Quantitative description of vapor-liquid equilibrium is very useful for designing separation processes. In this study, we combined the Peng-Robinson equation and the Huron-Vidal-Orbey-Sandler mixing rule into a modifi...Quantitative description of vapor-liquid equilibrium is very useful for designing separation processes. In this study, we combined the Peng-Robinson equation and the Huron-Vidal-Orbey-Sandler mixing rule into a modified UNIFAC model for the improvement of predicting vapor-liquid equilibria. The predictions of vapor-liquid equilibria for 62 systems including alcohol- alkane, alcohol-benzene, and amine-water systems demonstrate that the revised parameters remarkably improve the prediction accuracy for many systems. Especially for amine-water system, the mean deviation of components decreases from 0.094 to 0.021, and the mean deviation of pressure from 22.45% to 4.41%.展开更多
Although the channel-decoupling assumption is often used in design of three-dimensional guidance laws, it loses its rationality for aircrafts with strong kinematics coupling because body rotation arises. To overcome t...Although the channel-decoupling assumption is often used in design of three-dimensional guidance laws, it loses its rationality for aircrafts with strong kinematics coupling because body rotation arises. To overcome this trouble, a novel guiding method was proposed based on Lie-group. After a model of 3D guidance is formulated using vectors, the precision guidance with ending angular constraints can be transformed into a problem involving the relation between directional angles and rotational angular velocities of certain vectors. When the guidance model is imposed a SO(3)-based description, a novel 3D sliding mode guidance law with ending angular constraints can be developed via Lie-group control method and variable structure control theory. Finally, the feasibility and performance of the guidance law were shown by simulating the examples.展开更多
文摘Quantitative description of vapor-liquid equilibrium is very useful for designing separation processes. In this study, we combined the Peng-Robinson equation and the Huron-Vidal-Orbey-Sandler mixing rule into a modified UNIFAC model for the improvement of predicting vapor-liquid equilibria. The predictions of vapor-liquid equilibria for 62 systems including alcohol- alkane, alcohol-benzene, and amine-water systems demonstrate that the revised parameters remarkably improve the prediction accuracy for many systems. Especially for amine-water system, the mean deviation of components decreases from 0.094 to 0.021, and the mean deviation of pressure from 22.45% to 4.41%.
基金Sponsored by the National Natural Science Foundation of China (60374006)
文摘Although the channel-decoupling assumption is often used in design of three-dimensional guidance laws, it loses its rationality for aircrafts with strong kinematics coupling because body rotation arises. To overcome this trouble, a novel guiding method was proposed based on Lie-group. After a model of 3D guidance is formulated using vectors, the precision guidance with ending angular constraints can be transformed into a problem involving the relation between directional angles and rotational angular velocities of certain vectors. When the guidance model is imposed a SO(3)-based description, a novel 3D sliding mode guidance law with ending angular constraints can be developed via Lie-group control method and variable structure control theory. Finally, the feasibility and performance of the guidance law were shown by simulating the examples.
