U-Pb dating of early Mesozoic granodioritic intrusions in southeastern Hunan Province, South China and its petrogenetic implications

The NE-trended Mesozoic granodioritic intrusions are spatially and temporally associated with the copper multi-metal mineralization in southeastern Hunan Province, South China. U-Pb dating result of single-grained zircons of four samples respectively from Shuikoushan, Baoshan, western Tongshanling and eastern Tongshanling intrusions reveals that their crystallization age spans a range from 172 Ma to 181 Ma, which also represents the oldest age of the regional copper multi-metal mineralization. Some of the zircon grains give an upper intercept age of about 1753 Ma and 207Pb/206Pb apparent age of (1752 ± 4) Ma, implying the involvement of the pre-Cambrian metamorphic (possible Middle Proterozoic) basement in their genesis. The presence of such a kind of zircon grains in these granodiorites indicates either that the parental magmas were assimilated by basement rocks during magma ascent or that lower/middle crustal rocks were one of the important components during the melting process.

Late Mesoarchean crust growth event： evidence from the ca. 2.8 Ga granodioritic gneisses of the Xiaoqinling area, southern North China Craton

Recently, more attention has been paid to Precambrian magma events and crustal growth of the North China Craton(NCC), accompanying with controversy in activity stages and dynamic mechanism. In this study, we report the Archean(2802 ± 13 Ma) granodioritic gneisses in the Taihua Complex from the Xiaoqinling area, located in the southern margin of the NCC. The zircon Lu–Hf isotope analysis of the rocks showed ^(176)Hf/^(177)Hf ratios of0.280977–0.281228, corresponding to ε_(Hf)(t) values ranging from-3.5 to +6.6, and two–stage Hf model ages varying from 2836 to 3409 Ma. It was confirmed that late Mesoarchean(2.9–2.8 Ga) juvenile crust made contribution to the source material of these ca. 2.8 Ga granodioritic gneisses in the Xiaoqinling area. The whole rock geochemical data indicate that the granodioritic gneisses are high-K calc-alkaline series, probably generated at relatively high pressure and temperature, and formed under the continental arc setting. Statistically, we conclude that the magmatic activities during 2.9–2.7 Ga may represent the most intense crustal growth events in the NCC and these Archean rocks at different locations in southern NCC underwent a similar crustal evolution history.

Paleomagnetism of late Cretaceous dykes in the Gangdese belt: New constraints on the position and structure of the southern margin of Asia prior to the India-Asia collision

This paper report paleomagnetic data from late Cretaceous diorite dykes that sub-vertically intrude granodiorites in the eastern Gangdese belt near the city of Lhasa.Our research goals are to provide further constraints on pre-collisional structure of the southern margin of Asia and the onset of the India-Asia collision.Magnetite is identified as the main magnetic carrier in our study.The magnetite shows no evidence of metamorphism or alteration as determined from optical and scanning electron microscope observations.A strong mineral orientation is revealed by anisotropy of magnetic susceptibility analysis both for the intruded dykes and the country rocks.The authors interpret this AMS fabric to have formed during intrusion rather than deformation.Fifteen of 23 sites yield acceptable site mean characteristic remanences with dual polarities.A scatter analysis of the virtual geomagnetic poles suggests that the mean result adequately averaged paleosecular variation.The paleomagnetic pole from the Gangdese dykes yields a paleolatitude of 14.3°N±5.8°N for the southern margin of Asia near Lhasa.The paleolatitude corresponds to an in-between position of the Lhasa terrane during about 130‒60 Ma.Furthermore,the mean declination of the characteristic remanent magnetization reveals a significant counterclockwise rotation of 18°±9°for the sampling location since about 83 Ma.In the light of tectonic setting of the dykes,the strike of the southern margin of Asia near Lhasa is restored to trend approximately about 310°,which is compatible with the hypothesis that the southern margin of Eurasia had a quasi-linear structure prior to its collision with India.

Geology and mineralization of the Daheishan supergiant porphyry molybdenum deposit(1.65 Bt),Jilin,China:A review

The Daheishan supergiant porphyry molybdenum deposit(also referred to as the Daheishan deposit)is the second largest molybdenum deposit in Asia and ranks fifth among the top seven molybdenum deposits globally with total molybdenum reserves of 1.65 billion tons,an average molybdenum ore grade of 0.081%,and molybdenum resources of 1.09 million tons.The main ore body is housed in the granodiorite porphyry plutons and their surrounding inequigranular granodiorite plutons,with high-grade ores largely located in the ore-bearing granodiorite porphyries in the middle-upper part of the porphyry plutons.Specifically,it appears as an ore pipe with a large upper part and a small lower part,measuring about 1700 m in length and width,extending for about 500 m vertically,and covering an area of 2.3 km^(2).Mineralogically,the main ore body consists of molybdenite,chalcopyrite,and sphalerite horizontally from its center outward and exhibits molybdenite,azurite,and pyrite vertically from top to bottom.The primary ore minerals include pyrite and molybdenite,and the secondary ore minerals include sphalerite,chalcopyrite,tetrahedrite,and scheelite,with average grades of molybdenum,copper,sulfur,gallium,and rhenium being 0.081%,0.033%,1.67%,0.001%,and 0.0012%,respectively.The ore-forming fluids of the Daheishan deposit originated as the CO_(2)-H_(2)O-NaCl multiphase magmatic fluid system,rich in CO_(2)and bearing minor amounts of CH4,N2,and H2S,and later mixed with meteoric precipitation.In various mineralization stages,the ore-forming fluids had homogenization temperatures of>420℃‒400℃,360℃‒350℃,340℃‒230℃,220℃‒210℃,and 180℃‒160℃and salinities of>41.05%‒9.8%NaCleqv,38.16%‒4.48%NaCleqv,35.78%‒4.49%NaCleqv,7.43%NaCleqv,and 7.8%‒9.5%NaCleqv,respectively.The mineralization of the Daheishan deposit occurred at 186‒167 Ma.The granites closely related to the mineralization include granodiorites(granodiorite porphyries)and monzogranites(monzogranite porphyries),which were mineralized after magmatic evolution(189‒167 Ma).Moreover,these mineralization-related granites exhibit low initial strontium content and high initial neodymium content,indicating that these granites underwent crust-mantle mixing.The Daheishan deposit formed during the Early-Middle Jurassic,during which basaltic magma underplating induced the lower-crust melting,leading to the formation of magma chambers.After the fractional crystallization of magmas,ore-bearing fluids formed.As the temperature and pressure decreased,the ore-bearing fluids boiled drops while ascending,leading to massive unloading of metal elements.Consequently,brecciated and veinlet-disseminated ore bodies formed.

Alteration Typology and Geochemical Signatures of the Napélépéra Gold-Bearing Granodiorite in South-West Burkina Faso (West Africa)

The characterization of the relationships between mineralization and hydrothermal alteration is an essential element in understanding gold deposits. In south-west Burkina Faso, the Napélépéra mineralisation, the mobility of chemical elements and alteration-mineralization relationships were studied by means of selected core drilling and geochemical analyses using ICP-MS (Inductively Coupled Plasma Mass Spectrometry) and ICP-AES (Inductively coupled plasma atomic emission spectroscopy). The mineralised granodiorite is grey porphyroid with quartz, plagioclase, biotite and amphibole. It is metaluminous and located in the tholeiitic series. The Na2O + CaO versus Fe2O3 + MgO alteration diagram divides the samples according to alteration dominance. Chloritisation and carbonation are the main alterations. There is a relationship between gold mineralisation at Napélépéra and alteration, and the paragenesis of gold + pyrite ± carbonate ± silica ± sericite is the main characteristic. Carbonation is the result of fluid input in the shear corridor of the mineralised zone. The mass balance of comparative metals in the proximal and distal zones of the mineralisation shows the absence of metals, while As, Hg, Ag and Bi are strongly enriched from the distal zone to the mineralised zone. The oxides associated with the mineralisation are mainly NaO, SrO and CaO.

Archean (about 2500 Ma) anatexis in eastern North China Block

Two Neoarchean alkaline feldspar-rich granites sourced from partially melted granulite-facies granodioritic orthogneiss have been here recognised in the eastern part of the North China Block(NCB).These poorly foliated granites have previously been assumed to be Mesozoic in age and never dated,and so their significance has not been recognised until now.The first granite(AG1)is a porphyritic syenogranite with megacrystic K-feldspar,and the second(AG2)is a quartz syenite with perthitic megacryst.Zircons from the granites yield LA-ICP-MS U-Pb ages of 2499±10 Ma(AG1),and 2492±28 Ma(AG2),which are slightly younger than the granodioritic orthogneiss that they intrude with a crystallisation U-Pb age of 2537±34 Ma.The younger granites have higher assays for SiO_(2)(71.91%for AG1 and 73.22%for AG2)and K_(2)O(7.52%for AG1 and 8.37%for AG2),and much lower assays for their other major element than the granodioritic orthogneiss.All of the granodioritic orthogneiss and granite samples have similar trace element patterns,with depletion in Th,U,Nb,and Ti and enrichment in Rb,Ba,K,La,Ce,and P.This indicates that the granites are derived from the orthogneiss as partial melts.Although they exhibit a similar REE pattern,the granites have much lower total REE contents(30.97×10^(−6) for AG1,and 25.93×10^(−6) for AG2),but pronounced positive Eu anomalies(Eu/Eu^(*)=8.57 for AG1 and 27.04 for AG2).The granodioritic orthogneiss has an initial ^(87)Sr/^(86)Sr ratio of 0.70144,εNd(t)value of 3.5,and εHf(t)values ranging from−3.2 to+2.9.The orthogneiss is a product of fractional crystallisation from a dioritic magma,which was derived from a mantle source contaminated by melts derived from a felsic slab.By contrast,the AG1 sample has an initial ^(87)Sr/^(86)Sr ratio of 0.6926 that is considered too low in value,εNd(t)value of 0.3,andεHf(t)values between+0.57 and+3.82;whereas the AG2 sample has an initial ^(87)Sr/^(86)Sr ratio of 0.70152,εNd(t)value of 1.3,andεHf(t)values between+0.5 and+14.08.These assays indicate that a Sr-Nd-Hf isotopic disequilibrium exists between the granite and granodioritic orthogneiss.The elevatedεHf(t)values of the granites can be explained by the involvement of Hf-bearing minerals,such as orthopyroxene,amphibole,and biotite,in anatectic reactions in the granodioritic orthogneiss.Based on the transitional relationship between the granites and granodioritic orthogneiss and the geochemical characteristics mentioned above,it is concluded that the granites are the product of rapid partial-melting of the granodioritic orthogneiss after granulite-facies metamorphism,and their crystallisation age of about 2500 Ma provides the minimum age of the metamorphism.This about 2500 Ma tectonic-metamorphic event in NCB is similar to the other cratons in India,Antarctica,northern and southern Australia,indicating a possible connection between these cratons during the Neoarchean.

Geochronology and Geochemical Characteristics of the Early Mesozoic Tangquan Pluton in Southwestern Fujian and Its Tectonic Implications

The Tangquan granodioritic pluton in Dalian County, southwestern Fujian, China, which extends in a NE direction with an exposed area of about 130 km2, used to be considered a product of Early Cretaceous magmatism. The present study suggests for the first time that the pluton was formed in the Early Jurassic by using multiple methods for isotopic dating, which give zircon U-Pb ages of 186.8 Ma and 179.0 Ma, Rb-Sr isochron age of 162.02±4.5 Ma, and biotite 40Ar/39Ar plateau age of 158.1±0.7 Ma. The cooling rate for the pluton was relatively low (4.76℃/Ma) during the early stage (183-162 Ma) because of the compressional environment. It was emplaced in a higher cooling rate (50℃/Ma) in an extensional environment during the later stage (162-158 Ma). The granodiorites are metaluminous-peraluminous, relatively enriched in Na2O and depleted in K2O, and characteristic of I-type granites of crust-mantle mixed sources. They are moderately enriched in Rb, Th, Hf and LREE, and depleted in Ti, Nb, Ta and Sr, and have geochemical features of cal-alkaline rocks of an island arc or active continental margin. Their (87Sr/86Sr)i ratio varies from 0.70769 to 0.70822, εNd(t) from -9.68 to -10.07 and TDM from 1.52 to 1.55 Ga. They were formed by mixing of mantle-derived mafic magma with the granitic magma resulting from partial melting of crust-derived materials in an upwelling of the asthenospheric mantle in South China during the Early Mesozoic.

Paleo-Tethyan Oceanic Crust Subduction in the Eastern Section of the East Kunlun Orogenic Belt:Geochronology and Petrogenesis of the Qushi'ang Granodiorite

The Qushi’ang granodiorite（QSG） is located at the central east of the ophiolitic melange belt in the East Kunlun Orogenic Belt（EKOB） in the northern margin of the Qinghai-Tibetan Plateau. LA-MC-ICP-MS zircon U–Pb dating suggests that the granodiorite and mafic microgranular enclaves（MMEs） crystallized 246.61±0.62 and 245.45±0.9 Ma ago, respectively. Granodiorite, porphyritic diorite, and MMEs are metaluminous and medium-K calk-alkaline series, with island-arc magma features, such as LILE enrichment and HFSE depletion. The porphyritic diorite has high Cr（13.50 ppm to 59.01 ppm）, Ni（228.53 ppm to 261.29 ppm）, and Mg~#（46–54）. Granodiorite and porphyritic diorite have similar mineral compositions and evolved major and trace elements contents, particularly Cr and Ni, both of which are significantly higher than that in granites of the same period. The crystallization age of MMEs is close to that of granodiorite, and their major and trace elements contents are in-between porphyritic diorite and granodiorite. The results suggest that the original mafic magma, which was the product of mantle melting by subduction process, intruded into the lower crust（Kuhai Rock Group）, resulting in the formation of granodiorite. Countinous intrusion of mafic magma into the unconsolidated granodiorite formed MMEs and porphyritic diorite. The granodiorite reformed by late-stage strike-slip faulting tectonic event indicates that the strike-slip fault of Middle Kunlun and the collision of the Bayanhar block with East Kunlun were later than 246 Ma. Therefore, the formation of the QSG not only indicates the critical period of evolution of East Kunlun but also represents the tectonic transition from oceanic crust subduction to slab breaking.

Estimating Influence of Crystallizing Latent Heat on Cooling-Crystallizing Process of a Granitic Melt and Its Geological Implications

Based on the theory of thermal conductivity, in this paper we derived a formula to estimate the prolongation period （AtL） of cooling-crystallization process of a granitic melt caused by latent heat of crystallization as follows：△tL=QL×△tcol/（TM-TC）×CP where TM is initial temperature of the granite melt, Tc crystallization temperature of the granite melt, Cp specific heat, △tcol cooling period of a granite melt from its initial temperature （TM） to its crystallization temperature （Tc）, QL latent heat of the granite melt. The cooling period of the melt for the Fanshan granodiorite from its initial temperature （900℃） to crystallization temperature （600℃） could be estimated -210,000 years if latent heat was not considered. Calculation for the Fanshan melt using the above formula yields a AtL value of -190,000 years, which implies that the actual cooling period within the temperature range of 900°-600℃ should be 400,000 years. This demonstrates that the latent heat produced from crystallization of the granitic melt is a key factor influencing the cooling-crystallization process of a granitic melt, prolongating the period of crystallization and resulting in the large emplacement-crystallization time difference （ECTD） in granite batholith.

S and Pb Isotopic Constraints on the Relationship between the Linong Granodiorite and the Yangla Copper Deposit,Yunnan,China

The Yangla copper deposit, located in western Yunnan Province, China, is a typical giant, newly started mining copper deposit with an estimated Cu reserves of about 1,200,000 tons. The deposit is spatially and temporally associated with the Linong granodiorite, which is rich in SiO2 （SIO2=58.25 wt%-69.84 wt%） and alkalis （Na20＋K20=5.98 wt%-8.34 wt%）, indicating an association with shoshonitic series to high-K calc-alkaline series granites, and shows low contents of TiO2 （0.35 wt%- 0.48 wt%）, MgO （1.51 wt%-1.72 wt%）, and A1203 （13.38 wt%-19.75 wt%）. The 34S values of sulfides of the main ore stage from copper ores vary range from -4.2%o to -0.9%o, indicating a much greater contribution from the mantle to the ore-forming fluids. The 34S values of the late ore stage is -9.8%0, indicating enrichment of biogenic sulfur which may derive from the crustal hydrothermal fluid. The 208pb/204pb, 207pb/204pb and 206pb/204pb of sulfides of the main ore stage from copper ores range within 38.66-38.73, 15.71-15.74 and 18.35-19.04, respectively, implying that the Pb was derived from the mantle, with the crustal component, probably representing mixtures of mantle lead and crustal lead. Sulfide of the late ore stage in their Pb isotopic composition, 208pb/204pb= 38.69, 207pb/204pb=15.70, 206Pb/204pb=18.35, implying that the Pb was derived from the crust. The Linong granodiorite is syn- collisional, produced by partial melting of thickened lower crust, which was triggered by the westward subduction of the Jinshajiang Oceanic plate. During a transition in geodynamic setting from collision- related compression to extension, gently dipping ductile shear zones （related to subduction） were transformed to brittle shear zones, consisting of a series of thrust faults in the Jinshajiang tectonic belt. The tensional thrust faults would have been a favorable environment for ore-forming fluids. The ascending magma provided a channel for the ore-forming fluid from the mantle wedge. After the magma arrived at the base of the early-stage Linong granodiorite, the platy granodiorite at the base of the body would have shielded the late-stage magma from the fluid. The magma would have cooled slowly, and some of the ore-forming fluid in the magma would have entered the gently dipping thrust faults near the Linong granodiorite, resulting in mineralization.

Geochronology, Geochemistry and Tectonic Setting of the Bairiqiete Granodiorite Intrusion(Rock Mass) from the Buqingshan Tectonic Mélange Belt in the Southern Margin of East Kunlun

This study focuses on the zircon U-Pb geochronology and geochemistry of the Bairiqiete granodiorite intrusion （rock mass） from the Buqingshan tectonic mélange belt in the southern margin of East Kunlun.The results show that the zircons are characterized by internal oscillatory zoning and high Th/U （0.14-0.80）,indicative of an igneous origin.LA-ICP-MS U-Pb dating of zircons from the Bairiqiete granodiorite yielded an age of 439.0 ± 1.9 Ma （MSWD =0.34）,implying that the Bairiqiete granodiorite formed in the early Silurian.Geochemical analyses show that the rocks are medium-K calc-alkaline,relatively high in Al2O3 （14.57-18.34 wt％） and metaluminous to weakly peraluminous.Rare-earth elements have low concentrations （45.49-168.31 ppm） and incline rightward with weak negative to weak positive Eu anomalies （δEu =0.64-1.34）.Trace-element geochemistry is characterized by negative anomalies of Nb,Ta,Zr,Hf and Ti and positive anomalies of Rb,Th and Ba.Moreover,the rocks have similar geochemical features with adakites.The Bairiqiete granodiorite appears to have a continental crust source and formed in a subduction-related island-arc setting.The Bairiqiete granodiorite was formed due to partial melting of the lower crust and suggests subduction in the Buqingshan area of the Proto-Tethys Ocean.

In Situ Analyses of Trace Elements, U–Pb and Lu–Hf Isotopes in Zircons from the Tongshankou Granodiorite Porphyry in Southeast Hubei Province, Middle-Lower Yangtze River Metallogenic Belt, China

The Tongshankou Cu-Mo deposit, located in southeast Hubei province, is a typical skarn–porphyry type ore deposit closely related to the Tongshankou granodiorite porphyry, characterized by a high Sr/Y ratio.Detailed in situ analyses of the trace elements and U–Pb and Lu–Hf isotopes in zircons from the Tongshankou granodiorite porphyry were performed.Scarcely any inherited zircons were observed, and the analyzed zircons yielded highly concordant results with a weighted mean 206Pb/238 U age of 143.5 ± 0.45 Ma（n=20, mean square weighted deviation was 0.75）, which was interpreted to represent the crystallization age of the Tongshankou granodiorite porphyry.The chondrite-normalized rare-earth element pattern was characterized by a slope that steeply rises from the light-group rare-earth elements（LREE） to the heavy-group rare-earth elements（HREE） with a positive Ce-anomaly and inconspicuous Eu-anomaly, which was coincident with the pattern of the zircons from the Chuquicamata West porphyry, Chile.The analyzed zircons also had relatively low 176Hf/177 Hf ratios of 0.282526–0.282604.Assuming t=143 Ma, the corresponding calculated initial Hf isotope compositions（εHf（t）） ranged from-5.6 to-2.9.The results of the in situ analysis of trace elements and U–Pb and Lu–Hf isotopes in zircons from the Tongshankou granodiorite porphyry suggest that a deep-seated process involving a thickened-crust/enriched-mantle interaction may play an important role in the generation of high Sr/Y-ratio magma and potentially in the generation of porphyry Cu-Mo systems.

U-Pb Zircon Dating of the Yeniutan Granitic Intrusion in the Western Sector of the North Qilian Mountains

Zircons from granodiorite and biotite granite in the Yeniutan granitic intrusion in the western North Qilian Mountains yielded a weighted mean 206Pb/238U apparent age of 460±3 Ma, suggesting that the intrusion originated during the late stage of plate subduction. Its related Ta'ergou and Xiaoliugou deposits are two of the few large tungsten deposits formed in the plate subduction environment in the world. The U-Pb dating of the zircons from the biotite granite gave a discordant lower intercept age of 183±4 Ma, which implies that the Yanshanian event was probably superimposed on the North Qilian region.

New Zircon U-Pb Age of Granodiorite in Chifeng at the Northern Margin of North China Craton and Constraints on Plate Tectonic Evolution

Objective The North China Craton （NCC） is one of the oldest cratons in the world. The accretionary belt at its northern margin has been the focus of scholars both at home and abroad （Zhu Junbing and Ren Jishun, 2017）. In recent years, a series of Late Paleozoic-Mesozoic intrusions trending E-W have been discovered within the northern margin of the NCC, forming a magmatic belt. The study on the origin and tectonic setting of this magmatic belt not only has important significance for understanding the Late Paleozoic-Mesozoic tectonic evolution history of the northern margin of the NCC, but also can provide key constraints on the evolution of its surrounding Xing＇an- Mongolia orogenic belt and the Paleo-Asian Ocean. At present, no Devonian to early stage of Early Carboniferous intrusion has been reported within the northern margin of the NCC.

贺根山缝合带白音呼舒奥长花岗岩锆石U-Pb年龄、地球化学特征及构造意义

本文以出露于贺根山缝合带梅劳特乌拉蛇绿岩北侧的白音呼舒奥长花岗岩体为研究对象,通过野外地质调查和岩石学、地球化学、锆石LA-ICP-MS U-Pb年代学研究,探讨其成因、构造环境及二连—贺根山洋俯冲消亡过程。岩石地球化学研究表明,白音呼舒岩体富硅(SiO2=66.50%~73.04%)、高铝(Al2O3=15.11%~16.75%)、富钠(Na2O=3.50%~6.16%)、低钾(K2O=1.46%~2.38%),相对高锶(Sr=167.0×10^-6~441.0×10^-6)、低钇(Y=5.30×10^-6~9.51×10^-6),富集Ba、Sr等大离子亲石元素和LREE,亏损Nb、Ta、Ti、P等高场强元素和HREE,无明显Eu异常。岩石学和岩石地球化学特征表明,白音呼舒侵入岩体属于英云闪长岩—奥长花岗岩—花岗闪长岩(Tonalite—Trondhjemite—Granodiorite,TTG)岩系,与高Si高锶低钇中酸性岩(Adakite,埃达克岩)类似,形成于大洋俯冲带岛弧环境,为俯冲洋壳脱水熔融的产物。锆石LA-ICP-MS U-Pb测年表明,白音呼舒奥长花岗岩体的形成年龄为309.2±1.6 Ma,表明该岩体侵位于晚石炭世,反映了贺根山缝合带晚石炭世大洋俯冲带TTG岩浆作用事件。结合二连—贺根山缝合带石炭纪蛇绿岩、石炭纪—二叠纪岛弧型岩浆岩和中生代后造山A型岩浆岩的时空分布与演化关系,表明古亚洲洋二连—贺根山洋盆在晚石炭世并未关闭,而是处于大洋俯冲消减和陆壳增生过程中。

Zircon U-Pb age,trace element and Hf isotope composition of Sepon Au-Cu deposit, Laos:tectonic and metallogenic implications

The Truong Son Fold Belt,located at the northeastern margin of the Indochina Block,is considered to be tectonically linked to the subduction of the Paleotethys Ocean and subsequent collision.Sepon is one of the most important super large deposits of the Truong Son Fold Belt.Our LA-ICP-MS zircon U-Pb dating results show that granodiorite porphyry samples from the Sepon deposit have ages of 302.1-4-2.9 Ma, which is a crucial phase for magmatic-tectonical activities from the Late Carboniferous to Early Permian and has avital influence on the mineralization of copper and gold.Zircon from granodiorite porphyry yields εHf (t)values of 4.32 to 9.64,and TDM2 has an average age of 914 Ma,suggesting that the source of the granodiorite porphyry in the region were mainly mantle components but underwent mixing and contamination of crust materials.The Ce^4+/Ce^3+ value of zircon in the granodiorite porphyry varys greatly from 2.4 to 1438.29,which shows magma mixing might occur.Considering the characteristics of trace elements in the zircon and the whole rock geochemical characteristics of intrusion rocks as well as the characteristics of regional volcanic-sedimentary association,it is indicated that the tectonic setting may be the continental arc environment.The Sepon Au-Cu deposit is derived from emplacement of calc-alkaline intermediate-acid magma with coming from deep sources in the subduction process of the Paleotethys Ocean,forming porphyry Mo-Cu,skam Cu-Au mineralization and a hydrothermal sedimentary-hosted Au mineralization in the wall rocks.

Discovery of the Early Paleozoic Boin Sum-Ordor Sum Island Arc in the Hadamiao Gold Ore District, Inner Mongolia and its Significance to the Evolution of the Paleo-Asian Ocean

Early Paleozoic granodiorite has been identified on the northern margin of the North China craton in the east section of the central-Asian orogenic belt, which was previously known as early Indosinian in age. By using the LA-ICP-MS method, the obtained zircon U-Pb age is 445.6 2.7 Ma, which represents the crystallization age of the granodiorite. The granodiorite near the east of the large-sized Bilihe gold deposit is of the tholeiite series with low potassium. It is quasi-aluminous I-type granite, enriched in sodium （Na2 O/K2O=7.29 9.77） and magnesium （Mg # =0.51 0.67）. The ΣREE value is relatively low, obvious differentiation is shown between LREE and HREE and within LREE, and the Eu anomaly is low and negative （δEu=0.74 0.91）. In the primitive-mantle normalized spider diagrams of trace elements, the granodiorite is relatively rich in LREE and LILE （Ba, Sr, Th）, and strongly depleted in HFSE （Nb, Ta, Ti and P）, which shows features of subduction zone components （SZC）. In the discrimination diagrams of tectonic settings of granite for Rb vs. （Nb＋Y）, Rb vs. （Ya＋Ta）, La/Nb vs. Ba/Nb and Th/Nb vs. Ba/Nb, the granodiorite exhibits typical features of island arc granite. The normalized values of K and Rb are extremely low, while the values of Sr and Eu are very high, which are similar to those of island arc magma that has undergone metasomatism of fluid from the oceanic crust. The granodiorite is relatively depleted in ε Hf （t） （5.1 7.1） and low in ε Hf （t） model ages （1089 921 Ma）. In the ε Hf （t） vs. age （T） diagram, the distribution area of the granodiorite is accordant with the field of the Xing’anling-Mongolia orogenic belt, which indicates that the magmatic sources are mainly the mixture of partial melting of wedged mantle subjected to metasomatism of fluid from the oceanic crust and young substance from the crust. The granodiorite is similar to the felsic arc magma in the Damao Banner, Bate Obon, Boin Sum and Ordor Sum regions, and they altogether constitute an early Paleozoic accretionary island arc magmatic belt on the northern margin of the North China craton. A number of early Paleozoic zircons trapped in late Paleozoic intrusions in the Hadamiao and Bilihe regions and the discovery of the early Paleozoic island arc magmatic belt near the east of the Bilihe gold deposit suggest that the late Paleozoic volcanic-intrusive rocks have a basement of early Paleozoic arc accretionary complexes. This is just the evident of the multiphase subduction and accretion model of the Paleo-Asian Ocean （PAO）. Paleozoic structures and magmas on the northern margin of the North China craton are shown from south to north as the late Paleozoic Andes-type arc magmatic belt in the Inner Mongolia plateau, the Chifeng-Bayan Obo fault and the late and early Paleozoic arc magmatic belt, which shows that after the early Paleozoic arc-continent collisional orogeny and at the stage of the late Paleozoic accretionary orogeny, the PAO plate was likely to continuously pulsate and underthrust beneath the early Paleozoic island arc accretionary complex belt and its front, i.e. the North China craton. During the early Paleozoic collisional orogeny, the PAO plate might not experience large-scale breakup or delamination. The characteristics of the early Paleozoic island arc accretionary complex basement have a significant control on late Paleozoic diagenesis and metallization in the Hadamiao and Bilihe gold concentrated areas.

The Discovery of Late Ordovician Granodiorite in the Xiemisitai Area, Xinjiang and its Geological Significance

Objective The Xiemisitai area located in the northern part of the West Junggar, Xinjiang is an important component of the central Asian metallogenic domain. Recent studies show that the formation age of acid volcanic and intrusive rocks in the Xiemisitai area mainly ranges from the Late Silurian to the Early Devonian, and the age of the mineralized dacite porphyry is Early Silurian. These rocks are the principal part of the Early Paleozoic arc magmatic belt, which are related to the Paleo-Asian Ocean slab subduction. However, there have been no reports of the pre-Silurian arc granitoid, which has restricted the discussion on the Early Paleozoic tectonic evolution in the area. This work studied the newly discovered granodiorite mass near Yinisala in the Xiemisitai area to determine its formation age and tectonic environment, magma source and petrogenesis, providing new information for the discussion on the Early Paleozoic tectonic evolution in the Xiemisitai area.

Chronology,Geochemistry and Tectonic Settings of the Hadamiao Granodiorite on the Northern Margin of the North China Platform

The Hadamiao granodiorite,located on the northern margin of the North China platform and acting as the country rock of gold deposits in the Hadamiao region,was formed in the same age and similar tectonic settings with the Hadamiao gold deposit and the large-scale Bilihe gold deposit in the same area.By using the LA-ICP-MS method,the U-Pb age obtained is 267±1.3 Ma,which represents the crystallized age of the granodiorite,and that of the xenolithic zircon is 442.8±5 Ma. Base on the main elements,it exhibits the features of calc-alkaline to high-potassium calc-alkaline series,low silicon,and quasi-aluminous I-type granites,and with high magnesium（Mg~#=0.45-0.57） and high sodium contents（Na_2O/K_2O=0.98-2.29）.The SREE values（81.6-110.15 ppm） are relatively low,the fractionations between LREE and HREE are obvious,showing a right-inclined dispersion in the REE distribution diagram.Compared with the primitive mantle,the rock is relatively rich in LREE（La and Ce）,LILE（K,Sr,and Th）,and intensively depleted in HFSE（Ti,P,Nb and Ta）.The ratios of Sr/Y and（La/Yb）_N and the contents of Rb,Nb and Y are relatively low,the Sr values are high （436.35-567.26 ppm）,and the Yb contents of most samples are low（1.25-1.8）,which indicate the features of typical continental margin arc and adakitic rocks.According to the values ofε_（Nd）（t）（-2.4 to ＋0.2） and I_（Sr）（0.7028-0.7083）,and variations of the La/Sm ratios,the Hadamiao granodiorite was formed from mixing of the thickened molten lower crust and the mantle wedge substances.The rock was related to the southward subduction and accretion of the Paleo-Asia Ocean in the Late Paleozoic, being Late Paleozoic magma of the continental margin arc formed on the basement of the Early Paleozoic accretion complexes,and showing a trend of turning into adakitic rocks,which indicates their great metallogenic（Au） potential.

Mineralogy,geochemistry,radioactivity and environmental impacts of Gabal Marwa granites,southeastern Sinai,Egypt

The Gabal Marwa area is located in the southeastern part of Sinai,Egypt.It comprises gneisses and migmatites,granodiorites and monzogranites.Field,petrographic,mineralogic and chemical investigations indicated that the Gabal Marwa granites are classified as granodiorites and monzogranites.The monzogranites constitute the most predominant rock unit exposed in the study area.They have been subjected to hydrothermal alterations,especially along the shear zones.Sericitization,desilicification,nametasomatism and development of spotty or dendritic manganese oxides are the most pronounced alteration features.These alterations resulted in the increase of TiO2,Al2O3,FeOt,MnO,CaO,MgO,Na2O,K2O and Cr,Zr,Rb,Y and Sr and the decrease of SiO2,P2O5,Ni,Zn,Ba and Nb.Radiometric studies indicated that the altered granites belong to high thorium,high uranium granites.The U,Th,U and Th,Th/U,Th and U-K variation diagrams suggested that magmatic processes controlled the distribution of these elements but the effect of hydrothermal alteration processes were clearly distinct.The Scanning Electron Microscope and X-ray Diffraction analyses indicated that the most important radioactive minerals include uranothorite,thorite,zircon,monazite and samarskite.Cinnabar and Mn minerals were also found.From the U,Th,Ra and K activity concentrations obtained for all the studied granitic samples,radium equivalent activity(Raeq),external hazard index(Hex),and internal hazard index(Hin),were calculated to assess the radiation hazard to human beings living in dwellings made of the studied granites.Altered monzogranites have radioactivity above the proposed acceptable level and,therefore,caution must be taken when these granites are used as building materials.