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Influence of heat treatment on microstructure,mechanical and corrosion behavior of WE43 alloy fabricated by laser-beam powder bed fusion 被引量:5
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作者 Chenrong Ling Qiang Li +6 位作者 Zhe Zhang Youwen Yang Wenhao Zhou Wenlong Chen Zhi Dong Chunrong Pan Cijun Shuai 《International Journal of Extreme Manufacturing》 SCIE EI CAS CSCD 2024年第1期258-275,共18页
Magnesium(Mg)alloys are considered to be a new generation of revolutionary medical metals.Laser-beam powder bed fusion(PBF-LB)is suitable for fabricating metal implants withpersonalized and complicated structures.Howe... Magnesium(Mg)alloys are considered to be a new generation of revolutionary medical metals.Laser-beam powder bed fusion(PBF-LB)is suitable for fabricating metal implants withpersonalized and complicated structures.However,the as-built part usually exhibits undesirable microstructure and unsatisfactory performance.In this work,WE43 parts were firstly fabricated by PBF-LB and then subjected to heat treatment.Although a high densification rate of 99.91%was achieved using suitable processes,the as-built parts exhibited anisotropic and layeredmicrostructure with heterogeneously precipitated Nd-rich intermetallic.After heat treatment,fine and nano-scaled Mg24Y5particles were precipitated.Meanwhile,theα-Mg grainsunderwent recrystallization and turned coarsened slightly,which effectively weakened thetexture intensity and reduced the anisotropy.As a consequence,the yield strength and ultimate tensile strength were significantly improved to(250.2±3.5)MPa and(312±3.7)MPa,respectively,while the elongation was still maintained at a high level of 15.2%.Furthermore,the homogenized microstructure reduced the tendency of localized corrosion and favoredthe development of uniform passivation film.Thus,the degradation rate of WE43 parts was decreased by an order of magnitude.Besides,in-vitro cell experiments proved their favorable biocompatibility. 展开更多
关键词 laser-beam powder bed fusion WE43 alloys heat treatment mechanical performance biodegradation behavior
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Interface property of dissimilar Ti-6Al-4V/AA1050 composite laminate made by non-equal channel lateral co-extrusion and heat treatment
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作者 Juan Liao Mengmeng Tian Xin Xue 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第3期197-208,共12页
The purpose of this paper is to examine the effect of processing parameters and subsequent heat treatments on the microstructures and bonding strengths of Ti-6Al-4V/AA1050 laminations formed via a non-equal channel la... The purpose of this paper is to examine the effect of processing parameters and subsequent heat treatments on the microstructures and bonding strengths of Ti-6Al-4V/AA1050 laminations formed via a non-equal channel lateral co-extrusion process.The microstructural evolution and growth mechanism in the diffusion layer were discussed further to optimize the bonding quality by appropriately adjusting process parameters.Scanning electron microscopes(SEM),energy dispersive spectrometer(EDS),and X-ray diffraction(XRD)were used to characterize interfacial diffusion layers.The shear test was used to determine the mechanical properties of the interfacial diffusion layer.The experimental results indicate that it is possible to co-extrusion Ti-6Al-4V/AA1050 compound profiles using non-equal channel lateral co-extrusion.Different heat treatment processes affect the thickness of the diffusion layer.When the temperature and time of heat treatment increase,the thickness of the reaction layers increases dramatically.Additionally,the shear strength of the Ti-6Al-4V/AA1050 composite interface is proportional to the diffusion layer thickness.It is observed that a medium interface thickness results in superior mechanical performance when compared to neither a greater nor a lesser interface thickness.Microstructural characterization of all heat treatments reveals that the only intermetallic compound observed in the diffusion layers is TiAl_(3).Due to the inter-diffusion of Ti and Al atoms,the TiAl_(3) layer grows primarily at AA1050/TiAl_(3) interfaces. 展开更多
关键词 Shear strength CO-EXTRUSION heat treatment Microstructure Intermetallic compounds
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Role of alloying and heat treatment on microstructure and mechanical properties of cast Al-Li alloys:A review
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作者 Guo-hua Wu You-jie Guo +4 位作者 Fang-zhou Qi Shen Zhang Yi-xiao Wang Xin Tong Liang Zhang 《China Foundry》 SCIE EI CAS CSCD 2024年第5期445-460,共16页
Due to the prominent advantages of low density,high elastic modulus,high specific strength and specific stiffness,cast Al-Li alloys are suitable metallic materials for manufacturing complex large-sized components and ... Due to the prominent advantages of low density,high elastic modulus,high specific strength and specific stiffness,cast Al-Li alloys are suitable metallic materials for manufacturing complex large-sized components and are ideal structural materials for aerospace,defense and military industries.On the basis of the microstructural characteristics of cast Al-Li alloys,exploring the role of alloying and micro-alloying can stabilize their dominant position and further expand their application scope.In this review,the development progress of cast Al-Li alloys was summarized comprehensively.According to the latest research highlights,the influence of alloying and heat treatment on the microstructure and mechanical properties was systematically analyzed.The potential methods to improve the alloy performance were concluded.In response to the practical engineering requirements of cast Al-Li alloys,the scientific challenges and future research directions were discussed and prospected. 展开更多
关键词 cast Al-Li alloy ALLOYING microstructure mechanical properties heat treatment
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Effect of heat treatment on the microstructure,mechanical properties and fracture behaviors of ultra-high-strength SiC/Al-Zn-Mg-Cu composites
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作者 Guonan Ma Shize Zhu +3 位作者 Dong Wang Peng Xue BolüXiao Zongyi Ma 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第10期2233-2243,共11页
A high-zinc composite,12vol%SiC/Al-13.3 Zn-3.27 Mg-1.07Cu(wt%),with an ultra-high-strength of 781 MPa was success-fully fabricated through a powder metallurgy method,followed by an extrusion process.The effects of sol... A high-zinc composite,12vol%SiC/Al-13.3 Zn-3.27 Mg-1.07Cu(wt%),with an ultra-high-strength of 781 MPa was success-fully fabricated through a powder metallurgy method,followed by an extrusion process.The effects of solid-solution and aging heat treat-ments on the microstructure and mechanical properties of the composite were extensively investigated.Compared with a single-stage sol-id-solution treatment,a two-stage solid-solution treatment(470℃/1 h+480℃/1 h)exhibited a more effective solid-solution strengthen-ing owing to the higher degree of solid-solution and a more uniform microstructure.According to the aging hardness curves of the com-posite,the optimized aging parameter(100℃/22 h)was determined.Reducing the aging temperature and time resulted in finer and more uniform nanoscale precipitates but only yielded a marginal increase in tensile strength.The fractography analysis revealed that intergranu-lar cracking and interface debonding were the main fracture mechanisms in the ultra-high-strength SiC/Al-Zn-Mg-Cu composites.Weak regions,such as the SiC/Al interface containing numerous compounds and the precipitate-free zones at the high-angle grain boundaries,were identified as significant factors limiting the strength enhancement of the composite.Interfacial compounds,including MgO,MgZn2,and Cu5Zn8,reduced the interfacial bonding strength,leading to interfacial debonding. 展开更多
关键词 metal matrix composites heat treatment interfacial reaction mechanical properties fracture mechanism
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Customized heat treatment process enabled excellent mechanical properties in wire arc additively manufactured Mg-RE-Zn-Zr alloys
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作者 Dong Ma Chunjie Xu +7 位作者 Shang Sui Yuanshen Qi Can Guo Zhongming Zhang Jun Tian Fanhong Zeng Sergei Remennik Dan Shechtman 《International Journal of Extreme Manufacturing》 SCIE EI CAS CSCD 2024年第4期276-289,共14页
Customized heat treatment is essential for enhancing the mechanical properties of additively manufactured metallic materials,especially for alloys with complex phase constituents and heterogenous microstructure.Howeve... Customized heat treatment is essential for enhancing the mechanical properties of additively manufactured metallic materials,especially for alloys with complex phase constituents and heterogenous microstructure.However,the interrelated evolutions of different microstructure features make it difficult to establish optimal heat treatment processes.Herein,we proposed a method for customized heat treatment process exploration and establishment to overcome this challenge for such kind of alloys,and a wire arc additively manufactured(WAAM)Mg-Gd-Y-Zn-Zr alloy with layered heterostructure was used for feasibility verification.Through this method,the optimal microstructures(fine grain,controllable amount of long period stacking ordered(LPSO)structure and nano-scaleβ'precipitates)and the corresponding customized heat treatment processes(520°C/30 min+200°C/48 h)were obtained to achieve a good combination of a high strength of 364 MPa and a considerable elongation of 6.2%,which surpassed those of other state-of-the-art WAAM-processed Mg alloys.Furthermore,we evidenced that the favorable effect of the undeformed LPSO structures on the mechanical properties was emphasized only when the nano-scaleβ'precipitates were present.It is believed that the findings promote the application of magnesium alloy workpieces and help to establish customized heat treatment processes for additively manufactured materials. 展开更多
关键词 wire arc additive manufacturing heat treatment Mg-RE-Zn-Zr alloys LPSO structure mechanical properties
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Effect of heat treatment on corrosion behaviors of Mg-6Gd-3Y-0.5Zr alloy
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作者 Fei Wang Bin-guo Fu +3 位作者 Yu-feng Wang Tian-shun Dong Guo-lu Li Jin-hai Liu 《China Foundry》 SCIE EI CAS CSCD 2024年第5期599-612,共14页
The microstructures and corrosion behaviors of as-cast,T4-treated,and T6-treated Mg-6Gd-3Y-0.5Zr alloys were systematically investigated by SEM,TEM,immersion test,and electrochemical corrosion test.The results show th... The microstructures and corrosion behaviors of as-cast,T4-treated,and T6-treated Mg-6Gd-3Y-0.5Zr alloys were systematically investigated by SEM,TEM,immersion test,and electrochemical corrosion test.The results show that the microstructure of the as-cast alloy is composed ofα-Mg and Mg_(24)(Gd,Y)_(5) eutectic phase,and in T4-treated alloy,Mg_(24)(Gd,Y)_(5) phase dissolves into theα-Mg matrix,leading to an increase in the(Y,Gd)H_(2) phase.After T6 treatment,nanoscale Mg_(24)(Gd,Y)_(5) phase dispersedly precipitates from theα-Mg matrix,and exhibits a specific orientation relationship with the α-Mg:(332)Mg_((24)(Gd,Y)_(5))//(1011)_(α-Mg),[136]Mg_((24)(Gd,Y)_(5))//[1210]_(α-Mg).The corrosion resistance of the Mg-6Gd-3Y-0.5Zr alloys can be ranked in the following order:T6-treated alloy exhibits the highest corrosion resistance,followed by the T4-treated alloy,and finally,the as-cast alloy.The corrosion products of the alloys are all composed of MgO,Mg(OH)_(2),Gd_(2)O_(3),Y_(2)O_(3),and MgCl_(2).The corrosion behavior of Mg-6Gd-3Y-0.5Zr alloy is closely related to the precipitated phase.By establishing the relationship between corrosion rate,hydrogen evolution rate,and corrosion potential,it is further demonstrated that during the micro galvanic corrosion process,the coarse Mg_(24)(Gd,Y)_(5)phase in the as-cast alloy undergoes extensive dissolution,and(Y,Gd)H_(2) phase promotes the dissolution of theα-Mg matrix in the T4-treated alloy,intensifying the hydrogen evolution reaction.The T6-treated alloy,with dispersive precipitation of nanoscale Mg_(24)(Gd,Y)_(5) phase,exhibits better corrosion resistance performance. 展开更多
关键词 Mg-6Gd-3Y-0.5Zr alloy heat treatment MICROSTRUCTURE precipitated phase corrosion resistance
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Effect of heat treatment on the microstructure and mechanical properties of a multidirectionally forged Mg-Gd-Y-Zn-Zr-Ag alloy 被引量:4
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作者 Junkai Wang Chuming Liu +2 位作者 Shunong Jiang Yingchun Wan Zhiyong Chen 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2023年第6期2042-2053,共12页
Multidirectional forging(MDF)was successfully applied to fabricate large-size Mg-Gd-Y-Zn-Zr-Ag alloy in this work and effects of T4,T5 and T6 treatments on the microstructure and mechanical properties of the as-forged... Multidirectional forging(MDF)was successfully applied to fabricate large-size Mg-Gd-Y-Zn-Zr-Ag alloy in this work and effects of T4,T5 and T6 treatments on the microstructure and mechanical properties of the as-forged alloy were analyzed.Results show that dynamic recrystallization(DRX)occurs and second phase particles precipitate along the grain boundary during the MDF process.After annealing treatment(T4),the volume fraction and size of dynamic precipitates slightly increase at a lower temperature(430℃)compared with those of MDFed sample,while they are dissolved into theα-Mg matrix at a higher temperature(450℃).At the meantime,short plate-shaped long-period stacking ordered(LPSO)phases are observed in the DRX grains of the MDFed sample and then dissolved into theα-Mg matrix during annealing at both temperatures.Typical basal texture is identified in the MDFed sample,but the basal pole tilts away from final forging direction and rare-earth texture component with<1121>orientation parallel to penultimate forging direction becomes visible after annealing.The T6 sample annealing at 430℃for 4 h and ageing at 200℃for 34 h exhibits the superior strength and ductility in this study.The ultimate tensile strength,tensile yield strength and elongation to failure,which is 455 MPa,308 MPa and 7.7%,respectively,are overall improved compared with the directly-aged(T5)sample.This paper provides a superior heat treatment schedule to manufacture high-performance large-scale Mg-Gd-Y-Zn-Zr-Ag components for industrial production. 展开更多
关键词 Mg-Gd-Y-Zn-Zr-Ag alloy Multidirectional forging Dynamic precipitation heat treatment Mechanical properties
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Numerical simulation on directional solidification and heat treatment processes of turbine blades
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作者 Ye-yuan Hu Ju-huai Ma Qing-yan Xu 《China Foundry》 SCIE EI CAS CSCD 2024年第5期476-490,共15页
Study on turbine blades is crucial due to their critical role in ensuring the efficient and reliable operation of aircraft engines.Nickel-based single crystal superalloys are extensively used in the hot manufacturing ... Study on turbine blades is crucial due to their critical role in ensuring the efficient and reliable operation of aircraft engines.Nickel-based single crystal superalloys are extensively used in the hot manufacturing of turbine blades due to their exceptional high-temperature mechanical properties.The hot manufacturing of single crystal blades involves directional solidification and heat treatment.Experimental manufacturing of these blades is time-consuming,capital-intensive,and often insufficient to meet industrial demands.Numerical simulation techniques have gained widespread acceptance in blade manufacturing research due to their low energy consumption,high efficiency,and rapid turnaround time.This article introduces the modeling and simulation of hot manufacturing in single crystal blades.The discussion outlines the prevalent mathematical models employed in numerical simulations related to blade hot manufacturing.It encapsulates the advancements in research concerning macro to micro-level numerical simulation techniques for directional solidification and heat treatment processes.Furthermore,potential future trajectories for the numerical simulation of single crystal blade hot manufacturing are also discussed. 展开更多
关键词 single crystal blades Ni-based superalloy directional solidification heat treatment numerical simulation
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Effect of solution treatment on the microstructure,phase transformation behavior and functional properties of NiTiNb ternary shape memory alloys fabricated via laser powder bed fusion in-situ alloying
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作者 Rui Xi Hao Jiang +5 位作者 Guichuan Li Zhihui Zhang Huiliang Wei Guoqun Zhao Jan Van Humbeeck Xiebin Wang 《International Journal of Extreme Manufacturing》 SCIE EI CAS CSCD 2024年第4期202-223,共22页
Post-heat treatment is commonly employed to improve the microstructural homogeneity and enhance the mechanical performances of the additively manufactured metallic materials.In this work,a ternary(NiTi)91Nb9(at.%)shap... Post-heat treatment is commonly employed to improve the microstructural homogeneity and enhance the mechanical performances of the additively manufactured metallic materials.In this work,a ternary(NiTi)91Nb9(at.%)shape memory alloy was produced by laser powder bed fusion(L-PBF)using pre-alloyed NiTi and elemental Nb powders.The effect of solution treatment on the microstructure,phase transformation behavior and mechanical/functional performances was investigated.The in-situ alloyed(NiTi)91Nb9 alloy exhibits a submicron cellular-dendritic structure surrounding the supersaturated B2-NiTi matrix.Upon high-temperature(1273 K)solution treatment,Nb-rich precipitates were precipitated from the supersaturated matrix.The fragmentation and spheroidization of the NiTi/Nb eutectics occurred during solution treatment,leading to a morphological transition from mesh-like into rod-like and sphere-like.Coarsening of theβ-Nb phases occurred with increasing holding time.The martensite transformation temperature increases after solution treatment,mainly attributed to:(i)reduced lattice distortion due to the Nb expulsion from the supersaturated B2-NiTi,and(ii)the Ti expulsion from theβ-Nb phases that lowers the ratio Ni/Ti in the B2-NiTi matrix,which resulted from the microstructure changes from non-equilibrium to equilibrium state.The thermal hysteresis of the solutionized alloys is around 145 K after 20%pre-deformation,which is comparable to the conventional NiTiNb alloys.A short-term solution treatment(i.e.at 1273 K for 30 min)enhances the ductility and strength of the as-printed specimen,with the increase of fracture stress from(613±19)MPa to(781±20)MPa and the increase of fracture strain from(7.6±0.1)%to(9.5±0.4)%.Both the as-printed and solutionized samples exhibit good tensile shape memory effects with recovery rates>90%.This work suggests that post-process heat treatment is essential to optimize the microstructure and improve the mechanical performances of the L-PBF in-situ alloyed parts. 展开更多
关键词 shape memory alloy NiTiNb laser powder bed fusion in-situ alloying heat treatment
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Effect of Heat Treatment on Microstructure and Mechanical Properties of Multiscale SiC_p Hybrid Reinforced 6061 Aluminum Matrix Composites
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作者 吴健铭 许晓静 +3 位作者 ZHANG Xu LUO Yuntian LI Shuaidi HUANG Lin 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第1期174-181,共8页
The performance of solid solution aging treatment on aluminum matrix composites prepared by powder metallurgy and reinforced with 6061 aluminum alloy powder as matrix;meanwhile, nano silicon carbide particles(nm Si Cp... The performance of solid solution aging treatment on aluminum matrix composites prepared by powder metallurgy and reinforced with 6061 aluminum alloy powder as matrix;meanwhile, nano silicon carbide particles(nm Si Cp), submicron silicon carbide particles(1 μm Si Cp) and Ti particles were studied. The Al/Si Cp composite powder was prepared by high-energy ball milling, and then cold-pressed, sintered, hotextruded, and then heat-treated with different solution temperatures and aging times for the extruded composites. Optical microscopy, scanning electron microscopy, energy dispersive X-ray spectroscopy(EDS), X-ray diffractometer(XRD) and extrusion testing were used to analyze and test the microstructure and mechanical properties of aluminum matrix composites. The results show that after the multi-stage solid solution at 530 ℃×2 h+535 ℃×2 h+540 ℃×2 h, the particles are mainly equiaxed grains and uniformly distributed. There is no reinforcement agglomeration, and the surface is dense and the insoluble phase is basically dissolved. In the matrix, the strengthening effect is good, and the hardness and compressive strength are 179.43 HV and 680.42 MPa, respectively. Under this solution process, when the aluminum matrix composites are aged at 170 ℃ for 10 h, the hardness and compressive strength can reach their peaks and increase to 195.82 HV and 721.48 MPa, respectively. 展开更多
关键词 aluminum matrix composites Si C particles multiscale hybrid enhancement heat treatment mechanical properties
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Rapid Fabrication of Electrodes for Symmetrical Solid Oxide Cells by Extreme Heat Treatment
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作者 Weiwei Fan Zhu Sun +2 位作者 Manxi Wang Manxian Li Yuming Chen 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2024年第5期349-356,共8页
Symmetrical solid oxide cells(SSOCs)are very useful for energy generation and conversion.To fabricate the electrode of SSOC,it is very time-consuming to use the conventional approach.In this work,we design and develop... Symmetrical solid oxide cells(SSOCs)are very useful for energy generation and conversion.To fabricate the electrode of SSOC,it is very time-consuming to use the conventional approach.In this work,we design and develop a novel method,extreme heat treatment(EHT),to rapidly fabricate electrodes for SSOC.We show that by using the EHT method,the electrode can be fabricated in seconds(the fastest method to date),benefiting from enhanced reaction kinetics.The EHT-fabricated electrode presents a porous structure and good adhesion with the electrolyte.In contrast,tens of hours are needed to prepare the electrode by the conventional approach,and the prepared electrode exhibits a dense structure with a larger particle size due to the lengthy treatment.The EHT-fabricated electrode shows desirable electrochemical performance.Moreover,we show that the electrocatalytic activity of the perovskite electrode can be tuned by the vigorous approach of fast exsolution,deriving from the increased active sites for enhancing the electrochemical reactions.At 900℃,a promising peak power density of 966 mW cm^(-2)is reached.Our work exploits a new territory to fabricate and develop advanced electrodes for SSOCs in a rapid and high-throughput manner. 展开更多
关键词 electrochemical performance extreme heat treatment perovskite electrode symmetrical solid oxide cells
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The Impact of Heat Treatment and Surface Treatment on Thermal Conductivity of Heat Sinks Made of Aluminium Die Casting Alloys
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作者 Rajesh Kumar Manickam Dilip Raja Narayana 《Journal of Harbin Institute of Technology(New Series)》 CAS 2024年第4期34-41,共8页
This research contributes to understand the thermal management capabilities of Plate Fin Heat Sinks(PFHS)fabricated from AlSi10Mg.The uniqueness in this study is that the heat sinks were exposed to abrasive blasting,h... This research contributes to understand the thermal management capabilities of Plate Fin Heat Sinks(PFHS)fabricated from AlSi10Mg.The uniqueness in this study is that the heat sinks were exposed to abrasive blasting,heat treatment,and graphene coating,and a full evaluation of the influence of the aforementioned treatments on the thermal management capacities of PFHS was found.Untreated PFHS is compared with 1)abrasive blasted and graphene coated heat sink,and 2)heat treated and graphene coated heat sink.To assess the thermal efficiency of the PFHS variants,a dedicated experimental set up was meticulously constructed.It is noteworthy that a junction temperature of 60℃was assumed as the reference point for the analysis.The results revealed that the charging cycle time which denotes the time required attaining the junction temperature,increased 1.3 times for the sample being abrasive-blasted at 0.5 MPa pressure and graphene-coated for 0.5 mm when the maximum heat input of 45 W is evaluated.When low heat input of 15 W is evaluated,the results revealed that there is no significant difference in charging cycle when compared to the untreated heat sink.The charging cycle time increased 2 times for the sample which is heat-treated at 450℃and graphene-coated for 0.5 mm at heat input of 15 W.This finding unequivocally underscores the heightened capacity of the heat treated and graphene coated PFHS made of AlSi10Mg to withstand elevated junction temperatures. 展开更多
关键词 PFHS abrasive blasting heat treatment GRAPHENE
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Improving corrosive wear resistance of Mg-Zn-Y-Zr alloys through heat treatment 被引量:1
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作者 S.D.Wang M.Y.Wu +1 位作者 D.K.Xu En-hou Han 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2023年第6期1981-1995,共15页
The wear behavior of an as-received Mg-Zn-Y-Zr alloy before and after a facile heat treatment was investigated under sliding in air and 0.5 wt.%NaCl solution.Results revealed that the wear resistance of the alloy was ... The wear behavior of an as-received Mg-Zn-Y-Zr alloy before and after a facile heat treatment was investigated under sliding in air and 0.5 wt.%NaCl solution.Results revealed that the wear resistance of the alloy was remarkably enhanced after the heat treatment,irrespective of testing condition.The wear mechanism was predominantly abrasive wear accompanied by oxidation under the dry sliding condition,while corrosive wear was dominant under sliding in the NaCl solution.The superior corrosive wear resistance was attributed to the homogenous distribution of fine I-phase precipitates in the alloy by the heat treatment,leading to a reduction in wear,corrosion as well as wear-corrosion synergy.The wear-accelerated corrosion rate was remarkably alleviated after the heat treatment. 展开更多
关键词 Magnesium alloy heat treatment CORROSION WEAR TRIBOCORROSION
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Effect of substrate temperature and oxygen plasma treatment on the properties of magnetron-sputtered CdS for solar cell applications
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作者 Runxuan Zang Haolin Wang +9 位作者 Xiaoqi Peng Ke Li Yuehao Gu Yizhe Dong Zhihao Yan Zhiyuan Cai Huihui Gao Shuwei Sheng Rongfeng Tang Tao Chen 《中国科学技术大学学报》 CAS CSCD 北大核心 2024年第6期22-33,I0010,共13页
Cadmium sulfide(CdS)is an n-type semiconductor with excellent electrical conductivity that is widely used as an electron transport material(ETM)in solar cells.At present,numerous methods for preparing CdS thin films h... Cadmium sulfide(CdS)is an n-type semiconductor with excellent electrical conductivity that is widely used as an electron transport material(ETM)in solar cells.At present,numerous methods for preparing CdS thin films have emerged,among which magnetron sputtering(MS)is one of the most commonly used vacuum techniques.For this type of technique,the substrate temperature is one of the key deposition parameters that affects the interfacial properties between the target film and substrate,determining the specific growth habits of the films.Herein,the effect of substrate temperature on the microstructure and electrical properties of magnetron-sputtered CdS(MS-CdS)films was studied and applied for the first time in hydrothermally deposited antimony selenosulfide(Sb_(2)(S,Se)_(3))solar cells.Adjusting the substrate temperature not only results in the design of the flat and dense film with enhanced crystallinity but also leads to the formation of an energy level arrangement with a Sb_(2)(S,Se)_(3)layer that is more favorable for electron transfer.In addition,we developed an oxygen plasma treatment for CdS,reducing the parasitic absorption of the device and resulting in an increase in the short-circuit current density of the solar cell.This study demonstrates the feasibility of MS-CdS in the fabrication of hydrothermal Sb_(2)(S,Se)_(3)solar cells and provides interface optimization strategies to improve device performance. 展开更多
关键词 magnetron sputtering CDS substrate heating plasma treatment Sb_(2)(S Se)_(3) thin film solar cell
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Effect of heat treatment on microstructure,mechanical and tribological properties of in-situ (TiC+TiB)/TC4 composites by casting 被引量:1
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作者 Bo-wen Zheng Shuai Chen +6 位作者 Chun-yu Yue Xue-jian Lin Fu-yu Dong Hong-jun Huang Xiao-jiao Zuo Yin-xiao Wang Xiao-guang Yuan 《China Foundry》 SCIE CAS CSCD 2023年第3期207-217,共11页
To enhance the performance of in-situ synthesized 6vol.%(Ti C+Ti B)/TC4 titanium matrix composites fabricated by casting,a variety of heat treatment processes were carried out.Upon conducting microstructure observatio... To enhance the performance of in-situ synthesized 6vol.%(Ti C+Ti B)/TC4 titanium matrix composites fabricated by casting,a variety of heat treatment processes were carried out.Upon conducting microstructure observations following various heat treatments,it was found that the composites exhibit a basketweave microstructure,consisting of an α phase and a transformed β phase.The sizes of(α+β) phases were found to be refined to varying degrees after the heat treatment processes,while the morphology of Ti B remains largely unchanged and Ti C becomes granulated.Compressive testing revealed that all composites subjected to different heat treatments demonstrate a notable increase in ultimate compressive strength as well as a slight improvement in plasticity compared to the as-cast state.The results of the tribological performance test indicated that the heat-treated composites exhibit lower average friction coefficient,specific wear rate,and worn surface roughness compared to the as-cast composite.Among the heat treatment processes studied,the composite solution heated at 1,150 °C/1 h followed by air cooling,then 950 °C/1 h followed by air cooling,and finally 500 °C/4 h followed by air cooling,demonstrates the highest levels of hardness,compressive strength,and wear resistance.These improvements are attributed to the combined effects of solid solution strengthening,grain refinement,and the pinning of dislocation slip. 展开更多
关键词 titanium matrix composites heat treatment mechanical properties tribological properties
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Discussion on the Free Quenching Heat Treatment Process of Automotive Leaf Springs
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作者 Xianfeng Xu 《Frontiers of Metallurgical Industry》 2024年第1期9-11,共3页
Free quenching of automotive leaf springs is a new technology that has gradually started to be applied in the industry in China in recent years.Only a few manufacturers are applying it in the industry.Through more tha... Free quenching of automotive leaf springs is a new technology that has gradually started to be applied in the industry in China in recent years.Only a few manufacturers are applying it in the industry.Through more than half a year of on-site practice,the changes in the hot forming of spring plates before free quenching have been explored,and finally a heat treatment process that meets the production requirements of our company has been developed,achieving normal production. 展开更多
关键词 automotive leaf springs free quenching heat treatment TECHNOLOGY
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Influence of heat treatments on incipient melting structures of DD5 nickel-based single crystal superalloy
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作者 Zhi-hong Jia Chen-yang Li +4 位作者 Wen-xiang Jing Xiang-feng Liang Ze-kun Zhang Jia-le Xiao Yu-tao Zhao 《China Foundry》 SCIE CAS CSCD 2023年第5期395-402,共8页
The evolution of microstructure and formation mechanism of incipient melting microstructure of DD5 single crystal superalloy during solution heat treatment were studied by scanning electron microscopy(SEM),electron pr... The evolution of microstructure and formation mechanism of incipient melting microstructure of DD5 single crystal superalloy during solution heat treatment were studied by scanning electron microscopy(SEM),electron probe microanalysis(EPMA),and energy dispersive spectroscopy(EDS).The solidus and liquidus of single crystal alloy were obtained by differential scanning calorimetry(DSC).Results show that the mosaic-like eutectic and fan-like eutectic are dissolved at first,and the coarseγ'phase is dissolved later during the solution heat treatment of 1,390°C/2 h+1,310°C/4 h+1,320°C/10 h+air cooling(AC).The composition segregations of Al,Ta,W and Re are 0.99,0.96,1.04 and 1.16,respectively,which close to 1.The incipient melting is caused by the low local temperature of the alloy,and the micropore region with a lower melting point is the preferred position for incipient melting. 展开更多
关键词 SUPERALLOY solution heat treatment EUTECTIC composition segregation incipient melting
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热处理对选区激光熔化Al-Mn-Mg-Sc-Zr合金力学性能和腐蚀行为的影响 被引量:1
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作者 邓英 曹俊昌 +4 位作者 赖毅 郭一帆 梁美婵 潘清林 徐国富 《中国有色金属学报》 EI CAS CSCD 北大核心 2024年第4期1240-1251,共12页
以Al-4.77Mn-1.37Mg-0.67Sc-0.25Zr(质量分数,%)合金粉末为原料,在激光功率330 W和扫描速率700 mm/s下进行选区激光熔化(Selective laser melting,SLM)形成SLM Al-Mn-Mg-Sc-Zr合金,结合慢应变速率拉伸实验、电化学测试、析氢浸泡实验及... 以Al-4.77Mn-1.37Mg-0.67Sc-0.25Zr(质量分数,%)合金粉末为原料,在激光功率330 W和扫描速率700 mm/s下进行选区激光熔化(Selective laser melting,SLM)形成SLM Al-Mn-Mg-Sc-Zr合金,结合慢应变速率拉伸实验、电化学测试、析氢浸泡实验及显微组织表征手段,分析了(350℃,8 h)热处理对SLM Al-Mn-Mg-Sc-Zr合金力学性能和腐蚀行为的影响。结果表明:SLM Al-Mn-Mg-Sc-Zr合金力学性能优异,抗拉强度、屈服强度和伸长率分别为423 MPa、376 MPa和25.1%。热处理后,SLM Al-Mn-Mg-Sc-Zr合金晶内析出大量针棒状纳米Al_(6)Mn相,抗拉强度和屈服强度分别提升至509 MPa和478 MPa。此外,SLM Al-Mn-Mg-Sc-Zr合金具有良好的耐蚀性能,热处理可以促进SLM Al-Mn-Mg-Sc-Zr合金的钝化,在-0.5 V极化电位时出现钝化台阶,降低SLM Al-Mn-Mg-Sc-Zr合金的电流密度,增加SLM Al-Mn-Mg-Sc-Zr合金的阳极极化率,使SLM Al-Mn-Mg-Sc-Zr合金的平均析氢速率从0.242 mL/(cm^(2)·h)降至0.216 mL/(cm^(2)·h),应力腐蚀敏感因子从3.379%降至0.405%。与此同时,热处理也促进了晶内微米富Si相以及晶界富Mn相和Mg相的析出,增加了SLM Al-Mn-Mg-Sc-Zr合金点蚀形核位置,增大了SLM Al-Mn-Mg-Sc-Zr合金的晶界电化学成分非均匀性,降低了SLM Al-Mn-Mg-Sc-Zr合金的点蚀和晶间腐蚀抗力。 展开更多
关键词 选区激光熔化 热处理 应力腐蚀 晶间腐蚀 电化学 显微组织
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Effect of heat treatment on microstructure and mechanical property of Ti-steel explosive-rolling clad plate 被引量:14
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作者 江海涛 阎晓倩 +1 位作者 刘继雄 段晓鸽 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2014年第3期697-704,共8页
The effect of heat treatment on microstructure and mechanical properties of the Ti-steel explosive-rolling clad plate was elaborated by optical microscopy (OM), scanning electron microscopy (SEM), X-ray diffracti... The effect of heat treatment on microstructure and mechanical properties of the Ti-steel explosive-rolling clad plate was elaborated by optical microscopy (OM), scanning electron microscopy (SEM), X-ray diffraction (XRD), transmission electron microscopy (TEM), micro-hardness test and shear test. The composites were subjected to heat treatment at temperature of 650-950 ~C for 60 min. The results show that the heat treatment process results in a great enhancement of diffusion and microstructural transformation. The shear strength decreases as the treatment temperature increases. Heated at 850 ℃ or below, their shear strength decreases slowly as a result of the formation of TiC in the diffusion interaction layer; while at the temperature of 850 ℃ or above, the shear strength decreases obviously, which is the consequence of a large amount of Ti-Fe intermetaUics (Fe2Ti/FeTi) along with some TiC distributing continuously at diffusion reaction layer. 展开更多
关键词 Ti-steel explosive-rolling clad plate heat treatment DIFFUSION mechanical properties
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Effects of cooling rate on solution heat treatment of as-cast A356 alloy 被引量:13
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作者 杨长林 李远兵 +2 位作者 党波 吕贺宾 刘峰 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第10期3189-3196,共8页
The effect of cooling rate of the solidification process on the following solution heat treatment of A356 alloy was investigated,where the cooling rates of 96 K/s and 3 K/s were obtained by the step-like metal mold.Th... The effect of cooling rate of the solidification process on the following solution heat treatment of A356 alloy was investigated,where the cooling rates of 96 K/s and 3 K/s were obtained by the step-like metal mold.Then the eutectic silicon morphology evolution and tensile properties of the alloy samples were observed and analyzed after solution heat treatment at 540 °C for different time.The results show that the high cooling rate of the solidification process can not only reduce the solid solution heat treatment time to rapidly modify the eutectic silicon morphology,but also improve the alloy tensile properties.Specially,it is found that the disintegration,the spheroidization and coarsening of eutectic silicon of A356 alloy are completed during solution heat treatment through two stages,i.e.,at first,the disintegration and spheroidization of the eutectic silicon mainly takes place,then the eutectic silicon will coarsen. 展开更多
关键词 A356 aluminum alloy solution heat treatment eutectic silicon cooling rate
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