This paper is to explore the problems of intelligent connected vehicles(ICVs)autonomous driving decision-making under a 5G-V2X structured road environment.Through literature review and interviews with autonomous drivi...This paper is to explore the problems of intelligent connected vehicles(ICVs)autonomous driving decision-making under a 5G-V2X structured road environment.Through literature review and interviews with autonomous driving practitioners,this paper firstly puts forward a logical framework for designing a cerebrum-like autonomous driving system.Secondly,situated on this framework,it builds a hierarchical finite state machine(HFSM)model as well as a TOPSIS-GRA algorithm for making ICV autonomous driving decisions by employing a data fusion approach between the entropy weight method(EWM)and analytic hierarchy process method(AHP)and by employing a model fusion approach between the technique for order preference by similarity to an ideal solution(TOPSIS)and grey relational analysis(GRA).The HFSM model is composed of two layers:the global FSM model and the local FSM model.The decision of the former acts as partial input information of the latter and the result of the latter is sent forward to the local pathplanning module,meanwhile pulsating feedback to the former as real-time refresh data.To identify different traffic scenarios in a cerebrum-like way,the global FSM model is designed as 7 driving behavior states and 17 driving characteristic events,and the local FSM model is designed as 16 states and 8 characteristic events.In respect to designing a cerebrum-like algorithm for state transition,this paper firstly fuses AHP weight and EWM weight at their output layer to generate a synthetic weight coefficient for each characteristic event;then,it further fuses TOPSIS method and GRA method at the model building layer to obtain the implementable order of state transition.To verify the feasibility,reliability,and safety of theHFSMmodel aswell as its TOPSISGRA state transition algorithm,this paper elaborates on a series of simulative experiments conducted on the PreScan8.50 platform.The results display that the accuracy of obstacle detection gets 98%,lane line prediction is beyond 70 m,the speed of collision avoidance is higher than 45 km/h,the distance of collision avoidance is less than 5 m,path planning time for obstacle avoidance is averagely less than 50 ms,and brake deceleration is controlled under 6 m/s2.These technical indexes support that the driving states set and characteristic events set for the HFSM model as well as its TOPSIS-GRA algorithm may bring about cerebrum-like decision-making effectiveness for ICV autonomous driving under 5G-V2X intelligent road infrastructure.展开更多
This article presents a ground theory to explain why some individuals choose to be unhappy rather than happy,supported by empirical data collected from a sample of 750 professionals in Greece’s public and private sec...This article presents a ground theory to explain why some individuals choose to be unhappy rather than happy,supported by empirical data collected from a sample of 750 professionals in Greece’s public and private sectors.We begin by reviewing the existing literature on happiness and well-being,highlighting the debate between hedonic and eudaimonic perspectives.We then introduce our research questions and rationale,and describe our methods,sample,and psychometric tools used to measure happiness and other variables of interest.Our results indicate that various factors,including cultural influences,past experiences,and personal values,contribute to individuals’pursuit of unhappiness.We conclude with a thorough discussion of our results and their implications for future research and interventions aimed at promoting well-being.展开更多
<正> The transverse spin-2 Ising ferromagnetic model with a longitudinal crystal-field is studied within themean-field theory based on Bogoliubov inequality for the Gibbs free energy.The ground-state phase diagr...<正> The transverse spin-2 Ising ferromagnetic model with a longitudinal crystal-field is studied within themean-field theory based on Bogoliubov inequality for the Gibbs free energy.The ground-state phase diagram and thetricritical point are obtained in the transverse field Ω/zJ-longitudinal crystal D/zJ field plane.We find that there are thefirst order-order phase transitions in a very small range of D/zJ besides the usual first order-disorder phase transitionsand the second order-disorder phase transitions.展开更多
The classical frustrated antiferromagnetic J_1–J_2 model is considered in a description of the classical spin wave for a vector spin system. Its ground state(GS) spin ordering is analyzed by minimizing its energy. Ou...The classical frustrated antiferromagnetic J_1–J_2 model is considered in a description of the classical spin wave for a vector spin system. Its ground state(GS) spin ordering is analyzed by minimizing its energy. Our analytical derivations show that all the spins in the GS phase must lie in planes that are parallel to each other. When applying the derived formulations to concrete lattices such as the square and simple cubic lattices, we find that in the large J_2 region, a large continuous GS degeneracy concluded by a qualitative analysis is lifted, and collinear striped ordering is selected as the GS phase.展开更多
We study the electronic and magnetic properties of an oxygen-deficient perovskite Ca2Mn2O5 based on the first principle calculations. The calculations show that the ground state of Ca2Mn2O5 is a D-type anti-ferromagne...We study the electronic and magnetic properties of an oxygen-deficient perovskite Ca2Mn2O5 based on the first principle calculations. The calculations show that the ground state of Ca2Mn2O5 is a D-type anti-ferromagnetic structure with the anti-ferromagnetic spin coupling along the c-direction. The corresponding electronic structure of the D-type state is investigated, and the results display that Ca2Mn2O5 is an insulator with an indirect energy gap of -2.08eV. By the partiM density-of-state analysis, the valence band maximum is mainly contributed to by the 0-213 orbitMs and the conduction band minimum is contributed to by the 0-213 and Mn-3d orbitals. Due to the Coulomb repulsion interaction between electrons, the density of state of Mn-3d is pulled to -6--4.5eV.展开更多
Complete active space multiconfiguration self-consisten-field (CAS-MCSCF)calculations are carried out on the ground stae() of W_2. The spectroscopic properties(Re=2.078A. De=4.224eV and ωe=304.3cm-1) and the poential...Complete active space multiconfiguration self-consisten-field (CAS-MCSCF)calculations are carried out on the ground stae() of W_2. The spectroscopic properties(Re=2.078A. De=4.224eV and ωe=304.3cm-1) and the poential energy curve of the state are reported. The calculations predict the W-W bond order of 5.02.展开更多
The geometries, vibrational frequencies and bind energies are reported for the ground states of CaC 2H + 2, CaC 2D + 2 and CaC 2H + 4. CaC 2H + 2 and CaC 2H + 4 equilibrium geometries have C 2v symmetry with the metal...The geometries, vibrational frequencies and bind energies are reported for the ground states of CaC 2H + 2, CaC 2D + 2 and CaC 2H + 4. CaC 2H + 2 and CaC 2H + 4 equilibrium geometries have C 2v symmetry with the metal ion lying in the perpendicular bisector of the C-C bond. The ground state in both CaC 2H + 2 and CaC 2H + 4 molecules ia a 2A 1 state and the binding in the ground state is mainly electrostatic. For both CaC 2H + 2 and CaC 2H + 4 the ligand is only slightly distorted from its free ligand structure, the C-C distance has hardly increased and there is only a very small bending of the H atom away from the Ca atom. This is consistent with the electrostatic nature of the bonding. Two different approaches-Hartree-Fock(HF) and density functional theory methods(DFT)-are used and basis sets here used is 6-311+G(3df,2p). The DFT results are in good agreement with experiments, namely, DFT methods provide the benefits that some more expensive ab initio methods can do, but at essentially HF cost. So it is important to include electron correlation for accurate results in this study.展开更多
采用研究双原子分子离子XY+的能量自洽法(energy-consistent method for ion XY+,ECMI)研究了双原子分子负离子CP-基态X2Σ+的势能行为,得到了负离子CP-基态X2Σ+的解析势能函数ECMI势,并将这个ECMI势、中性双原子分子的势能函数如Mors...采用研究双原子分子离子XY+的能量自洽法(energy-consistent method for ion XY+,ECMI)研究了双原子分子负离子CP-基态X2Σ+的势能行为,得到了负离子CP-基态X2Σ+的解析势能函数ECMI势,并将这个ECMI势、中性双原子分子的势能函数如Morse势、Huxley-Murrell-Sorbie(HMS)势直接用于研究CP-基态X2Σ+势能行为得到的结果与基于实验的Rydberg-Klein-Ress(RKR)数据进行了比较.结果表明,CP-基态X2Σ+的势能函数ECMI势与RKR数据符合得很好,明显优于中性双原子分子势能函数Morse势和HMS势在该分子离子电子态的表现,并且ECMI势还给出了对原子分子碰撞研究非常重要的正确离解极限和全程势能数据.展开更多
Photodeposition is widely adopted for implanting metal/metal oxide cocatalysts on semiconductors.However,it is prerequisite that the photon energy should be sufficient to excite the host semiconductor.Here,we report a...Photodeposition is widely adopted for implanting metal/metal oxide cocatalysts on semiconductors.However,it is prerequisite that the photon energy should be sufficient to excite the host semiconductor.Here,we report a lower-energy irradiation powered deposition strategy for implanting CrO_(x) cocatalyst on TiO_(2).Excitingly,CrO_(x)-400 implanted under visible-light irradiation significantly promotes the CH4 evolution rate on TiO_(2)to 8.4μmolg·^(-1)h^(-1) with selectivity of98%from photocatalytic CO_(2)reduction,which is 15 times of that on CrO_(x)-200 implanted under UV-visible-light irradiation.Moreover,CrO_(x)-400 is identified to be composed of higher valence Cr species compared to CrO_(x)-200.This valence states regulation of Cr species is indicated to provide more active sites for CO_(2) adsorption/activation and to modulate the reaction mechanism from single Cr site to Cr-Cr dual sites,thus endowing the superior CH_(4)production.This work demonstrates an alternative strategy for constructing efficient metal oxides cocatalysts on wide bandgap semiconductor.展开更多
基金funded by Chongqing Science and Technology Bureau (No.cstc2021jsyj-yzysbAX0008)Chongqing University of Arts and Sciences (No.P2021JG13)2021 Humanities and Social Sciences Program of Chongqing Education Commission (No.21SKGH227).
文摘This paper is to explore the problems of intelligent connected vehicles(ICVs)autonomous driving decision-making under a 5G-V2X structured road environment.Through literature review and interviews with autonomous driving practitioners,this paper firstly puts forward a logical framework for designing a cerebrum-like autonomous driving system.Secondly,situated on this framework,it builds a hierarchical finite state machine(HFSM)model as well as a TOPSIS-GRA algorithm for making ICV autonomous driving decisions by employing a data fusion approach between the entropy weight method(EWM)and analytic hierarchy process method(AHP)and by employing a model fusion approach between the technique for order preference by similarity to an ideal solution(TOPSIS)and grey relational analysis(GRA).The HFSM model is composed of two layers:the global FSM model and the local FSM model.The decision of the former acts as partial input information of the latter and the result of the latter is sent forward to the local pathplanning module,meanwhile pulsating feedback to the former as real-time refresh data.To identify different traffic scenarios in a cerebrum-like way,the global FSM model is designed as 7 driving behavior states and 17 driving characteristic events,and the local FSM model is designed as 16 states and 8 characteristic events.In respect to designing a cerebrum-like algorithm for state transition,this paper firstly fuses AHP weight and EWM weight at their output layer to generate a synthetic weight coefficient for each characteristic event;then,it further fuses TOPSIS method and GRA method at the model building layer to obtain the implementable order of state transition.To verify the feasibility,reliability,and safety of theHFSMmodel aswell as its TOPSISGRA state transition algorithm,this paper elaborates on a series of simulative experiments conducted on the PreScan8.50 platform.The results display that the accuracy of obstacle detection gets 98%,lane line prediction is beyond 70 m,the speed of collision avoidance is higher than 45 km/h,the distance of collision avoidance is less than 5 m,path planning time for obstacle avoidance is averagely less than 50 ms,and brake deceleration is controlled under 6 m/s2.These technical indexes support that the driving states set and characteristic events set for the HFSM model as well as its TOPSIS-GRA algorithm may bring about cerebrum-like decision-making effectiveness for ICV autonomous driving under 5G-V2X intelligent road infrastructure.
文摘This article presents a ground theory to explain why some individuals choose to be unhappy rather than happy,supported by empirical data collected from a sample of 750 professionals in Greece’s public and private sectors.We begin by reviewing the existing literature on happiness and well-being,highlighting the debate between hedonic and eudaimonic perspectives.We then introduce our research questions and rationale,and describe our methods,sample,and psychometric tools used to measure happiness and other variables of interest.Our results indicate that various factors,including cultural influences,past experiences,and personal values,contribute to individuals’pursuit of unhappiness.We conclude with a thorough discussion of our results and their implications for future research and interventions aimed at promoting well-being.
文摘<正> The transverse spin-2 Ising ferromagnetic model with a longitudinal crystal-field is studied within themean-field theory based on Bogoliubov inequality for the Gibbs free energy.The ground-state phase diagram and thetricritical point are obtained in the transverse field Ω/zJ-longitudinal crystal D/zJ field plane.We find that there are thefirst order-order phase transitions in a very small range of D/zJ besides the usual first order-disorder phase transitionsand the second order-disorder phase transitions.
基金Supported by the National Natural Science Foundation of China under Grant No 11774002
文摘The classical frustrated antiferromagnetic J_1–J_2 model is considered in a description of the classical spin wave for a vector spin system. Its ground state(GS) spin ordering is analyzed by minimizing its energy. Our analytical derivations show that all the spins in the GS phase must lie in planes that are parallel to each other. When applying the derived formulations to concrete lattices such as the square and simple cubic lattices, we find that in the large J_2 region, a large continuous GS degeneracy concluded by a qualitative analysis is lifted, and collinear striped ordering is selected as the GS phase.
基金Supported by the National Basic Research Program of China under Grant No 2014CB931703the National Natural Science Foundation of China under Grant Nos 11404172,51101088,and 51171082the Fundamental Research Funds for the Central Universities
文摘We study the electronic and magnetic properties of an oxygen-deficient perovskite Ca2Mn2O5 based on the first principle calculations. The calculations show that the ground state of Ca2Mn2O5 is a D-type anti-ferromagnetic structure with the anti-ferromagnetic spin coupling along the c-direction. The corresponding electronic structure of the D-type state is investigated, and the results display that Ca2Mn2O5 is an insulator with an indirect energy gap of -2.08eV. By the partiM density-of-state analysis, the valence band maximum is mainly contributed to by the 0-213 orbitMs and the conduction band minimum is contributed to by the 0-213 and Mn-3d orbitals. Due to the Coulomb repulsion interaction between electrons, the density of state of Mn-3d is pulled to -6--4.5eV.
文摘Complete active space multiconfiguration self-consisten-field (CAS-MCSCF)calculations are carried out on the ground stae() of W_2. The spectroscopic properties(Re=2.078A. De=4.224eV and ωe=304.3cm-1) and the poential energy curve of the state are reported. The calculations predict the W-W bond order of 5.02.
文摘The geometries, vibrational frequencies and bind energies are reported for the ground states of CaC 2H + 2, CaC 2D + 2 and CaC 2H + 4. CaC 2H + 2 and CaC 2H + 4 equilibrium geometries have C 2v symmetry with the metal ion lying in the perpendicular bisector of the C-C bond. The ground state in both CaC 2H + 2 and CaC 2H + 4 molecules ia a 2A 1 state and the binding in the ground state is mainly electrostatic. For both CaC 2H + 2 and CaC 2H + 4 the ligand is only slightly distorted from its free ligand structure, the C-C distance has hardly increased and there is only a very small bending of the H atom away from the Ca atom. This is consistent with the electrostatic nature of the bonding. Two different approaches-Hartree-Fock(HF) and density functional theory methods(DFT)-are used and basis sets here used is 6-311+G(3df,2p). The DFT results are in good agreement with experiments, namely, DFT methods provide the benefits that some more expensive ab initio methods can do, but at essentially HF cost. So it is important to include electron correlation for accurate results in this study.
文摘采用研究双原子分子离子XY+的能量自洽法(energy-consistent method for ion XY+,ECMI)研究了双原子分子负离子CP-基态X2Σ+的势能行为,得到了负离子CP-基态X2Σ+的解析势能函数ECMI势,并将这个ECMI势、中性双原子分子的势能函数如Morse势、Huxley-Murrell-Sorbie(HMS)势直接用于研究CP-基态X2Σ+势能行为得到的结果与基于实验的Rydberg-Klein-Ress(RKR)数据进行了比较.结果表明,CP-基态X2Σ+的势能函数ECMI势与RKR数据符合得很好,明显优于中性双原子分子势能函数Morse势和HMS势在该分子离子电子态的表现,并且ECMI势还给出了对原子分子碰撞研究非常重要的正确离解极限和全程势能数据.
基金supported by the National Key Research and Development Program of China(2016YFB0700205,2017YFA0403402,2019YFA0405602,2017YFA0204904)the National Natural Science Foundation of China(52002367,21673214,U1732272,U1632273,U1832165)+1 种基金the foundation from Users with Excellence Program of Hefei Science Center CAS(2020HSC-UE001)the Fundamental Research Funds for the Central Universities(WK2310000093)。
文摘Photodeposition is widely adopted for implanting metal/metal oxide cocatalysts on semiconductors.However,it is prerequisite that the photon energy should be sufficient to excite the host semiconductor.Here,we report a lower-energy irradiation powered deposition strategy for implanting CrO_(x) cocatalyst on TiO_(2).Excitingly,CrO_(x)-400 implanted under visible-light irradiation significantly promotes the CH4 evolution rate on TiO_(2)to 8.4μmolg·^(-1)h^(-1) with selectivity of98%from photocatalytic CO_(2)reduction,which is 15 times of that on CrO_(x)-200 implanted under UV-visible-light irradiation.Moreover,CrO_(x)-400 is identified to be composed of higher valence Cr species compared to CrO_(x)-200.This valence states regulation of Cr species is indicated to provide more active sites for CO_(2) adsorption/activation and to modulate the reaction mechanism from single Cr site to Cr-Cr dual sites,thus endowing the superior CH_(4)production.This work demonstrates an alternative strategy for constructing efficient metal oxides cocatalysts on wide bandgap semiconductor.
