ADVN （2,2＇-Azobis （2,4-dimethyl） valeronitrile）, a free radical initiator, is widely applied for the polymerization reaction of polymers in the chemical industries. When ADVN releases free radical during the deco...ADVN （2,2＇-Azobis （2,4-dimethyl） valeronitrile）, a free radical initiator, is widely applied for the polymerization reaction of polymers in the chemical industries. When ADVN releases free radical during the decomposition process, it can accompany abundant heat and huge pressure to increase the possibility of thermal runaway and hazard, causing unacceptable thermal explosion or fire accidents. To develop an inherently safer process for ADVN, the thermal stability parameters of ADVN were obtained to investigate thermal decomposition characteristics using a DSC （differential scanning calorimetry） and TG （thermogravimetry）. We used various kinetic models to completely depict the kinetic behavior and determine the thermal safety parameters for ADVN. The green thermal analysis approach could be used to substitute for complicated procedures and large-scale experiments of traditional thermal analysis methods, avoiding environmental pollution and energy depletion.展开更多
This paper explains the benefits and challenges of urban green spaces based on the critical discussion of study results from different studies in different cities. The important roles played by green spaces are social...This paper explains the benefits and challenges of urban green spaces based on the critical discussion of study results from different studies in different cities. The important roles played by green spaces are social, economic, cultural and environmental aspects of sustainable development. Urban green spaces can be a comprehensive tool for long term protection of environmental sustainability through improving the quality of life and air quality, increasing property value due to their amenity and aesthetic characteristics, and reducing the energy costs of cooling buildings. Urban green spaces also can provide ecosystem services in which the recreation and relaxation facilities are especially available to urban dwellers and tourists too. To confirm the multiple roles played by green spaces, certain level of qualitative improvements and distribution of green spaces within the urban area should be considered and incorporated effectively into the environmental sustainability agenda. To do this, an integrated approach regarding the planning, monitoring, designing and maintaining of urban green spaces is required for improving the environmental sustainability in cities in different countries.展开更多
The study of green compression strength of a green sand mould using statistical approach has been undertaken. Empirically generated data in National Metallurgical Development Centre, Jos Sand Testing Laboratory were u...The study of green compression strength of a green sand mould using statistical approach has been undertaken. Empirically generated data in National Metallurgical Development Centre, Jos Sand Testing Laboratory were used for the study. Coefficient of correlation, coefficients of determination and coefficient of multiple determinations were used to explain the relationship existing between the two independent variables of clay and moisture content and green compression strength, the dependent variable. The study showed that the coefficient of determination for Ys: X1 was 0.88 while the coefficient of correlation was 0.94, coefficient of determination for Ys: X2 was 0.90 while the coefficient of correlation was 0.95 and the coefficient of multiple determination was 0.72;these coefficients assisted tremendously in the study of green compression strength. A mathematical model was developed for the prediction of green compression strength;it was tested and proved to be a good estimation tool for estimating green compression strength values on the foundry shop floor. The study has clearly shown that statistical approach is a good tool for studying green compression strength of green sand moulds.展开更多
Approaches toward the sustainable development need integrated considerations of technical, economical, environmental/ecological and social issues. Current approaches from different disciplines can be grouped into at l...Approaches toward the sustainable development need integrated considerations of technical, economical, environmental/ecological and social issues. Current approaches from different disciplines can be grouped into at least three levels: micro-scale, meso-scale and macro-scale. At the micro-scale, green chemistry carries out chemical activities such as chemical design and synthesis so that environmentally benign chemicals can be synthesized without using and generating hazardous substances. Green engineering, at the meso-scale, develops green industrial processes or clean technologies via pollution prevention and cleaner production, which will cause minimal damages or dangers to the environment and ecosystems when the product is manufactured and used. Industrial ecology at the industrial complex or community level seeks to optimize energy and materials use and minimize waste generation in industrial systems or communities by promoting planned materials and energy exchanges. Incorporation of ecological principles with the life cycle thinking in the chemical pathway synthesis, product design, process development, and industrial system and community planning appears to be the most promising engineering approach in achieving sustainable industrial development.展开更多
文摘ADVN （2,2＇-Azobis （2,4-dimethyl） valeronitrile）, a free radical initiator, is widely applied for the polymerization reaction of polymers in the chemical industries. When ADVN releases free radical during the decomposition process, it can accompany abundant heat and huge pressure to increase the possibility of thermal runaway and hazard, causing unacceptable thermal explosion or fire accidents. To develop an inherently safer process for ADVN, the thermal stability parameters of ADVN were obtained to investigate thermal decomposition characteristics using a DSC （differential scanning calorimetry） and TG （thermogravimetry）. We used various kinetic models to completely depict the kinetic behavior and determine the thermal safety parameters for ADVN. The green thermal analysis approach could be used to substitute for complicated procedures and large-scale experiments of traditional thermal analysis methods, avoiding environmental pollution and energy depletion.
文摘This paper explains the benefits and challenges of urban green spaces based on the critical discussion of study results from different studies in different cities. The important roles played by green spaces are social, economic, cultural and environmental aspects of sustainable development. Urban green spaces can be a comprehensive tool for long term protection of environmental sustainability through improving the quality of life and air quality, increasing property value due to their amenity and aesthetic characteristics, and reducing the energy costs of cooling buildings. Urban green spaces also can provide ecosystem services in which the recreation and relaxation facilities are especially available to urban dwellers and tourists too. To confirm the multiple roles played by green spaces, certain level of qualitative improvements and distribution of green spaces within the urban area should be considered and incorporated effectively into the environmental sustainability agenda. To do this, an integrated approach regarding the planning, monitoring, designing and maintaining of urban green spaces is required for improving the environmental sustainability in cities in different countries.
文摘The study of green compression strength of a green sand mould using statistical approach has been undertaken. Empirically generated data in National Metallurgical Development Centre, Jos Sand Testing Laboratory were used for the study. Coefficient of correlation, coefficients of determination and coefficient of multiple determinations were used to explain the relationship existing between the two independent variables of clay and moisture content and green compression strength, the dependent variable. The study showed that the coefficient of determination for Ys: X1 was 0.88 while the coefficient of correlation was 0.94, coefficient of determination for Ys: X2 was 0.90 while the coefficient of correlation was 0.95 and the coefficient of multiple determination was 0.72;these coefficients assisted tremendously in the study of green compression strength. A mathematical model was developed for the prediction of green compression strength;it was tested and proved to be a good estimation tool for estimating green compression strength values on the foundry shop floor. The study has clearly shown that statistical approach is a good tool for studying green compression strength of green sand moulds.
文摘Approaches toward the sustainable development need integrated considerations of technical, economical, environmental/ecological and social issues. Current approaches from different disciplines can be grouped into at least three levels: micro-scale, meso-scale and macro-scale. At the micro-scale, green chemistry carries out chemical activities such as chemical design and synthesis so that environmentally benign chemicals can be synthesized without using and generating hazardous substances. Green engineering, at the meso-scale, develops green industrial processes or clean technologies via pollution prevention and cleaner production, which will cause minimal damages or dangers to the environment and ecosystems when the product is manufactured and used. Industrial ecology at the industrial complex or community level seeks to optimize energy and materials use and minimize waste generation in industrial systems or communities by promoting planned materials and energy exchanges. Incorporation of ecological principles with the life cycle thinking in the chemical pathway synthesis, product design, process development, and industrial system and community planning appears to be the most promising engineering approach in achieving sustainable industrial development.
