface fractal dimension evolution presents a negative correlation with the evolution of pore diameters.In shallow coal,the surface fractal dimension evolution presents a Langmuir-type correlation with the adsorption time.展开更多
基金Funded by the National Science Foundation of China(No.51574055)the Key State Laboratory of Coastal and Offshore Engineering(No.LP1720)
文摘To obtain the influence laws of the fine gangue rate on the properties of coal gangue cementitious paste, the slump, divergence, stratification, bleeding, setting time and mechanical strength with the change of fine gangue rate were studied on the basis of keeping the amount of cementing material and slurry concentration unchanged. The porosity and the distribution of pore diameter of the filling specimen for curing 28 d were tested by a mercury injection instrument under different fine gangue rate conditions. It was shown that the slump, divergence, setting time and compressive strength of the paste firstly increased and then decreased with increasing fine gangue rate. The stratification and bleeding rate decreased with increasing fine gangue rate. The smaller the critical pore size of the paste was, the smaller the porosity was, the smaller the average pore size was. When the fine gangue rate was 40%, the maximum critical pore diameter of the paste was 55.79 μm, and the corresponding porosity was 17.54%, and the properties of filling paste were the best. When the fine gangue rate further increased, the aggregate surface area increased, and the reaction product of cementitious materials could not effectively fill the pores. It weakened the agglomeration effect. The particles surface of coal gangue was fragmental and flake deposit with irregular shape and uneven fold morphology. It was easy to be bonded with the surface of other filling material. The hydration products of coal gangue cementitious material were a large number of C-S-H gel with fibrous shape and ettringite（AFt） with compact block structure. The theoretical reference was provided for the preparation of low cost gangue cemented filling materials in coal mines.
基金supported by the National Natural Science Foundation of China (grant Nos.U1910206,52004293,52225402)Beijing Natural Science Foundation (grant No.8232057)+4 种基金the Open Project Program of State Key Laboratory of Coal and CBM Co-mining (grant No.2022KF21)Fundamental Research Funds for the Central Universities (grant No.FRF-TP-20-034A1)the Open Project Program of Key Laboratory of Deep Earth Science and Engineering (Sichuan University)Ministry of Education (grant No.DESE 202004)China Postdoctoral Science Foundation (grant No.2018M641526).
文摘Coal seam CO_(2) sequestration is an important option to address global warming.A better knowledge on coal pore structure evolution during gas adsorption can provide guidance for coal seams CO_(2) seques-tration.However,few investigations on the pore structure evolution differences between the deep and shallow coal were conducted during gas adsorption.In this study,based on the real-time synchrotron radiation small-angle X-ray scattering(SAXS)observation,the average pore diameter and pore surface fractal dimension evolution differences between deep and shallow coal were investigated from the as-pects of coal compositions and stress history.Two types of coal deformation(inner-swelling and outer-swelling)coexist during gas adsorption.Coal compositions have significant impact on the dominance of deformation type.The dominance of inner-swelling in deep coal is induced by the higher ash contents,and there is the decrease of average pore diameter during gas adsorption.The impact of stress-history(burial depth)on adsorption-induced deformation is more prominent than that of gas adsorption ca-pacity.In deep coal,the surface fractal dimension evolution presents a negative correlation with the evolution of pore diameters.In shallow coal,the surface fractal dimension evolution presents a Langmuir-type correlation with the adsorption time.
