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Edge and lithium concentration effects on intercalation kinetics for graphite anodes
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作者 Keming Zhu Denis Kramer Chao Peng 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第3期337-347,I0009,共12页
Graphite interfaces are an important part of the anode in lithium-ion batteries(LIBs),significantly influencing Li intercalation kinetics.Graphite anodes adopt different stacking sequences depending on the concentrati... Graphite interfaces are an important part of the anode in lithium-ion batteries(LIBs),significantly influencing Li intercalation kinetics.Graphite anodes adopt different stacking sequences depending on the concentration of the intercalated Li ions.In this work,we performed first-principles calculations to comprehensively address the energetics and dynamics of Li intercalation and Li vacancy diffusion near the no n-basal edges of graphite,namely the armchair and zigzag-edges,at high Li concentration.We find that surface effects persist in stage-Ⅱ that bind Li strongly at the edge sites.However,the pronounced effect previously identified at the zigzag edge of pristine graphite is reduced in LiC_(12),penetrating only to the subsurface site,and eventually disappearing in LiC_(6).Consequently,the distinctive surface state at the zigzag edge significantly impacts and restrains the charging rate at the initial lithiation of graphite anodes,whilst diminishes with an increasing degree of lithiation.Longer diffusion time for Li hopping to the bulk site from either the zigzag edge or the armchair edge in LiC_(6) was observed during high state of charge due to charge repulsion.Effectively controlling Li occupation and diffusion kinetics at this stage is also crucial for enhancing the charge rate. 展开更多
关键词 graphite anode EDGE Interface Lithium-ion batteries Density functional theory
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Impedance Characterization of the Film Formation Process at the Graphite Anodes 被引量:1
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作者 Bo Hua DENG Yong Fang LI Hua Quan YANG 《Chinese Chemical Letters》 SCIE CAS CSCD 2000年第10期915-918,共4页
In this paper, the formation mechanism of the passive SEI film at the natural graphite anodes was investigated with tilt: electrochemical impedance spectroscopy (EIS). A characteristic semicircle was observed in the l... In this paper, the formation mechanism of the passive SEI film at the natural graphite anodes was investigated with tilt: electrochemical impedance spectroscopy (EIS). A characteristic semicircle was observed in the lower frequency range of the EIS spectrum for the irreversible charge process (lithium intercalation) at ca. 0.75V, 0.40V and 0.20V. 展开更多
关键词 electrochemical impedance spectroscopy surface film graphite anodes Li-ion battery
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ZnO-Embedded Expanded Graphite Composite Anodes with Controlled Charge Storage Mechanism Enabling Operation of Lithium-Ion Batteries at Ultra-Low Temperatures 被引量:1
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作者 Kun Ryu Michael J.Lee +1 位作者 Kyungbin Lee Seung Woo Lee 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2023年第4期31-39,共9页
As lithium(Li)-ion batteries expand their applications,operating over a wide temperature range becomes increasingly important.However,the lowtemperature performance of conventional graphite anodes is severely hampered... As lithium(Li)-ion batteries expand their applications,operating over a wide temperature range becomes increasingly important.However,the lowtemperature performance of conventional graphite anodes is severely hampered by the poor diffusion kinetics of Li ions(Li^(+)).Here,zinc oxide(ZnO) nanoparticles are incorporated into the expanded graphite to improve Li^(+)diffusion kinetics,resulting in a significant improvement in lowtemperature performance.The ZnO-embedded expanded graphite anodes are investigated with different amounts of ZnO to establish the structurecharge storage mechanism-performance relationship with a focus on lowtemperature applications.Electrochemical analysis reveals that the ZnOembedded expanded graphite anode with nano-sized ZnO maintains a large portion of the diffusion-controlled charge storage mechanism at an ultra-low temperature of-50℃ Due to this significantly enhanced Li^(+)diffusion rate,a full cell with the ZnO-embedded expanded graphite anode and a LiNi_(0.88)Co_(0.09)Al_(0.03)O_(2)cathode delivers high capacities of 176 mAh g^(-1)at20℃ and 86 mAh g^(-1)at-50℃ at a high rate of 1 C.The outstanding low-temperature performance of the composite anode by improving the Li^(+)diffusion kinetics provides important scientific insights into the fundamental design principles of anodes for low-temperature Li-ion battery operation. 展开更多
关键词 diffusive and capacitive charge storages expanded graphite composites anode lithium-ion battery low-temperature operation transition metal oxide
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The Film-forming Properties of Propylene Carbonate (PC) on Graphite Anodes
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作者 Honghe Zheng, Qunting Qu (Department of Chemistry, Henan Normal University, Xinxiang 453007, China) 《复旦学报(自然科学版)》 CAS CSCD 北大核心 2007年第5期851-,共1页
1 Results Propylene carbonate (PC) is well known having a series of excellent properties including low melting point,wide liquid-phase range and wide electrochemical window.In addition,PC is well compatible with diffe... 1 Results Propylene carbonate (PC) is well known having a series of excellent properties including low melting point,wide liquid-phase range and wide electrochemical window.In addition,PC is well compatible with different cathode materials.However,the poor compatibility of PC with graphite anode limits the utilization of PC solvent into lithium ion batteries.It is generally accepted that PC molecules co-intercalate into graphite interlayer with solvated Li ions and cause exfoliation of graphite structur... 展开更多
关键词 PC graphite anode ELECTROLYTE ADDITIVE
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Residual fluoride self-activated effect enabling upgraded utilization of recycled graphite anode
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作者 Shuzhe Yang Qingqing Gao +7 位作者 Yukun Li Hongwei Cai Xiaodan Li Gaoxing Sun Shuxin Zhuang Yujin Tong Hao Luo Mi Lu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第6期24-31,I0002,共9页
Recycling graphite anode from spent lithium-ion batteries(SLIBs)is regarded as a crucial approach to promoting sustainable energy storage industry.However,the recycled graphite(RG)generally presents degraded structure... Recycling graphite anode from spent lithium-ion batteries(SLIBs)is regarded as a crucial approach to promoting sustainable energy storage industry.However,the recycled graphite(RG)generally presents degraded structure and performance.Herein,the residual fluoride self-activated effect is proposed for the upgraded utilization of RG.Simple and low-energy water immersion treatment not only widens the interlayer spacing,but also retains appropriate fluoride on the surface of RG.Theoretical analysis and experiments demonstrate that the residual fluoride can optimize Li~+migration and deposition kinetics,resulting in better Li~+intercalation/deintercalation in the interlayer and more stable Li metal plating/stripping on the surface of RG,As a result,the designed LFP||RG full cells achieve ultrahigh reversibility(~100%Coulombic efficiency),high capacity retention(67%after 200 cycles,0.85 N/P ratio),and commendable adaptability(stable cycling without short-circuiting,0.15 N/P ratio).The energy density is improved from 334 Wh kg^(-1)of 1.1 N/P ratio to 367 Wh kg^(-1)of 0.85 N/P ratio(total mass based on cathode and anode).The exploration of RG by residual fluoride self-activated effect achieves upgraded utilization beyond fresh commercial graphite and highlights a new strategy for efficient reuse of SLIBs. 展开更多
关键词 Spent lithium-ion batteries Recycled graphite anode FLUORIDE Self-activated effect Upgraded utilization
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Regulated adsorption-diffusion and enhanced charge transfer in expanded graphite cohered with N,B bridge-doping carbon patches to boost K-ion storage
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作者 Haiyan Wang Haowen Du +5 位作者 Hucheng Zhang Songjie Meng Zhansheng Lu Hao Jiang Chunzhong Li Jianji Wang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第1期67-74,I0003,共9页
The great challenges are remained in constructing graphite-based anode with well built-in structures to accelerate kinetics and enhance stability in the advanced K-ion batteries(KIBs).Here,we firstly report the design... The great challenges are remained in constructing graphite-based anode with well built-in structures to accelerate kinetics and enhance stability in the advanced K-ion batteries(KIBs).Here,we firstly report the design of expanded graphite cohered by N,B bridge-doping carbon patches(NBEG)for efficient K-ion adsorption/diffusion and long-term durability.It is the B co-doping that plays a crucial role in maximizing doping-site utilization of N atoms,balancing the adsorption-diffusion kinetics,and promoting the charge transfer between NBEG and K ions.Especially,the robust lamellar structure,suitable interlayer distance,and rich active sites of the designed NBEG favor the rapid ion/electron transfer pathways and high K-ion storage capacity.Consequently,even at a low N,B doping concentration(4.36 at%,2.07 at%),NBEG anode shows prominent electrochemical performance for KIBs,surpassing most of the advanced carbon-based anodes.Kinetic studies,density functional theory simulations,and in-situ Raman spectroscopy are further performed to reveal the K-ion storage mechanism and confirm the critical actions of co-doping B.This work offers the new methods for graphite-electrode design and the deeper insights into their energy storage mechanisms in KIBs. 展开更多
关键词 Heteroatom dual-doping graphite anodes K-ion batteries Adsorption and diffusion energy Charge transfer
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The influence of formation temperature on the solid electrolyte interphase of graphite in lithium ion batteries 被引量:11
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作者 Chong Yan Yu-Xing Yao +4 位作者 Wen-Long Cai Lei Xu Stefan Kaskel Ho Seok Park Jia-Qi Huang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2020年第10期335-338,共4页
Lithium-ion battery has greatly changed our lifestyle and the solid electrolyte interphase(SEI)covered on the graphite anode determines the service life of a battery.The formation method and the formation temperature ... Lithium-ion battery has greatly changed our lifestyle and the solid electrolyte interphase(SEI)covered on the graphite anode determines the service life of a battery.The formation method and the formation temperature at initial cycle of a battery determine the feature of the SEI.Herein,we investigate the gap of formation behavior in both a half cell(graphite matches with lithium anode)and a full cell(graphite matches with NCM,short for LiNixCoyMn1-x-yO2)at different temperatures.We conclude that high temperature causes severe side reactions and low temperature will result in low ionic conductive SEI layer,the interface formed at room temperature owns the best ionic conductivity and stability. 展开更多
关键词 graphite anode Fast charging Solid electrolyte interphase(SEI) Full battery Formation temperature
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Understanding the mechanism of capacity increase during early cycling of commercial NMC/graphite lithium-ion batteries 被引量:7
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作者 Jia Guo Yaqi Li +3 位作者 Jinhao Meng Kjeld Pedersen Leonid Gurevich Daniel-Ioan Stroe 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2022年第11期34-44,I0003,共12页
A capacity increase is often observed in the early stage of Li-ion battery cycling.This study explores the phenomena involved in the capacity increase from the full cell,electrodes,and materials perspective through a ... A capacity increase is often observed in the early stage of Li-ion battery cycling.This study explores the phenomena involved in the capacity increase from the full cell,electrodes,and materials perspective through a combination of non-destructive diagnostic methods in a full cell and post-mortem analysis in a coin cell.The results show an increase of 1%initial capacity for the battery aged at 100%depth of discharge(DOD)and 45℃.Furthermore,large DODs or high temperatures accelerate the capacity increase.From the incremental capacity and differential voltage(IC-DV)analysis,we concluded that the increased capacity in a full cell originates from the graphite anode.Furthermore,graphite/Li coin cells show an increased capacity for larger DODs and a decreased capacity for lower DODs,thus in agreement with the full cell results.Post-mortem analysis results show that a larger DOD enlarges the graphite dspace and separates the graphite layer structure,facilitating the Li+diffusion,hence increasing the battery capacity. 展开更多
关键词 Capacity increasing Lithium-ion battery Full cell Coin cell graphite anode
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Kinetic Limits of Graphite Anode for Fast‑Charging Lithium‑Ion Batteries 被引量:5
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作者 Suting Weng Gaojing Yang +9 位作者 Simeng Zhang Xiaozhi Liu Xiao Zhang Zepeng Liu Mengyan Cao Mehmet Nurullah Ateş Yejing Li Liquan Chen Zhaoxiang Wang Xuefeng Wang 《Nano-Micro Letters》 SCIE EI CAS CSCD 2023年第11期518-529,共12页
Fast-charging lithium-ion batteries are highly required,especially in reducing the mileage anxiety of the widespread electric vehicles.One of the biggest bottlenecks lies in the sluggish kinetics of the Li^(+)intercal... Fast-charging lithium-ion batteries are highly required,especially in reducing the mileage anxiety of the widespread electric vehicles.One of the biggest bottlenecks lies in the sluggish kinetics of the Li^(+)intercalation into the graphite anode;slow intercalation will lead to lithium metal plating,severe side reactions,and safety concerns.The premise to solve these problems is to fully understand the reaction pathways and rate-determining steps of graphite during fast Li^(+)intercalation.Herein,we compare the Li^(+)diffusion through the graphite particle,interface,and electrode,uncover the structure of the lithiated graphite at high current densities,and correlate them with the reaction kinetics and electrochemical performances.It is found that the rate-determining steps are highly dependent on the particle size,interphase property,and electrode configuration.Insufficient Li^(+)diffusion leads to high polarization,incomplete intercalation,and the coexistence of several staging structures.Interfacial Li^(+)diffusion and electrode transportation are the main rate-determining steps if the particle size is less than 10μm.The former is highly dependent on the electrolyte chemistry and can be enhanced by constructing a fluorinated interphase.Our findings enrich the understanding of the graphite structural evolution during rapid Li^(+)intercalation,decipher the bottleneck for the sluggish reaction kinetics,and provide strategic guidelines to boost the fast-charging performance of graphite anode. 展开更多
关键词 Fast-charging graphite anode Cryogenic transmission electron microscopy(cryo-TEM) High-rate kinetics
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Graphite Anode for Potassium Ion Batteries: Current Status and Perspective 被引量:4
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作者 Xiaodan Li Jinliang Li +4 位作者 Liang Ma Caiyan Yu Zhong Ji Likun Pan Wenjie Mai 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2022年第2期458-469,共12页
With the increased demand from the storage of renewable energy sources,some safe and inexpensive energy storage technologies instead of Li-ion batteries become urgently needed.Therefore,K-ion batteries(KIBs)have attra... With the increased demand from the storage of renewable energy sources,some safe and inexpensive energy storage technologies instead of Li-ion batteries become urgently needed.Therefore,K-ion batteries(KIBs)have attracted much attention and evolved significant development because of the low price,safety,and similar property compared with Li-ion batteries.Due to the high reversibility,stability,and low potential plateau,graphite becomes a current research focus and is regarded as one of the most promising KIB’s anode materials.In this review,we mainly discuss the electrochemical reaction mechanism of graphite during potassiation-depotassiation process and analyze the effects of electrode/electrolyte interface on graphite for Kion storage.Besides,we summarize several kinds of methods to improve the performance of graphite for KIBs,including the design of graphite structure,selection of appropriate binder,solvent chemistry,and salt chemistry.Meanwhile,a concept of“relative energy density”is raised,which can be more accurate to evaluate the genuine electrochemical performance of graphite anode involving the specific capacity and potential.In addition,we also summarize the considerable challenges to current graphite anode in KIBs and we believe our work will offer alterative solutions to further explore high-performance graphite anode of K-ion storage. 展开更多
关键词 electrochemical reaction mechanism graphite anode K-ion batteries methods to improve performance
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Revealing the critical effect of solid electrolyte interphase on the deposition and detriment of Co(Ⅱ) ions to graphite anode 被引量:2
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作者 Qiming Xie Jiawei Chen +6 位作者 Lidan Xing Xianggui Zhou Zekai Ma Binhong Wu Yilong Lin Hebing Zhou Weishan Li 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2022年第6期389-396,I0011,共9页
"Dissolution,migration,and deposition"of transition metal ions (TMIs) result in capacity degradation of lithium-ion batteries (LIBs).Understanding such detrimental mechanism of TMIs is critical to the develo... "Dissolution,migration,and deposition"of transition metal ions (TMIs) result in capacity degradation of lithium-ion batteries (LIBs).Understanding such detrimental mechanism of TMIs is critical to the development of LIBs with long cycle life.In most previous works,TMIs were directly introduced into the electrolyte to investigate such a detrimental mechanism.In these cases,the TMIs are deposited directly on the fresh anode surface.However,in the practical battery system,the TMIs are deposited on the anode covered with solid electrolyte interphase (SEI) film.Whether the pre-presence of SEI film on anode surface influences the deposition and detriment of TMIs is unclear.In this work,the deposition of Co element on graphite anode with and without SEI film were systematically studied.The results clearly show that,in comparison with that of fresh graphite (SEI-free),the presence of SEI film aggravates the deposition of Co ions due to the Li^(+)–Co^(2+) ion exchange between the SEI and Co^(2+)-containing electrolyte without the driving of the electric field,leading to faster capacity fading of graphite anode.Therefore,how to regulate electrolytes and film-forming additives to design the components of SEI and prevent its exchange with TMIs,is a crucial way to inhibit the deposition and detriment of TMIs on graphite anode. 展开更多
关键词 Lithium-ion batteries Transition metal ions Ion exchange graphite anode SEI film
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Sulfolane-Graphite Incompatibility and Its Mitigation in Li-ion Batteries 被引量:1
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作者 Qinfeng Zheng Guanjie Li +3 位作者 Xiongwen Zheng Lidan Xing Kang Xu Weishan Li 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2022年第3期906-911,共6页
The non-flammability and high oxidation stability of sulfolane(SL)make it an excellent electrolyte candidate for lithium-ion batteries(LIBs).However,its incompatibility with graphitic anode prevents the realization of... The non-flammability and high oxidation stability of sulfolane(SL)make it an excellent electrolyte candidate for lithium-ion batteries(LIBs).However,its incompatibility with graphitic anode prevents the realization of these advantages.To understand how this incompatibility arises on molecular level so that it can be suppressed,we combined theoretical calculation and experimental characterization and reveal that the primary Li^(+) solvation sheath in SL is depleted of fluorine source.Upon reduction,SL in such fluorine-poor solvation sheath generates insoluble dimer with poor electronic insulation,hence leading to slow but sustained parasitic reactions.When fluorine content in Li^(+)-SL solvation sheath is increased via salt concentration,a high stability LiF-rich interphase on graphite can be formed.This new understanding of the failure mechanism of graphite in SL-based electrolyte is of great significance in unlocking many possible electrolyte solvent candidates for the high-voltage cathode materials for next-generation LIBs. 展开更多
关键词 graphite anode interphasial incompatibility mechanism lithium-ion batteries SULFOLANE
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A Novel Modification Approach for Natural Graphite Anode of Li-ion Batteries
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作者 周向阳 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2004年第2期85-89,共5页
To improve the rate capability and cyclability of natural graphite anode for Li-ion batteries,a novel modification approach was developed.The modification approach included two steps:(a)high-energy ball milling in a r... To improve the rate capability and cyclability of natural graphite anode for Li-ion batteries,a novel modification approach was developed.The modification approach included two steps:(a)high-energy ball milling in a rotary autoclave containing alumina balls,H_3PO_4 and ethanol;(b)coating with pyrolytic carbon from phenlic resin.The treated graphite shows obvious improvement compared with the original natural graphite in electrochemical properties such as cyclability and rate capability,especially at high current density.The primary reasons leading to the improvement in rate capability and cyclability are that the diffusion impedance of Li^+ in graphite is reduced due to the fact that P filtered into graphite layers can mildly increase interlayer distances,and the fact that the structural stability of graphite surface is enhanced since the coated pyrolytic carbon can depress the co-intercalation of solvated lithium ion. 展开更多
关键词 Li-ion batteries natural graphite anode high-energy ball milling COATING pyrolytic carbon
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Alkali Metal Ion Substituted Carboxymethyl Cellulose as Anode Polymeric Binders for Rapidly Chargeable Lithium-Ion Batteries
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作者 Seoungwoo Byun Zhu Liu +9 位作者 Dong Ok Shin Kyuman Kim Jaecheol Choi Youngjoon Roh Dahee Jin Seungwon Jung Kyung-Geun Kim Young-Gi Lee Stefan Ringe Yong Min Lee 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2024年第1期77-82,共6页
The increasing demand for short charging time on electric vehicles has motivated realization of fast chargeable lithium-ion batteries(LIBs).However,shortening the charging time of LIBs is limited by Li^(+)intercalatio... The increasing demand for short charging time on electric vehicles has motivated realization of fast chargeable lithium-ion batteries(LIBs).However,shortening the charging time of LIBs is limited by Li^(+)intercalation process consisting of liquid-phase diffusion,de-solvation,SEI crossing,and solid-phase diffusion.Herein,we propose a new strategy to accelerate the de-solvation step through a control of interaction between polymeric binder and solvent-Li^(+)complexes.For this purpose,three alkali metal ions(Li^(+),Na^(+),and K^(+))substituted carboxymethyl cellulose(Li-,Na-,and K-CMC)are prepared to examine the effects of metal ions on their performances.The lowest activation energy of de-solvation and the highest chemical diffusion coefficient were observed for Li-CMC.Specifically,Li-CMC cell with a capacity of 3 mAh cm^(-2)could be charged to>95%in 10 min,while a value above>85%was observed after 150 cycles.Thus,the presented approach holds great promise for the realization of fast charging. 展开更多
关键词 de-solvation digital twins fast charging graphite anodes polymeric binders
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Stable operation of highly loaded pure Si-Fe anode under ambient pressure via carboxy silane-directed robust solid electrolyte interphase
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作者 Guntae Lim Dong Guk Kang +6 位作者 Hyeon Gyu Lee Yen Hai Thi Tran Kihun An Junghyun Choi Kwang Chul Roh Do Youb Kim Seung-Wan Song 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第7期568-576,共9页
Incorporation of higher content Si anode material beyond 5 wt% to Li-ion batteries(LIBs)is challenging,owing to large volume change,swelling,and solid electrolyte interphase(SEI)instability issues.Herein,a strategy of... Incorporation of higher content Si anode material beyond 5 wt% to Li-ion batteries(LIBs)is challenging,owing to large volume change,swelling,and solid electrolyte interphase(SEI)instability issues.Herein,a strategy of diacetoxydimethylsilane(DAMS)additive-directed SEI stabilization is proposed for a stable operation of Si-0.33FeSi_(2)(named as Si-Fe)anode without graphite,which provides siloxane inorganics and organics enrichment that compensate insufficient passivation of fluoroethylene carbonate(FEC)additive and reduce a dependence on FEC.Unprecedented stable cycling performance of highly loaded(3.5 mA h cm^(-2))pure Si-Fe anode is achieved with 2 wt%DAMS combined with 9 wt%FEC additives under ambient pressure,yielding high capacity 1270 mA h g^(-1)at 0.5 C and significantly improved capacity retention of 81% after 100 cycles,whereas short circuit and rapid capacity fade occur with FEC only additive.DAMS-directed robust SEI layer dramatically suppresses swelling and particles crossover through separator,and therefore prevents short circuit,demonstrating a possible operation of pure Si or Sidominant anodes in the next-generation high-energy-density and safe LIBs. 展开更多
关键词 High-energy Li-ion battery Pure Si-Fe anode without graphite Silane additive SEI layer Suppressed swelling
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Flame-retardant oligomeric electrolyte additive for self-extinguishing and highly-stable lithium-ion batteries:Beyond small molecules
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作者 Yi-Zhou Quan Qing-Song Liu +4 位作者 Mei-Chen Liu Guo-Rui Zhu Gang Wu Xiu-Li Wang Yu-Zhong Wang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第9期374-384,共11页
Preparing both safe and high-performance lithium-ion batteries(LIBs) based on commonly used commercial electrolytes is highly desirable,yet challenging.To overcome the poor compatibility of conventional small-molecula... Preparing both safe and high-performance lithium-ion batteries(LIBs) based on commonly used commercial electrolytes is highly desirable,yet challenging.To overcome the poor compatibility of conventional small-molecular flame-retardants as electrolyte additives for safe LIBs with graphite anodes,in this study,we propose and design a novel low-cost flame-retardant oligomer that achieves an accurate and complete reconciliation of fire safety and electrochemical performance in LIBs.Owing to the integration of phosphonate units and polyethylene glycol(PEG) chains,this oligomer,which is a phosphonatecontaining PEG-based oligomer(PPO),not only endows commercial electrolytes with excellent flame retardancy but also helps stabilize the electrodes and Li-ion migration.Specifically,adding 15 wt% of PPO can reduce 70% of the self-extinguishing time and 54% of total heat release for commercial electrolytes.Moreover,LiFePO_(4)/lithium and graphite/lithium cells as well as LiFePO_(4)/graphite pouch full cells exhibit good long-term cycling stability. 展开更多
关键词 Flame-retardant oligomer Safety Compatibility graphite anodes Lithium-ion batteries
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Battery impedance spectrum prediction from partial charging voltage curve by machine learning 被引量:5
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作者 Jia Guo Yunhong Che +1 位作者 Kjeld Pedersen Daniel-Ioan Stroe 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第4期211-221,共11页
Electrochemical impedance spectroscopy(EIS) is an effective technique for Lithium-ion battery state of health diagnosis, and the impedance spectrum prediction by battery charging curve is expected to enable battery im... Electrochemical impedance spectroscopy(EIS) is an effective technique for Lithium-ion battery state of health diagnosis, and the impedance spectrum prediction by battery charging curve is expected to enable battery impedance testing during vehicle operation. However, the mechanistic relationship between charging curves and impedance spectrum remains unclear, which hinders the development as well as optimization of EIS-based prediction techniques. In this paper, we predicted the impedance spectrum by the battery charging voltage curve and optimized the input based on electrochemical mechanistic analysis and machine learning. The internal electrochemical relationships between the charging curve,incremental capacity curve, and the impedance spectrum are explored, which improves the physical interpretability for this prediction and helps define the proper partial voltage range for the input for machine learning models. Different machine learning algorithms have been adopted for the verification of the proposed framework based on the sequence-to-sequence predictions. In addition, the predictions with different partial voltage ranges, at different state of charge, and with different training data ratio are evaluated to prove the proposed method have high generalization and robustness. The experimental results show that the proper partial voltage range has high accuracy and converges to the findings of the electrochemical analysis. The predicted errors for impedance spectrum are less than 1.9 mΩ with the proper partial voltage range selected by the corelative analysis of the electrochemical reactions inside the batteries. Even with the voltage range reduced to 3.65–3.75 V, the predictions are still reliable with most RMSEs less than 4 mO. 展开更多
关键词 Impedance spectrum prediction Lithium-ion battery Machine learning EIS graphite anode
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Investigation of interfacial processes in graphite thin film anodes of lithium-ion batteries by both in situ and ex situ infrared spectroscopy 被引量:3
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作者 LI JunTao SU Hang +1 位作者 HUANG Ling SUN ShiGang 《Science China Chemistry》 SCIE EI CAS 2013年第7期992-996,共5页
Graphite thin film anodes with a high IR reflectivity have been prepared by a spin coating method. Both ex situ and in situ mi- croscope FTIR spectroscopy (MFFIRS) in a reflection configuration were employed to inve... Graphite thin film anodes with a high IR reflectivity have been prepared by a spin coating method. Both ex situ and in situ mi- croscope FTIR spectroscopy (MFFIRS) in a reflection configuration were employed to investigate interfacial processes of the graphite thin film anodes in lithium-ion batteries. A solid electrolyte interphase layer (SEI layer) was formed on the cycled graphite thin film anode. Ex situ MFTIRS revealed that the main components of the SEI layer on cycled graphite film anodes in 1 tool L 1 LiPF6/ethylene carbonate + dimethyl carbonate (1:1) are alkyl lithium carbonates (ROCOzLi). The desolvation process on graphite anodes during the initial intercalation of lithium ion with graphite was also observed and analyzed by in situ MFTIRS. 展开更多
关键词 graphite anode interfaciai process FTIR spectroscopy lithium-ion battery
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The Puzzles in Fast Charging of Li-Ion Batteries
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作者 Sheng Shui Zhang 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2022年第4期1005-1007,共3页
Fast charging of Li-ion cells faces two aspects of challenges,1)accelerated capacity fade and 2)inferior charging capability.It is commonly believed that the former is due to Li plating and its resultant reactions wit... Fast charging of Li-ion cells faces two aspects of challenges,1)accelerated capacity fade and 2)inferior charging capability.It is commonly believed that the former is due to Li plating and its resultant reactions with electrolyte at the graphite anode,which results in a loss in the inventory of Li+ions and an increase in the cell’s impedance.While the latter is ascribed to the high voltage polarization in relation to the slow transport of Li+ions between two electrodes.However,there are many other hidden facts that essentially affect the fast charging performances of Li-ion cells.This commentary intends,from the view of materials,to uncover these hidden factors,including failure of the solid electrolyte interphase and exfoliation of the graphite structure at the anode,structural degradation of the Ni-rich layered cathode materials,as well as the high solvation and desolvation activation energies of Li+ions in the electrolyte.Meanwhile,some solutions to the fast-charging problems of Li-ion cells are proposed based on the understanding of these hidden factors. 展开更多
关键词 ELECTROLYTE fast charging graphite anode layered cathode Li-ion battery
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Electrochemical Behavior of Magnolol on FeWO4 Nanoflower Modified Carbon Paste Electrode
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作者 胡卫兵 ZHANG Wen +2 位作者 SONG Nannan QU Wanyun HU Sheng 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2016年第4期722-726,共5页
In order to establish a simple,sensitive,and fast reliable detection method to determine the magnolol,FeWO4 nanoflower was synthesised through a solvothermal technique and FeWO4 nanoflower modified carbon paste electr... In order to establish a simple,sensitive,and fast reliable detection method to determine the magnolol,FeWO4 nanoflower was synthesised through a solvothermal technique and FeWO4 nanoflower modified carbon paste electrode(CPE) was developed.The voltammetric behavior of magnolol on the modified electrodes was studied using cyclic voltammetry(CV),linear sweep voltammetry(LSV),and differential pulse voltammetry(DPV).The experimental results showed that the modified electrode remarkably enhanced the electrochemical response of the magnolol and exhibited a wide linear range for determination of the magnolol from 1.0×10-7 to 1.0×10-4 mol/L with a low detection limit of 5.0×10-8 mol/L. 展开更多
关键词 voltammetry Paste paste remarkably Modified graphite paraffin anodic electrolyte silica
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