In the present work,transparent and anti-fogging AlPO_(4)-5 films were prepared on glass substrates using a novel developed process.The process entails a simple in-situ sol–gel followed by vapor phase transport.The i...In the present work,transparent and anti-fogging AlPO_(4)-5 films were prepared on glass substrates using a novel developed process.The process entails a simple in-situ sol–gel followed by vapor phase transport.The in-situ sol–gel process was implemented by coating the precursor sols for the synthesis of AlPO4-5 on the glass substrates successively using the spin-coating method.The films and powders scribed from the films were characterized by X-Ray diffraction(XRD),Fourier transform infrared spectroscopy(FT-IR),scanning electron microscope(SEM),atomic force microscope(AFM),X-ray photoelectron spectroscopy and transmission electron microscope(TEM).The unique films were composed of oblique oriented nanoflake AlPO_(4)-5 crystals with the thickness of about 20 nm.The formation of nano-flake crystals can be ascribed to the high concentration of the precursors,resulting in the formation of a supersaturation system.The obtained films showed high antifogging performance due to the superhydrophilicity with a water contact angle of lower than 1.0°.The silicone oil contact angle was also low about 8.2°.In addition,heteroatom-substituted AlPO_(4)-5 films showing different colors can be obtained easily by simply adding transition metal ions in the phosphate acid solution during the preparation that can extend the application of the method for different coating demand.展开更多
A new approach to synthesize liquid crystalline polymer with narrow polydispersity index（PDI） was developed.Photopolymerization of 4-cyanophenyl-4＇-（6-acryloyloxyhexyloxy）benzoate（RM23） in nematic liquid crysta...A new approach to synthesize liquid crystalline polymer with narrow polydispersity index（PDI） was developed.Photopolymerization of 4-cyanophenyl-4＇-（6-acryloyloxyhexyloxy）benzoate（RM23） in nematic liquid crystals with macroscopic orientation was studied.The effects of the monomer concentration on the molecular weight and PDI of the resulting polymers were studied through gel permeation chromatography（GPC） and polarized optical microscopy.The low PDI of 1.19 and 1.22 was obtained in the reverse and normal modes,respectively.The PDI and molecular weight increased with monomer concentration.展开更多
‘Oriental Show’ is a generation of new cucumber variety, with the superi-or inbred line ‘101’ as the female parent and inbred line ‘102’ as the male par-ent. The growth vigor tends to be strong and the first fem...‘Oriental Show’ is a generation of new cucumber variety, with the superi-or inbred line ‘101’ as the female parent and inbred line ‘102’ as the male par-ent. The growth vigor tends to be strong and the first female blossom produces on the 4th or the 5th internode. Fruit is 34 cm long and 32 cm in transverse diameter. Per fruit weighs about 230 g. lt is dark green, densely covered with thorns. lt tastes crisp, containing 167.7 mg/kg Vc, and it is resistant to downy mildew, pow-dery mildew and bacterial angular leaf spot disease. lt is yielding and tolerant to low temperature and weak luminance. The yield can be as high as over 112 443.778 kg/hm^2, and ‘Oriental Show’ is suitable to be cultivated in greenhouses in early spring or solar greenhouses in north China or Henan province.展开更多
In the different stages of the development of the old-age service, the responsibility and function of the government will be different. In the new period, the government should redefine its role in advancing the socia...In the different stages of the development of the old-age service, the responsibility and function of the government will be different. In the new period, the government should redefine its role in advancing the socialization of the old-age service. The level of socialization of old-age services is not high, the lack of vitality of the pension market, the imperfect system and other problems arise because the government is not clear. The government should deal with the relationship between the main body of the market and avoid the ＇double failure＇ of the government and the market. The government should play a guiding role in the policy, laws and regulations and other aspects of good service work for the social services of the elderly to provide a good development environment.展开更多
基金financial support from the Key University Science Research Project of Jiangsu Province(16KJA430007)Opening Topic of Key Laboratory of Attapulgite Resources Utilization in Jiangsu Province(HPK201804)Opening Topic of National Local Joint Engineering Research Center for Deep Utilization of Mineral and Salt Resources(SF201804)。
文摘In the present work,transparent and anti-fogging AlPO_(4)-5 films were prepared on glass substrates using a novel developed process.The process entails a simple in-situ sol–gel followed by vapor phase transport.The in-situ sol–gel process was implemented by coating the precursor sols for the synthesis of AlPO4-5 on the glass substrates successively using the spin-coating method.The films and powders scribed from the films were characterized by X-Ray diffraction(XRD),Fourier transform infrared spectroscopy(FT-IR),scanning electron microscope(SEM),atomic force microscope(AFM),X-ray photoelectron spectroscopy and transmission electron microscope(TEM).The unique films were composed of oblique oriented nanoflake AlPO_(4)-5 crystals with the thickness of about 20 nm.The formation of nano-flake crystals can be ascribed to the high concentration of the precursors,resulting in the formation of a supersaturation system.The obtained films showed high antifogging performance due to the superhydrophilicity with a water contact angle of lower than 1.0°.The silicone oil contact angle was also low about 8.2°.In addition,heteroatom-substituted AlPO_(4)-5 films showing different colors can be obtained easily by simply adding transition metal ions in the phosphate acid solution during the preparation that can extend the application of the method for different coating demand.
基金The authors are grateful to NSF of China(No.50703013)Independent Innovative Position of Hubei Province for financial support of this work
文摘A new approach to synthesize liquid crystalline polymer with narrow polydispersity index（PDI） was developed.Photopolymerization of 4-cyanophenyl-4＇-（6-acryloyloxyhexyloxy）benzoate（RM23） in nematic liquid crystals with macroscopic orientation was studied.The effects of the monomer concentration on the molecular weight and PDI of the resulting polymers were studied through gel permeation chromatography（GPC） and polarized optical microscopy.The low PDI of 1.19 and 1.22 was obtained in the reverse and normal modes,respectively.The PDI and molecular weight increased with monomer concentration.
基金Supported by National Modern Agricultural Technology Industry System(CARS-25-G-28)Zhengzhou Science and Technology Major Project(162PDZX188)~~
文摘‘Oriental Show’ is a generation of new cucumber variety, with the superi-or inbred line ‘101’ as the female parent and inbred line ‘102’ as the male par-ent. The growth vigor tends to be strong and the first female blossom produces on the 4th or the 5th internode. Fruit is 34 cm long and 32 cm in transverse diameter. Per fruit weighs about 230 g. lt is dark green, densely covered with thorns. lt tastes crisp, containing 167.7 mg/kg Vc, and it is resistant to downy mildew, pow-dery mildew and bacterial angular leaf spot disease. lt is yielding and tolerant to low temperature and weak luminance. The yield can be as high as over 112 443.778 kg/hm^2, and ‘Oriental Show’ is suitable to be cultivated in greenhouses in early spring or solar greenhouses in north China or Henan province.
文摘In the different stages of the development of the old-age service, the responsibility and function of the government will be different. In the new period, the government should redefine its role in advancing the socialization of the old-age service. The level of socialization of old-age services is not high, the lack of vitality of the pension market, the imperfect system and other problems arise because the government is not clear. The government should deal with the relationship between the main body of the market and avoid the ＇double failure＇ of the government and the market. The government should play a guiding role in the policy, laws and regulations and other aspects of good service work for the social services of the elderly to provide a good development environment.
